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By Leon Lorenzen, Victor E. Ross, Anton W. Kleingeld

Key to successful innovation, whether at organization, industry or national level, is the alignment and utilization of resources in the most appropriate and efficient way. Innovation needs to be directed strategically, and it needs to be auditable in a systematic and integrated fashion. In the light of these considerations, this paper describes the construction and use of a topographical map of the innovation landscape. The purpose of the map is to provide a holistic view of the key factors that enable innovation (the so-called ’landmarks’), how well they are aligned to support a particular type/nature of innovation in the organization, and to identify possible gaps. The significance (importance) and height (performance) of the landmarks in supporting and enabling innovation within the organization is determined by means of a selfappraisal audit. The topography of the landscape derived thus is subsequently interpreted in terms of the organization’s particular innovation strategy and environmental context. The application of the Innovation Landscape Methodology is illustrated in a number of organizations within the Mining and Minerals Industry of South Africa. Important observations and conclusions regarding the strategic alignment of enabler strengths within these organizations are made.

Jan 1, 2003

By L. Gao, X. Gui

Fine coal obtained from Kailuan mine served as the processing object of this study. This material was difficult to separate. A flotation rate experiment was designed to investigate the process distribution characteristics of size and density during fine coal flotation. Size and density analyses of five clean were studied. The mineral morphology of flotation rate experiment cleaning was observed through scanning electron microscopy. The fractions -0.074+0.045 mm and -0.045 mm exhibited the best practical floatability and presented the highest combustible body recovery rates, but the selectivity and natural floatability of these two fractions were the worst. The - 0.074 mm fraction has contaminated the clean coal from the early stage of flotation, and the cumulative clean coal ash of -0.074 mm reached up to 17.20%. The low and middle-density classes displayed varying flotation behavior, but the flotation yield difference was only nearly 3%. The middle-density class caused the clean coal to have high ash content. The poor selectivity of fine coals, middle-density fraction, and fine mud resulted in high-ash clean coals during flotation. Thus, improving the selectivity of fine coal, restraining the flotation of fine mud, and grinding the coal to decrease the middle density mass fraction to liberate clean coals can yield high-quality clean coals through flotation.

Jan 1, 2014

By M. Saba

In cyanide leaching procedure, achieving an acceptable efficiency for silver and gold is very time-consuming, thus, enough studies have not been performed for optimization and modeling of this process. The kinetics of cyanide leaching includes two steps: first step comprises a sharp slope while the other has a slight increasing trend. In the present study, in order to reduce the time and cost, the cyanide leaching process of a sulfide silver/gold ore was optimized in the first period. The applied parameters and their ranges are: temperature 20-40 (°C); time 1-8 (hrs); cyanide concentration 1-2 (mole cyanide / mole Cu); the percentage of solid to liquid 1-2 (%) and pH 10-12. For design of experiments fractional factorial 2(5-1) was used. Also four center points were applied to increase the accuracy of the model. In addition, by analysis of variance (ANOVA) the most effective parameters were identified and the optimized condition was determined. A regression model was proposed to describe the effects of independent variables and their interacting role on silver recovery. Results showed that the model was linear for silver and nonlinear for gold. In the gold recovery process, the two important parameters are time and pH with the former being more effective. Due to the existence of cyanide ions in the medium, temperature and cyanide concentration have less influence in the gold recovery process. Solid to liquid ratio, in addition, comprises a slight negative impact on the procedure. This emphasizes the different kinetics of silver/ gold cyanide leaching. Finally, using the optimum condition the amount of silver and gold obtained were 61% and 67% in 8 hours, respectively. While in general conditions, the results were 37% and 54% in 24 hours, respectively. Keywords: cyanide leaching, refractory gold/silver ore, modeling, optimization

Sep 1, 2012

By C. Kleine

Coal sorting with an x-ray-transmission (XRT) sensor has experienced a lot of development since first described by Jekinson et.al. in 1974. Powerful computers and increasingly sensitive X-ray scintillation counters enabled the development of high-performance sensor-based sorting machines. The first industrial installation of a belt-type XRT-sorting for coal is in operation since 2004. It is upgrading high quality coal from 1% ash to 0.7% ash for cathode production. In comparison to the high quality coal which is treated with a belt-type sorter, the chute type sorter has been successfully optimized for high volume coal treatment of lower quality coals. This project was funded by the German Environmental Fund (Project Nr.244444). In cooperation with the RWTH Aachen University and Isambane Processing, CommodasUltrasort(now Tomra Sorting Solutions) conducted extensive pilot test work under production conditions in 2010 for the destoning of power station coal at Arnot Power Station in South Africa. The experience gained during this pilot test phase led to an optimized, redesigned PRO Secondary XRT Chute sorter which is now in operation at a South African coal mine. This flexible semi-mobile modular destoning plant is treating a size range of -120 mm +30 mm at a throughput of 150 tph. The implementation of this plant not only reduces the ash content, abrasiveness index and sulfur content significantly, but also reduces royalties, water treatment and transport costs.

Sep 1, 2012

By Z. G. Song, C. Y. Sun, X. R. Zhang, Y. Yu

In skarn type scheelite deposit, there are calcium minerals with floatability similar to scheelite, such as calcite, fluorite, etc., which are difficult to separate. Heating cleaning method developed by Petrov has been widely applied in processing rough concentrate of scheelite for nearly half a century, but there exists a general lack of full understanding of the interaction between floatation reagent and mineral particles surfaces. The mechanism on separation of scheelite and calcium minerals in heating cleaning process was investigated by mineral flotation experiments, XPS analysis, as well as solution chemistry and crystal chemistry calculations. The results showed that the sequence of minerals floatability using sodium oleate as collector and a large amount of sodium silicate as modifier in heating flotation test was scheelite > calcite > fluorite, which was the same as solution chemistry calculations based on Gibbs free energy vs. pH and also the same as Ca-X intensity order by crystal chemistry analysis. There are two sides about the mechanism of heating cleaning method: one is that the adsorbed collector on calcium minerals surface is desorbed more easily than scheelite, and the other is selective dissolution of calcium ions from the mineral surface because of Ca-X intensity difference in heating and stirring process.

Jan 1, 2014

By Takashi Furuyama, Sukeyuki Mori, Tetsuo Ikejiri, Abel Bissombolo, Yoshitsugu Koga, Masamichi Hata

In Japan, the increasing number of automobiles newly put into circulation is followed by a larger amount of end-of-life vehicles from which valuable metals are being recovered in shredder and related plants. Nevertheless, the processing of these scrapped automobiles which has reach a recycling rate of about 75%, generates a huge volume of waste, locally known as .shredder dust., which is commonly dumped on landfills. The saturation and depletion of valuable disposal sites in the near future, as well as the social and environmental problems related to the accumulation of these residues disposals are a major challenge for the automobile shredding industry. To promote an alternative way for the management of these disposals, the authors have initiated and developed a system for their processing, on the basis that more than 90% of these residues are combustible materials that could be used as refuses derived fuel. The developed processing system points out the mechanical/physical separation of shredded automobiles residues into two streams by means of an ascending airflow passing through a vertical zigzag separator and, the compaction of the light-density fraction of materials (that is about 60% of auto shredder residue recovered as float products and mainly composed of cotton, sponges and light plastics) to form a refuse derived fuel (RDF), the density, calorific value and ignition loss of which are 1.19 g/cm3, 4470 kcal/kg and 60.7%, respectively.

Jan 1, 2003

By Yimin Zhu

This paper introduces the sixteen mappings and rules of mineral flotation and the subgroup, period etc in periodic table of chemical element to provide mineral flotation workers to refer in theory and practice research. the nine mappings and rules of mineral flotation and the subgroup, period are Saline minerals including the first main groups and collectors of aliphatic acid and aliphatic amines, Minerals including the second main group elements and collector of aliphatic acid, Hydrated ion of the second main group elements and quartz flotation, The floatability of oxidized minerals including the four main group elements, Organic acid including the fifth main group elements and wolframe, tin flotation collectors, The floatability of sulfide minerals including the fifth main group elements, Inorganic compounds including the seventh main group elements and mineral flotation regulator, Oxidized minerals including the forth Subgroup elements and organic flotation agents with phosphorus and arsenic, Oxidized minerals including the fifth subgroup elements and organic floating agents including the fifth main group elements, Minerals including the first subgroup elements and CN-, Sulfide minerals including the second subgroup elements and CN-, The effect of the highest N-valency inorganic acids or salts including p area elements of the third period in mineral flotation, Oxidized minerals including transition elements of the forth period and 3# flocculating agent, The floatability of minerals including elements of the sixth period, Element area of generating compositions and the collecting theory of mineral flotation and so and. Keywords: mineral flotation, periodic table of chemical element, subgroup, period, regulator, coordination chemistry

Sep 1, 2012

By S. S. Indi, D. Santhiya, S. Subramanian, K. A. Natarajan

The interaction of sphalerite- and galena-adapted Bacillus polymyxa (B. polymyxa) cells with sphalerite and galena has been investigated through adsorption, electrokinetic and flotation studies. The amount of sphalerite-adapted cells adsorbed onto sphalerite and galena is found to decrease with increase in pH. On the other hand, the adsorption density of galena-adapted cells onto galena shows a feeble maximum around pH 8, and the amount adsorbed is marginally higher in the pH range of 8 . 11.5. In the case of sphalerite the amount adsorbed is higher in the pH range of 5 to 7. The adsorption density of both the adapted cells is higher for galena vis-à-vis sphalerite. Electrokinetic studies indicate significant surface chemical changes on the chosen sulphide minerals and the bacterial cells, consequent to microbe-mineral interactions. Selective flotation tests on a synthetic mixture of galena and sphalerite confirm that sphalerite could be preferentially floated from galena, using galena-adapted cells, but not with the sphalerite-adapted cells. The cells adapted to galena assay a higher polysaccharide content and are more hydrophilic, while the sphalerite-adapted cells have a higher protein content and possess greater hydrophobicity. Transmission electron microscopic studies have provided evidence in support of the differences between the cell surface characteristics of sphaleriteand galena-adapted cells. Possible mechanisms of interaction between the minerals and the bacterial cells are discussed.

Jan 1, 2003

By D. Vega, P. R. Brito-Parada

"Small diameter (10 mm) hydrocyclones have been applied successfully for the separation of particle suspensions in the micron size range. These hydrocyclones are attractive because they show a bypass fraction larger that the water recovery, resulting in a high particle recovery to the underflow as well as low water recovery. However, this is a disadvantage when the purpose of the hydrocyclone is classification because of the large amount of fine particles that are misplaced in the underflow. The aim of this study is to explore, experimentally and computationally, the influence of design parameters on the classification process. In this work, a full factorial experimental design was defined to carry out comprehensive experimental tests using glass beads (0-20 µm) as the particulate system. We show that the dimensions of spigot and vortex finder diameter can be effectively manipulated to change the separation performance of the system and the energy consumption. A CFD model was developed that is able to predict particle size distribution. The numerical results for the partition curves showed very good agreement with the experimental data. INTRODUCTION Small diameter hydrocyclones are a very attractive separation technology for fine particle suspensions. Since the hydrocyclone diameter is directly proportional to the cutsize that can be achieved, 10mm hydrocyclones have been shown to be very effective in collecting particles in the micron-size range. In addition, while in large hydrocyclones the bypass, i.e. the fraction of particles that report to the underflow without classification, is similar to the water recovery, in 10mm hydrocyclones the bypass fraction is considerably larger than the water recovery. Its high particle recovery and low water recovery makes small hydrocyclones ideal for ultrafine particle classification and dewatering applications in mineral processing. The separation of mineral suspensions achieved using small hydrocyclones has been the focus of various studies. Pasquier and Cilliers (2000) derived a general classification model from experimental data of fine silica concentration in 10mm hydrocyclones; the model was able to describe the fish-hook partition curve. The effect of operating conditions has also received some attention in the literature. Cilliers et al. (2004) showed that an increase in temperature positively effects the recovery of fine silica particles in small hydrocyclones, by increasing the bypass and decreasing the cutsize. Neese et al. (2015) showed that the cutsize in 10mm hydrocyclones can be further decreased by operating at higher pressure, which also trebled the throughput."

Jan 1, 2018

By Juan B. Yianatos

"After almost 100 years, since the first commercial application began in Australia, flotation has shown an extraordinary growth and nearly 2 billion tons of ore per year are presently treated by flotation processes. During this time flotation has promoted a wide scope of research activities ranging from fundamental chemistry and hydrodynamic studies to studies of industrial operations. In general, fundamental studies have been mainly related to ideal situations. In recent years, however, large efforts have been focusing on achieving a better insight into the actual sub-processes provided by the development of new and more sophisticated instrumentation. Since the massive incorporation of flotation columns, around 15 years ago, a renewed interest in flotation fundamental studies, process modelling and new cell designs have been observed worldwide. The key role of the froth has been recognized as an independent and sometimes rate limiting process step. Thus, separation of pulp and froth process stages seems the most appropriate in terms of process modelling, diagnostic, design and scale-up purposes.In relation to flotation equipment development, until the middle of the 1970?s, only the sub-aeration mechanical cells were dominant. Since the 1980?s, the use of pneumatic cells and forced air mechanical cells has emerged strongly. Also, in the last decade, flotation equipment has shown a dramatic increase in size, reaching values of 200m3 in unitary mechanical cells and more than 300m3 in columns. The general feeling, however, is that, despite the great advance observed in terms of process knowledge, the mechanisms and principles of industrial flotation cells design and scale-up are still not fully understood.Advances in process instrumentation and control now in use allow for more efficient operations, both in metallurgical performance and savings in operating costs.INTRODUCTIONFlotation is a widely used process within the minerals processing industry, as well as being used for water treatment and de-inking of recycled paper. Froth flotation started in Australia at the beginning of the 20th century and since then flotation technology has made significant advances. Flotation was firstly applied to sulfide ores. The largest tonnages treated by flotation are copper and copper/molybdenum ores, handling about 50% of the total ore processed. Also significant are phosphate, iron ore and coal treatments. At present, Chile is the foremost copper producer in the world with around 35% of the world?s production. Figure 1(a) shows the evolution of copper production in Chile over the last decade. The total amount of fine copper produced in year 2001 was 4.7 million tons, from which 3.2 million tons was processed by flotation while 1.5 million tons went through LIX-SX-EW processes, which also showed significant development during the same period (Anon, 2001). The total flotation treatment of copper ores in Chile is about 325 million tons per year (Anon, 2002), so the world treatment of copper ore by flotation can be estimated at about 1 billion tons per year. Consequently a total of nearly 2 billion tons of ore per year is presently processed worldwide by flotation (Fuerstenau, 2001). In order to handle the higher tonnage of low-grade ore, a worldwide trend towards the development and use of larger flotation machines began in the 1960?s. Figure 1(b) shows that the trend became extremely marked from the beginning of the 1990?s, which is consistent with the strong increase in copper production during the same period."

Jan 1, 2003

By K-O. Mickelsson, S. Töyrä, H. Esbensen

Accurate information of physical, chemical and metallurgical quality characteristics such as moisture content, iron grade and particle size are crucial for successful process control and for producing products within customer specifications. Correct moisture content of pellet feed is an important variable for successful balling of iron ore pellets and to minimize power consumption in the sintering process. Control of the filtering process in the pelletizing plant is therefore essential for both productivity and high product quality. The current measurement systems for moisture content at LKAB are based on two types of manual grab sampling, subsequently analyzed with rapid moisture determination methods. Previous studies of the measurement systems have indicated high sampling variability resulting in lowered possibilities for successful process control. The objective of the present study is to evaluate an alternative filter sampling approach and testing of on-line Infra-Red analysis (IR-analysis). On-line IR-analysis has the advantage of eliminating physical sample extraction and allowing for continuous monitoring of moisture content. However, this approach is sensitive to the surrounding environment, making careful calibration and control crucial for the quality of measurement results. Furthermore, as IR-sensors only target the surface of the conveyed pellet feed, several incorrect sampling errors need to be considered and counteracted to eliminate sampling bias and reduce the remaining measurement variability. Variographic characterization was applied to the two current grab sampling approaches of combined filtered material, to the alternative filter sampling method, and to the On-line IR-analysis. The results indicate that both the sampling of separate filters (using composite sampling and ISO-standardized moisture analysis), as well as a calibrated and well- maintained IR-sensor can improve the relative variability significantly, by lowering the total measurement system variance from 60% to 25%.

Jan 1, 2018

By S. V. Volkova, S. V. Mamonov, T. P. Dresvyakyna

"The purpose of the work is complex processing of sulphide-magnetite ores with the separation of iron into iron concentrate, copper and noble metals into copper concentrate.The work shows the research results of the material composition of the sulfide-magnetite ore in the South part of the Peschanskoye deposit. According to the research results it is found that ore contains 0.59% of copper, 66% of which is related to chalcopyrite; 39.9% of iron, 81% of which is magnetite and 3.87% is sulfur, 42% of which is associated with pyrrhotite, 65% of which is a monoclinic modification. According to the results of the mineralogical analysis, it is found that the main iron-containing mineral in the ore under study is magnetite, the content of which is 45%. In addition to magnetite, iron is found in carbonates, pyroxenes, amphiboles, chalcopyrite, pyrrhotite and pyrite. The main copper mineral in the sample is chalcopyrite; covellite, chalcosine, bornite have a subordinate value. The total content of copper minerals in the sample is about 1%. The processing technology provides the three-stage grinding of the ore to a size of 65% of the class-71 µm; a cycle of copper flotation; a cycle of pyrrhotite flotation; wet magnetic separation of flotation hosts. The following optimal parameters are established for the ore under study: the alkalinity of the slurry is 250-280 g/m3 of free calcium oxide in the liquid phase of the slurry; the duration of the main copper flotation is 20 min; the consumption of butyl potassium xanthate is 20 g/t; the consumption of the foam generator T-92 is 15 g/t; the consumption of copper sulfate for the activation of pyrrhotite is 300 g/t; the magnetic field strength is 1500 Oersteds.A complex flotation-magnetic technology for the enrichment of sulfide-magnetite ore has been developed in the laboratory in order to produce a copper concentrate containing 21.6% of copper with 91.7% extraction and an iron concentrate with 66.5% of iron mass fraction and 1.2% of sulfur with an extraction of iron into the concentrate of 87.9%."

Jan 1, 2018

Mineral processing is an energy and water intensive activity. Mill comminution equipment usually has high energy requirements which necessitate extensive cooling to remove heat. Cooling requirements are typically 10% to 20% of the comminution energy. If there is an adequate supply of suitable water, open water-based cooling systems are the simplest, cheapest and most energy efficient cooling method available. This paper describes a method to determine the water demand for open water-based cooling systems at a plant and to determine whether the mine has sufficient water to meet that demand.

Jan 1, 2014

By I. N. Gridasov, V. V. Khromov, R. I. Ismagilov

"Over 50 mln.tonne is the average annual output of oxidized ferruginous quartzites typically containing Fe38-42% mined in Mikhailovskoye ore field. The most promising and cost-effective way to expand concentrate production maintaining current output of magnetite is processing of oxidized ferruginous quartzites (hereinafter referred to as OFQ) mined as a by-product in Mikhailovsky open pit mine. However lack of proven and efficient concentration and agglomeration process applicable to OFQ and insufficient data for feasibility evaluation of OFQ processing encumbered full-scale addressing of this challenge. Based on outcomes of multiple various studies a process of OFQ flotation was designed by MC Metalloinvest LLC and PJSC Mikhailovsky GOK engineers. Comparative lab-scale testwork have proven performance and production advantages of flotation against magnetic separation feat. flotation and combined concentration method. Lab-scale flotation enabled production of concentrate with average Fe66.6% and SiO22.06% grade. Geologic and production contouring of OFQ deposited in Mikhailovskoye ore field has been carried out to collect necessary data for feasibility study incl. cost and profit estimation. As a result processing and production properties of over 3,500 samples have been analyzed which is characteristic of every direction and level of prospective ore mining within Mikhailovskoye ore field up to year 2032. Following work has been done based on geologic and production contouring of OFQ: – natural typification of ores and production (processing) grades of OFQ, determination of average mineral composition; – correlation analysis of interrelation between OFQ mineral composition and processing features thereof for overall bulk of samples as well as for individual data blocks related to various directions of open pit mine; – OFQ classification with account of defined mineral composition and processing features. Total Fe weight content in chamber product of flotation (known as concentrating ability in flotation) was applied as a major differentiating factor for processing grade classification of OFQ. Three processing grades of oxidized ferruginous quartzites were established as a result of flotation tests run to determine concentrating ability, i.e. – hard concentrated OFQ (TO) – below Fe65%; – mean concentrated OFQ (SO) – Fe65-67%; – easy concentrated OFQ (LO) – over Fe67%. Outcome of this work provided initial data for feasibility study and cost-profit evaluation of medium-term industrial-scale processing of OFQ deposited in Mikhailovskoye ore field."

Jan 1, 2018

By Gabriel Barrios, Juan Pérez-Prim, Marcelo Tavares

"The application of High Pressure grinding Rolls (HPGR) has been growing in the mining industry for the last 10 to 15 years. The major benefits generally supporting this trend are better energy efficiency, improved grinding capacity, less sensitivity to ore grindability variations and higher metal recovery in downstream processes such as heap leaching and flotation. The HPGR machine comprises a pair of counter-rotating rolls mounted in a sturdy frame. One roll is fixed in the frame, while the other is allowed to float on rails and is positioned using pneumohydraulic springs. The feed material is introduced in the gap between the rolls and is crushed by the mechanism of interparticle breakage. Comminution performance is largely determined by the pressure exerted on the bed of particles by the floating roll hydraulic system. The operating bed pressure depends on the hydraulic system start-up parameters and the loading response of the feed material. The work describes how the coupling of the multi-body dynamic simulation with Discrete Element Method in which particle breakage is described using the particle replacement method, can be effectively used to predict the performance of the HPGR. The model considers important variables as the HPGR rolls geometry and design, the hydraulic spring system start-up parameters and the material loading response, to describe operational key outputs as material throughput, operating gap and roller pressure distribution. The preliminary version of the model has been used to predict the effect of material properties on the operating gap and the load distribution on the surface of the rolls, demonstrating that it can describe qualitatively the HPGR operation, indicating that the model will be a power full tool for the simulation and selection of industrial HPGR units."

Jan 1, 2014

By A. Makavetskas

"The purpose of the research is to study the mineralogical features of the structure of the wall accretion formed during melting on the working surface of the walls of metallurgical aggregates and adversely affect the stability of the lining of blast furnaces (BF). We presented the results of studies of the material composition of lining and wall accretion of the furnaces of blast furnaces of the metallurgical plant specializing in the smelting of ferromanganese, nodular and pig iron. It is established that the garnissage is an aggregate of layered texture, formed as a result of the crystallization of slag and metallic melts. Refractory calcium and magnesium silicates and aluminosilicates (minerals of the melilite group, leicite, olivine group minerals) and amorphous glassy oxide solid solutions of variable composition crystallize from the slag melts in the upper part of the hearth. In the slag matrix, inclusions of carbon (amorphous and graphite) and products of crystallization of metallic melts of alpha-iron, iron carbides and / or manganese are observed. Evidence of carbon evolution (in the form of graphite) is precisely in the crystallization of metal melts, there are significant differences in the structure of carbon in coke and in the garnissage. The conducted studies confirm that it is impossible to obtain reliable information on the material composition of new formations in the blast-furnace process without using a complex of modern methods of technological mineralogy.INTRODUCTION The formation of the wall accretion (garnissage) - a solid protective layer as a result of smelting products crystallization on the inner (working) surface of the liner. This is due to the design of blast furnaces with a high-efficiency heat sink using copper coolers and the use of carbon blocks with high thermal conductivity in the lining. The objective of the study was research of the material composition of the lining and wall accretion of the blast furnace hearth of one metallurgical plant that specialized in smelting ferromanganese, nodular and pig iron, to assess the effect of new formations for stability of the lining of blast furnaces (BF)."

Jan 1, 2018

By Yu. E. Emelyanov, A. V. Bogorodsky, R. N. Nabiulin, S. V. Balikov

"The paper describes the results of the study of gold-copper flotation concentrate atmospheric oxidation at different sizes of material, varying oxidation time, with air or oxygen blow. The study showed the low rate of sulphide oxidation during oxidation of flotation concentrate at a feed size (P98 -74 µm). The coppery recovery into solution was 48%; the recovery of gold by subsequent cyanidation reached 86%. Preliminary flotation concentrate grinding to P98 -20 µm provided oxidation of 90% of copper minerals, 80% of arsenopyrite and 15% of pyrite. The gold recovery by atmospheric oxidation of a fine-ground flotation concentrate increased by 59%, from 36% to 95%, the NaCN consumption reduced by 21 kg/t, from 30 to 9 kg/t. INTRODUCTION Processing of sulphide gold-copper ores and concentrates using conventional cyanidation technology results in higher reagent consumption and lower gold recovery. Destruction of sulphide minerals and extraction of copper from a processed product prior to cyanidation is essential for improving efficiency of precious metals recovery and reducing main reagents consumption. Atmospheric oxidation (AO) is one of the most promising hydrometallurgical methods of refractory gold-copper concentrates processing, along with biooxidation and pressure oxidation. The nature of this approach lies in oxidation of sulphides at 90-95°C, in acidic or alkaline conditions, with bubbling of oxygen or air, after preliminary ultrafine grinding (1-4). The following reactions of sulphide oxidation occur during atmospheric oxidation of a gold-copper flotation concentrate. Pyrite is oxidized with the formation of ferric sulphate (1) and elemental sulphur at low temperatures (2), whereas some portion of elemental sulphur reacts to form sulphuric acid: FeS2+3,75O2+0,5H2O=0,5Fe2(SO4)3+0,5H2SO4; ?G=-1144,02 kJ/mol (1)"

Jan 1, 2018

By G. Mucsi, F. Kristály, Á. Rácz, É. Gregus, K. Bohács

"Stirred media mills are widely used in the industry for fine grinding. Most of the applications work in wet mode, however dry grinding in stirred media mill comes forward more frequently nowadays. The present paper deals with the differences and similarities of the wet and dry grinding in stirred media mill from energetic and mechanochemical point of view as well. Grinding experiments in batch stirred media mill were carried out with different materials. During the experiments zeolite and kaolin were used as feed material. The grinding experiments were carried out at different stress energy and stress number values; the grinding work was measured during milling. After grinding X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), particles size analyzes by laser scattering were carried out on the ground materials. As a result of the systematic grinding and analytical measurements a comprehensive comparison was carried out on the wet and dry grinding and their usefulness for mechanical activation in stirred media mill. INTRODUCTION The natural zeolites are crystalline hydrated aluminosilicates of alkali and alkaline earth characterized by the structure that contains frameworks responsible for the high cation exchange capacity (CEC) and absorption capacity. The frameworks are interconnected by cavities and resided by cations variable in size, coordinated by water molecules. Since zeolite comprises SiO4 and AlO4 tetrahedra interlocked by oxygen atoms that are situated in the structural nodes, their characteristics differ due to the varieties in the structure-directing agents and Si/Al ratio (Colella and Wise, 2014; Malekian et al., 2011; Terzic et al., 2017). The most common natural zeolite occurring in high amount, of industrial importance and involved in milling and MA is the clinoptilolite, in the literature equivalent to “natural zeolite” designated for high clinoptilolite bearing volcanic tuffs. Its amount in the host rock must reach ~ 40 % by weight to obtain the CEC and adsorption desired in its applications. In the highest quality rock might reach 80-90 % by weight (Favvas et al., 2016), but most often is the 40-60 % by weight content, associated with smectites, improving the CEC and adsorption of the tuffaceous rock. The application of such natural zeolites is problematic in many cases due to high silica (quartz, cristobalite and volcanic glass) content and beneficiation (concentration and extraction of pure zeolite) are not feasible. Thus, mechanical activation is a possible way to alter the other than clinoptilolite minerals generating high specific surface area and functionalized particle surfaces to enhance adsorption, reaction or particle adhesion. The zeolites easy availability and the utilization cost-effectiveness have prompted the research on their physicochemical and structural properties (e.g. adsorptive and molecular-sieve activity, heat resistance, and microporous cage structure) and finding new options for their application (Kusuma et al., 2013; Musyoka et al., 2014; Rida et al., 2013; Terzic et al., 2015b). Apart from the presence of exchangeable framework cations which are crucial for the adsorption ability, and a certain degree of pozzolanic reactivity. The thermal stability of dehydrated phases is another important characteristic for use of the zeolite in composite materials that are exposed to high temperature. Thereby, the zeolites found a wide application possibility in the design of the construction composites (Albayrak et al., 2007; Najimi et al., 2012; Vejmelková et al., 2015), as well as for resolving of the environmental protection issues like wastewater refining or heavy metal elimination (Gómez-Hortigüela et al., 2014) even from contaminated groundwater using passive methods like permeable reactive barriers (Gombköto et al, 2016). The grinding treatment of zeolite is a common and frequently applied procedure, both on laboratory (Bohács et al. 2017, Faitli and Czél, 2014)"

Jan 1, 2018

By G. Semenchenko

Heterotrophic microorganisms Pseudomonas aureofaciens, microscopic fungi Fusarium sp. and their combinations with some chemical substances were used for gold leaching from refractory ore and flotation concentrateof Akbakaj deposit. All biological additives raised the speed of noble metals dissolution. The best results of gold extraction from ore were in the presence of bacteria or their associations with other solvents and from flotation concentrate in the presence of fungus - 30 % of additional amount of gold. The maximum extraction of gold speed value was during the first 8 hours of process. The electronic-microscopic researches of the ore samples showed almost complete decay of pyrite and arsenopyrite under bacteria influence whereas at chemical leaching most of these minerals stayed uncrushed. The presence of microscopic fungi in flotation concentrate during leaching provided full distraction of pyrite, but some crystals of antimony and arsenopyrite were undestroyed. During cyanide leaching of flotation concentrate there were accumulation of antimony and incomplete pyrite decomposition. Keywords: gold bioleaching, bacteria, fungi, complex solution

Sep 1, 2012

By Tiago de Souza, Caroline Gonçalves, Carlos Eduardo de Castro, Everton Dias

The Miraí plant from Votorantim Metais, has two screening stages to the bauxite classification after scrubbagem. The final product has hold the larger size of 0,84 millimeters (20 mesh). There are two sieves Haver & Boecker (model R-TE 3658 x 10972), which have four modules with cut size sieves of 10 mesh (1.70 millimeters) and ¼ inch (6.35 millimeters) on the primary screen, and 20 mesh (0.84 mm) on the secondary screen, all made of polyurethane. The actual configuration was established according to the empirical tests realized that aimed the increase material load on the secondary screening. However, having in mind the screening process improvement and use the fractions smaller than 0,84 mm, which have significant levels of Alumina and low reactive silica, was proposed a new test of change the sieves opening for 6 mesh in the primary screen and 28 mesh for the secondary sieve. The objective of this work was measure the ore alterations on the particle size distribution on the screening steps, increasing the plant weight and ratio recovery before and after the test.

Jan 1, 2014