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By D. R. Lentz, S. H. Mcclenaghan, J. A. Walker

"Abstract - The Orvan Brook deposit is one of several (Zn+Pb>>Cu)-rich sulfide deposits hosted by the Spruce Lake Formation (California Lake Group) in the northwestern part of the Bathurst Mining Camp. This parautochthonous deposit is hosted by a narrow band of highly deformed, locally graphitic shale that appears to conformably overlie felsic volcanic rocks of the Spruce Lake Formation, and is in tectonic contact with overlying mafic volcanic and related sedimentary rocks of the Canoe Landing Lake Formation. The Spruce Lake Formation is dominated by felsic volcanic rocks and subordinate fine-grained sedimentary rocks, and mafic volcanic rocks (Canoe Landing Lake member). The felsic volcanic rocks can be divided into aphyric and feldspar-phyric rock types. The feldspar-phyric rocks and a few of the aphyric varieties have a Zr/TiO2 ratio of 0.06, and fall into the California Lake Group field on a Y/TiO2 versus Zr/TiO2 diagram. In contrast, the aphyric felsic volcanic rocks have Zr/TiO2 ˜ 0.09 and are marked by high Zr and Th, which is consistent with highly fractionated felsic magma of Spruce Lake affinity. Major and trace element analyses of host rocks suggest that weak to moderate hydrothermal alteration developed on the south side (stratigraphic footwall) of the deposit, which is consistent with a north-younging succession. The sulfide lens strikes east-west for approximately 2.3 km, extends down-dip for at least 500 m locally, and has an average thickness of between 0.75 and 1 m, but is locally up to 5.5 m thick. The contacts of the massive sulfide lens with its host rocks are invariably sharp. Host rocks show evidence of intense ductile deformation as well as later brittle deformation. Compositional layering and sulfide breccia textures in the sulfide body are interpreted to result from deformation or tectonic enhancement of original primary layering. The deposit contains an estimated resource of 2.69 Mt grading 1.73% Pb, 5.95% Zn, 0.37% Cu, 72 g/t Ag, and 0.9 g/t Au. Similarities in bulk d34S between the Orvan Brook (+8.6‰) and the nearby Cu-rich McMaster deposit (+8.2‰) suggest a common depositional setting."

Jan 1, 2006

By P. Lostritto, G. E. Agar, G. Labonte, M. Cherevaty

"A locked cycle flotation test was done on a sample from the ovoid portion of the Voisey 's Bay copper-nickel sulphide ore. The chemical conditions for this test were generated by prior independent testing. In this test work the time in each of the five separation stages was optimized prior to executing the locked cycle test. A numerical simulation of the continuous circuit material balance was done prior to the locked cycle test. The test results were not fully satisfactory because the flotation of pyrrhotite in the bulk rougher and cleaner stages was not consistent. The preliminary indication was that the samples had oxidized to varying degrees during storage.INTRODUCTIONINCO has performed batch laboratory flotation testing on ore from Voisey's Bay which is a mixture of chalcopyrite, pentlandite and pyrrhotite. Earlier, Lakefield Research was contracted by Diamond Field Resources to test the ""flotability"" of the ore, which included a pilot plant trial. INCO's J. Roy Gordon Research Laboratory has repeated many of the batch tests that Lakefield did to verify their results. Based on their own work, INCO has modified the circuit proposed by Lakefield Research. The modified circuit is based on batch test work, but no locked cycle test (LCT) was done. It is believed that this circuit will produce a copper concentrate at 29-30% copper and a primary nickel concentrate at 15-20% with recoveries of 80% or above.For several years the University of Toronto has been working with INCO to provide ""hands on"" experience for undergraduate students as an Industrial Research Project (IRP). This year, the objective for IRP was to optimize the time for each of the five separation stages for the Voisey's Bay ore then to numerically and experimentally simulate the material balance for a continuous circuit."

Jan 1, 1998

By Paul Bedard, Réal Daigneault, Guy Perrault

"La mine Lamaque est située a Val d'Or, Québec; les roches hônes appartiennent au groupe de Malartic, partie supérieure, et sont des andésites et des pyroclastites. On y retrouve deux formes d'intrusifs; des petites cheminées (ca. 150 m D) et des dykes (ca. 10 m d'epaisseur). Les petit es cheminées contiennent:1 - des diorites et des tonalites (cheminées principale, est et ouest) d'affinité calco-alcaline: Zr 140 ppm, Sr 761 ppm, P2O5 0.31% et (La/Sm)n 3.0;2 - des diorites (cheminée 4) d'affinités tholéiitique: Zr 32 ppm, Sr 181 ppm, P2O5 0.27% et (La/SM)n 1.5.La diorite de la cheminée no 5 contient deux fractions, une de chacune de ces deux affinités. Les dykes tant de porphyre feldspathique quartzifére que ceux de prophyre feldspathique sont d'affinité calco-alcaline: Zr 83 ppm, Sr 500 ppm et P2O5j 0.10%.Le gisement de 10 mine 2 est filonien: veines subhorizontales (""flats "") surtout et veines sub-verticales dans des zones de cisaillement. Le dernier réajustement structural de direction de compression nord-sud a broyé le quartz des veines existant es et rendu possible leur minéralisation. Les veines minéralisées contiennent du quartz, de la tourmaline, de la calcite avec des traces de scheelite, de pyrite et d'or; elles sont bordées par de minces (2 à 20 cm) bordures d'altération où l'on retrouve un enrichissement en carbonate, paragonite, apatite, rutile, saphène et zircon et où les phases ferromagnésiennes sont disparues. On a documenté le migrations géochimiques suivantes:I - de la bordure d'altération vers l'éponte, K2O, Rb et MgO;2 - de l'éponte vers la bordure d'altération, Na2O;3 - de l'éponte vers la veine, SiO2.P2O5, TiO2, Zr, Y, Nb et CaO sont enrichis dans la bordure d'altération."

Jan 1, 1983

By X. Shi

Magnesium, the lightest structural metal, has not yet been considered as a serious contestant for automotive use due to its weaknesses in corrosion. Electroless nickel-boron alloys are well known for their corrosion resistance and hardness. An electroless nickel-boron layer was successfully deposited first on the chemical conversion pre-treated AZ31 alloy and also on the Ni-P coating which was deposited on the conversion coating. The electroless bath contained nickel sulphate and dimethylamine borane (DMAB) as main salts and the samples were activated by a 5 g/L AgNO3 solution before the electroless plating process. The presence of the conversion coating between the nickel coating and the AZ31 substrate acted as a barrier and prevented corrosion of the alloy. The morphology of the nickel-boron layer was studied using SEM. The crystal structure and the composition were examined by EDS and the hardness was measured. The corrosion behaviour of the nickel-boron layer deposited on the conversion coating and on the Ni-P coating was studied using potentiodynamic polarization in a 0.5M NaC1 solution. A saturated standard calomel electrode was used as a reference electrode. The results show that the nickel-boron coatings had a significantly better corrosion resistance than the AZ31.

Jan 1, 2006

By H. Oterdoom, S. Pilger, T. P. Bui, J. Rotarius

"Most FeNi furnaces used to rely on post-combustion and off-gas cooling inside the furnace to eliminate the produced CO gas, and control the off gas temperature. As furnace load, capacity, and thus gas volumes increased over the years, this led to increased instabilities that can cause problems in controlling the operation. Some of the large capacity furnaces nowadays work with partial or full combustion outside the furnace, more similar to the steel industry. Forced combustion with or without enriched air and other additions can support in controlling post-combustion, stabilizing and even reducing off gas amounts, and affecting composition. This paper presents some of the possibilities and advantages of having a specially designed post-combustion system for the FeNi laterite industry, but that could also be applied to other processes as well.Large Scale Furnaces In the FeNi industry, the Rotary Kiln Electric Furnace (RKEF) process is still going strong in spite of continuous hope that hydrometallurgical processes will one day make the RKEF plant obsolete. Within the pyrometallurgical plants there is a continuous trend for larger scale furnaces. The development for a number of furnaces that were started before 1985 and increased capacity by “natural growth” is given in Figure 1. Natural growth refers to the development of the plants that after having mastered a certain level of operation, were ready for a higher load that could be installed either with a new furnace on the same site, or during a revamp. The advantages of natural growth are numerous, for example: •,Deep knowledge of the ore and its’ behavior, no need for testing, and little risk of surprises. •,Mining, laboratory, equipment, etc. is all proven technology for the conditions on site. •,Starting a furnace with increased capacity is a re-start, not a green-field commissioning. •,Typically, when increasing the production capacity of an existing plant, not the entire plant is commissioned for the first time, but only a part. In the FeNi laterite industry for example, the kilns may already have had the capacity to provide enough material."

Jan 1, 2017

By Gordon E. Forward

Sustainable development in the mining and metallurgical industrial sectors can be implemented by two distinct groups: 1. The managers and operators of existing facilities ? working with industrial processes and systems that have been operating for many years, in some cases several decades 2. Those who are engineering and building new facilities or upgrades of existing plants. The focus of this paper is to look at approaches and tools available to bring sustainable development thinking and action to these two distinct areas. The paper will discuss: 1. The concept of working with existing facilities and processes to minimize waste and maximize product from a regional raw material/resource consumption perspective using By-product Synergy. The BPS concept has been carried out in Texas (TXI-Chaparral?s STAR Example), in Calgary, Alberta with Suncor assistance, in Montreal, Quebec with Noranda as project leader and currently in Ontario with Dofasco as industry champion. Successful outcomes are presented. 2. A new approach to designing greenfield facilities or upgrades to existing plants using a sustainable development review process. Undertaking the review early in every project can institutionalize the concept of discussing and implementing waste elimination, design for environment, eco-efficiency, risk minimization and community awareness and involvement in the future capital stock. The review process has been developed as an excellent tool for measuring and reporting on a corporation?s sustainable development progress. Examples of how this approach has been adopted in the mining and metallurgical industry, and the resultant outcomes are given.

May 1, 2002

By W. H. Gauvin, N. J. Themelis

I N ADDITION to its practical importance in the beneficiation of iron ores and in direct-iron processes, the study of the reduction of iron oxides involves many aspects of challenging theoretical interest. The complexity of the reduction process combined with the fact that under different experimental conditions the controlling stage for the reaction may not necessarily be the same, has led experimenters in this field to a wide diversity of opinion regarding the reaction mecl1anism. As a rule, each investigation has been restricted to the study of one or two variables over a comparative]~• narrow range of experimental conditions, and consequently, it be-comes necessary to examine the significance of each published work in the light of the results of other experimenters in the field.

Jan 1, 1962

By E P. Graham

Orebodies occur in an infinite variety of grades, shapes and sizes, and take many millions of years to grow. When extraction starts there is only one possible end -the mine sooner or later will run out of ore and shut down. If the mineral industry is to supply the ever increasing demands of modern civilizations, more and more metals must be found and mined. This will require a never-ending search for ore, and the development of every economic body, large or small. To justify the mining of a small orebody, it first of all must pay its way. If the size of the burden imposed by the capital cost estimates is not carefully worked out, an otherwise promising situation could be killed. The very nature of mining, as a transient industry, re-leases a steady stream of good used equipment, and the trained personnel to install and operate it. All manner of plans and layouts, which can be utilized at a new property, are available. Working these and other economies into the estimates will sometimes make enough difference to give a prospect the green light.

Jan 1, 1964

By Dalton Fowler

"Pressure vessels used in pressure leaching and pressure oxidation processes in the mining industry are often lined with acid resistant brick and membrane systems. Although the options available when it comes to selecting materials and linings designs for these vessels appear somewhat limited there are, nevertheless? several choices which must be made in order to successfully design, manufacture and construct these linings. These choices require careful evaluation of materials properties which include, among others, thermal conductivity, thermal expansion, chemical swell, and modulus of elasticity, as well as a variety of construction methods.Some of the options available, and some of the means of evaluating them objective of this discussion."

Jan 1, 1999

By Scott Honan, Tassos Grammatikopoulos, Mike Johnson, Kelton Smith, Niels Verbaan, Ernesto Bourricaudy, Eric Larochelle, Rick Sixberry

"NioCorp is developing the niobium/scandium/titanium Elk Creek carbonatite resource deposit. The carbonatite phase contains significant niobium (0.71% Nb2O5), titanium (2.68% TiO2) and scandium (72 g/t) and is composed predominantly of calcite, dolomite and ankerite. Niobium is mostly (80%) contained in the pyrochlore and the balance in various Fe-Nb-Ti oxides, which also host most of the titanium. Scandium is distributed homogeneously throughout the ore mineral assemblage. The process flowsheet recovers separate niobium, titanium and scandium products. Scandium is extracted from whole ore hydrochloric acid leach solutions through solvent extraction, and is further refined through a re-leach and precipitation process. Scandium leach residues are treated with sulphuric acid to recover separate niobium and titanium precipitates. Both hydrochloric acid and sulphuric acid reagents are recycled within the flowsheet. This paper will discuss key bench and pilot test results (focusing on the scandium flowsheet) and will present a conceptual flowsheet developed by the project team for NioCorp at SGS Minerals.INTRODUCTION NioCorp is developing North America's only niobium/scandium/titanium project. The Elk Creek project is located near Elk Creek, Nebraska, and is the highest grade niobium project in North America and the largest prospective producer of scandium in the world. These elements are unique and valuable superalloy materials that are strategic and critical to many industries and national defense technologies. The project includes the Elk Creek Carbonatite (the Carbonatite) that intruded older Precambrian granitic and low to medium grade metamorphic basement rocks. Both the carbonatite and Precambrian rocks are interpreted to be unconformably overlain by approximately 200 meters (m) of Paleozoic marine sedimentary rocks of Pennsylvanian age. As a result of this thick cover, there is no surface outcrop within the Project area of the carbonatite, which was identified and targeted through magnetic surveys and confirmed through subsequent drilling. The available magnetic data indicate dominant northeast, west-northwest striking lineaments, and secondary northwest and north oriented features that mimic the position of regional faults parallel and/or perpendicular to the Nemaha Uplift."

Jan 1, 2017

By M. Laframboise, M. Buarzaiga

High-pressure acid leaching (HPAL) of nickel laterites has received considerable attention in recent years. High paymetals extraction, good selectivity, and advances in pressure hydrometallurgical technology are some of the reasons for this interest. Falconbridge Limited (Sudbury. Ontario) investigated the HPAL process using both fresh water and seawater for ore processing. The use of seawater resulted in a chloride concentration of 7.8 g/L in the autoclave feed. A test program was developed to study the effect of process water and leach temperature on the leaching behaviour of different ore compositions from the Koniambo deposit in New Caledonia. The work showed that salinity has a major effect on autoclave chemistry. This paper explores the results.

Jan 1, 2004

By E. Uzun

"In this study, H2SO4 and HCl leaching behaviour of an ore sample containing 1.87% of Ni, obtained from the Karaçam (Eskisehir-Turkey) lateritic deposit that started operation recently was investigated. Acid concentration, temperature and reaction time were investigated as variables by comparative leaching tests and the optimum leaching conditions were selected on teh basis of Ni, Fe, Co and Mg behaviour. For H2SO4 leaching, optimum leach parameters were 95°C, a 12 normal H2SO4 concentration and 90 minutes of reaction time, and under these conditions Ni and Fe dissolutions were 97.6% and 95.4% respectively. On the other hand, 70°C, an 8 normal HCl concentration and a reaction time of 90 minutes were found to be the optimum parameters for HCl leaching, and Ni and Fe dissolutions found were 97.1% and 97.8%, respectively.INTRODUCTION Today, nickel and various nickel compounds are obtained from sulphide and lateritic nickel ores (Moskalyk & Alfantazi, 2002). Even though about 72% of the world's nickel reserves constitute lateritic ores, only about 42% of nickel is produced from these ores. The decrease in production from sulphide deposits, on the other hand, and increases in the use of nickel in the iron and steel, and battery production sectors, and especially the production of nickel cast irons in recent years, have accelerated the importance of making use of lateritic deposits (Luo et. al., 2010; Chang et. al., 2010). In the beneficiation of sulphide nickel ores, mostly pyrometallurgical methods are used. On the other hand, about 39% of lateritic ores are beneficiated by pyrometallurgical, and 61% are beneficiated by hydrometallurgical methods (USGS, 2009). In laterite beneficiation, the ore properties are of significance; that is to say, limonitic ores are eneficiated by high pressure acid leaching or via the Caron process, nontronitic ores are beneficiated by high pressure acid leaching or heat treatment (smelting), and ores containing serpentine by pyrometallurgical methods (Berezowsky, 2004; McDonald & Whittington, 2008a; Dreisinger et. al., 2015)."

Jan 1, 2017

By C-D. Johansson, B. Ögren, B. M. Ludvigsson, K-Å. Johansson, R. Lindh, G. Berg, M. Maliarik

This paper presents the High Current Density (HCD) Silver Electrorefining Process. A 25-year history of development of the silver electrorefining process as well as associated equipment is given. The process is simple and robust, but at the same time highly automated. With low operating costs and man power requirement it allows consistent production of 99.99 % quality cathode silver. The process ensures that no toxic gases are formed in the working environment. Silver Electrorefining is a heart of a Silver Refinery plant covering the complete range of processes from casting of silver Doré anodes to casting of the bars of refined silver or/and silver granulation. The process has been successfully applied at 11 installations world-wide with plant capacities ranging from 30 to 1500 tpa.

Jan 1, 2014

By A. Mitrašinovic, A. Wolf

"The aim of this investigation was to determine the most suitable additive for recovering metals from converter slags generated during Ni extraction. Fluxes analyzed were silica and lime and reductants included pig iron, ferrosilicon and copper-silicon compound. Slag was settled at 1300°C for one hour to simulate the smelting environment. The newly formed matte and slag were characterized by chemical composition and morphology. Microstructural studies showed that slag formed after adding reductants consisted of primarily fayalite, with traces of magnetite. Entrained matte was present in the slag mostly as prills of Ni3S2-FeS matrix and a Cu2S-FeS secondary phase below 10µm in diameter. Kinetic parameters of matte formation, valuable metal recovery rates and partition coefficients were deduced. Silica additions generated higher partition coefficients for copper and nickel than the addition of lime. Additives used as reducing agents had higher valuable metal recovery rates and partition coefficients. Silica additions favoured the formation a higher grade matte while lime additions will hinder metal recovery. Pig iron, ferrosilicon and Cu30Si were the most effective reductants for valuable metals recovery. Cu10Si and coke additions had little to no effect on valuable metals recovery."

Jan 1, 2015

By D. R. Lentz, J. A. Walker

"Abstract -The Flat Landing Brook Zn-Pb-Ag deposit of the Bathurst Mining Camp occurs within a narrow thrust-bound nappe containing felsic volcanic and volcaniclastic rocks of the Tetagouche Group. Within the host nappe, the Tetagouche Group is represented by the Nepisiguit Falls Formation and the overlying Flat Landing Brook Formation. The Nepisiguit Falls Formation is divided into two members: quartz- and quartz-feldspar-phyric volcaniclastic rocks ± minor lavas (Grand Falls member), and aphyric, fine-grained volcaniclastic rocks (Little Falls member). The Flat Landing Brook Formation consists of aphyric rhyolite flows and interbedded pyroclastic rocks. Several gabbroic intrusions occur in both the footwall and hanging-wall sequences. These gabbros locally cut out the mineralized horizon at shallow levels, and are considered to be feeders to tholeiitic basaltic flows (Forty Mile Brook member) of the Flat Landing Brook Formation. The Flat Landing Brook deposit has many of the characteristics typical of volcanogenic massive sulfide deposits occurring within the highly productive Nepisiguit Falls Formation in the eastern part of the Bathurst Mining Camp. Mineralization occurs within or at the top of the Grand Falls member and comprises four or more massive to semi-massive sulfide lenses that vary in thickness between 3 and 5 m. Massive lenses are laterally gradational to, or underlain by, zones of disseminated sulfides up to 38 m thick. The deposit contains an estimated resource of 1.7 Mt grading 4.9% Zn, 0.94% Pb, and 19.54 g/t Ag to a depth of approximately 150 m. From 150 to 300 m below surface, mineralization is low grade and mostly disseminated. However, below 300 m, ore-grade (>10% Pb+Zn) massive sulfide lenses have been intersected over mineable widths. Oxide facies iron formation overlies and (or) grades laterally into the sulfide lenses. The oxide facies has strong positive Eu anomalies and gently sloping rare earth element (REE) profiles suggesting that it was formed from relatively hot acidic fluids that had interacted with felsic volcanic rocks in the footwall. In contrast, the silicate facies iron formation that is more distal to sulfide accumulations has very weak positive Eu anomalies and gently sloping REE profiles, suggesting either cooler hydrothermal fluids or dilution of the hydrothermal component by detrital material. Hydrothermal alteration has affected most footwall rocks. Most notably, albite-destructive alteration has resulted in Na2O depletion, whereas mass addition of K2O is manifested in the formation of sericite (white mica). In more intensely altered quartz- and feldspar-phyric volcaniclastic rocks of the Grand Falls member, feldspar destruction is accompanied by chlorite alteration, producing quartz-phyric rocks similar to those in the footwall of many Bathurst Camp deposits."

Jan 1, 2006

By Michel Jébrak, Claude Bellehumeur

Abstract - Regional and orientation geochemical stream sediment surveys were carried out by the Quebec Department of Energy and Resources in southwestern Quebec, over a part of the Mont­ Laurier Terrane of the Grenville Province. The area contains some small stratiform zinc deposits. The response of Zn mineralization to geochemical surveys is weak; the known mineralization is not defined by anomalous samples and consistent patterns. This study uses a technique that increases the geochemical signature of Zn mineralization in filtering out geochemical background components related to lithologies and surficial conditions. The background variations were modelled using principal component analysis, and the filtering technique consists of the partial reconstruction of the data matrix from results of principal component analysis . The filtering procedure considerably enhances the Zn anomalies located in the catchment basins of Zn deposits, and defines some new anomalies in proximity to the marbles of the Mont-Laurier Terrane, the principal metallotect of Zn mineralization.

Jan 1, 1993

By A. E. M. Warner, P. J. Mackey

"In 1988, two of the present authors Warner and Vahed [1] were amongst several co-authors on a seminal paper reviewing nickel pyrometallurgical operations of the era. Given that significant changes in the nickel industry have occurred since that time, including the overall political landscape, technology, the overall world energy picture, the countries sourcing nickel and finally the nickel market itself, the present authors considered it timely to provide a 2015 update. In 1988, total world nickel production from sulphide and laterite sources, including production in the former "Centrally Planned Economies"- was about 0.86 million tonnes/a, while in 2014 total world nickel production reached an all-time high of almost 2 million tonnes/a - some 230% higher. On the other hand, while in 1988, about 94% of world nickel was produced pyrometallurgically and of the order of 33% via laterites, today, about 88% of nickel is by pyrometallurgy, with some 41% from laterites, thus showing that more nickel is now sourced from laterites, a trend which is expected to continue.During the period under review, new processing technologies were developed and introduced, along with substantial improvements in both the technologies employed and the scale of operations. Significant productivity gains have been achieved in sulphide pyrometallurgy in part through more efficient mineral processing, particularly in pyrrhotite rejection, and the use of ever larger-scale process equipment. This made it possible to treat lower grade and more complex ores. The significant game-changer from a production perspective was the introduction in the early 2000s of nickel pig iron (NPI) in China via modified iron blast furnace smelting, an old technology long ago cast aside by other nickel producing countries. With the exception of the emergence of this new NPI capacity in China, in the laterite industry modernization and expansion of existing operations has been employed to gain productivity, to cut costs and/or offset the effect of declining ore grades. The NPI technology development has become a game changer in the traditional global supply and demand relationship, opening up a new frontier to supply nickel to low grade utility steel producers. One other key nickel development was the Indonesian ban on nickel ore exports effective in January 2014, thus effectively curtailing NPI production at existing Chinese plants, but on the other hand, potentially prompting new smelting facilities in Indonesia. This paper reviews and updates major pyrometallurgical sulphide and laterite operations worldwide, including changes in nickel extractive metallurgy. It also provides a brief review of new developments in pyrometallurgical operations, with special focus on the NPI process and presents an outlook of the potential future direction of the industry."

Jan 1, 2015

By N. S. Spence

INTRODUCTION WHILE TITANIUM, the element, has been known for over 150 years, titanium, the metal, is a relative newcomer to the metallurgical and industrial scene. The reasons for this chiefly lie in the refract1Hy nature of titanium compounds; the high melting point of the metal; the great activity of elemental titanium, particularly at temperatures close to .and above the melting point; and the pronounced deleterious influence of certain impurities on its mechanical proper-ties. Early efforts at production of the metal were, consequently, either unsuccessful or resulted in products having sub-metallic properties. With the considerable improvement in equipment, materials, and skills that have developed within the past twenty-five years, later investigators have had a better opportunity to overcome some of the inherent practical obstacles and to come to grips with the essential technical problems. NATURAL ABUNDANCE OF TITANIUM Titanium is one of the most abundant metallic elements. It has been estimated (1) that titanium comp-rises about 0.65 per cent of the earth's crust, and therefore ranks fourth among the structurally useful metals in the order: aluminum, iron, magnesium, titanium. It must be appreciated that the relative abundance of the element is only a crude indication of its potential availability, since a very substantial proportion is present as a minor constituent in practically all igneous rocks. By comparison, present-day ores of titanium are relatively few and are but a minor fraction of the estimated total titanium contained in the earth' s crust.

Jan 1, 1951

By Michel Dostie

Un séchoir à vis chauffé par induction électromagnétique a été développé et implanté chez Mines Niobec pour le séchage d?un concentré de niobium. Ce séchoir a permis une réduction des émissions de poussières et des gaz à effet de serre de l?usine. Il offre une grande souplesse de contrôle, une meilleure efficacité énergétique et peut être utilisé pour le séchage de granulats, de poudres ou autres substances habituellement traitées dans un four rotatif ou à l?aide de vis chauffées par un caloporteur. Le principe de fonctionnement du séchoir est simple. Trois inducteurs opérant à la fréquence du réseau électrique assurent le chauffage des parties métalliques du séchoir, dont des vis qui servent à convoyer le matériel. Le contact du matériel avec les parties métalliques chaudes permet le transfert de l?énergie requise pour le séchage. La conception de ce type de séchoir requiert un équilibre adéquat entre les besoins associés au chauffage par induction et ceux liés au transfert de chaleur par contact et au transport du matériel dans le séchoir. Cette première implantation industrielle a nécessité des efforts de développements importants et une collaboration des différents intervenants. Une revue des principes de conception, des difficultés rencontrées et des performances obtenues sera présentée.

May 1, 2007

By J. Zollinger, J. R. Kennedy, J. H. Park, D. Daloz

"In order to improve the properties of cast Ti-Al alloys to replace Ni-based superalloys past the low pressure stages of aircraft engines investigations into inoculation for grain refinement were carried out. Previous work showed isomorphic self-inoculation using Ti-Al-Nb particles was effective for grain refinement, however the relatively fast diffusion of Nb in Ti-Al make it difficult to observe the mechanism of nucleation. An alternative alloy was developed in the Ti-Ta system for isomorphic self-inoculation, maximizing the Ta content to improve the particles survivability in the melt. The powder processing produced comparatively small inoculant particles which dissolved, however larger particles were seen to survive solidification. The density difference between the inoculant particles and melt resulted in an inhomogeneous mixing of the particles and the melt with larger particles found near the outer edges of the ingots. Variations on particle size and interaction time between the inoculants and the melt resulted in the Ti-Ta inoculant reducing the as-cast equiaxed grain size by a factor of two compared to non-inoculated samples as well as increasing the equiaxed fraction in the ingot.INTRODUCTION Lightweight metals are of particular interest in aerospace applications. The hot sections of turbines are dominated by blades made of nickel based superalloys. Recently the GEnx turbine introduced TiAl blades in the last low pressure stage of the turbine to reduce weight and improve fuel efficiency (Kim & Dimiduk, 1991). In order to carry these benefits deeper into the turbine the high temperature (>800oC) properties of the alloys must be improved. Current grain refinement methods to improve properties rely on boron additions which may not be applicable for all blades as brittle precipitates may be formed during processing (McCullough, Levi, Mehrabian, & Hyman, 1991). A novel grain refinement process was previously introduced called “isomorphic self-inoculation” using Ti-Al-Nb particles to successfully grain refine TiAl (Kennedy, Zollinger, Bouzy, & Daloz, 2016). In order to better understand the mechanism of this process an investigation was carried out using the same process but with a Ti-Ta alloy which is more stable in the TiAl melt than the Ti-Al-Nb."

Jan 1, 2017