Search Documents

By Wengui Su, Qi Zhang, Junce Wang, Zhijun Ma, Xingyuan Weng

"Mesoporous materials with large specific surface area, pore size, and pore volume have been widely used in many fields such as ion exchange, gas separation, adsorption, and catalysis. Mesoporous materials prepared using natural zeolite have the advantages of both acid and alkali resistance. In this work, mesoporous materials were prepared using natural zeolite as the starting material and diethylenetriamine (DETA) as a template. The resulting samples were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD) and N2 adsorption-desorption experiments. The influence of the crystallization temperature and crystallization time on the specific surface area, pore volume, pore size, and morphology of the resulting mesoporous materials are also discussed. Our results show that for an increase in both the crystallization temperature and time, the average pore size first increases then decreases, while the specific surface area first decreases then increases. Based on this work, we concluded that the optimal crystallization temperature was 2003 and the optimal crystallization time was 60 h. These conditions gave an average pore size of 17.93 nm, a pore volume of 0.048 cm3g-1, and a specific surface area of 16.48 m2g-1.INTRODUCTIONMesoporous zeolite, as the name implies, is a highly porous crystalline zeolite. This material is of interest due to its high hydrothermal stability, its adsorption and diffusion properties for macromolecules, and its excellent selectivity and activity as a catalyst. In recent years, it has become a hot spot among research of porous catalytic materials and has been widely used in petroleum and natural gas processing, fine chemical processing, various adsorption and separation tasks, and other uses (Carvalho & Urquieta- Gonzalez, 2015; Teh, Triwahyono, Jalil, Mukti, Aziz, & Shishido, 2015)."

Jan 1, 2016

By N. Afrin

The microstructure and tensile properties of AZ31B-H24 magnesium (Mg) alloy after friction stir welding (FSW) were evaluated. The grain size was observed to increase from approximately 5 µm to about 9 µm after FSW. The obtained Hall-Petch type relationship showed a strong grain size dependence of the hardness values. While the FSW led to about half of the yield strength of the base magnesium alloy, the ultimate tensile strength after FSW could reach about two thirds of that of the base alloy. The hardening capacity of the FSWed samples was about twice of that of the base alloy. The strain hardening exponent of the base alloy was found to be about 0.1 whereas it became larger than 0.3 for the FSWed samples. After yielding the base alloy showed a high initial and almost constant work hardening rate, corresponding to linear hardening stage II, followed by stage III with a decreasing hardening rate. Stage II linear hardening was observed to be absent in the FSWed samples.

Jan 1, 2007

By M. Phylli Bray

"Mining has the reputation of being a very ""macho"" industry. Recently, wider educational opportunities for women in nontraditional occupations and changes in mine technology have combined to make mining a viable career choice for women also. To benefit from this new resource, the mining industry faces the challenge of developing a different work environment from the one now burdened with sexism. Management supported initiatives are needed to facilitate such a transformation. The same rethinking of gender attitudes might also be extended to mining women in their traditional role as ""wife of"". The assumption that the male worker's wife is an unpaid adjunct is being questioned. It is suggested that women's separate concerns both as helpmate and as part of the mining workforce should be considered when planning for mining into the 21st century.IntroductionI must confess that, during the preparation of this paper, there have been many moments when I questioned my temerity. After all, I am not male, I am not an engineer, and I have never had a position in mine management. But as the wife of a mining engineer and a long-time resident of Northern Ontario mining towns, I do have an interest in the mining industry. This interest has had little to do with the technical and management aspects of the industry. Instead my research has been concerned with the impact the mining industry has on the people involved, particularly women, whether directly as employees or indirectly as wives. As I look toward the 21st century, I believe that the whole question of gender relations in the mining industry is one of the critical management issues smouldering below the surface."

Jan 1, 1995

By Frank Baczek, R. Q. Honaker, D. P. Patil, B. K. Parekh

Fine refuse slurry impoundment is a requirement for the coal industry to dispose the fines. Impoundment maintenance is an on going problem for the coal industry and its breakage creates environmental as well as financial problems. Deep Cone thickener technology which has been successfully applied in the alumina industry to dewater red mud was evaluated for fine refuse slurry. Preliminary obtained in a pilot-plant test showed that properly flocculated conventional thickener underflow slurry could be thickened to about 52.5 wt % solids and could replace belt filter press. The Deep Cone thickener was also found to dewater clean coal slurry to about 70 wt % solids. Further testing of the unit at other coal preparation plant is in progress.

Jan 1, 2004

By F. Rosenblum, P. Spira

"Self-heating of broken sulphide ore or waste rock underground can lead to ignition and cause serious problems in a mine operation. An extensive study has demonstrated that it is caused by oxidation of certain species of pyrrhotite. Self-heating was found to take place in two stages, first progressing from ambient temperature to 1000C with exothermic formation of elemental sulphur in the presence of moisture and oxygen, and proceeding to a second stage in which the sulphur oxidizes to SO2. Ignition may eventually follow. An apparatus was developed to assess the propensity of sulphide rock to self-heating and the potential for hazardous behaviour. The effect of temperature, time, rock size, and surface treatment with chemicals is presented. On the basis of these results, possible approaches for preventing a runaway reaction are suggested for further investigation.IntroductionThe oxidation of sulphide ore, waste rock or tailings backfill, which may cause hazardous conditions underground through heating, oxygen depletion and, in some cases, fire, is well documented (Farnsworth, 1977; Ninteman, 1978; Rosenblum et al., 1982; Reimers, 1987). The self-heating mechanism, nevertheless, has not been satisfactorily explained. The onset of heating from ambient temperature, in particular, has not drawn the attention of researchers. In the course of a previous study (Rosenblum et al., 1982) aimed at finding a method to assess the hazard from using sulphide tailings as backfill, the authors developed an apparatus to measure self-heating rate under controlled, near ambient conditions. This has since provided decisive information in backfill investigations in the Noranda Group.The test methodology devised for tailings failed to predict self-heating in a broken waste rock known to be active. Upon repeated testing, however, a freshly crushed sample began to exhibit appreciable heating and oxygen uptake (Fig. I). After 14 tests, the self-heating rate reached a plateau of about 4O°C/h and then fell progressively to < 5°C/h after 30 tests. It was hypothesized that weathering in the presence of moisture and oxygen during testing had caused the onset of self-heating. Active tailings, on the other hand, are exposed to natural surface oxidation and need not be weathered to show heating. Based on this finding, a new apparatus was developed capable of simultaneously weathering a sample of rock and monitoring its self-heating behaviour."

Jan 1, 1995

By R. G. McDonald

"High iron solution concentrations often result in the formation of basic ferric sulfate during the high temperature oxidation of sulfidic materials such as base metal and refractory gold concentrates. Consequently, the “Hot Cure Process” followed by limestone neutralization is required to facilitate subsequent processing and/or disposal of the leach residue. The present paper discusses strategies that can be employed to influence the composition and nature of the high-iron content leach residues produced during pressure leaching.INTRODUCTION Control of iron deportment in hydrometallurgical processing remains a key challenge for a range of reasons. Strategies generally relate to the control of conditions under which iron is optimally rejected (Demopoulos, 2009). Supersaturation provides the driving force for crystallization and this can be controlled by a number of factors that include (1) pH and/or Eh control, (2) the presence of matrix anions and impurities, (3) dilution, (4) complexation and dissociation and (5) manipulation of the rate at which the metal to be precipitated is released to solution. Each of these factors is impacted by temperature. Good control of crystallization is essential to the control of precipitate properties such as the degree of crystallinity, stability, particle size and quality which covers both the extent of impurity uptake and suitability of the precipitate for waste disposal. The quality and properties of iron precipitates in turn can impact downstream processing. It is the aim of this paper to discuss the generation of iron-containing residues produced during the pressure oxidation of sulfidic ores and concentrates and how the nature of these can be controlled to potentially facilitate further processing. A brief overview of several related topics will now be given and include, where relevant, discussion of work undertaken in our laboratories. In addition, brief discussions of selected process options that enable good control of iron rejection will be provided."

Jan 1, 2016

By W. J. D. Stone

"INTRODUCTION Over the past decade, a number of publications have described the advances in High Intensity Wet Magnetic Separation. A number of significant, but small capacity installations were made and are successfully operating. These were followed some three years ago by larger installations treating ilmenite gravity concentrates; at least one machine treating 25 tons per hour of new feed was installed and is successfully operating.However, this still did not result in general acceptance that High Intensity Wet Magnetic Separation could be applied on a large scale. Neither did it dispel the feeling that High Intensity Wet Magnetic Separation was ""expensive"" and hence, confined to small scale – high value applications suchas the cleaning of tin concentrates. In addition, there is the usual reluctance of being the ""guinea pig"" which has resulted in waiting to see ""someone else"" make the first large installation decision. Such a decision and installation has now been made.Therefore, the purpose of this paper is to show that High Intensity Wet Magnetic Separation has been commercially accepted on a large scale and to show its general application to the base metal mineral industry.Examples are confined to a few specifics due to the large volume of preliminary test data that is available. The art has now reached the stage where much of the preliminary work should be taken through to serious evaluation."

Jan 1, 1971

By H. Tokuichi, H. Ohta, K. Sato

A physical separation technique of tantalum capacitors from waste print circuit boards is in a development phase in Japan. A tantalum capacitor consists of an exterior coating of resin (epoxy resin) mixed with silica fillers and a sintered tantalum compact, the latter of which is impregnated with manganese dioxide (MnO2). In this study, we developed a process to recover tantalum oxide from tantalum capacitors by roasting, fluidized-bed separation, and hydrometallurgical treatments. Our aim was to recover tantalum oxide with high purity from waste tantalum capacitors. In this process, the exterior resin was selectively decomposed by roasting without oxidation and pulverization of the sintered tantalum compact at a proper temperature. Furthermore, the decomposed resin with silica filler on the surface of the sintered tantalum compact was mostly removed by fluidized-bed separation. The surface of the sintered tantalum compact was cleaned by ultrasonic irradiation in an acid solution to remove the MnO2 paste as well as residual Ag paste and silica filler. The impregnated MnO2 in the sintered tantalum compact was leached as Mn(II) ions using acid solutions via the reducing effect of tantalum metal to recover purified tantalum oxide.

Jan 1, 2014

By Paul J. Beck

The impact of mining development on the environment can be minimized through comp careful construction and accurate monitoring. Key to meeting these objectives is t information at all stages of design, development, operation and decommissioning. This paper will describe cost-effective means of gathering and managing reliable fiel groundwater flow and surface water regime within and surrounding the mine site, as localized contaminant plumes associated with mine operations, and monitoring ground quality. Recent research has led to the development of inexpensive, easy to install syst sampling/monitoring from different zones within a single borehole. Advances in elect developed small diameter probes and pumps for measuring water levels and taking wat continuous monitoring stations in remote areas can be colldeacttaeldo gaguetrosm aatnidc adlolwyn luosaidnegd from a central facility using telemetry systems powered by direct, battery or solar radio frequency, landline or cellular telephones, and satellite. Two case studies will illustrate the use of datalolgagregres sacnadl et eblaesmient rwyi dien mao nitoring sc and the use of multilevel samplers for managing a contaminant plume.

May 1, 2004

By Chris Brothen

The introduction of new technology in mine operations has provided real opportunities for increased efficiencies and production gains which translate into enhanced profits. Computing and network technology usage has become integrated into surface mining operations and on average these investments in technology have proven beneficial for efficiency and productivity improvements. Embracing new technologies however, does not guarantee positive results. The expectations or improvements derived through the technology must be confirmed and clarified well before implementation. Tire Pressure and Temperature Monitoring Systems are an excellent example of an existing technology that can provide full time automated performance measurements of tires operating under harsh conditions and environments. Prompt warnings or alarms signaling when a tire has exceeded operating capacities will provide savings through lowered maintenance costs and increased productivity. To truly quantify the projected savings in tire life, fuel consumption, and increased levels of production, all costs associated with the technology, both direct and indirect must be considered. Apart from the initial cost of the system implementation, ongoing maintenance and support costs must be considered as well as the costs of system integration into existing mine operations

May 1, 2008

By H. Gharahbagheri, S. Shafiei Zadeh, H. Hassan Nejad

Waste Electrical and Electronic Equipment (WEEE) is one of the fastest growing types of solid waste in the world, and often contains precious metals, especially gold. Gold processing and recovery from secondary materials, especially WEEE, have been under investigation for more than a decade now; however, a comprehensive review that illuminates the future path is missing in the literature. The aim of this short paper is to discuss the recent advances in gold processing and recovery from secondary electronic materials and why it has not yet become practical. The role of pyrometallurgical and hydrometallurgical methods, as well as their advantages and disadvantages will be discussed; however, the focus will be on Biosorption and recent advances.

Jan 1, 2014

By Robin Perry, Claude Bazin

"Discrete transfer functions which use the grinding circuit feed tonnage to predict mass flowrates at reagent addition points in a flotation circuit were calibrated using a dynamic grinding/flotation circuit simulator. Predicted mass flow values are multiplied by reagent addition ratios to obtain actual reagent flow. The transfer functions are currently integrated into the distributed control system of Les Mines Selbaie.IntroductionThe development of adequate tools for the control of flotation processes is a continuous challenge. Since the early 1970s there have been numerous publications dealing with practical aspect of control of flotation processes. Most plants use a combination of feedback and feedforward controls to reduce the effect of the following flotation process disturbances (McKee, 1991):• changes in throughput;• changes in feed grade;• changes in particle floatability (size, liberation, surface oxidation ... ); and • deliberate changes of setpoint;Feedforward control manipulates variables such as reagent and/or air flow rate to attenuate the effect of disturbances such as changes of feed rate and mineral content. The feed forward strategy is driven by measurements of these disturbances. Feedback control is used to maintain process variables to targeted set-points of concentrate or tails grades. The feedback control action is driven by deviation from the set-point, caused by a deliberate change of set-point or disturbances.This paper proposes a method to improve feed forward control schemes by the addition of a simple model for solids transportation. The feedforward strategy considered in this paper is the ratio type, in which the manipulated variable is changed according to a predefmed ratio between this variable and the measured disturbance. A typical example is the ratio of the reagent addition to mass flow of ore.The paper reviews the state of the art in feed forward control strategy applied to flotation processes and describes the method used for predicting mass flow rates. The last section shows an application of the method in the Les Mines Selbaie flotation circuit."

Jan 1, 1994

By Gary M. Bone

The autonomous control of vehicles interacting forcibly with their environment, such as dozers and tractors, is an unsolved and challenging problem. Forces and motions are inherently coupled between the tool and the means of vehicle propulsion. Furthermore, they are often operated within uncertain and unstructured environments, such as those encountered in underground mining. There is a growing industrial interest in the development of robotic vehicles to improve productivity, efficiency and safety in mining and construction. This paper focuses on the modeling and control of autonomous robotic dozing for a material removal operation. A dozing process model has been developed based on observations of both a fullscale dozer and a scaled-down version. The model characterizes the dynamic interactions between the blade position, material accumulation on the blade, material distribution in the environment, and the motions of the dozer. The dozing control objective is to remove the loose material as rapidly as possible by driving forwards at full power while automatically raising/lowering the blade in response to sensor measurements. Two different controllers were developed to meet this objective. The first controller is based on a set of heuristic rules, and the second is an optimal controller based on the dynamic model. An instrumented scaled-down robotic dozer and dozing environment, designed to emulate the full-scale operation, are used to implement the controllers and compare their performances over multiple dozing passes. Experimental results are presented showing that the model-based controller increased the material removal rate by 33% compared to the rule-based controller. Lastly, technologies for full-scale implementation are discussed, followed by proposed future work and conclusions.

Aug 1, 2013

By Neri Roux, Ross Gilders, Yemi Oyediran, Leo Cheung

Quest Rare Minerals Ltd. is developing their Strange Lake B Zone REE deposit located in Northern Quebec. An extensive batch bench scale testing program was launched to investigate open circuit rougher flotation performance under different conditions. The objective of the flotation study was to demonstrate the effectiveness of rejecting gangue minerals to flotation tailings while concentrating rare earth elements as well as yttrium, zirconium, and niobium into a concentrate suitable for further hydrometallurgical processing. Mineralization of interest at Strange Lake occurs within peralkaline granite-hosted pegmatites and minor aplite. The REE and high field strength element (HFSE)-bearing phases are hosted primarily in pegmatites as relatively fine-grained phases or pseudomorphs. The gangue phases comprise of quartz, feldspar, amphibole, and pyroxene. Potential ore minerals comprise predominantly of kainosite, gerenite, gadolinite, zircon, pyrochlore, and gittinsite. These complex mineralogical characteristics increase the difficulty for processing and provide a challenge for choosing the correct reagent scheme in rougher flotation. Process options including reverse flotation to reject the gangue minerals and de-sliming prior to the direct rougher flotation were investigated. Optimization trials were conducted using various reagent regimes and under different flotation conditions. Encouraging results were found using a combination of collector reagents supplied by Cytec Canada Inc.

Jan 1, 2014

By N. Aydogan, H. Dundar, Å. Partapuoli, A. Fredriksson, P. Wikström, K. Tano, G. Adolfsson

The Autogenous milling of ores holds an increasing attraction as the focus moves towards reducing energy usage, both direct and embodied in grinding media. However, most of the early AG mills were converted to SAG for improved stability and increased throughput. This imposes a huge penalty in steel grinding media consumption. The LKAB iron ore operations in Sweden process highgrade magnetite through fully-autogenous milling lines to a final product P80 of about 45µm. The outcomes of P9O AMIRA research surveys, covering a wide range of mill fillings and throughputs and with different feed blends, are presented. Insights are provided on operational strategies, opportunities, the influence of feed size control and balancing the blend of competent gangue and softer magnetite. Areas of importance in the successful operation and control of energy-efficient autogenous circuits are highlighted.

Jan 1, 2012

By George P. Demopoulos

In this paper the author will provide an overview of over 20 years of research & developments in the area of hydrometallurgical arsenic immobilization that culminated recently in the industrial implementation of the atmospheric scorodite process. The paper will consider various aspects of arsenic fixation in the non-ferrous metal industry from the iron-arsenic co-precipitation process employed to arsenic-bearing effluent solutions; to autoclave processing of arsenical copper and gold feedstocks and the fate of the in-situ formed iron sulphato-arsenate precipitate phases; the precipitation and stability of scorodite; the possible stabilizing role of mineral phases like yukonite, and the development of "scoroditeplus" processes employing novel encapsulation strategies. Emphasis is placed on the characterization and long-term stability of the various forms of arsenic-immobilized phases under either oxic or anoxic conditions over a wide pH range and the establishment of critical links between process parameters and hazardous material stability, contributing thus to advancement of new generation safe and sustainable waste management technologies.

Jan 1, 2014

By Tedd E. Lister, Andre Anderko, Peiming Wang

Mobile electronic devices such as smart phones and tablets are a significant source of valuable metals that should be recycled. Value metals in phones are gold, palladium, silver, copper, cobalt and nickel. Devices now contain increasing amounts of rare earth elements (REE). Effective recycling schemes should include the recovery of these critical materials. Targeted recycling of items containing more of the less available critical materials could address their future criticality. This presentation will describe an electro-hydrometallurgy approach to efficient recycling of metals from scrap mobile electronics. The electrorecycling (ER) process generates oxidizing agents at an anode while reducing dissolved metals at the cathode. Development of the process involved generation of E vs pH diagrams, complemented with metals dissolution experiments used to assess the effectiveness of various solution chemistries. Although several schemes were envisioned, a two stage process has been the focus of work: 1) initial dissolution of Cu, Sn, Ag and magnet materials using Fe+3 generated in acidic sulfate and 2) final dissolution of Pd and Au using Cl2 generated in an HCl solution. Results from laboratory work will be discussed.

Jan 1, 2014

By Curtis Rempel, John Bartlett, Alex Holtzapple

METSIM is a powerful program capable of modelling and simulating every known metallurgical and inorganic chemical process. METSIM is used by companies throughout the world to design, simulate and control operations from mine to tailings and everything in between. At its absolute simplest, METSIM can be used to create a process flowsheet. METSIM modules and built-in unit operations cover mass and energy balances for either steady-state or dynamic simulations of mine, stockpile, heap leach, material handling, comminution, beneficiation, hydrometallurgy, pyrometallurgy, gas and steam handling, and tailings management processes. Data for the material being processed can include mineralogy, particle size analysis, grade by size or multicomponent size analysis, washability data, mechanical, physical and thermodynamic properties. METSIM is written in APL (A Programming Language). Unlike C++, APL is simple and easy to learn, allowing the user to program whatever they can imagine, without first obtaining a degree in computer science. METSIM can also interface with EXCEL and other software through dynamic data exchange (DDE), allowing data to be imported and exported for viewing, analyzing and controlling. METSIM can answer simple or complex metallurgical and process questions allowing the user to predict and engineer without the issues of clumsy and tortuous spreadsheets.

Jan 1, 2014

By Robert B. Parsons

"This article is based on a paper presented by Jim Scott at the 1988 annual convention of the Prospectors and Developers Association of Canada. The paper suggests a number of factors that might be taken into account in negotiating royalty terms.IntroductionRoyal ties are a part of mining life in Canada. They are used by many kinds of individuals in many kind s of situations. Prospectors commonly take royalty interests back when they transfer claims to development companies. Mining companies disposing of undeveloped (or sometimes even developed) properties are often paid at least in part by royalties. Royalties are even used by institutional investors with no other connection with the resource industry.Such different royalty holders have different investment goals, different cash flow requirements, and different risk / return preferences. These differences have given rise to a number of different royalty type s. These types range from the simplest cents-per-ton royalty (where the operator pays a royalty at a fixed rate per ton milled) to net smelter return or ""NSR"" royalties (where the royalty is based on a percentage of the operator&apos;s NSR) all the way to net profit interest or ""NPI"" royalties (where the royalty is based on the operator&apos;s bottom-line net profit),The fundamental difference between the many royalty types is in the risk/ return relationship. The cents-per-ton royalty, for example, is relatively risk-free. Of the many economic factors which affect a mine, the only one which will affect the royalty holder is the amount of ore physically milled. On the other hand, the potential for significant gains under a cents-per-ton royalty is also very limited. The royalty holder will not share in any increases in the market price of the end product or any cost reductions achieved by the producer."

Jan 1, 1988

By Chris McBean

Due diligence mistakes ? lost opportunity ? High profile write-downs and cost overruns ? Result ? tight market for financing ? Implications for due diligence ? need to get it right ? maybe only one chance ? Where should focus be?

May 1, 2013