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By Nirmal Weerasekara

Mill liners serve the dual purpose of protecting the shell from wear and transferring the rotary motion of the mill to an effective grinding action. As the liners wear, the efficiency of energy transfer changes, so there is balance between liner profile for wear and for milling efficiency. A tool that can simultaneously predict the evolution of the liner profile and the associated change in milling efficiency should prove most useful in optimal liner design. This paper presents such an approach, based on measured 3D liner profile data informing 3D DEM simulations of charge motion and liner wear modelling.

Jan 1, 2012

By G. R. Sadowski

"Large subhorizontal joints have been found in the foundation excavations in basalt and granite of Brazilian Dams. Some spread for hundreds of square meters showed slickensides—polished surfaces plus striations—and laminations interpreted as related to shear displacement, what substantially reduced their shear strength and imposed special reinforcement measures against the potential sliding of overlying concrete structures. The geological characteristics of these discontinuities have raised speculations related to their origin, be it related to mechanisms of bulging, cambering or to some tectonic or primary geological event.Several geologists and engineers from the northern hemisphere including Terzaghi already showed to be concerned with their role in granite foundations while in the southern regions Brazilian authors have found similar occurrences but also affecting individual lava flows of continental flood basalts in the foundations of major dams of the Parana Basin, which they designated under the particular name of “fault-joints”. This double-standard designation is self-explanatory of the difficulties involving their origin and related geomechanical properties: faults or just shear joints?Recently, similar features were encountered in the foundations of large dam constructions in anorogenic granites inserted in the realm of the Brazilian Amazon, where some of these discontinuities exhibit features common to tectonic thrusting combined with deep tropical weathering.The evidence of preshearing along the surfaces of such fractures, also associated to products of deep weathering, reduces their geomechanical strength substantially, suggesting values of ultimate phi spanning 12 to 28°. The detection of these descontinuities during initial investigation phases continues to be a major complex task in geological risk evaluations surveys. Trenching associated to some geophysical exploration techniques, although considered to be very basic exploration techniques are still the suggested methods for their forecast and previous determination."

Jan 1, 2015

By T. S. Golosinski

"This paper reviews the types of selective continuous miners (SCMs) available at present, and compares their main features. Furthermore, operating practices and mine planning aspects of the SCMs applications are reviewed and conditions for efficient application of this equipment are defined. Finally, the potential applications of the SCMs in surf ace mining of oil sands are discussed INTRODUCTIONIn the 1970s the United States Bureau of Mines (USBM) conducted a program of investigations, design and demonstration of various continuous surface mining concepts, This included continuous mining equipment which was an adaptation of several civil engineering and/or underground mining machinery concepts to surface mining. Upon termination of this program, the related development was continued by a number of equipment manufacturers, leading to development of several types of SCMs. This new type of surface mining equipment is able to mine selectively hard and thin multi-layered formations at high, sustained, and economically viable production rates.While used mostly in coal mining at present, the characteristic features of this equipment permit conclusion that it may prove to be an efficient tool for surface mining of oil sand, and/or related overburden stripping. Of particular interest here may be the ability to mine thin layers of hard material, without a need for its earlier fragmentation, and the ability of the SCMs to load a variety of haulage equipment, including belt conveyors."

Jan 1, 1989

By D. A. Trotter

"This paper traces the main advances in mine lighting from neolithic times to the 1960s. The earliest lights consisted of reeds or strips of wood soaked in grease. As man's knowledge increased, the oil lamp, the candle, kerosene, acetylene and finally electricity have allowed him to see where no natural light could penetrate. These advances in technology, however, did not come easily. Many false starts were made and great dedication was required by a few lighting pioneers to overcome the many technical difficulties that were encountered. The lighting of coal mines in particular caused unique problems, as there was the ever-present threat of methane explosions. Advances in mine lighting will continue, but these advances are only possible because men like Davy, Wolf, Marsuat and Edison paved the way.IntroductionMan's first efforts at mining consisted of merely picking rock off the surface of the earth. The sun was his only source of light. The early mines of the Neolithic age were simply vertical pits, 5 to 8 m deep. In order to follow an orebody, miners began to dig horizontally from the bottom of these pits, and as work progressed the need for additional light became apparent. With the discovery of the light-giving properties of fire, man was no longer dependent on natural light. Figure 1 gives an impression of the earliest artificial mine lighting used.Early Evidence of Mine LightingCarbonized residue from wood chips which had been inserted into rock cracks can be found in early Neolithic workings. The mines at Krzemionki Opatowski in Poland contain very narrow low tunnels that were lit in this fashion and were worked from 2300 to 1800 B. C. The wood had to burn downward to provide light and because wood burns poorly in this position, the chips were probably soaked in animal fat to make them burn more easily."

Jan 1, 1982

By G. Danko, C. Lu

"High temperature and humidity at the working negatively affect safety and health in deep and hot underground mines. It is necessary to predict during design the dynamic changes in temperature with heat and moisture emitted into the mine ventilation-thermal-humidity (VTH) system from various sources such as auto-compression, wall of strata, mining equipment and workers. Currently available mine ventilation and climate models are either furnished with a simplified, step-change-type (SCT) model for thermal solver (such as in Climsim, VnetPC, Minevent, MFire, etc), or with more advanced models to account for the “thermal history effect” (also known as thermal flywheel effect), such as in Ventsim and MULTIFLUX. The goal is to quantify the modelling error caused by the lack of variable thermal history component in the SCT model. Two models are compared: one with and one without the thermal history component in long, single airway examples with long-term climate simulations for 20 years assuming an input air temperature with daily variation. The examples illustrate the magnitude and the time-lag phase of the variation of the modelling errors with space, time and model conditions. Large errors are shown in the order of +14°C and –7°C errors, persistent for long time periods, up to 20 days in one example.INTRODUCTIONIt is important to predict the heat and humidity distributions during the design of hot and humid underground mines for the safety and health of the workers. The feasibility of extracting a rich deposit in great depth may depend on the extent of ventilation and mine climatization for maintaining an acceptable working environment. The cost of ventilation and cooling may be substantial, up to 40–50% of the total energy cost of mining (Clausen, 2017). The accuracy of model solution is important in view of the low profit margin in mine feasibility for deep and hot mines. Safety and health of the miners, the primary concerns, are therefore inherently connected to finding ever better solutions in simulation methods and ventilation control techniques."

Jan 1, 2019

By Alf Hartling

"Most of the Paleozoic section of the Williston Basin is a thick accumulation of numerous carbonate to evaporite, shallowing upward, cyclic sequences. These sediments were deposited in broad epeiric seas, and the deposition of the evaporite facies marked the final stage of each cycle. Many of the sequences display a pervasive replacement dolomite in the uppermost portion of the carbonate units. This secondary dolomitization is, at least in part, an early diagenetic event, synchronous with evaporite deposition.The inception of evaporite precipitation resulted in the seepage of a dense, Mg-rich brine into the underlying sediment. The heavy brine moved down the gentle regional dip displacing the more normal marine interstitial pore fluid and dotomitized the primary calcitic sediments en route. The supply of Mg-ions decreased away from the source, and correspondingly, the degree of dolomitization decreased and larger crystals formed because of slower nucleation at fewer sites.The seepage refluxion of dolomitizing brines gave rise to the frequently observed textural variation of cryptocrys talline, impervious dolomite grading into a finely sucrosic, permeable dolomite down-dip. This diagenetic facies change provides the critical up-dip barrier for potential hydrocarbon reservoirs. The lateral pool boundaries are controlled by either structural relief or a similar diagenetic facies change. The reservoirs are capped by the tight evaporites.Hydrocarbon production is attained from diagenetic traps in the Mississippian Oungre Zone and the Ordovician Red River 'C' Zone . Reservoir creation and the pooling mechanism are the result of dolomitization by the seepage refluxion of dense, Mg-rich brines beneath restricted, hypersaline lagoons. When formulating an exploration/ exploitation program for these oil prone horizons, it is essential to understand the complete geological history in order to establish where the reservoirs will be found and to define the areal extent of each accumulation."

Jan 1, 1984

By Dean Gerhardt

Why the need for proactive loose detection? ?? Past history of ground falls in Saskatchewan mines prompted research into new techniques for ground control. ?? Traditional tools for ground assessment (i.e. visual inspection, sounding with scaling bars) are not proactive and can often be time consuming. ?? Need existed for a system that was non-evasive, time efficient, and could be managed by a single operator. Ground Penetrating Radar (GPR) immerged showing the greatest potential.

May 1, 2008

By C. H. Bertoni

"The Superior Province of the Canadian Shield is the largest gold producing area within Archean greenstone rocks in the world, with total production of over 140 million ounces of gold. One hundred and fifty-five mines have individually produced more than 8,000 ounces, although only a relatively limited number of deposits (33) produced more than one million ounces of gold. The output from these 33 deposits accounts, however, for 85% of total gold production. The majority of grades (68%) ranges between 0.10 and 0.30 ounce per ton, and there is no linear relationship between grade and tonnage.Development of new gold mines reflects the history of gold prices. However, the response to the latest increase in gold prices was not as marked. It is concluded that gold deposits are becoming increasingly more difficult to find and new exploration techniques are urgently required.IntroductionWith most of its production coming out of the Superior Province, the Canadian Shield is the largest producer of gold from Archean greenstone rock s in the world. In total gold production, the Superior Province is surpassed only by the paleo-placers of Witwatersrand and the placers of the USSR (Anhaeusser, 1976). There has been no attempt so far to compile the historical production of the Province as a whole in a single document. The aim of this work is to fill this gap, not only for the convenience of having a complete list of gold producers, but, more importantly, as a basis on which to study the tonnage and grade characteristics of these deposits."

Jan 1, 1983

By W. K. Chan, R. Lahaie

"The Suncor Oil Sands Mine located north of Fort McMurray, Alberta, produces about 80000 m' per day of tailings waste which must be disposed of economically in an environmentally acceptable manner. To date, this has been accomplished by impounding the high water content tailings wastes behind large dykes, many of which approach 100 m in height .The dykes are constructed using suitable overburden material stripped prior to the mining of the oil sands feed and/ or the coarse sandy fraction of the tailings waste itself. Although the above is common practice at many mining operations, the large volumes handled and the resultant costs require designs to be meticulously fine-tuned toward the optimum. As a result, considerable effort is expended on planning, designing and construction, and performance monitoring. The lack of precedent experience (Suncor pioneered oil sands mining), coupled with the realities of long, harsh winters and a variety of troublesome site conditions and construction materials, has led to some very unique dyke construction.This paper overviews current tailings disposal plans as welt as some of the key issues related to the design, construction and performance of these large dykes."

Jan 1, 1988

By C. A. Born

This paper describes the rejuvenation of a molybdenum mine mill complex at the head of Alice Arm, 500 miles north of Vancouver and 85 miles north of Prince Rupert, British Columbia. It includes a description of the property history of the deposits and of the previous operations, together with details of the project for re-opening the mine.

Jan 1, 1979

By Jim Robertson

Summary of Presentation ??What is the GARD Guide ??The Need for a GARD Guide ??Mining Industry?s Commitment to Solving ARD Problems ??The Ultimate Solution ?You ??The GARD Guide ?Scope ??The GARD Guide ?Structure ??Wiki Demonstration

May 1, 2009

By D. C. Brady

"Within six months from award of a project management contract, Les Mines Dumagami Limitée, Cadillac, Quebec, was operating its new hoisting facility. This was accomplished with less than a six-week shutdown of mine production while still maintaining shaft access for underground maintenance.The work involved installing a refurbished /3.5 ft diameter double drum hoist, replacing a timber headframe with a newsteel headframe, increasing the ore bin capacity from 500tons to 1000 tons, constructing a new substation, and upgrading related facilities.This paper describes the work and methods used by various contractors, Les Mines Dumagami Limitée and J.S. Redpath Mining Consultants Limited to bring this project to a successful completion. It discusses the history of the project from proposal stage through to the design, procurement, scheduling, and construction management. The paper also comments on problems that were encountered and the methods used to overcome them.IntroductionThe Donald J. Laronde Mine of Les Mines Dumagami Limitée (Dumagarni), a gold and copper producer, is located in northwestern Quebec, approximately half way between Val d'Or and Rouyn. The mine started production in the spring of 1988 and the first gold bar was poured in June 1988.Following a request by Dumagami, on February 22, 1989, J.S. Redpath Mining Consultants Limited(Redpath) delivered a proposal to increase hoisting capabilities from 1500 tpd to a minimum of 2500tpd. Although various concepts were considered, Redpath proposed a new hoist house along the same shaft axis as the existing hoist, and located on the site of the existing substation. They would then provide a new substation, replace the headframe with a largersteel structure , gain extra storage capacities by increasing the bin heights, and raising the roof of the bin house accordingly.Although underground mining would have to be stopped for a month, the mill production would be maintained by feed from Dumagami's open pit.Figure 1 shows the original plant layout and Figure 2 represents the general arrangement after the project was completed . Table 1 compares the original hoisting facilities to the new facilities.On March 2, Dumagami awarded Redpath a contract that included preliminary engineering, detailed engineering, procurement and contract administration, and later added construction management. The preliminary engineering refined the initialconcept, selected major equipment, and prepared schedules and capital cost estimates for the total project."

Jan 1, 1991

By S. Srinivasan, R. Coté

"India is undergoing a massive electrification program using local coal to provide fuel for thermal generating plants. The Rajmahal mine in northern Bihar is scheduled to produce coal at the rate of 10 million tonnes per year by the end ofa sixty six month contract with MET-CHEM Canada Inc. for mine development. In order to control maintenance performance and warehouse inventory MET-CHEM is installing some proven computer-controlled programs and will provide extensive training to ensure that the systems are properly used. The programs are Maintenance Planning and Control System (MPCS) and Materials Management System (MMS), both of which were developed and used by Quebec Cartier Mining Company at its iron ore mine in northern Quebec. In addition, a Predictive Maintenance Program (PMP) using vibration analysis will be introduced . This paper discusses the three systems.IntroductionIndia is currently undergoing a massive countrywide industrialization and electrification program. Most of the power will be supplied by coal-fired thermal electric plants.One of the mines being developed as part of the over-all program is the Rajmahal Open Cast Coal project in the Godda District of Bihar, approximately 270 km north , and slightly west of Calcutta.The project is based on an agreement signed in January, 1989 between two government organizations - Canadian Commercial Corporation (Ccq and Coal India Limited (CIL). MET-CHEM Canada Inc. (MET-CHEM), an international consulting engineering organization which has worked in India since 1976, is CCCs Canadian executing agency for the project. METCHEM was the engineer-constructor and mining associate for the development of the 7.5 mtpy Kudremukh Iron Ore Project. This US$430 million project was completed on schedule and under the original budget estimate. The Rajmahal deposit is the responsibility of Eastern Coalfields Limited (ECL), a subsidiary of CIL. The project is to produce coal at the rate of 10.5 million tonnes per year in 1994."

Jan 1, 1991

By Törbjorn Naarttijärvi, Bengt Ludvig, Agne Rustan

"Falling rock is one of the major causes of serious injuries and deaths in Swedish mines. The research at the Division of Mining and Underground Construction was therefore directed toward controlled blasting in hard intense jointed rock.The project was started with an extensive literature review. Model tests with a new equivalent model material have been initiated to find ways of improving blasting techniques. The result showed that long cracks arise at the perimeter holes when there is a long time delay between adjacent holes. This led to the theoretical development of a new initiation method with ultra short delays (1,5 ms) f or controlled blasting, called ""Cutblasting"".Full-scale tests have been done at LKAB in Malmberget in hard intense jointed magnetite ore. Four different types of perimeter charges have been tested, namely: tube charges, ANFO mixed with plastic beads, detonating cord and linear shaped charges. Three types of initiation of the perimeter holes have been used, conventional (half-second delay detonators), instantaneous and ultra short ""cutblasting initiation"" (1,5 ms delay). The change in rock strength before and after blasting has been studied with bore hole periscope, vibration measurement and ocular observation of the rock surfaces.Thefull-scale tests showed that ""cutblasting"" with detonating cord in the perimeter holes gave the smallest damage to the surrounding rock. A combination of cutblasting initiation and tube charges are anticipated to give an even better result. A new method of controlled blasting using linear-shaped charges has also been tested, however, this charge type needs further development.The full- scale test also showed that the damage which can be seen on the rock surf ace is about the same for different controlled blasting methods but the not-visual-damage zone varies as much as from 0,1 to 0,7 m.A new classification system for controlled blasting regarding the damage to the surrounding rock has been devised."

Jan 1, 1985

By Raja V. Ramani, Sukumar Bandopadhyay

"The dispersion of diesel contaminants into the mine atmosphere is a variant of general class of diffusion-dilution problems relevant to underground mining practice. The equipment operations in underground mining are characterized by different activities with different time duration s, i.e. varying duty cycles. Therefore the volume and quality of diesel emissions and consequently, instantaneous concentrations are quite variable. Design of mine ventilation systems under these conditions becomes complex. In this paper, the development and use of mathematical models of mine production system, the engine exhaust air quality and engine exhaust transport in the design of ventilation system are discussed.IntroductionThe turbulent diffusion of suspended matter in an atmosphere is not only a topic of considerable intrinsic interest to the mathematical physicist and meteorologist, but also a problem of great practical interest. Release of particulate matter into the atmosphere at large has created o ne of the acute problems of the present day. Pollution of environment by industrial and domestic smoke, fumes and grit is widespread and has necessitated extensive studies in order to determine the concentration and distribution of pollutants in various areas. Pollutants discharge from stacks, whether chemical or radioactive, give rise to similar, but more localized, problems. The laws which govern turbulent diffusion in the atmosphere are also applicable to the study of the diffusion of toxic gases and the deposition of radioactive dust from nuclear explosion.The dispersion of diesel contaminants into the mine atmosphere is but a variant of a general class of diffusion-dilution problems relevant to underground mining practice. Most of the mine air pollutants, such as respirable dust, methane, diesel exhaust, and blasting fumes are produced in the face areas and haulage ways. Understanding of their dispersion in the mine airways is important to calculate their concentrations. In this paper, the development and use of mathematical models of mine production system, the engine exhaust air quality and engine exhaust transport are discussed. The over-all objective of this research effort is to evaluate the impacts of dieselization on production and ventilation systems and to aid in mine planning and design, as shown in the flow model in Figure I."

Jan 1, 1983

By Réal Marcotte

L'industrie minière représente un apport économique important pour le Québec ; cette production est très diversifiée et répartie dans plusieurs régions. Hormis les forges du St- Maurice au XVIIe siècle, l'industrie minière québécoise commence en 1862 dans la Beauce avec l'exploitation de placers aurifères dans les affluents de la rivière Chaudière; à la même époque, on met en production les mines de cuivre Eustis, Albert et Capelton, près de Sherbrooke1; à partir de 1881, les mines d'amiante et de chromite au voisinage d'Asbestos et de Thetford commencent à voir le jour. Dans les années ?20, l'extraction de métaux précieux et usuels débute en Abitibi- Témiscamingue; durant les années '50, le fer et l'ilménite de la Côte Nord, ainsi que le cuivre de Murdochville et Chibougamau, commencèrent à être mis en valeur. Plus récemment, soit durant les années '80, le sel des Iles-de-la-Madeleine et le graphite des Hautes Laurentides s'ajoutèrent aux produits que nous commercialisons. Finalement, soit en 1998, le Québec devenait un important producteur de nickel avec le démarrage de la mine Raglan, au Nunavik. L'exploitation d'une mine peut nécessiter l'extraction de grandes quantités de roches stériles, particulièrement lorsque la production se fait à partir d'une fosse à ciel ouvert. De plus, étant donné que les minéraux et les métaux mis en marché ne constituent qu'une fraction du minerai extrait, il faut le concentrer : on se retrouve alors avec des proportions plus ou moins importantes de résidus finement broyés. Ces deux types de rejets totalisent bon an mal an environ 100 millions de tonnes. Lorsque cela est possible, ceux-ci sont, soit valorisés comme matériaux de construction ou retournés dans leur lieu d'origine afin de soutenir les murs des excavations. Toutefois, une bonne partie est accumulée en surface dans des aires aménagées spécifiquement à cette fin ; comme le montre la figure 1, la superficie utilisée à cette fin a progressé parallèlement aux booms miniers que nous venons de mentionner pour atteindre actuellement environ 15,600 hectares, dont environ la moitié sont situés sur des aires encore en activité.

Nov 1, 2002

By K. H. Singh, J. N. Szuck, J. A. Riddell

"Hydraulic rock drilling equipment has been in use at Falconbridge over the past two years in both production and development situations. This paper deals with the experience gained in the application of hydraulic drilling in the company's mines and discusses the benefits and problems encountered during their use. The paper primarily focuses on technical, operating, maintenance and economic aspects of the machines, and does not attempt to compare the performances of different machines from the various manufacturers.IntroductionThe Sudbury Operations of Falconbridge Nickel Mines Limited are comprised of five operating mines and two mines under development. All the production comes from underground mines, mostly at depths below 1000 metres. The company, faced with increases in operating costs and difficult mining conditions, has continued to seek solutions with the help of new mining technology.The development of electric-hydraulic drilling machines in Europe had been pursued with great interest and, in 1979, a decision was made to test these machines to prove their technical and economic viability under operating conditions. Since then, a number of electric-hydraulic machines have been evaluated in different situations and currently nine hydraulic machines are being used in the company's various mines. These machines are comprised of two-boom drilling jumbos for development, one-boom machines for longhole drilling and a large-hole-diameter drilling rig for blasthole drilling. One hydraulic jumbo has also been used in a cut-and-fill stope."

Jan 1, 1982

By Lynne Bowen

"On the da y shift in Number One Mine at Nanaimo on Vancouver Island, on May 3, 1887, William Griffiths, a coal miner with many years experience, fired a shot to advance the face of the crosscut. A flame ran out for a distance of fifteen feet along the roof and then extended up the slope for ten to twelve feet, and although many would have called this a blowing out shot, Griffiths said it was just a feeder. ""A blower"", he said, ""would have caused an explosion."" 1There was no explosion. Griffiths reported gas and the area was cleared for three hours and then work resumed. When the shift changed at 3:00 p.m., the fireman reported all places clear of gas and the ventilation good.2The ventilation in Number One Mine was the best anyone had ever seen. The air in the mine was almost too cold. The current was so strong that it sometimes blew out the flame on the miners' fish oil lamps. It delivered five to six hundred cubic feet of air for every man and animal working in the mine. The law required only one hundred cubic feet 3The miners considered Number One to be relatively safe. The manager was proud of the mine and its up-to-date equipment"". Recently, there had been reports from France and America about the explosiveness of coal dust, but the manager did not think his mine was sufficiently dusty to be dangerous.5 The dust lay thick on the floor of the mine. Sometimes when a shot was fired the dust rose in great clouds. When a miner was shovelling it, the dust would billow up and be carried off by the current of air. The dust was also in the roof and in the stopings, put there intentionally to fill up the spaces and prevent the accumulation of methane gas."

Jan 1, 1992

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003

By Michael Chender

Emerging Equity Sources ? Larger IPOs ? China Inc. ? Other sovereign wealth funds ? New funds and higher allocations ? Private equity

May 1, 2010