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Rotor speed is one of the key hydrodynamic parameters in froth-flotation and it plays an important role in bubble-particle attachment. Laboratory scale studies for optimizing the rotor speed to achieve maximum flotation rate constant (K) of quartz, ground by ball mill, are. Purity of quartz was 99.4 percent and d80 of ball mill product was 230 µm. Each size fraction was separately subjected to flotation at three different rotor speeds, namely, 1200, 1000 and 800 rpm, and the flotation rate constant was calculated. The results showed that the flotation rate constant was high at the rotor speed of 1200 rpm. The flotation rate constants achieved at 1200 rpm were 8.676, 8.232, 7.818, 7.248, 7.068 and 6.984 min-1forthesize fractions of +300, -300+250, -250+212, -180+150, -150+125 and -125+106 µm, respectively. Keywords: froth flotation, rotor speed, flotation rate constant, ball mill, quartz

Sep 1, 2012

By Rhulani F. Maluleke, Francis W. Petersen, John H. Marsh, Johann de T. Steyl, Allan Nesbitt

"Pressure leaching of chalcopyrite and nickeliferrous pyrrotite at temperatures between 105 and 200 ºC has been proposed as a potentially viable route for the extraction of mineral elements from sulphide concentrates. In general, these concentrates contain iron, and the economic success of the processes is partially dependent on the choice of the environmentally acceptable iron-removal technique. One of the most widely used methods for the removal of iron from sulphate liquors is precipitation as hematite, goethite, or jarosite. The nature of the iron precipitate formed dictates downstream dewatering and residue treatment and disposal options. However, a better understanding of iron precipitation under the defined process conditions would consequently be of benefit in process design and optimisation.This study investigated the precipitation of iron in the autoclave at temperatures between 105 and 200 ºC. The effects of temperature, acid concentration, iron concentration, and the presence of other metal cations on the nature and composition of the precipitates were determined."

Jan 1, 2003

By E. V. Zelinskaya, V. U. Starostina

"The Irkutsk region is a raw material region. There are a lot of big enterprises for extraction and processing of oil, gas, coal, iron, gold and rock salt. Besides of it, refractory clays, limestone, mica, gypsum and talc are mined in the region. The most important type of mineral raw material is a gold. More than 8.5% of the total mining in the Russian Federation is extracted in Irkutsk region. It is about 0.7% of the world production. The environmental problems of mining and processing enterprises are a complex set of issues that requires of the searching of effective methods to be solved. One of the key environmental problems remains the reduction of waste generation and the introduction of environmentally safe waste management. After analysing different methods of environmental impact assessment it is established that the method of Life Cycle Assessment is one of the most effective methods for mining production. This method base? on the material balance of flows of raw materials, products and waste. The method of Life Cycle Assessment allows to identify the effects of environmental pollution under the influence of mining and processing at a quantitative level and to show real quantitative forecasts of the possibility of managing the flows of raw materials and waste.INTRODUCTION The Irkutsk region is a raw material region. There are a lot of big enterprises for extraction and processing of oil, gas, coal, iron, gold and rock salt. Besides of it, refractory clays, limestone, mica, gypsum and talc are mined in the region. The most important type of mineral raw material is a gold. More than 8.5% of the total mining in the Russian Federation is extracted in Irkutsk region. It is about 0.7% of the world production. The main provider of precious metal is the Bodaibo region. This is a main location for the major ore companies such as “Vysochaishy”, which produces about 5.0 tons a gold per year; “Pervenets”(PJSC Polyus, the largest gold producer in Russia) - 4.5 tons/year, “Druza” - 0, 5 tons/year. Placer gold is extracted by more than 40 enterprises. In connection with this, there are many plans about a building of new and reconstruction of concentrating factories. Consequently, an increase in the volume of processing is expected. The main projects are the construction of a new mill of the Mining and processing plant GOK “Vysochaishy” with a capacity of 2.6 million tonnes of ore per year; the development of the “Uhakhan” gold-field - 23 km from the “Goltsa Vysochaishy” gold-field; the opening in the Bodaibo region the next parts of the gold-deposit ""Pervenets"". Additional, the growth in a gold production can be achieved by a store of gold in the “Sukhoi Log” deposi"

Jan 1, 2018

By X. Tan

In this paper, the application of the metallurgical residue produced from oceanic cobalt-rich crusts leaching process is studied in the area of wastewater treatment. The modification of the sulfuric acid leached residue and the adsorption behavior behaviour of heavy metal ions such as (Pb(II), Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), Co(II), As(III)) in the waste-water on the surface of the residue are investigated. The rate of adsorption efficiency of heavy metal ions in the wastewater on the modified sulfuric acid leached residue is investigated. It is showed that when the initial pH value of wastewater containing heavy metal ions including Pb(II), Cu(II), Co(II), Ni(II), Mn(II), Zn(II), Cd(II) and As(III) range from 1.4 to 1.9, with the use of the modified leached residue, As(III) ion can be selectively separated from wastewater, and the separation efficiency can reach 90%~100%. The adsorption efficiency is affected by pH, reaction time, amount of adsorbent and the initial concentration of heavy metal ions in wastewater. The results showed that the optimum pH was natural pH value and the absorption equilibrium time was 2 hours. The adsorption efficiency of heavy metal ions increases with the addition of adsorbent and de- creases with the increase of the initial concentrations of heavy metal ions in wastewater. The heavy metal ions polluted wastewater, of which concentration is about 22.5~793.6 mg/L, can meet the national disposal standard for industrial wastewaters in China very well, after 2 hours treated by 3.75~7.50 g/L modified adsorbent at room temperature. Standard methods were used to investaged investigate the absorption behaviour between abosorbentabsorbent and metal ions in the wastewater. It is concluded that the adsorption behaviour of Co(II), Mn(II) and As(III) ion fits Freundlich iso-therm, while the adsorption behaviour of Pb(II), Cu(II), Zn(II), Cd(II) and Ni(II) ions fits Langmuir isotherm, and the saturated adsorption amount of the modified adsorbent is about 54.0~336.7mg metal/g?adsorbentabsorbent. It is suggested that the modified sulfuric acid leached residue produced from oceanic cobalt-rich crusts is environmentally attractive and meaningful as absorbent used in heavy metal ions polluted wastewater.

Jan 1, 2014

By Tingting Li, Guodong Li, Dezhou Wei, Cong Han, Shuling Gao, Yanbai Shen

"The aim of this study is to solve the problem of tungsten leaching from scheelite concentrate using sodium hydroxide in the presence of phosphate by an autoclaving process, which is one of main development techniques for tungsten recovery. To understand the applicability and leaching performance of tungsten leaching from scheelite concentrate, the main work is to investigate the effects of leaching parameters such as initial concentrations of NaOH and Na3PO4, reaction temperature, stirring speed, liquid-to-solid ratio and reaction time on WO3 dissolution rate to obtain the optimal leaching conditions. The chemical composition and phase composition of the samples were evaluated by means of XRF and XRD. The content of WO3 in the leaching residue obtained via washing, filtering and drying was analyzed by thiocyanate spectrometric method. The optimal leaching conditions were found to be NaOH concentration of 6.76 mol·L-1, Na3PO4 concentration of 1.35 mol·L-1, reaction temperature of 180°C, stirring speed of 400 rpm, liquid-to-solid ratio of 2.0 and reaction time of 90 min. The results showed that tungsten leaching rate of 99.20% was reached under the optimal conditions. The technology exhibited superior leaching performance, which not only reduced the consumption of sodium hydroxide but also greatly decreased reaction time in comparison to a conventional autoclaving process. INTRODUCTION Tungsten is an important strategic metal, which is widely utilized in a variety of industries due to its high melting point, superior mechanical properties and heat-resistant performance [1-3]. The chief raw materials for the production of tungsten in nature are wolframite and scheelite [4, 5]. Among them, approximately two-thirds of the tungsten reserves contain scheelite deposits in the world [6, 7]. With the progressive exhaustion of high-quality wolframite resources, scheelite has become a predominant primary resource for the production of tungsten [8, 9]."

Jan 1, 2018

By C. A. C. Sequeira, G. N. Anastassakis

Electrochemical processes occur on nano-, micro- and macro- scale in numerous applications such as fuel cells, batteries, hydrogen production, mineral extraction, water treatment, electrotherapy, sensors and many others. In most of these applications, gases evolve either at one or both electrodes due to electrolysis. These gases form bubbles play a crucial role in electrochemical systems. For example, in electrowinning (EW) that is used to extract and refine metals such as Cu, Zn, Ni, Mn, and Cd from their solutions, in most cases the solution is acidic and oxidation of water molecules at the anode is the common counter reaction, which results in the liberation of oxygen bubbles. This generally requires a high overpotential and accounts for a considerable percentage of the energy consumed in metal EW electrolytic cells, apart from producing acid mist that is very corrosive for other cell equipment and building structures. The behaviour of bubbles in electrochemical systems is still a complex challenging topic which requires a better understanding of gas bubbles hydrodynamics and their interactions with electrode surface and bulk liquid, as well as between the bubbles themselves. The objective of the current paper is to briefly review the fundamental hydrodynamics of both gas bubbles on the electrode surface and gas bubbles interaction with the liquid bulk solution. The current work also investigates the impact of gas bubbling and some operating parameters in copper EW, such as current density (100-500 A/m2), temperature (25-75ºC), acidity (50-300 g/L) and a typical chemical mist suppressant (<50 ppm). The results clearly show that both suppressant and temperature reduced the overall surface tension of the solution. Also, chloride concentration and applied current improved electrolyte flow and copper quality at higher current densities. The current paper contributes to the development of mineral processing (specifically to copper hydrometallurgy), as it deals with fundamental hydrodynamics and interactions of gas bubbles that formed during copper EW and play a crucial role in copper electrochemical systems.

Jan 1, 2018

By L. G. Wang

The stability of foams and froth plays an important role in flotation, in which small amounts of relatively weak non-ionic surfactants (frothers) are used to produce air bubbles and foams. In the present work, factors affecting the stability of the foams produced in the presence of common frothers, such as n-pentanol, n-octanol, methyl isobutyl carbinol (MIBC), and polypropylene glycol (PPG), have been studied. We used the thin film pressure balance (TFPB) technique of Schelud-ko-Exerowa type to measure the equilibrium film thicknesses. The results were used to determine the contributions from the various surface forces to the disjoining pressures in the thin lamellae (foam) films formed between air bubbles. In addition, we used a model developed by Wang and Yoon (Colloids and Surfaces A: Physicochem. Eng. Aspects, 2006) to calculate the elasticities of the lamellae films at the critical thicknesses at which films rupture. The surface forces and elasticity da-ta were then compared with the foam stabilities in the presence of the various flotation frothers. It was found that foam stabilities are controlled by both film elasticity and surface forces, the relative contributions of which change with frother type and concentration. In general, surface forces play a more important role at relatively low frother concentrations, while elasticity plays a more important role at higher concentrations. At the frother additions usually employed in the mining industry, MIBC relies on surface forces while PPG-400 relies on film elasticity in producing stable foams. The former is capable of dampening the hydrophobic force, which is a major attractive force destabilizing lamellae films, while the latter is capable of reducing surface tensions at low concentrations.

Jan 1, 2014

By N. I. Tyushkova

This is a brief survey of the technological solutions for deep cleaning of baddeleyite?s concen-trate. Baddeleyite is part of kamaphorite of composite apatite-magnetite ore in alkaline-ultrabasic mountain range of Kola Peninsula. Baddeleyite?s concentrate, which is being produced by Kovdorsky GOK (ore mining and processing enterprise) contains 97.5%~98.5% (Zr?2 + ?f?2) and also scandium oxide (0.05%). It is usually used without any chemical processing. World demand for zirconium oxide is constantly on the rise. Its consumption grows in ceramic industry and in high-tech spheres. That?s why the demand for its purity is very important nowadays (additional cleaning from phosphorus, silicon, iron, aluminium). The mechanism and kinetics of interaction of activated bad-deleyite with sulphuric acid has been studied as well. While applying method of mathematical mod-eling it was confirmed that the mechanical activation is effective for the intensification of sulphation process of baddeleyite?s concentrate with the aim of purifying it from dirt. The use of the calculated optimal regimes allows to reduce such technological operation factors as: temperature, the du-ration of process, the sulphuric acid consumption. It also allows to determine the conditions of anticipatory abstraction of scandium and main dirt in solution in comparison with zirconium oxide.

Jan 1, 2014

By V. Beskrovnaya

Oxidised lead-bearing ores of one of the deposits of Russian Federation represent complex raw materials. Its main components are lead (3.2%~4.7%), silver (100~300 g/t) and zinc (0.7%~0.8%). The sample is characterized as oxidized ore. Silicium (37.4%) and iron (33.2%) are its main com-ponents and present in oxide form. Lead presents as cerussite, anglesite and plumbojarosite have a subject role. Zinc occurs as smithsonite. Certain part of zinc is associated with manganese minerals (psylomelane-pyrolusite). Close association of valuables with manganese-iron mineralization is ob-served. Silver is present in native finely dispersed form. Three options of flowsheets have been developed to recover valuables from the ore. 1. Hydrometallurgical flowsheet of lead and silver recovery on the basis of chloride leaching. 2. Flotation. 3. Flotation -flotation tailings cyanidation. Hydrometallurgical flowsheet of ore processing on the basis of chloride leaching (option I) al-lows to achieve recovery into saleable products of 68.8% Pb and 70.2% Ag. High quality lead concentrate with 71.7% lead and 700 g/t silver was obtained during flotation (option 2). Flotation tailings cyanidation (option 3) provides 24% silver additional recovery (from the ore). Technical and economical evaluation demonstrated that ore flotation (option 2) and flotation with subsequent flotation tailings cyanidation (option 3) are the most cost-efficient. Option II is the most cost-efficient variant of 1 tonne of ore processing (9.05 US dollars).

Jan 1, 2014

By Steven Wright, Sharif Jahanshahi, Shouyi Sun

"While there is a large industry based on recovering platinum group metals (PGM) from complex sulphide ores containing Cu and Ni, there is little information on the thermodynamics of the matte phase formed on smelting the ore and in particular the behaviour of Pt in the matte.The equilibrium between metallic platinum and industrial mattes was studied in a series of experiments where a small quantity of matte (5g) and platinum foil of 150 µm thickness (0.5 g) were equilibrated in magnesia crucibles at 1400°C under conditions where the oxygen and sulphur partial pressures were controlled.The chemistries of the phases were determined from EDS analysis using a scanning electron microscope. Line scans were initially used to confirm that the foils had attained a uniform composition across their thickness. The composition of the matte was determined from analysis of an area of matte including the small metallic droplets and dendrites.The distribution of Pt in Cu-Fe-Ni mattes (Pt: 1.5 – 3%) and solid Pt alloys (Pt: 54 – 72%) was studied. For a matte of base composition 45%Fe, 11%Ni, 8% Cu, at a base temperature 1400°C, the following behaviour was observed for the Pt distribution ratio:Under the range of sulphur and oxygen pressure of this study (log pO2 from -15 to –12.2, log pS2 from – 4.6 to –2.2), the distribution ratio of Pt between matte and alloy was independent of the sulphur and oxygen pressure, having a value of 0.04.The Pt distribution ratio increased from 0.02 to 0.08 with temperature from 1340 to 1450 oC.For mattes where the proportions of Cu and Ni were kept constant, a slight decreasing trend was shown for the distribution ratio of Pt versus the iron content (37 to 53%) in the matte but was not confirmed because of experimental uncertainty."

Jan 1, 2003

By Silvia França, Hudson Couto

"In this paper, an alternative beneficiation process was developed to recover nickel minerals from low-grade weathered ores. The studied sample, 0.3% Ni grade, is essentially composed of nickel sulfides (pyrrhotite and pentlandite); magnetite and silicates (mostly talc and amphibolites) are the primary gangue minerals. The particle size distribution was controlled using a grinding operation to avoid producing an excess of fine particles by overgrinding. The sample underwent a grinding step for the fine degree of liberation. The slimes (-20 ?m) were removed via two desliming stages in hydrocyclones (diameters of 1.5" and 2"); the ground material, which was classified in a range of (-150+20) ?m, was processed by column flotation in three different stages: rougher flotation for magnesium silicates, rougher flotation for sulfides, and cleaner flotation for sulfides, using pilot flotation columns (2" and 6" in diameter and 20 ft high). The goal of using the preliminary magnesium silicate flotation step was to remove hydrophobic minerals (mostly talc) that would float naturally with the sulfides, which would decrease the Ni grade in the concentrate, as well as to reduce the MgO content because this compound is considered harmful in metallurgical processes when a grade greater than 9% is used. The final concentrate obtained in the cleaner flotation step reached up to 2% Ni and 7.0% MgO. The global and flotation recoveries in the process were approximately 30% and 60%, respectively, due to the losses of Ni during the desliming process. Despite this low global recovery, the adopted beneficiation process can be considered an interesting alternative to produce nickel concentrate from tailings or waste materials."

Jan 1, 2014

By D. Y. Liang

Rare metal ores have those features of high industrial value and bad performance in ore separation. Most of rare metals ores are with low grade of valuable components, rareness of useful minerals, complicated combination of associated minerals and high difficulty in separation and enrichment of minerals. For those single (Ta, Nb) or (Ta, Nb, Sn) ore occurred in granite and pegmatite, the ways of gravity separation and magneto electric separation to concentrate (Ta, Nb) minerals are adopted. There are many mines being explored successfully both at home and aboard. While, for complex (Nb-Zr-REE) ores associated with Be and Ti minerals, they are commonly considered as rich rare metals ore but more difficult to process. One of rare metals mine in Inner Mongolia has the features as with large reserves and high grade of columbium and zirconium and accompanies with REE and beryllium, therefore with significant industrial value. After the utilization of research method of process mineralogy, detailed mineralogy research has been made on the rare metals ore. The test results show that there are abroad isomorphism replacements among such elements, such as Ti, Mn, Fe, Nb and Ta, between Be and REE in metallic oxide minerals of that ore, which makes the mineral composition of that ore extremely complicated. This research identifies clearly the mineral composition, and investigate at the technological property and the occurrence of those elements as Nb, Zr, Be and REE in the rare metal ore. The achievements of this research provide important mineralogy basis for ore dressing research of refractory rare metallic ores.

Jan 1, 2014

By Felix M. Zhuravlev, Vitalij P. Lyalyuk

"While there is a large industry based on recovering platinum group metals (PGM) from complex sulphide ores containing Cu and Ni, there is little information on the thermodynamics of the matte phase formed on smelting the ore and in particular the behaviour of Pt in the matte.The equilibrium between metallic platinum and industrial mattes was studied in a series of experiments where a small quantity of matte (5g) and platinum foil of 150 µm thickness (0.5 g) were equilibrated in magnesia crucibles at 1400°C under conditions where the oxygen and sulphur partial pressures were controlled.The chemistries of the phases were determined from EDS analysis using a scanning electron microscope. Line scans were initially used to confirm that the foils had attained a uniform composition across their thickness. The composition of the matte was determined from analysis of an area of matte including the small metallic droplets and dendrites.The distribution of Pt in Cu-Fe-Ni mattes (Pt: 1.5 – 3%) and solid Pt alloys (Pt: 54 – 72%) was studied. For a matte of base composition 45%Fe, 11%Ni, 8% Cu, at a base temperature 1400°C, the following behaviour was observed for the Pt distribution ratio:Under the range of sulphur and oxygen pressure of this study (log pO2 from -15 to –12.2, log pS2 from – 4.6 to –2.2), the distribution ratio of Pt between matte and alloy was independent of the sulphur and oxygen pressure, having a value of 0.04.The Pt distribution ratio increased from 0.02 to 0.08 with temperature from 1340 to 1450 oC.For mattes where the proportions of Cu and Ni were kept constant, a slight decreasing trend was shown for the distribution ratio of Pt versus the iron content (37 to 53%) in the matte but was not confirmed because of experimental uncertainty."

Jan 1, 2003

By V. I. Lakshmanan

The growing concerns on process efficiency, escalating operating and capital costs along with environmental and social concerns of using conventional technology for extracting gold and titanium dioxide demand an in-depth understanding of the fundamentals and a broader understanding of the various process steps involved. This will allow development of efficient process flowsheet for product recovery and compliance with regulatory guidelines. This paper will discuss our recent developments in mineral processing and hydrometallurgical technologies to recover gold and titanium dioxide from a wide range of feed materials including ores, concentrates and tailings.

Sep 1, 2012

By S. J. Neethling

"This paper examines the impact of several key variables on the performance of flotation cells. The study makes use of a simulator for the froth phase of the flotation vessel, as the main purpose of this study is to separate the impact of different variables from one another. In experiments it is very difficult to separate the effect of variables from one another as a change in a singe input parameter, such as air rate, invariably also affects many of the other key variables, such as bubble size and bubble bursting rates.In order to achieve this a base case simulation that is typical of many of the rougher cells found in sulphide flotation circuits was carried out. Four key variables, air rate, incoming bubble size, surface bubble size and the fraction of the bubbles flowing out of the cell unburst, were varied in order to obtain the system.s response.The most significant results were obtained when the bubble size was varied. An increase in the incoming bubble size has the effect of reducing the pulp zone recovery, but increases the froth zone recovery. If it were possible to vary the incoming bubble size without influencing the overflowing bubble size, the impact of the change would be unclear because of these two competing effects. The effect of a change in the overflowing bubble size has an opposite effect on the froth recovery, with larger bubbles resulting in lower froth recoveries.A final interesting result is that all the effects examined affect the process to a similar degree, which implies that none of these variables can be disregarded, either in industry or in further research."

Jan 1, 2003

By Rodney J. Hundermark, Sharif Jahanshahi, Shouyi Sun

"The major platinum producers in South Africa make use of electric furnaces for the melting of PGM bearing nickel - copper concentrates. To gain better understanding of the furnace operation, research was conducted at CSIRO Minerals in Melbourne, Australia. One aspect of the research project was the investigation of the factors affecting the electrical conductivity of melter type slags.Electrical conduction in slags can occur through two mechanisms: ionic and electronic. There is good understanding of the ionic mechanism. In slags containing high levels of iron, the dominant mechanism is electronic. There is limited understanding of the electronic mechanism and one of the aims of the research was to investigate this mechanism further.Experimental work was carried out on Al2O3.CaO.FeOx.MgO.SiO2 slags similar in composition to the melter slags. Conductivity increased significantly with iron oxide content. Above 20wt% FeOx, electronic conduction was significant and the conductivity varied with the oxidation state of the slag. As the iron oxide content was increased further, the electronic mechanism became more dominant. The conductivity reached a maximum at around pO2 = 10-7 to 10-4 atm., although this value was dependent on the total iron oxide content and basicity of the slag."

Jan 1, 2003

By R. Marandi

Biosorption of heavy metals can be an effective process for the removal of heavy metal ions from aqueous solutions. In this study, the adsorption properties of nonliving (boiling in NaOH) biomass of phanerochaete chrysosporium. For Pb (II) and Zn (II) were investigated by using batch adsorption techniques. The effects of initial metal ion concentration, initial pH, biosorbent concentration, stirring speed, effect of temperature and contact time on biosorption efficiency were studied. Experimental results indicated that the uptake capacity and adsorption yield of one metal ion were reduced by the presence of the other metal ion. In the experiments the optimum pH value was found out 6.0. The experimental adsorption data were fitted to the Langmuir and Frundlich adsorption models. The highest metals uptake was calculated for Zn (II) and Pb (II) were 57 and 87 respectively. desorption of heavy metal ions was performed by 50 mM HNO3 solution. The results indicated that the biomass of p.chrysosporium is a suitable biosorbent for removing heavy metals ion from aqueous solution.

Jan 1, 2014

By J. K. Wen

The Mojiang nickel deposit is situated in Mojiang county, yunnan province, a tropical area in the southwestern China. The known geological resource (measured and inferred) includes 4 million tons of nickel sulphide ore at an average grade of 0.50% Ni and 0.34% As. Nickel minerals are mainly gersdorffite (NiAsS), millerite(NiS), morenosite (NiSO4?7H2O), and more than 50% nickel minerals is gersdorffite which contains arsenic. Pyrite is the dominant sulfide mineral, 22% in the ore and part of nickel minerals are locked in pyrite. It is difficult to attain the nickel concentrate quality allowed by a smelter and the acceptable nickel recovery through flotation due to the high arsenic in the ore and the nickel minerals locked in pyrite. The shake flask tests and column tests for nickel recovery from the Mojiang nickel sulfide ore had been finished by the end of 2003. The column bioleaching tests were carried out using the columns with diameter of 120 mm and height of 1200 mm, and 70% of nickel dissolution was attained in 300 days. A 10,000t pilot test heap was built in the Mojiang Nickel Mine by June 2003. The ore used in the test heap was supplied from the underground mine and was crushed to -20 mm before being feeding to the test heap, which is 4~5 m high, 30 m wide and 50 m long. The naturally adapted mesophile and moderate thermophile have been inoculated into the leaching pile by June 2003. The operating temperature in the heap ranges from 38? to 55?, varying with season. 30% of nickel dissolution was achieved in 3 months and the typical pregnant leach so-lution (PLS) contains 2~3 g/L Ni and 20~30 g/L Fe. The Ni sulfide which was produced by us-ing Na2S 10 t/t?Ni contains 16%~20% Ni and Ni recovery was 98%. 70% of Ni dissolution is expected in 12 months. The test heap was scaled up to 60,000 t of ore per year by mid of 2005. In this paper metallurgical studies and performance of the pilot test heap will be described. The results of mineralogy, shake flask tests and column tests on bioleaching of the nickel sulfide ore are reviewed. The key test heap operation parameters, the performance of bio-heap leahing-Na2S precipitation, ferrous oxidation-ferric precipitation-Na2CO3 precipitation, bacteria in the pile, water and acid balance, effluent disposal, capital and operation costs are also discussed.

Jan 1, 2014

By Danfeng Xu

The majority of the world?s nickel (Ni) resources occur as laterite ores, which are exceptionally complex, lower grade (<1.5% Ni) and expensive to treat using conventional smelting and high temperature/pressure autoclave methods. Heap leaching is a promising, less costly, alternative technology for processing low grade nickel laterite ores. However, significant technical challenges remain with Nickel laterite heap leaching, preventing its general adoption. This paper presents some highlights of laboratory column leaching studies undertaken to characterise, evaluate and optimise sulphuric acid leaching behaviour of Nickel laterite agglomerates. They provide basic but valuable information regarding Nickel laterite agglomerate structure stability and leaching performance under industrially-relevant, continuous acid irrigation conditions. In particular, Nickel and other key metals? (e.g. Co, Fe, Al and Mn) extraction rates, free acid concentration, bed slump and structural changes were determined at a given acid percolation rate as a function of time. Potential implications of the findings, for devising strategies for improved Nickel laterite plant heap leach operations are discussed. Keywords: nickel laterite, column leaching, agglomerates, leaching kinetics, acid consumption

Sep 1, 2012

By Renato S. Costa, Afonso H. Martins, Flávia D. Mendes

"This paper presents some important aspects regarding the ion exchange treatment of an Ni and Co sulphate acidic liquor using chelating resins. Chelating resins possessing iminodiacetic or bis-picolylamine functional groups were compared in terms of nickel and cobalt recovery. The experimental resin with bispicolylamine functionalities (Dowex M4195) was evaluated with respect to Ni and Co uptake, and compared with Rohm &Haas commercial chelating iminodiacetate acid resin. The Rohm & Haas chelating resin, Amberlite IRC 748, with its weakly acidic groups, did not work in acidic solution but exhibited good results at pH 4 and above. The resin that efficiently removed metals from high acidic solutions was the bis-picolylamine resin. Maximum nickel uptake values ranged between 85 g and 112 g Ni per Kg of resin.The experimental part dealt with the working conditions, resin characteristics and the influence upon the resin maximum exchange capacity of the following factors: nickel concentration, temperature, pH and resin-to- solution ratio. Based on the experimental data obtained, it has been proposed a innovative technological treatment."

Jan 1, 2003