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By V. G. Papangelakis, G. A. Moldoveanu

"Rare earths adsorbed on clay minerals are easily recovered via ion exchange during leaching with inorganic monovalent salt solutions. The leaching efficiency of various salts at 0.5M and 25°C was investigated as a function of cation type and salt system (sulphates vs. chlorides). (NH4)2SO4 was identified as the lixiviant of choice and a procedure was established to investigate the influence of lixiviant concentration, temperature, pH and agitation on desorption kinetics and REE extraction levels. It was determined that the kinetics were fast and the optimum leaching conditions (for >80% total REE extraction) required pH below 5 and moderate temperatures (<50°C). INTRODUCTIONRare earth elements (REE) are at the core of numerous advanced applications due to their various uses in high strength permanent magnets, lasers, automotive catalytic converters, fiber optics/superconductors, and electronic devices (as phosphors in TVs and display screens for computers and cell phones). Because of the ongoing development of new technologies, there is an increased demand for REE in the international market, with emphasis on identifying new resources to insure an adequate supply for present and future use. World production of rare earths is dominated by China, the United States and Australia; however, in terms of resources, China dominates the world potential with reserves estimated to be over 90% of the total (Chen, 2011).The main commercially significant REE sources, as reviewed by O’Driscoll (1991) are bastnasite (carbonate) and monazite (phosphate) minerals, containing up to 70% wt. rare earth oxides (REO). In spite of being high grade, these ores are associated with elevated recovery costs due to difficulty in mining, separation and beneficiation. Moreover, aggressive conditions are required to solubilize the REE from the mineral, such as leaching with hot, concentrated acids or baking in 70% NaOH (Gupta & Krishnamurti, 2005)."

Jan 1, 2012

By T. G. Phillips

"This paper gives an inside look at a bulk terminal and describes the preparations that must be made by a company in developing such a terminal and its position in today's traffic pattern. The following headings cover the subject material: (a) Traffic pressures, their detection and measurement, (b) position in the traffic flow -selection of site, (c) transportation connections -present and possible future routes, (d) engineering studies and costs, (e) contracts, the basic material for insured traffic, (f) financing, (g) budgetary control, (h) development of new techniques, (i) growth into new cargoes or cargo-handling methods and (j) consolidation."

Jan 1, 1968

By Christopher R. Lattanzi

"Discounted cash flow analysis provides a means of relating the magnitude of expected future cash profits to the magnitude of the initial cash investment required to purchase an asset or to develop it for commercial production. The objectives of discounted cash flow analysis are to determine:.. The net present value of a stream of expected future cash revenues and expenditures... The rate of return which the expected future cash flows will yield on a given level of initial cash investment.In the case of mineral properties, discounted cash flow analysis is generally accepted as the preferred method of valuation, whenever sufficient data are available to permit its reasoned application. Sufficient data are required to support estimation of all of the individual elements of cash revenue and cash expenditure which will be associated with the development and operation of the property, up to the end of its estimated life. It is the accuracy of these input estimates which determines the validity of the resulting determinations of profitability and rate of return on invested capital.In undertaking any discounted cash flow analysis, it is important to recognize certain fundamental attributes of the mining industty:.. The basis of any mineral development is the existence of an ore reserve... Costs are determined by the number of tonnes mined and processed, while revenues are determined by the number of pounds or ounces of metal produced. The two are related by the recovered grade of the ore... Profit is typically more sensitive to changes in revenue than it is to changes in cost... Commodity price is a principal determinant of revenue, but it is also the factor with which is associated the greatest level of financial risk.In the end, of all of the factors which must be considered in the discounted cash flow valuation of a mineral property, the most significant are the reliability of the reserve estimate, particularly with respect to recovered grade, the price at which the product is to be sold, and the risk of not maintaining the projected level of price."

Jan 1, 2003

By H. Utsunomiya, J. Su, K. S. Tamimi, S. Yue, M. Sanjari, L. Kestens, A. S. Kabir, R. Petrov

The recrystallization and texture evolution of AZ31 sheets obtained through two stages was investigated at different stages of post-rolling annealing. The specimens were rolled at the temperature of 100? and at a fast speed of 1000m/min and low speed of 15m/min with a reduction of 30% in one pass. The results show thatAZ31B sheets rolled at 15 m/min and 100 °C has fractured for reductions of more than 30% per pass. However, by increasing the rolling speed to 1000 m/min the rollability was improved significantly and the material can be rolled to reductions of more than 70% per pass. The high speed and heavily deformed materials are fully recrystallized even at 100 °C.

Jan 1, 2015

By A. M. Martinez, L. Melis, R. C. Peláez, L. G. Garcia

Orovalle Minerals S. L. operates a copper/gold mine in the Asturias region of northern Spain, with the operation dating back to December 1997. The feed to the El Valle mill, consisting of oxide/sulphide (skarn) mineralization, is highly variable, even on a shift by shift basis and presents challenges to the mill operating staff on a daily basis. The mineralogical characteristics of the ore are quite complex with copper present as native copper and sulphides as well as copper minerals with deleterious elements. Gold is present as native gold and electrum. The mill circuit includes SAG/ball mill grinding, gravity recovery of native copper and gold, flotation of copper concentrate, carbon-in-leach gold recovery and SO2/air cyanide destruction. The paper will provide a description of the different unit operations and present operating data of the mill operation.

Jan 1, 2019

By R. Poulin, M. R. Samis

Real options valuation is an alternative net present value framework that is able to incorporate both management flexibility and dynamic project risks. In this paper, management is considering the development of a satellite low-grade zone while operations in a developed high-grade zone continue. If the lowgrade zone is developed prior to high-grade zone exhaustion, mine capacity must be expanded before additional production from the low-grade zone can be processed. This expansion can be avoided only if low-grade zone development is delayed until the high-grade zone is exhausted. The real option model presented here allows the development and capacity expansion decisions to be reconsidered on a discrete half-year basis. It delineates price regions, for given levels of high-grade zone reserves, in which it is optimal to develop the low-grade zone, defer low-grade zone development and abandon the mine irrevocably.

Jan 1, 2006

By J B. Magee

Sheep Creek Mines Limited has developed several operating techniques that have greatly assisted in keeping unit costs at reasonable levels. Some of the techniques, as described in this paper, include organization, accounting, warehousing, bonus and contracts. INTRODUCTION THIS paper is a non-technical report on operating techniques developed by Sheep Creek Mines Limited at their Mineral King mine, located near lnvermere, B.C. Depressed metal prices and continually rising labour and materials costs have necessitated a continuous search for method to keep operating costs down. The newly developed techniques and practices have greatly assisted in maintaining unit costs. Sheep Creek Mines Limited is a mining company incorporated under the laws of the Province of British Columbia. The Company&apos;s share capital is 3,500,000 common shares, witl1 a par value of 50 cents each, of which there are 1,875 000 shares is-sued. The Company has eight di-rectors. The administration, exploration and accounting offices are located in Nelson, B.C. The Company&apos;s working capital is approximately $1,500,000.

Jan 1, 1963

By G. M. Behrend

"AbstractMeasurement and control systems in minerals processing plants are usually well thought out and designed. The criteria and design parameters have been interpreted correctly.However, these systems often fail to perform satisfactorily or break down altogether as a result of in-plant conditions which are unpredictable and over which the instrument systems designer has no direct control. The foresight necessary to anticipate the problems and allow for them in the systems design can only be generated by experience.This paper lists the most common of these problems and offers practical methods for their solution. It then follows with an analysis of instrument installation practices and comments on special points that need watching.Finally, instrument maintenance is discussed with a view to achieving good maintenance at the best possible economy.Good MeasurementGeneralTHE MINES and mineral processing plants of the nineteen seventies, after decades of sensible caution, have now committed themselves to extensive automatic control. X-ray analyzers are freely specified. Sample acquisition systems are efficient and automated, computers are reliable and relatively cheap, and computer control systems in conjunction with the new analyzers are operating in a good many plants and are proving to be profitable.The sight of shift foremen and floor operators assembled in front of a TV-tube and taking a computer data display as gospel truth is quite common now, and yet was quite unthinkable only ten years ago."

Jan 1, 1977

By M. Potesser

Higher prices for natural gas or oil have motivated the copper industry to reexamine the modes of oxygen and oxy-fuel burner usage at operating plants. With rising energy costs and the growing importance of environmental protection, burner usage and burner operations have become the focus of several investigations and optimization efforts. One possible approach to lower energy usage is through combustion using tonnage oxygen. When such oxygen is used, the flame temperature increases and operational efficiency is improved. As well, with the correct technology, due to the presence of lower levels of harmful substances such as NOx in the off gas, there is improved environmental performance. As regards copper production, furnaces are employed for both concentrate smelting or for melting and casting operations. The use of tonnage oxygen in concentrate burners for smelting provides for a higher thermal efficiency. For furnaces employed for melting, air-operated burners may in fact have an initial advantage because a long radiant flame is typically generated, thus providing for a higher degree of heat transmission. This paper describes the new experimental burner chamber of Messer Austria GmbH which provides for testing of the combustion of natural gas with oxygen or oxygen-enriched air and the use of special water cooling ducts that simulates a metal charge during melting, The operational effectiveness of the burner is determined from temperature and off-gas analysis data. The paper also discusses future trends in burner technologies including a new patented burner. Cu2007 - Volume III (Book 2) The Carlos Diaz Symposium ou Pyrometallurgy Edited by A.E.M. Warner, C.J. Newman, A. Vahed, D.B. George, P.J. Mackey, A. Warczok Toronto, Canada,

Jan 1, 2007

By I. Farr, M. R. Mock, J. C. Robison

"HPAL and POX autoclave vapor-space gasses are vented through an autoclave PCV (Pressure Control Valve). The downstream steam-born mist of liquid droplets and solid particles travels in excess of 1000 m/s with megawatts of kinetic power at temperatures up to 160 C. The characteristics of downstream states often result in problems with corrosion, erosion, noise and vibration. Comprehension of those and related characteristics aids in improved pressure control, overpressure control and autoclave level control. We introduce compressible multiphase flow concepts and constructs germane to such flow including choked flow, continuous phase change, shock waves and supersonic flow plumes. Flow modeling based on first principles quantitatively predicts such flows providing a tool for component sizing and a method to estimate effects of water injection on flow. Insight deduced from modeling aids in mitigation of afore mentioned problems of which we share some from-site examples.INTRODUCTION First principles related to fluid thermodynamics and compressible flow have been employed akin to their application in the rocket industry. We will present the results of the application of those principles conceptually and authentically without mathematical rigour while using language of the pertinent disciplines. The autoclave (AC) vapor space over the slurry of a POX (Pressure Oxidation) or HPAL (High-Pressure Acid Leach) system (depicted in Figure 1) is vented via a PCV (pressure control valve) followed by certain ducting, and perhaps a nozzle, before exiting at atmospheric (typically) pressure. As indicated by its name the PCV controls the AC pressure as the flow control component of a pressure control loop."

Jan 1, 2017

By Jose Alberto Gonzalez, Said Sharif Mahboob, Jeffrey L. Shepherd

"During the industrial electrowinning of zinc, uneven growth can cause short-circuits and make the deposits more sensitive to the presence of impurities that can significantly impact current efficiency. To produce levelled zinc deposits, additives such as glue, licorice and sodium silicate are often added to the electrolyte. Even in the presence of additives, uneven zinc growth still takes place because of the combination of hydrodynamic and electrolysis conditions in the cell house. Recent advancements in imaging spectroscopy and scaling analysis have opened an avenue to further study the effects of additives on zinc growth morphology. In this study, Atomic Force Microscopy (AFM) and scaling analysis have been used to monitor zinc growth characteristics including roughness, periodicity, aspect ratios and growth mechanisms as a function of electrolyte composition as well as deposition time. Zinc was electrodeposited from an industrial electrolyte containing a host of additives onto an aluminum cathode with a platinum wire serving as the anode. AFM images of the samples were collected to obtain 3D topographical information on which scaling analysis was performed to extract details on root-mean-squared (rms) roughness, periodicity (grain size), aspect ratio of surface features and growth mechanism. This analysis provided information on the mechanism by which the previously mentioned variables can impact short term growth and also provided a prediction of expected growth at long deposition times.INTRODUCTIONElectrowinning is one of the final stages in the industrial production of zinc metal. It is during this process where dissolved zinc ions undergo electro-reduction from an acidic electrolyte onto an aluminum cathode and are later recovered by stripping the zinc metal from the substrate. However, due to the nature of zinc growth as well as the various operating conditions, zinc deposition may occur unevenly, sometimes causing short-circuits that can cause electrode damage and reduced zinc production."

Jan 1, 2016

By E. L. Bruce

EUROPEAN Russia is mainly a great plain, the average elevation of which is only 600 feet above sea level and the maximum elevation less than 1,200 feet (Figure 1). The main divide between the Arctic ocean and the Black sea and Caspian sea is an indistinguishable topographic feature from which the Dneiper and Don rivers flow southward to the Black sea and the Volga river to the Caspian. The valleys of these rivers are but little below the general level (Figure 2). To the south, this great, rolling plain is broken by a low ridge of Precambrian gneisses and intrusive rocks. The Crimea is an upland from which the descent to the Black Sea coast is precipitous (Figure 3). The Ukrainian Soviet Socialist Republic occupies the southern part of the plain. It is the southwestern unit of the Union, bordered by Rumania and Poland on the west and by the Crimean Soviet Socialist Republic on the south.

Jan 1, 1938

By J. R. Parga T., P. J. Valenzuela G., L. S. Quiroz C., P. Guerrero G., J. L. Valenzuela G.

"Pressure oxidation is a hydrometallurgical pre-treatment process used for refractory auriferous sulfide ores. In the work reported here, a refractory pyrite ore sample from the Mulatos mine, Sonora, Mexico was characterized. The sample was subjected to atmospheric cyanidation, and simultaneous pressure oxidation and cyanidation under different conditions of temperature and pressure. The mineral characterization showed that pyrite is the main species in the sample. The gold extraction tests were carried out in an 1-litre Parr pressure vessel at a temperature range of 90-120 °C, a pressure range of 87.5–150 psi (using oxygen), and a cyanide concentration range of 0.8-1.2 %wt. The gold extraction results showed that diffusion through product layer is the rate controlling step.INTRODUCTIONIn hydrometallurgical precious metals extraction, the most commonly used process is sodium cyanide leaching, as shown in the next reactions involving gold and silver (Fleming, 1992; Marsden & House, 2006):4Au(s) + 8CN- (aq) + 2H2O(l) + O2(g) ? 4Au(CN)2 -(aq) + 4OH- (aq) (1)4Ag(s) + 8CN- (aq) + 2H2O(l) + O2(g) ? 4Ag(CN)2 (aq) + 4OH- (aq) (2)“Refractory” auriferous ores or concentrates often contain gold and silver locked inside other sulfide phases such as pyrite. This renders cyanidation ineffective, so oxidative pre-treatments are used in order to convert the sulfide minerals into porous oxide minerals and make cyanidation work more efficiently. Reaction (3) shows the oxidation of pyrite in alkaline media and the formation of the porous oxide (Koslides & Ciminelli, 1992):2FeS2 (s) + 15/2 O2 (g) + 8H- (aq) ? Fe2O3 (s) + 4SO4 2- (aq) +4H2O(l) (3)A process of simultaneous chemical pressure oxidation and cyanide leaching for a flotation concentrate produced in the mine of Bacís, Durango, in Mexico, gave good results (Parga et al., 2007). In the study presented here, it was intended to use this treatment for a refractory pyrite mineral from the Mulatos mine in Sahuaripa, Sonora, Mexico, modifying variables such as pressure, temperature and cyanide concentration to find the best conditions for oxidation and leaching."

Jan 1, 2012

By R. D. White

"The Cumberland Basin of Nova Scotia has long been considered a structural basin by virtue of the elliptical outcrop and inward dip pattern of the Pennsylvanian outcrops. Recent published and unpublished data indicate that subsidence began in the late Devonian, perhaps resulting from a graben or rift. The Mississippian sediments which filled the growing depression were continental, lacustrine and marine with evaporites. The cessation of the riftforming processes is recorded by the alluvial swamp-type sediments of the Pennsylvanian which filled the depression. In excess of 25,000 feet of Carboniferous rocks are believed to be present in the deepest part of the Basin. Starting with the rift hypothesis, we can speculate on the kinds of sediments, their location and the structural features present beneath the Pennsylvanian surface. Using surface exposures and a limited amount of subsurface data, we theorize that (1) the Mississippian evaporites acted as glide zones which effectively divided the Basin into two horizontal structural layers. The rocks above the evaporites, responding to Appalachian stresses, formed the long diapiric folds with cores of overthickened evaporites. Below the evaporites the structures are related to movements of the rift floor, compaction closures and structures formed by differential horizontal movements of the rift walls. (2) The rift, in its deeper parts, will have more and a greater variety of marine rocks than the outcrops indicate. Should the rift hypothesis be correct, the possibility of finding hydrocarbons is enhanced."

Jan 1, 1972

By C. L. Lewis

"The development of computer process control at the Lake Dufault concentrator is reviewed and the on-stream X-ray analysis -computer system is described briefly. Some applications of the computer in metallurgical process control are described.The computer sequences slurry sample streams to the analyzer and translates the analytical results from voltage signals to elemental percentages. The required flotation reagent flow rates are calculated from analyses and mill-feed tonnage rates and the reagent feeders are set automatically to provide such flow rates. X-ray calibration time has been reduced from about 45 minutes to 15 minutes by the use of a computer program. Metallurgical and operating personnel have acquired the ability to program the computer and have extended the system capability to allow the calculation of recoveries, averaging of mill data, application of ore specific gravity in grinding control, control of oxidized ore flotation and the development of an economic recovery program."

Jan 1, 1971

By G. W. H. Norman

"The La Corne molybdenite-bearing veins, discovered in 1915, lie halfway between Amos and Val d'Or near the southwest corner of La Corne township, Abitibi county, Quebec. The Molybdenite Reduction Company, which carried on operations during 1927 to 1930, sank a 200-foot inclined shaft to develop the property and produced about 22 tons of concentrntes from a 30-ton mill during 1929. Hollinger Consolidated Gold Mines, Limited, carried on further underground exploration in 1930. The Molybdenite Corporation of Canada drilled a part of the property in 1938 to 1939 and produced 1 ton of concentrates in 1938. Wartime Metals operated the property from 1942 to July 15, 1945. At this time the mill was enlarged to treat 200 tons daily. Molybdenite Corporation of Canada since July 15th, 1945, have continued the operation of this property and have revised the mill flow-sheet in order to produce both a bismuth and a molybdenite concentrate.The production for the period 1942-1946 is as follows:Total molybdenite production from the mine in the 1942 to 1946 period was about 4,127,400 lb.The La Corne deposit occurs at the northwest contact of a small mass of biotite granite with biotite schist. The form and extent of the biotite granite mass is concealed by a wide sand plain that extends northwest and west from the deposit and overlies bed-rock except in four small outcrop areas. These are spaced 1,000 and 2,000 feet apart along a narrow strip extending 5,000 feet south from the mine. The outcrops suggest that the granite must be at least 1,500 feet wide and 3,000 feet long northeastward. Where exposed in the mine workings the contact dips 70°N.W., but is not a sharply defineable feature due to the presence of numerous granite dykes and tongues in a zone of biotite schist 100 feet wide along the margin of the granite. The biotite schist in the few outcrops that flank the north and south sides of the granite strikes northeast and dips 60° to 70° S.E."

Jan 1, 1954

By Carl Faessler

Abstract Some Canadian geologists believe chat, in the Grenville sub-province of Eastern Canada, there is no granitic intrusion older than the anorthosite. The writers are among those who hold the contrary view. They suggest a new means to distinguish between rocks belonging to intrusions respectively older (Laurentian) or younger (Pine Hill) than the anorthosite. This new method is based on microscopical observations which demonstrate that the Pine Hill intrusives contain a large amount of exsolution perthite, whereas the Laurentian intrusives are completely devoid of exsolution perthite. Where perthite is present in Laurentian rocks, it is the result of lacer hydrothermal replacement. Introduction The present paper is the result of a systematic study of some acidic intrusive rocks in the Grenville sub-province. These rocks underlie large areas of the Canadian shield in the Province of Quebec, mostly along the southern border of the shield.

Jan 1, 1946

By G. V. Sirianni, G. E. Viens, R. A. Campbell, G. N. Banks, R. L. Sachdeva

"A combined shaft-electric furnace for the smelting of ores and the melting of metallized iron pellets is being developed. The materials are preheated, and in some cases pre-reduced, in the shaft before being transferred to the electric furnace, where melting or smelting is completed. It has been demonstrated that this combination of equipment will enable much of the relatively expensive electrical energy to be replaced by cheaper energy in the form of oil or natural gas, and preliminary experiments indicate that the total energy requirements for a melting or smelting operation are significantly reduced. Projections based on results obtained from the preliminary experiments indicate that further improvements will be possible when certain modifications to the equipment are completed."

Jan 1, 1968

By G. F. Colborne, A. Thunaes

"When the Canadian uranium milling plants went into operation during the early 1950's, they utilized flowsheets developed at the Radioactivity Division of the Federal Mines Branch in Ottawa. Since then, numerous process improvements have been made by the Mines Branch, by the operating companies themselves and by other research organizations. This paper will consider uranium milling technology from the standpoint of a new mine operator charged with the responsibility for the design of an economic flowsheet, and will indicate the range of process elements available to him and the testwork required to enable an intelligent decision to be made."

Jan 1, 1968

By I. C. Edwards, D. C. Smith

THE milling plant of Bicroft Uranium Mines Limited at Ban-croft, Ontario, was one of the first in Canada to employ ion excl1ange for the selecti1•e recovery of uranium from acid leach liquors. The ion ex-change circuit started operating early in November, 1956, and by June 1 I959, had handled more than two million tons of pregnant solution containing I,830,000 pounds of U3Os. Each column had been saturated and eluted about 430 times. The ion exchange columns are the conventional fixed bed type. Uranium is eluted from the resin with a sodium chloride-sulphuric acid solution and is precipitated continuous-ly with magnesia. After filtering and drying, the precipitate, or "yellow cake," is packaged in drums for shipment to the refinery.

Jan 1, 1962