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By Graeme G. Strathdee

"IntroductionThis paper presents an overview of the industry status, describes current potash industry practices at three mills, and summarizes developments that have taken place since the previous review by Banks (1985).The commodity potash is produced in both New Brunswick and Saskatchewan from the evaporite ore sylvinite. This ore is a mixture of co-crystallized halite, NaCl, and sylvite, KCl, and a minor assortment of silica, carbonate, sulphate, and clay minerals. Carnallite, KMgCl3.6H20, is also dispersed throughout the bedded deposits and can affect the recovery of sylvite for fertilizer and industrial uses.Canada continues to be a principal source of supply of agricultural and industrial potash products. Figure 1 shows the sector performance between 1989 and 1997 in the context of the world supply and demand situation as reported by Prud'homme (1997) of Natural Resources Canada.Potash industry output is traditionally measured as the quantity of potassium nutrient and reported as tonnes ofK20. Mineralogically, the principal form of potash produced in Canada is sylvite, KCl, and 1 nutrient tonne K20 corresponds to approximately 1.64 tonnes of sylvite of agricultural grade, about 95% KCI. In 1997, the Canadian industry milling capacity was 13.4 million metric tons (Mt) ofK20 (22 Mt KCl) while the actual production was 9.0 Mt K20 (14.8 Mt KCl). Worldwide milling capacity in 1997 was 35.9 Mt K20 (58.8 Mt KCl) and global consumption was 25.3 Mt K20 (41.6 Mt KCl). Canadian producers can deliver about 35% of the global demand for potash commodities"

Jan 1, 2000

By B. Jakovljevic, M. D. Soderstrom, T. McCallum, A. J. Quilodrán

Cytec has developed a new organophosphorus based solvent extraction (SX) reagent for rare earth separations. The new product, CYANEX® 572, has been formulated to allow efficient extraction while minimizing the strip acid requirements. The optimization of formulation strength is expected to significantly reduce the operating costs of these circuits. Modeling capabilities for CYANEX® 572 (similar to those used successfully in Cu and Co/Ni SX) have also been developed to aid in the design and optimization of the SX circuits. Simulations will be shown comparing CYANEX® 572 to a traditional rare earth extractant.

Jan 1, 2014

By Philippe Portella

Current Ownership : AREVA NC-France & affiliates (63.4%), ONAREM-Niger (36.6%)Related Mines : Ariège, Artois, Arlette(initial Somaïrlease) and Tamou, Taza, Takriza, Tamgak(SMTT lease)Mining Method : Open Pits Reserves : about 14 000 tU Average grade : 0.3 % UEnvironmental Management : Certified ISO 14001 since November 2002Key figures :2003 output : 1126 tU number of employees at year end : 565 Current Ownership : AREVA NC-France & affiliates (34%), ONAREM-Niger (31%), OURD-Japan (25%), ENUSA-Spain (10%) Related Mines : the Akouta mine provides access to several adjacent orebodies(Akola, Akouta, and coming Afasto with Ebba North / South)Mining Method : Underground ?mainly room & pillars Reserves : about 29 000 tU Average grade : 0.40 to 0.50 % U3O8Environmental Management : Certified ISO 14001 since January 2003Key figures :2003 output : 2017 tU number of employees at year end: 1070

May 1, 2006

By P. O. Parfitt

At the McIntyre mine, there are two distinct operations: a gold mine with narrow veins, mined by cut-and-fill methods, and a copper mine with large, open, long-hole stopes. The application of the Critical Path Method to scheduling work in the copper mine, where it has been used successfully for several years, is de-scribed briefly. This application is relatively simple. Use of C.P.M. has now been extended to the gold mine. To replace the former method of scheduling from bar-charts, a procedure was developed for scheduling automatically. To handle an operation of this size and complexity, a computer was essential. Improved schedules are now being produced, with a saving in time.

Jan 1, 1967

By Ian E. Efford

The paper gives an assessment of Canada's energy supply-and-demand position, the current situation and projections into the future, as well as a review of some alternative energy futures for Canada. The main elements of Canada's energy strategy for the period 1977-1990, with particular reference to the role of energy conservation, are discussed, leading in to the development of the national energy conservation program.

Jan 1, 1977

By C R. Crook

A brief outline of production methods and processes is given to show how maintenance fits into the picture at this plant. The work force, and the tools needed to carry out this function, are then described. Preventive maintenance practices, scheduled annual shutdowns and routine check-downs are explained, especially as related to planning and to the materials and labour involved for a mini-mum downtime. A brief explanation of the materials, sup-plies and spare parts program, as well as the part played by the Stores Department in conjunction with the Maintenance Department, is given. Cost control and equipment expenditure indicators are explained. Some specific examples of maintenance jobs are described in order to show the flexibility of the program. S HERRITT GORDON Mines Limited has been in continuous production, except for the planned downtimes needed for expansion tie-ins, or the annual shutdown check-over periods, since the first shipment of nickel on a commercial basis in July of 1954.

Jan 1, 1964

By G. M. Behrend

"The mining and processing of mineral ores is a very old industry which is steeped in tradition. Rising demand for metals has recently forced the exploitation of lower-grade orebodies which require extensive beneficiation. The high capital expenditures involved, together with market pressures for high-quality concentrates and pellets, have forced the development of new process technologies which are heavily dependent on automatic process control. Development of suitable instrumentation has been rapid and it is being applied to mining processes today with a high degree of sophistication. The drive for higher efficiency and profitability goes on and has reached a level at which modern digital computers appear to be the only answer. However, the efficient application of a digital process computer is extremely complicated and is therefore approached by the mining industry with considerable hesitation.Some of the benefits promised by the digital computer can be obtained today by other means, which are more manageable and can provide immediate payoff. The result would be a building-block system which would utilize the digital process computer as its final component, to perform true plant optimization, free from routine chores."

Jan 1, 1971

By G. D. Garland

The influence of natural electric currents, induced in the earth by changes in the earth's magnetic field, on the electric logging of boreholes has not always been recognized. Measurements made with fixed electrodes of changes in the vertical potential gradient in a hole near Calmar, Alberta, have indicated the effect of earth currents related to magnetic disturbances. It is found that appreciable errors in self-potential logging could arise during periods of magnetic storms, but the precise pat-tern of disturbance in any area seems to depend on the local structural conditions. As the amplitude of the natural earth currents increases toward the auroral zone, it is suggested that periods of magnetic disturbance be avoided, if possible, when electric logs are taken in the northern part of the western sedimentary basin. NATURAL electrical currents flow continuously near the surface of the earth, apparently as a result of electromagnetic induction

Jan 1, 1962

By V. I. Ryaboy, S. A. Kondratyev

"The paper describes influence of desorbed species (DS) of a number of xanthates and higher dialkyldithiophosphates on the collective ability of these reagents. Adsorbed on mineral DS of the reagents in the form of products of non-stoichiometric interaction between xanthates and heavy metal salts can pass to the gas–liquid interface and remove liquid from the layer between mineral particle and water surface. A high-speed video recording displays the process of spreading of DS of xanthates and dialkyldithiophosphates over water at the moment of local rupture of the water layer. Expansion of “dry” spot on the mineral surface after DS of xanthate capture and displace liquid from the layer has been proved with video images. The comparative analysis of collecting ability and dynamic surface activity of dialkyldithiophosphates shows that these characteristics are in good correlation. The forces exerted by spreading film of the reagent’s DS on liquid in the water layer are evaluated, and the water flow rate from the layer is determined. The line of the reduction in thickness of the water layer behind the front of spreading film of DS of dialkyldithiophosphates and xanthates coincides with the line of the increase in their dynamic surface activity. Their force on the liquid volume in the water layer characterizes collecting ability of the DS film of xanthates and dialkyldithiophosphates. It has been supposed that the collecting ability of DS of a reagent is a part of its overall flotation activity, conditioned by surface tension of solution and, thus, defined by the structure of hydrocarbon fragment of the reagent.INTRODUCTIONIt is believed that collecting ability and selectivity of collecting reagents is mainly governed by adsorption of a reagent at the solid–liquid interface. A few studies have shown that activity of collecting reagents at the gas–liquid interface may have deep influence on their collecting capacity and selectivity. Experimental researches have revealed correlation between surface pressure in a carboxylic acid film on liquid’s free surface and floatability of useful components (Kulkarni & Somasundaran, 1975; 1980; Quast, 2006). According to Quast (2006), it is not always that surface pressure of a reagent film influences collecting ability of carboxylic acid. For instance, pH range of adsorption of tetradecanoic acid on hematite does not coincide with pH range of high surface pressure. So, surface properties of this acid contribute little to flotation efficiency.The correlation between reagent film surface pressure and mineral floatability has been reveled for quartz and cationic reagents, too (Bleier, Goddard, & Kulkarni, 1977). Finch & Smith (1973) showed that combination of adsorption of ion–molecular amine complexes on mineral surface and high surface tension of “fresh bubbles” was favorable for flotation performance. The use of bubbles with reduced surface tension resulted in a decrease in quartz floatability."

Jan 1, 2016

By M. J. Fairweather

"The nature of minor element values and impurities are important both in the assessment of new properties and in the continuing improvement of operating plants. Impurity elements are frequently present as fixed solid solution impurities in association with the constituent minerals of a deposit or process streams in a concentrator. This paper uses five case studies to illustrate the application of simple regression analysis to the evaluation of minor element distribution in both operating mines and new deposits using analytical information readily available. This information maybe used to determine opportunities for improvements to the performance of an operating mine, to the economic assessment of anew deposit, or to the subsequent planning of an experimental study.IntroductionThe nature of minor element values and impurities are important, both in the assessment of new properties and in the continuing improvement of operating plants. Minor element values often contribute appreciable incremental revenue to a complex base metal deposit. Examples of valuable elements include precious metals, but may also include elements such as indium and bismuth which can be recovered at a profit by smelters provided with the necessary recovery circuits. During preliminary metallurgical studies of a new property there is usually a strong incentive to maximize the recovery of such valuable by-product elements. For example, the extent to which the by-product gold in a porphyry copper deposit is associated with chalcopyrite rather than pyrite may determine theeconomics of developing a new property.The nature of impurity elements in base metal concentrates is correspondingly important in minimizing the penalties which may be imposed by smelters in the treatment of such concentrates. Penalty elements include silica, dolomite (magnesia), arsenic, antimony, mercury, nickel and cobalt. The mineralogical association of these minor elements determines the ability of the mine to remove them in the concentrating process. This paper discusses means of assessing the mineralogical nature of such impurities without the use of sophisticated micro-analytical techniques."

Jan 1, 1997

By Carl Pelletier

The Sigma-Lamaque Complex is considered a lode-gold deposit characterized by narrow vein structures, which have been mined historically by underground methods. In addition to the narrow vertical structures, mining also took place on horizontal veins, ?North Dipper? veins and dykes mineralized with sub-horizontal veins and stringers. Over the 60 + years of production, mining took place to a depth of 1.8 km. The upper portion of the deposit was considered all but exhausted, when viewed from an underground mining perspective. The year 1998 is considered a turning point for the Complex when a small open pit was mined at Sigma. The resource evaluation methods used underground were applied to surface mining, which allowed small pits to be mined. The resource evaluation method considered only the narrow vertical structures and was not well adapted to open pit mining. As a consequence, resources were consistently under evaluated. It became clear that a new geological approach was necessary to more accurately define resources (i.e., what was being mined). In order to integrate all characteristics (geometry, mechanics and chronology) of this complex lode-gold deposit, a new geological model was proposed. Due to this new approach, dating to February 2000 and updated in December 2000, the reserves evaluated in the first 180 meters now stand at 15 million tonnes @ 2.61 g/t Au (1,265,350 oz). Those reserves cover an east-west corridor extending 1,500 m by 750 m.

May 1, 2001

By S. Harshaw, C. Doyle, A. E. M. Warner, D. Stremlaw

"In the Utility Nickel furnaces, the hearth and sidewalls are lined with high-Al2O3 bricks. During charging and thermal cycling (more so as the linings on these reverberatory furnaces age), pieces of brick spall or abrade from the refractory and collect on the top of the bath. These pieces are removed using a non-corrosive slag toward the end of the heat when the bath temperature is ~1600°C.This benign liquid can be generated by two methods. First and most obvious, suitable ingredients can be pre-mixed so that the flux (flux A) is isochemical with the non-corrosive slag. All that is needed to produce this targetted slag is heat. Second, in other proportions (flux B), the pre-mixed ingredients generate a corrosive slag that melts completely at -1200 °C and corrodes some but not all of the brick particles on the bath surface. As the reaction progresses, the slag changes composition eventually attaining the targetted benign composition. Using this option, additions are monitored to avoid overfluxing. In both cases, the generated slag/brick mixture can then be rabbled from the furnace. This practice has been successfully used for over two years and has been a factor in extending Utility Nickel furnace life to its current levels (about25% increase)."

Jan 1, 1993

By Mohammad Reza Khalesi, Ruhollah Rezazadeh, Mohsen Izadi Yazdan Abadi, Mahmoud Abdollahy

"The rotary vacuum drum filter (RVDF) is widely used for dewatering in mining industrial. In general, different parameters have influence in the solid-liquid separation such as: solid percent, level of vacuum, particle size distribution, filter cloth and chemical additives. These parameters can influence on some variables such as cake moisture, throughput and filter cloth life time. The aim of this study is to propose some chemical additives to improve the rate of filtration and decrease cake moisture of Gol-E Gohar iron ore concentrate by using laboratory scale bottom feed vacuum filter and suggest a filter cloth with long life time (more than 400 hours). Effect of particle size distribution on filtration investigated in large scale by measuring the thickness of cake and cake moisture.Increasing molecular weight of anionic flocculant lead to increases throughput but cake moisture increases too; While the filter aid increases throughput and decreases cake moisture simultaneously; the combination of them show different behavior. TSS and filter cloth life time have directly relation with material and type of filter cloth weave. Depending to type of feed, two polyester and polypropylene filter cloth are suggested. More over twill and satin weave have the best results. To prove the laboratory results some industrial tests performed in Gol-E Gohar hematite iron ore concentrate plant.INTRODUCTION“The process of grinding and classification involves the use of large quantities of water. The separation of solids from liquids is usually achieved by gravity sedimentation in thickeners. For fine particles this is a slow process. In general, 75–80% of the water can be separated and removed by thickeners. For further water removal, filters are used where in excess of 90% of the water can be removed” (Gupta, 2006).“Many types of filters are available, which are broadly classified here as vacuum, pressure, precoat and depth filters. Each classification contains a number of sub-processes. A category of filter that uses vacuum induced driving forces and semipermeable media to facilitate the separation of solids from suspension. While pressure differences across the filter are limited to less than 85 KPa (usually 75 KPa), most units are capable of processing a wide range of feed materials in a continuous manner” (Rushton, 2008)."

Jan 1, 2016

By E. Peek, L. Becze, K. Reading

"Gallium oxide is an important semiconductor material used in optoelectronic devices (flat panel and solar cell) catalysts and sensors. One of the methods to produce ?-Ga2O3 is the so-called hydrothermal route. It is practiced by Neo Gallium Compounds and comprises of two steps: (1) the production of mainly gallium-oxy-hydroxide in a pressure vessel by reacting metallic gallium with water at 200-220 ºC and (2) the calcination of gallium-oxy-hydroxide at 700-750 ºC to convert it into ?-Ga2O3. This paper describes this pressure hydrometallurgy process supported with relevant thermodynamic data and presents the characteristics of the ?-Ga2O3 powder produced for commercial purposes. INTRODUCTIONGallium is a relatively new metal, having been predicted by D. Mendeleev in 1871, discovered by P.E. Lecoq de Boisbaudran in 1875, and first commercially produced in the USA in 1943. Gallium is not rare, being more abundant in the earth crust than antimony, bismuth, molybdenum, silver and tungsten. However, few gallium minerals exist in nature, and the dispersion of gallium within other minerals add to the complexity of its recovery. In practice, gallium is found in dispersed state primarily in bauxites and in some sphalerites, and, to a much smaller extent, in some coals. At present, a very large proportion of the primary gallium in the world is recovered as a by-product of aluminum plants, mostly Bayer plants, where gallium is extracted from a bleed of the Bayer liquor (Roskill, 2011). In 2011, world production of primary gallium was estimated at 200 metric tonnes. In addition, there is a significant contribution of recycling to the overall yearly availability of the metal.Gallium exhibits fairly remarkable properties: it is liquid above 29.76 ºC, can be supercooled, and with its high boiling point (2204 ºC), is the metal with the widest liquid range. Gallium is magnetic, and is an excellent conductor of both heat and electricity. Gallium also displays a marked anisotropic electrical conductivity (Roskill, 2011). All these properties render gallium almost irreplaceable in the semiconductors (GaAs, GaN, GaSb, GaP wafers) and the optoelectronics industry (flat panel, solar cell)."

Jan 1, 2012

By W. Beres, M. Bielawski

Recent research on the development of erosion resistant coatings has been directed to the finite element modelling of the behavior of coating and substrate, and their interface under the impact of eroding particles. The approach presented in this paper is based on advanced computer simulation techniques using ABAQUS/Explicit to investigate stress and strain at the surface and at the coating/substrate interface of multilayer coatings under single particle impact. It was found previously that solid particle erosion mechanisms are predominantly governed by the kinetic energy of the impacting particles. However, recent modelling efforts revealed that effects of various material models could be also significant. Therefore, different material models representing relevant coating and substrate properties were investigated and the effects of these models on the coating/substrate response were studied. Particularly, differences between elastic, elastic-plastic and brittle cracking model responses were assessed.

Jan 1, 2006

By M. Krasowska, K. Malysa, M. Krzan

The paper presents fascinating, in our opinion, observations on mechanism and course of processes occurring during bubble collision with hydrophobic and hydrophilic solid surface. Hydrophobicity of particle surface is a necessary condition for the particle attachment to bubble. We have observed that even in the case of such hydrophobic solid surface as Teflon, the bubble attachment didn't occur at first collision. In distilled water the bubble bounced a few times without attachment. Influence of a-terpineol and n¬pentanol on bubble local and terminal velocity and the phenomena occurring during bubble collisions with hydrophobic and hydrophilic solid surfaces was studied. Bubble collisions with the solid surfaces were monitored and recorded using the high-speed (1182 frames per second) camera. It was found that in distilled water the velocity variations of the "approach-bounce" cycles were identical for Teflon and glass. Four distinct "approach-bounce" cycles were detected both at Teflon and glass surfaces. Moreover, the amplitude and frequency of the velocity variations were identical on collisions with the hydrophobic (polished) and hydrophilic surface. There was no immediate three phase contact formation, with the hydrophobic Teflon surface, what we found really astonishing. Roughness of Teflon surface seems to be important parameter, which affects probability of the bubble attachment as a result of a presence of micro-and/or nano-bubbles at the surface. It was detected that the presence of the micro-bubble affected attachment of the colliding bubble even in distilled water. Presence of a small amount of a-terpineol or n-pentanol affects dramatically the bubble velocity, but their role in mechanism of the bubble attachment needs further study.

Jan 1, 2004

"Acid resistant brick lined autoclaves and related vessels are utilized in pressure oxidation for the recovery of gold, copper, and other metals. The combination of the corrosion resistant membrane, acid resistant brick, mortar and steel shell is a composite system that requires a sophisticated stress analysis. In order to obtain meaningful results both the model and physical properties of the materials must be carefully selected. Evaluation of the calculated results requires an understanding of both the failure mechanisms of ceramics and experience with the performance of existing lining systems.INTRODUCTIONAcid brick lining systems are used in pressure oxidation autoclaves and related vessels to provide thermal and mechanical protection for corrosion resistant membranes that are applied directly to the interior of the vessel shell. The acid brick and mortar must be resistant to the process conditions and must provide a mechanically reliable structure.The construction of lined vessels incorporates a wide range of materials that can include the carbon steel vessel, austenitic weld overlay, lead lining, organic membrane, ceramic brick, mortars and other alloy components. The physical properties of the materials can vary by orders of magnitude and when combined in the construction of the lined vessel create a complex composite structure. The materials may be bonded together or act independently of each other. Stresses are induced into the lined vessel include pressure, thermal expansion, chemical expansion and mechanical loads.The complexity of these systems makes it is very difficult to account for all of the variables in the structural analysis of lined vessels. Historically calculations were simplified and designers primarily relied on experience with previous applications.The greatly improved tools for Finite Element Analysis (FEA) available today allow for detailed calculation of the stresses imposed on the vessel shell and lining. Koning & Lauzon (2004) presented a paper on design fundamentals including a discussion on the application of FEA methods at Pressure Hydrometallurgy 2004 in Banff. When a designer carefully constructs a model and selects the correct materials properties for the calculations, meaningful and useful results can be achieved."

Jan 1, 2012

By J. M. Cummings

The importance of controlled sand properties to the production of quality castings has been recognized by foundry men for many years, but the maintenance of requisite standards results in a relatively high sand consumption, which in steel foundries, for instance, may range from half a ton to over one ton of sand per ton of finished casting. During the war, obtaining and maintaining adequate sand supplies became a serious problem in many foundries, owing to increased wartime production and serious 'bottlenecks' in transportation. As a result, considerable interest was aroused in the possibilities of various sand reclamation systems by which up to 85 or 90 percent of discarded sand may be returned to a usable condition. During the past five years or so, a number of sand recovery installations have been made by both ferrous and non-ferrous foundries in Canada and the United States, and have resulted in substantial reductions in sand costs in every case. The possible benefits of sand reclamation are particularly apparent in British Columbia where no suitable sands for steel and heavy iron foundries occur naturally, and where freight costs on imported sands are considerably higher than initial selling prices. This is well illustrated by the fact that silica sand, which sells for about $2.00 per ton at pits in Illinois, is laid clown in British Columbia for around $11.00 or $12.00 per ton. The operating costs quoted for certain of the reclamation schemes, i.e. $0.25 to $1.50 per ton, may actually be no higher than the cost of waste sand disposal in city-located foundries. In view of the foregoing considerations, the British Columbia Research Council has undertaken a study of the possibilities for sand reclamation, with particular attention directed to its application in local steel foundries. No commercial occurrences of silica sand are known in the Province, and, with this in view, the Council previously investigated the possibility of recovering silica sand from local impure sands. Results were definitely encouraging, but it was felt that the present market is too small to permit economical production by the method developed.

Jan 1, 1947

By H. W. Smith, R. D. Fournier

This paper presents the results of an investigation of a full-scale rod mill. Appropriate numerical techniques are developed for the experimental determination of the parameters of a dynamic mathematical model from steady state data. The results confirm that this full-scale rod mill behaves similarly to laboratory-scale ball mills for which results have previously been obtained. It is noted, however, that although the model presented is adequate for predicting over-all particle size distributions, the size distributions of individual components of a multicomponent ore cannot be predicted.

Jan 1, 1972

By Z. Xie

Gas diffusion electrodes (GDEs) for high temperature polymer electrolyte fuel cells (PEFCs) have been prepared using ZrP-modified Nafion ionomer. The performances of these GDEs as cathodes and anodes were evaluated and compared with conventional Nafion ionomer GDEs using Nafion 112 as the PEM under elevated temperature and reduced relative humidity. ZrP-modified Nafion ionomer was incorporated into the catalyst layer to enhance water retention and/or increase the protonic conductivity. The fabrication of ZrP-GDEs was implemented by the ion exchange of Nafion solution with zirconyl chloride, followed by the impregnation of GDEs in H3PO4 solution. The composite electrolytes in the catalyst layer possessed a ZrP content of 20% by weight. GDEs were characterized by TGA, SEM, XRD, and CV. Scanning electron microscopy (SEM) indicated evenly distributed elemental Zr and P within the catalyst layer. Cyclic voltammetry shows a reduced electrochemically-active surface area when the ZrP is incorporated into GDEs. Polarization and impedance analyses indicate the cathode with ZrP-modified Nafion ionomer did not show an enhanced or decreased performance, compared with conventional Nafion ionomer GDEs under elevated temperature and decreased humidity. However, when GDEs with ZrP¬Nafion ionomer were used as the anode, an improved performance was observed. Preliminary experiments show that the anode is more sensitive to dehydration than the cathode under elevated temperature and/or low humidity. Improving the anode water retention capability will help to reduce losses at the anode. However, the incorporation of hygroscopic agents in the cathode catalyst layer is not essential because it is self-humidified by electrochemically-produced water even under elevated operating temperature and lower humidity.

Jan 1, 2005