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By R. G. Hamm

A brief outline covering the shovels and draglines in use in the open-pit mines of Western Canada, including British Columbia, Alberta and the Yukon, is given, followed by the procedure for the selection of the correct wire rope for each application. Such fa ctors as wire rope constructions, lay directions and types of cores are mentioned. Once the correct wire rope has been selected, there are variousfactors that can affect the service fife ofthe rope and the reduction ofdown-time during rope change-overs. Factors such as hairpin winding, types of Becket loops, and shovel drum and bail adaptors are described.

Jan 1, 1979

By A. J. Vivyurka

"This is a talk about the experiences that Rio Algom Mines Ltd. has had in the Elliot Lake uranium area trying to make the tailings more compatible with the surrounding environment. To get a better idea of the problem that we are associated with we have to go back to the location. The Elliot Lake uranium area is situated about half way between Sault Ste Marie and Sudbury and is about 20 miles north of Lake Huron. In 1950, uranium was discovered along the north shore of Lake Huron and by 1961 we had up to 9 mines operating in the area. Then the United States Atomic Energy Connnission withdrew their contracts so that at present there are only 2 mines operating. From all the mines that we had operating, we ended up with 7 tailings areas. From these 7 tailings areas we have 5 sites where we have active treatment or rehabilitation. There is the Pronto site where we are treating uranium tailings and copper tailings. There is the Lacnor-Nordic site which is located just out of Ellio Lake. The Milliken-Stanleigh site is in the Crotch Lake area. The Panel tailings is off the north end of Quirke Lake and finally there is the operating property of Rio Algom Mines at Quirke Lake.To understand fully the problem with this rehabilitation we have to look at the constituents of the ore. The ore body is a quartz conglomerate with uraninite and brannerite as the uranium bearing minerals in a fine ground mass of quartz, sericite and pyrite which separates the larger quartz pebbles. The approximate composition of the ore is: 80% quartz, 13% chlorite, 7% pyrite and 0.2% uranium minerals. The processing method also adds a few constituents to the final tailings."

Jan 1, 1975

By P. Mark. Hawley

Development of Barrick Gold?s Pierina Gold Mine in north-central Peru requires construction of a waste dump for disposal of non-ore grade materials stripped from the open pit to expose the ore. The waste dump site is located near the open pit in a U-shaped valley that is underlain by thin colluvial and morainal soils with locally thick peats and glaciolacustrine deposits. Bedrock underlying the site consists of variably weathered volcanics. The site is subject to moderately high seasonal rainfall and significant seismicity. The geotechnical quality of the waste rock is highly variable, ranging from low quality, degradable, soil-like materials containing appreciable quantities of silt and clay, to high quality, hard, durable, blocky waste rock. A hybrid dump design concept was developed that requires in-pit segregation of high and low quality waste, and selective placement of materials in the dump to maximize stability and enhance internal and subsurface drainage. The design includes a rock drain beneath the dump along the axis of the valley and a series of connected finger drains. Extensive peripheral diversions and stormwater control measures to inhibit infiltration of precipitation are also included. This paper discusses the unique challenges presented by the site and waste materials, the design methodology and stability analyses, and planned monitoring systems.

May 1, 2002

By K. Szafran, R. E. L. Seal, M. Tansey

Conversion of hydraulic equipment to fire resistant fluids has been hampered by less than satisfactory component performance and in some cases, catastrophic equipment failure. Concern over identifying possible causes to these problems led to a joint research project between the Potash Corporation of Saskatchewan Mining Limited and the University of Saskatchewan. This paper summarizes some of the results and conclusions derived from this joint project. In this study, the research was limited to evaluating the effects of potash contamination on the performance of hydraulic equipment. Two separate types of tests were conducted in order to provide a basis upon which trends could be established. This study concluded that the presence of potash dust in the hydraulic fluid can induce severe wear over relatively short periods of time. It was also deduced that a contaminant free fluid combined with proper fluid maintenance could extend the performance of hydraulic components using fire resistant fluids even under very severe operating conditions, such as elevated pressures and temperatures. Recommendations as to how to achieve this goal and the practicality of doing so are presented.

Jan 1, 1988

By H. Warren Newcomen

The southwest wall of the Lornex Pit at the Highland Valley Copper mine has been experiencing slope displacements since 1978. Measures to manage the displacements on previous pushbacks have included stepping out, scheduling pushbacks to unload the crest of unstable areas, slope dewatering and mining with intensive slope monitoring. The final pushback on this wall is currently being mined and substantial modifications to the slope geometry could prove to be uneconomic. As a result, a campaign of surface water collection and diversion, horizontal drainhole drilling and deep well drilling is currently underway to maintain an acceptable degree of stability to the end of mine life. The various factors contributing to instability, including engineering geologic controls, rock mass strength, and surface and groundwater hydrology are presented. Movement trends, displacement magnitudes and stability analyses results are also discussed.

May 1, 2002

By Derek H. C. Wilton, David T. W. Evans

"Abstract - The Midas Pond gold prospect, central Newfoundland, is hosted by sheared and altered felsic and mafic pyroclastic rocks of the Tulks Hill volcanics, Victoria Lake Group, and has been trenched and tested by 19 diamond-drill holes. Gold values are sporadic, with the best diamond-drill intersection assaying 7.3 g/t over 0.9 m, and the highest grade channel sample containing 14.7 g/t over 1.15 m. Alteration and mineralization are confined to a 200 m wide brittle-ductile shear zone. This shear zone formed in response to regional D1 deformation, and the shear zone fabric parallels the regional S1 foliation. D2 deformation resulted in broad Z-shaped flexuring of the shear zone. The deformation was probably related to the ca. 396 Ma to 420 Ma Salinic Orogeny.Advanced argillic alteration and an extensive halo of Fe-carbonate and pyrite surround the gold mineralization. Alteration minerals include pyrophyllite, paragonite, quartz, plagioclase, chlorite, fluorite, Fe-carbonate, and pyrite. As such, the alteration seems to reflect combined epithermal (argillic) and mesothermal (carbonate) mineralizing environments. The argillic alteration and fluorite represent a regional hydrothermal effect on the felsic volcanic rocks; whereas, the Fe-carbonate and pyrite represent a mesothermal alteration associated with auriferous quartz veins. The Au, which is spatially associated with pyrite, occurs in three structurally-controlled vein sets. These veins are confined to the contact between a highly deformed breccia (the banded mafic tuff) and structurally overlying, altered felsic tuffaceous rocks. The vein sets include: V1 boudinage veins that parallel the shear-zone fabric (C-shear veins), and V2 and V3 extensional fracture veins which are controlled by an S2 fracture cleavage. V1 veins are the earliest and contain the lowest concentrations of Au. V2 and V3 veins are concentrated within the hinges of the D2 flexures.Pb isotope data for galena separates indicate that the Pb in the vein systems was probably of local derivation. Sulfur, C, and O isotope data for mineral separates are similar to data for typical mesothermal lode gold deposits. Fluid inclusion data suggest the presence of at least three hydrothermal fluid types in the region, viz., (1) an early saline fluid which produced the argillic alteration, (2) a CO2-bearing fluid directly related to the auriferous mineralization, and (3) H2O-NaCl fluids which flowed through the Midas Pond shear zone at a lateral distance from the zone of mineralization. The mineralizing fluids are interpreted to have been CO3 -2-rich types which originated through metamorphic dehydration and decarbonation of mixed island-arc and continental crustal rocks. Gold precipitation resulted from the reaction of these fluids with the Fe-rich breccia unit. Pre-existing and simultaneously crystallizing pyrite served as loci for Au precipitation."

Jan 1, 2000

By W. Greg Maybee

Separations, which form along stratigraphic boundaries in the roofs of potash mines, pose a serious safety concern. If these separations go undetected they can lead to falls of ground. The current method of identifying the location and extent of these separations is through manual scaling (sounding) using an aluminium rod. The potash mining companies would like to have a tool, which could quickly and reliably detect these separations and distinguish between them and clay seams. This paper presents the results of field trials undertaken at various potash mines in Saskatchewan belonging to the member companies of the Saskatchewan Potash Producers Association. A ground penetrating radar instrument from RST called SUSI (stepped frequency, ultra-wideband, synthetic aperture radar instrument) was used. SUSI has the ability of working over various frequency bandwidths. Four mines were chosen for these field trials, covering the different geological characteristics encountered in the Saskatchewan potash mines: Potash Corporation of Saskatchewan?s (PCS) Allan and Lanigan Divisions, Agrium?s Vanscoy Potash Operations and IMC Potash?s K2 Mine. These field trials indicated that stepped frequency ground penetrating radar technology could be ?tuned? to identify both separations and clay stratigraphy in the softrock, potash mine environment, based on the different spectral responses of the features.

May 1, 2004

By T. J. Yeomans

"The Kidd Creek metallurgical site is situated twenty-six kilometres east of Timmins, Ontario. The site consists of a 4.5 niillion tonne per year concentrator, a 127,000 tonne per year electrolytic zinc plant and a 79,000 tonne per year copper smelter/refinery complex.The concentrator commenced operations in 1966 and was expanded to its present capacity in 1978. The zinc plant commenced operations in 1972, and the copper smelter/refinery in 1983.The concentrator tailings, and both liquid and solid waste products from the other plants are disposed of within a 1215 hectare tailings disposal area. Here, a method known as centraljzecl thickened discharge is used to form a stable cone-shaped hill. A low permanent perimeter dyke structure encloses the cone and directs cone run-off and thickener overflow to a treatment pond. After treatment with lime slurry, this neutralized effluent is recycled to the metsite and also discharged into the Porcupine River system.The tailings system has been in operation in its present form since 1972, upon completion of dykes and a 110 metre thickener unit. Underflow densities were continuously increased until thickener overloading became a serious problem. This necessitated the construction of a second 110 metre thickener, which was completed in 1983. Target densities have been achieved without difficulty since then.This paper discusses the operation of the tailings system, reviews past performance, and outlines future operations."

Jan 1, 1986

By J. E. Scott, L. M. Heaman, R. A. Creaser, G. S. Salazar

"Schaft Creek is a calc-alkaline porphyry Cu-Mo-(Au) deposit located in northwestern British Columbia. The deposit formed in a volcanic arc setting, likely on a back-arc rifted continental fragment. It is hosted by Late Triassic basaltic to andesitic volcanic rocks of the Stuhini Group (Stikine Terrane), and is associated with porphyritic granodiorite dikes emanating from the nearby Hickman batholith. The age of the Hickman batholith is approximately constrained here by a composite U-Pb zircon date of 222.1 ± 9.6 Ma, which is in broad agreement with a well-constrained age for mineralization at Schaft Creek of 222.0 ± 0.8 Ma (Re-Os molybdenite). The deposit is in most respects typical of calc-alkaline porphyry systems, but displays silica-poor sericite-chlorite alteration in mafic country rocks in place of classic phyllic altera¬tion. The deposit comprises three distinct, but related, zones: the northern Paramount zone, the Main zone, and the West Breccia zone. Two phases of mineralization are observed. The first phase occurs as hydro-thermal veins and breccias, and minor disseminations. It consists of bornite, chalcopyrite, molybdenite, and pyrite with potassic and sericite-chlorite alteration. The second phase is minor and consists of veins of molybdenite ± specularite, as well as Cu-Pb-Zn sulfide veins without any significant corresponding alteration. Extensive structural modification has affected the deposit both during and after its formation.Schaft Creek est un gîte porphyrique de Cu-Mo-(Au) calco-alkalin situé dans le nord-ouest de la Colombie Britannique. Ce gîte s’est formé dans environnement d’arc volcanique, probablement situé sur un fragment continental bordé par un bassin d’arrière-arc. Le gîte est encaissé par les roches volcaniques basaltiques à andésitiques du Groupe de Stuhini (Terrane de Stikine) d’âge Triasique tardif, et est associé à des dykes de granodiorite porphyrique provenant du batholithe de Hickman avoisinant. L’âge du batholithe de Hickman est estimé par un âge U-Pb composite sur zircon de 222.1 ± 9.6 Ma, lequel est grossièrement en accord avec l’âge de la minéralisation de Schaft Creek, estimé a 222.0 ± 0.8 Ma (Re-Os sur molybdénite).Ce gisement, bien qu’à plusieurs égards typique des systèmes porphyriques calco-alcalins, présente une altération en séricite-chlorite pauvre en silice dans l’encaissant mafique a la place de l’altération phyllique classique. Ce gîte comprend trois zones distinctes bien que connexes : la zone Paramount au Nord, la zone Principale et la zone West Breccia. Deux phases de minéralisation sont observées. La première phase se présente sous forme de veines et de brèches hydrothermales ainsi qu’en disséminations mineures et consiste en bornite, en chalcopyrite, en molybdénite et en pyrite avec une altération potassique et en séricite-chlorite. La seconde phase est mineure et consiste en veines de molybdénite ± spécularite ainsi qu’en veines de sulfures de Cu-Pb-Zn sans association à une altération particulière. Le gisement a été profondément modifié par la déformation a la fois durant et après sa formation."

Jan 1, 2008

By John Folinsbee, Brian Danyliw, Tony Y. Chong

"Control of fugitive dust has become increasingly important in the mining industry both from a health and safety and environmental standpoint. Mining operations in particular have required improved fugitive dust control due to recent lowering of the allowable airborne silica concentration to which workers can be exposed. Experience has now proven that the implementation of a surfactant based chemical dust suppression system can enhance existing mechanical dust control methods resulting in much more efficient control of fugitive dust.The Porcupine Joint Venture (Dome Mine) utilizes dry secondary crushing and screening that makes it particularly prone to fugitive dust emissions. A variety of potential dust control systems were evaluated and this led to the installation of a surfactant based water spray system to augment the existing mechanical dust collection systems.A great deal was learned through the implementation of this system. This paper describes the entire process, from testing, system design and installation, through optimization and standardization of operation. In addition a variety of problems were identified, and innovative solutions were provided. Also, the metallurgical impacts on down stream processing are highlighted. Finally, a full discussion of overall results including a discussion of the relationship between silica and total dust concentrations is included."

Jan 1, 2005

By G. M. Ritcey, K. E. Haque, S. H. Lucas

"Laboratory-scale hydrochloric acid leach tests were conducted on an Elliot Lake uranium ore. Hydrochloric acid leaches without an oxidant or with molecular oxygen (i.e., air or pure oxygen gas) as an oxidant favoured uranium and radium extractions. Conditions for maximum uranium, thorium and radium extractions with hydrochloric acid in the presence of sodium chlorate were determined. The highest extractions of uranium (96%), thorium (81%) and radium (91%) were obtained using a mixture of 44.0 kg HCI and 2.5 kg NaCIOJ per tonne of ore at 75°C with 18 hours ' retention.Flowsheets for two-stage leaching are proposed. The residues obtained from the second-stage leach contain uranium (0.002%), thorium (0.006%) and radium (15 to 20 pCi/g). Tailings of this nature are considered suitable for mine backfill, and, if pyrite is removed, suitable for surface disposal.IntroductionThe nuclear energy industry forecasts an increasing demand for uranium. This increasing demand requires not only largescale mining and processing of conventional and complex uranium ores, but also leads to the consideration of new and nonconventional sources of uranium, e.g., black shales, phosphate rocks, granite, sea water and fossil-fuel ash."

Jan 1, 1980

By J. Molgaard, J. Masounave, J. Prinsen, P. Beaulieu, G. Huard

"A study carried out on behalf of the National Research Council (NRC) indicates that economic losses due to wear in the Canadian mining industry are in excess of $700 million annually. Severe wear, mainly by abrasion, was identified as the most important wear mechanism in terms of possible savings. One way to reduce losses would be the proper use of databases. A joint project of The Canadian Institute of Mining and Metallurgy (CIM) and NRC (Tribology laboratories at IMRI) has been initiated to create a factual database containing all relevant experience in the area of wear in the Canadian mining industry. As a first step, a prototype covering slurry pumps is being built. This should help to answer many questions, such as the number of people involved, interest from industry, cost vs benefits, etc.IntroductionTribology is concerned with the understanding of the mechanisms of friction, wear, and lubrication.Tribology is concerned with the correct use of materials for interacting solid surfaces, with the interaction of those surfaces with lubricants, with the chemistry, physics and use of lubricants and their additives. It is concerned with the reduction of friction and wear (or, in the case of belts, brakes, clutch plates, and similar devices, in achieving optimum friction with minimum wear) and is concerned with the avoidance of associated failures in machinery.Lubrication is usually the solution to a problem of friction and wear. Yet far from all the problems of friction and wear are solved by lubrication. The wear of grinding rods or shovel track pads can hardly be solved by lubrication, to name just two examples with which mining engineers will be familiar. There are indeed many situations of wear and friction where the surfaces in contact are unlubricated.In part, tribology is a matter of design. A major aspect, however, has to do with the choice of materials, to satisfy external constraints upon the component design or choice. The operating conditions for much industrial equipment, particularly in mining are, often very severe. The development of wear resistant materials, including materials which are applied as coatings, is clearly an important technology from the point of view of tribology."

Jan 1, 1987

By Bernard Jones

LTUG ? A meeting of many mining companies that are using large tires ? Introduction of the mines and size ? Companies go over their usage of tires and performance ? As a group we discuss how the manufactures are doing with supplies and performance (who's running what sizes and manufactures they are using) ? The mine's best practices they use (which ones work for them and which ones don't) ? Where the mines see themselves going in the future ? What type of tire management the mines have in place

May 1, 2009

By K. Hoover, G. Labarre, S. Rantanen

"As part of the Namew Lake project a mill was constructed to treat 1900 tpd of ore grading approximately 0.90% CU and 2.45% Ni to produce copper and nickel concentrates.Nickel occurs mainly as pentlandite and violarite while copper occurs as chalcopyrite. Two main ore types are present1 lower grade disseminated sulphides in a talcose ultramafic gangue and a higher grade solid sulfide with a granitic breccia matrix.Primary crushed ore from underground is treated on surface in a conventional closed circuit crushing plant using 2-stage cone crushing. Crushed ore is conveyed to storage and then fed at a controlled rate to a grinding circuit employing a rod and ball mill with hydrocyclone classification. Rougher flotation separates and cleans nickel and copper sulfides from waste materials followed by a high lime separation circuit to separate the minerals into final concentrates. Dewatering is achieved through use of high capacity thickeners and pressure filters prior to delivery to a loadout area. The crushing and milling control is highly automated.Plant design was based on metallurgical samples obtained from drill cores. After the first year of operations, plant results compared favourably with design projections.INTRODUCTIONThe Namew Lake Project is a joint venture partnership between Outokumpu Mines Ltd. (Canada) and Hudson Bay Mining and Smelting Company Ltd. (60%). The project included construction of a mine and milling complex to treat approximately 500,000 tonnes per year of copper-nickel ore grading o.91% and 2.44% Ni. Known reserves are estimated at 2. 65 million tonnes. The deposit is located approximately 65 km south of Flin Flon (120 km by road) and about 5 km east of the Manitoba-Saskatchewan border. The decision to construct a concentrating facility was made June 15, 1987 and construction started a week later. The facility, designed for 1900 tonne per day throughput, was ready for commissioning in September 1988. Outokumpu Engineering of Finland was chosen to prepare metallurgical flowsheets, select and develop plant layouts, and provide construction management. Kilborn (Toronto) contributed detailed engineering for civil, structural, mechanical and electrical components and outokumpu Equipment of Canada, the design, the supply, and commissioning of the instrumentation package. Hudson Bay undertook the initial metallurgical test work and preliminary design work."

Jan 1, 1990

By Norman O. Lotter, Lori Kormos, Greg J. Wilkie, Peter J. Whittaker, Johannes S. Stickling

"Assessment of opportunities to improve mineral processing performance in existing concentrators and in describing undeveloped orebodies is key to improving the business case of a mining company. This assessment has traditionally been performed using the distinct and separate inputs from Mineral Processing and Mineral Science.More recently, Process Mineralogy has been used to integrate these two disciplines. This trend has been driven by the need to develop and process more challenging ore deposits, and has been assisted by the availability of modern automated instruments. Together with the acquisition of a QemSCAN (Quantitative Evaluation of Materials by Scanning Electron Microscope) from CSIRO in Australia, and with the use of a supporting SEM with EDX / WDX capabilities and an XRD, the development of Process Mineralogy at Falconbridge commenced in 1997.The sampling challenges in presenting a QemSCAN with representative sample material at the polished section level are significant, but have been effectively addressed. The full description of this aspect is beyond the scope of this paper.It is shown that, by use of this approach, the set nature of an orebody can be best exploited with selected flowsheet changes in a concentrator which address the generic characteristics of the orebody. In this way, the flowsheet provides a process that more effectively fits the mineral processing requirements of the ore. This leads to clear and tangible improvements in grade and recovery."

Jan 1, 2002

By David Clarry

?The issue ?reduction requirement ?Planning abatement steps ?Energy Management & Energy Efficiency ?Energy Recovery / Utilization ?Alternative Energy Professional Services Overview ?Capital Projects and Construction ?Project Development and Planning ?Engineering ?Project management ?Construction management ?Consulting ?Process ?Business ?Environmental ?Technology ?Operational Services ?In-house engineering services for operations

May 1, 2009

By L. D. Smith

Net Present Value Impact of Discount Rate The Discounted Cash Flow (DCF) method of valuations is universally used and accepted. The main criticism of the method is that it does not recognize the value of projects long life projects. This can be seen in the preceding graph where the present value of cash flows in later years are small for discount rates over about 10%. This graph covers a project that has a 25 year operating life. It is clear from the low height of the NPV bars at 10% and 15% in the last years of the project that an additional 25 years would add almost no value to total project NPV. As an example of this effect, an colleague undertook the evaluation of a pulp and paper project. The plant could be justified, but it was not possible to justify planting the trees as they took too long to grow and so had not appreciable NPV. The plant had to purchase wood to feed the plant.

May 1, 2013

By Jan E. Nesset, Julie Fournier, Jorge Torrealba, Colin Hardie

"Gas dispersion studies have been used to benchmark and optimize plant flotation performance for more than a decade, although this technology is not as widely in use as it likely should be based on the significant improvements that have been reported. Part of the reason may be a general lack of awareness within the industry of just what these improvements have been. This paper reviews a number of the reported case studies, groups them into categories of improvement, and draws some general conclusions. The paper will be of interest to plant engineers and technology providers seeking new approaches and tools for improving their own and clients’ processes.INTRODUCTIONThe sector of flotation hydrodynamics that is now known as gas dispersion technology, and the corresponding terminology, had its beginnings in the 1980’s and early 1990’s in the laboratories of McGill University where the students of Prof. J.A. Finch and Dr. C. Gomez conducted studies of gas holdup, superficial gas rate and water recovery on laboratory flotation columns (Laplante et al., 1983; Xu et al., 1991;, Banisi and Finch, 1994; Finch et al., 1999; Nesset, 2011). Sensors were developed for gas holdup (eg), gas rate (Jg) and bubble size (Db) distribution (Tavera et al., 1996: Finch et al., 1999; Dahlke et al., 2001; Chen at al., 2001; Hernandez-Aguilar et al, 2002, 2005). The sensor measurements were rapidly adapted for use in mechanical flotation machines in plant environments (Gomez and Finch, 2002; Gomez et al., 2003; Cooper et al, 2004; Torrealba-Vargas et al, 2004; Nesset et al., 2007). Somewhat parallel developments were being conducted by Gorain and colleagues at the University of Queensland’s JKMRC on pilot and industrial flotation machines using the McGill approach but utilizing alternate sensor designs for eg, Jg and Db (Gorain et al., 1997, 1999; Schwarz and Alexander, 2006) to link flotation kinetics to bubble surface area flux (Sb). Early industrial applications were those led by the university teams from McGill (Canada), the JKMRC (Australia) and the University of Santa Maria (Chile) at plants in North and South America, Australia, South Africa, Asia and Europe. Industrial organizations that brought the technology on-board in the early 2000’s included Teck Resources (then Teck Cominco), COREM, Vale (then Inco), Anglo American Platinum. Several of the major flotation cell manufacturers also purchased the McGill bubble viewer technology for their own equipment studies. The sensors have continued to evolve with multiple and continuous measurement of Jg (Torrealba-Vargas and Finch, 2006, Bartolacci et al., 2008), gas holdup by acoustic means (O’Keefe, 2007) and a combined Jg-Db device called the Anglo Bubble Sizer (Harbort and Schwarz, 2010). A review of the gas dispersion technology use and development have been provided by Gomez and Finch (2002), Harbort and Schwarz (2010) and Nesset (2010)."

Jan 1, 2015

By Carol E. Jones

Outline ? Reclamation is a primary mitigation. ? Understand baseline environment and land use. ? Determine reclamation goals. ? Selecting reclamation technology. ? Determine technical risk. Reclamation ? Primary Mitigation ? Through land and water disturbance, mining can have significant local and regional environmental impacts. ? Impacts can also result from associated land use changes. ? Reclamation is a primary tool that the mining industry uses to manage its environmental impacts.

May 1, 2008

By M. -C. Noël, G. P. Demopoulos

In this work the formation and environmental stabilization potential of arsenate-containing fluoroapatites is considered. In particular in this research various compounds were precipitated from synthetic solutions containing fluoride, arsenate/phosphate and calcium by varying different parameters-temperature, Ca:As ratio, pH, and P:As ratio, and aging time. The results obtained helped determine the operating window that should be used for the formation of highly crystalline fluoroapatites, in particular svabite (Ca5(AsO4)3F). It was found that svabite has a specific pH range of precipitation, with lower pH yielding CaF2 and calcium arsenate compounds such as CaHAsO4•H2O. At higher pH, a mixture of svabite and johnbaumite (Ca5(AsO4)3OH) precipitated, yielding a less stable material. This range of precipitation varied with the concentration of arsenic in the starting solution, and widened with higher initial concentrations of Ca2+, AsO4 3- and F-. Furthermore, svabite/fluoroapatite solid solutions were formed by using the same procedure as svabite but replacing some of the arsenate in solution by phosphate. The increase in phosphate content yielded a gradual change in morphology and crystallinity. Work on stability evaluation is currently under way.

Jan 1, 2014