Search Documents

Scale build-up in titanium palladium alloy spent electrolyte heat exchangers in the residue treatment plant commissioned at Risdon, Tasmania in 1971 was shown to be a mixture of manganese dioxide and anhydrite (CaSO4). The manganese dioxide was deposited as a result of thermal decomposition of permanganate ions present in the spent electrolyte. It was shown that deposition of manganese dioxide and associated anhydrite scale could be prevented by prior reduction of permanganate ions to the manganous (Mn++) state by the addition of ferrous ions. In the plant this was conveniently accomplished by injecting into the inlet line to the heat exchangers sufficient zinc plant solution containing ferrous sulfate to decolourise the spent electrolyte. This action prevented deposition of such scale for another 21 years, until the heaters were finally decommissioned in March 1992. Measurements indicated that addition of the reducing solution lowered the anodic potential of the titanium alloy by 200 - 300 mV (depending on the solution resistance), but that it was still +300 to 400 mV with respect to a standard calomel electrode. It was shown that, if necessary, a small impressed current could be applied to provide anodic protection. Before scale deposition was overcome by the addition of ferrous sulfate solution, badly scaled heat exchangers were cleaned by recirculating a solution of hydrogen peroxide in spent electrolyte or dilute aqueous sulfuric acid, after laboratory testing of a variety of possible solvents for the scale. Corrosion tests indicated that attack on the titanium alloy by the acidic peroxide cleaning solution was insignificant.

Jan 1, 2005

In recent years a large amount of work has been done at various plants overseas, and also at Broken Hill Associated Smelters, Port Pirie, South Australia, on the use of Dwight Lloyd sintering plant gases for sulphuric acid manufacture by the contact process.Several plants have modified their sintering machines and operating procedure, and some have adopted gas recirculation techniques, to obtain a relatively high proportion of the sintering plant gas at an S02 concentration acceptable to a contact acid plant 1.These adaptations were investigated at Port Pirie, and it was found that gases of suitable S02 concentration could be obtained. The results justified installation of a contact acid plant and a decision was accordingly made in 1949 to construct such a plant.However, the local conditions presented some difficulties not generally encountered at other plants, the chief differences being:a. For maintenance of production of 98% H2S04 , an unusually high S02 concentration is required, because of the prevailing high temperature 'of the purification train cooling water.b. The entire sintering operation is conducted on two large machines, 55ft. x 10ft., operating in series as "First" and "Second over" machines (a two-pass roast.) Any interruption" to either machine causes a complete interruption of plant operation and gas flow.

Jan 1, 1951

By Woodcock JT

This paper reviews the chemistry of flotation pulps with the aim of gaining a better understanding of the effect of chemical environment in flotation and ap- plying the knowledge to improving the con- trol of reagent additions. Theories of flotation are considered briefly, but they are only of limited help in specifying an appropriate chemical environment and in establishing control techniques. The chemical nature of flotation pulps is reviewed. Four distinct phases are present - solids, an aqueous liquor con- taining many dissolved reactive sub- stances, organic liquids, and gases. All of these vary in many ways and interact with each other. It has now been estab- lished that there are many previously- unsuspected materials present in plant pulps that can or might affect flotation. Concentration profiles of selected para- meters in operating plants are given to show some typical changes that occur. Recent advances in collector chemistry, especially that of xanthate and related species, are reviewed. Modes of decompo- sition and/or formation in pulps of xan- thate, dixanthogen, perxanthate, xanthyl thiosulphate, and monothiocarbonate are reviewed, and their W absorption spectra are compared. Some relevant information on dithiophosphates, mercaptobenzothia- zole, and thionocarbamate is summarized, and some speculative comments are made about reactions of these collectors.

Jan 1, 1984

By Smitham J. B

A selection of Australian washed coal samples was examined to determine the effect of sample hydrophobicity (rank) and particle size on froth stability in the flotation process. The results indicate distinct rank-based variations in froth volume and stability for flotation tests conducted without the use of collector, over a series of particle size distributions.High-rank coals showed a greater tendency to generate stable, high-volume froths than coals of lower rank. Implications for circuit design and operation are outlined.

Jan 1, 1988

By Deutsch G. P

The output of an underground mine often depends entirely on the mine winding system. -Decisions made--at the design stage affect the economy and operation'of the mine'.througb -its entire life. A modern mine winding installation is an integrated system and its design requires a multidisciplinary approach including expertise in the-materials handling, mining, mechanical, civil, structural, electrical and control engineering fields. The paper-sets out the elements of typical mine wind- ing systems-and describes some of the more important decisions which must be made during the planning and design process, It is no longer.adequate to. base the choice of a system on the pre- ferences and experiences of individuals. Major Australian winding install- ations are usually designed on the basis of overseas experience and some of the detail design is often carried, out overseas. Differences in basic design criteria occur from country to

Jan 1, 1973

By Barrett D

The paper discusses the justification for the Open Pit Mining Operation at Central Norseman Gold Corporation Limited's North Royal facility.Open pit mining history is outlined together with production statistics and associated costs. Underground mining practice is discussed together with an outline of the problems with mining in oxidised ground.

Jan 1, 1984

Opinions vary widely within the community on what are legitimate environmental social respon- sibilities. The extreme conservationists see the responsibility as the total preservation of the natural environment achieved by opposition to all forms of industrial development that would disturb it. The `growth-at-any-price men' consider it more important to stimulate economic growth, develop new industries, and maximize profit letting the environment take care of itself: within this wide spectrum of concern are the middle-of- the-road men, part of the vast majority, fully aware of the need to compromise to achieve a satisfactory economic growth rate whilst pre- serving to the greatest extent practicable the con- ditions upon which we depend for a balanced self-perpetuating existence. Environmental change is not new. It is the inevitable accompaniment of human activity. Plato wrote in the 5th Century B.C.* of the devastating changes wrought by man and his animals on the ancient world of the Mediter- ranean. Down through the ages rural development to *The Dialogues of Plato: `What are now her moun- tains were lofty, soil-clad hills; her so-called shingle plains of the present day were full of rich soil; and her mountains were heavily afforested-a fact of which there are still visible traces. There are moun- tains in Attica which can now keep nothing but bees, but which were clothed, not so very long ago, with fine trees producing timber suitable for roofing the largest buildings; and roofs hewn from the timber are still in existence. There were also many lofty cultivated trees, while the country produced bound- less pasture for cattle. The annual rainfall was not lost, as it is at present, through being allowed to flow over the denuded surface into the sea, but was received by the country, in all its abundance, into her bosom, where she stored it in her impervious potter's earth and so was able to discharge the drain- age of the heights into the hollows in the form of perennial springs and rivers throughout the land.' provide the necessities of life for expanding populations has required the destruction of vast areas of forest. Industrial activities over the last 200 years have discharged enormous quantities of solid wastes, liquid and gaseous effluents that were environmental pollutants of the worst kind. Urbanization has drawn people, their machines, and industries into vast concentrations aggregat- ing the environmentally bad effects of each to the extent that there is evidence that through thermal pollution these large urban industrial complexes nrp nffPrtina raainnnl rlimnta.c

Jan 1, 1978

By J Rutter, M NoppT

Ridgeway Gold Mine is part of Cadia Valley Operations which is wholly owned and managed by Newcrest Mining Limited. Ridgeway is an underground sublevel cave (SLC) operation mining approximately 5.6 Mt of gold-copper ore per annum. Ore tracking and accounting systems monitor gold and copper grades, copper mineralogy, host lithology and ore sizing. These factors have material impacts on concentrator throughput and metal recovery. Drawpoint recovered grades are routinely reconciled back to design data to monitor and assess draw performance. Grade control at Ridgeway has been based upon sampling the ore from SLC drawpoint bunds using 15 kg grab samples combined to form 30 kg samples prior to assay. This large sample size was selected in an attempt to representatively sample the coarsely-sized broken ore, the samples collected having a nominal diameter of about 130 mm. The assay results for gold and copper from these samples are extremely variable and the usefulness of the results has been questioned by the mine, particularly given the onerous and OH&S hazardous activity of handling large sample masses. Granulometry testwork at Ridgeway confirmed the extent of the relationship of decreasing sample grade variability with particle size. Based on this relationship, drawpoint sampling tests were carried out using 9 kg samples sieved to -45 mm at the drawpoint site. The gold and copper results from the finer 9 kg samples were significantly less variable than those from the normal, coarser 30 kg samples. The variance reduction was similar to that predicted from broken ore sample theory for the selected sample mass and nominal particle size. This relationship therefore allowed Ridgeway to assess the sample mass and particle size required to achieve a particular precision. In addition to improving the precision, the reliability of assay results from smaller samples from the fine particle fraction for drawpoint control depends on the accuracy of the results. The assumption is that the grade of the finer ore is similar to that expected from the lot, or that if a bias exists, then the extent of this bias is acceptable and consistent enough to be accounted for in the grade control system. The distribution of grade with particle size and the reconciliation of drawpoint sample and mine results is currently under investigation.

Jan 1, 2005

By Woodcock J. T, Rummel P. H, Sparrow G. J, MacRae C. M

A rapid automated search method, developed for the location of native gold grains in polished sections with a scanning electron microscope (SEM), has been extended to locate platinum group elements (PGE), in particular platinum and palladium, and their minerals down to 1 ¦m in size. Problems associated with the search for PGE minerals are discussed and examples of PGE minerals located with the facility in drill core sections, crushed ores, and metallurgical test products are given.

Jan 1, 1991

By Moon N. T, Torrance A. C

This study has considered the effect of mechanical shock on the resilience of the glass microspheres commonly used to sensitize an explosive emulsion. The damage to the glass microspheres caused by detonating cord, emulsion manufacture and the manufacture of the glass microspheres were considered along with the effect of sensitizer concentration on explosive performance. Reductions of up to 50% in the glass microsphere concentration of an emulsion explosive can result from poor initiation practice, such as the use of high strength detonating cord as downlines during initiation. Laboratory results suggest that detonating cords of strength greater than 3.5 g/metre should not be used as this can seriously affect explosive performance, particularly in small diameter charges. This reduced performance results from damage to the sensitizer elements and recrystallization of part of the emulsion phase.

Jan 1, 1990

By Shining Z

The strength and deformation of more than two hundred coal samples have been tested in the condition of triaxial compression. The regression equation showing the relationship between coal strength and pressure in the pores, as well as confining pressure, was obtained. The appropriate calculation for stress-strain curve was carried out. Further, an analysis shows the variation of coal strength and its modulus of elasticity in methane medium.

Jan 1, 1992

By Swift D. G

For some time the Electricity Trust of South Australia (ETSA) has been investigating the application of new mining methods and equipment to minimise the cost impact of the steadily increasing depth of mining brought about by the 20¦ dip of the coal seams at the Leigh Creek Coalfield. Exhaustive examination of all suitable mining systems showed that highly mechanised systems involving belt conveyors displayed no eco- nomic or operational advantages over shovel and truck methods. However, the configuration of the Leigh Creek coalfield allows for two quite different approaches to mining by shovel and truck. The current strip mining method involves removing overburden from the highwall in 60 m to 200 m wide strips to progressively expose the coal down dip, and requires all waste to be hauled to the surface. The alternative ter- race haulback method involves opening a boxcut to full depth at one end of the coalfield, then mining the full section along strike and placing the spoil in the mined out area. On a strictly economic basis, the latter is clearly advantageous, but the former has significant less tangible advantages. In deciding between the two methods ETSA is faced with the need to examine the applicability of each method under a wide range of possible future demands on the coalfield, and to assess the importance of many intangible factors.

Jan 1, 1989

By Fazakerley VW

The Murrin Murrin deposit is located about 210 km NNE of Kalgoorlie and 50 km E of Leonora in the North Eastern Goldfields region of Western Australia at latitude 28¦ 50'S. longitude 121¦ 54'E on the Laverton (SH 51-2) 1:250 000 map sheet. The tenements are held by Anaconda Nickel NL. Geological investigations between 1994 and 1996 resulted in resource calculations being completed for the ten lateritic nickel cobalt deposits shown in Figure 1. At a 0.8 per cent nickel cut-off the resources at May 1996 for the nine deposits are 116.8 Mt at 1.10 per cent nickel and 0.082 per cent cobalt. The nickel-cobalt mineralisation is contained in a laterite profile developed over Archaean serpentinised peridotites. A bankable feasibility study has been completed and the project is scheduled to be in production by the beginning of 1998.

Jan 1, 1996

A number of gases, such as carbon dioxide, methane, water vapour, nitrous oxide, ozone and chlorofluorocarbons are transparent to incoming short-wave radiation, but are relatively opaque to outgoing longwave radiation. Variations in the concentration of these gases in the troposphere can alter the thermal balance of the earth's atmosphere. Outgoing terrestrial radiation which would otherwise escape to space, is trapped within the inner layer of the atmosphere, resulting in a greenhouse effect. It is estimated that at present greenhouse gases other than carbon dioxide, contribute about 50% to the greenhouse effect. However, in the future, the contribution made to the greenhouse effect by gases other than C02 will become increasingly more significant. Greenhouse gases arise from a wide range of sources and their escalating increease is largely related to an increase in the world's population, an increase in the standard of living of many areas and changes in lifestyle. The effect of increasing man-made greenhouse gases in the troposphere is unknown but it is proposed that it may increase temperature and may modify climate, agricultural response and land use. The sources of greenhouse gases are identified and found to comprise a wide range of activities. The contribution that coals use makes to the greenhouse effect is examined in detail. It is concluded that coals total contribution is small being about 10% of man made greenhouse gases. Envisaged expansion of coal's use will only cause a small increase in greenhouse gas emissions. Whilst developing technology for coal's use for power generation has the potential to reduce greenhouse gas emissions from new plants by approximately 25%.

Jan 1, 1989

Gold mineralisation at Wapolu lies within an exposed arcuate zone at the decollement contact between a basement dome of high grade metamorphics and an overlying ophiolite sequence. This contact was originally a thrust fault which has since become a decollement zone for gravity sliding in association with basement doming. Hydrothermal models for the gold mineralisation postulate an epithermal system in which fluids were channelled up the decollement with boiling of those fluids causing hydrothermal brecciation and subsequent gold deposition. The alteration assemblages, fluid inclusion data and geochemistry indicate that the upper levels of the system are exposed.

Jan 1, 1987

By Wyborn L. A I, Idnurm M, Hinman M. C

Comparison of the Proterozoic Apparent Polar Wander Path (APWP) for Australia with the corresponding geology of northern Australia suggests that a number of discrete interplate tectonic events, manifested on the APWP as bends or inflections, may have controlled sedimentary basin evolution, ore fluid production and the timing of mineralisation. Similar features in the Phanerozoic APWP for the North American plate appear to correlate with major orogenic events, basin deformation, movement and 'entrapment' of hydrocarbons and minerals. Interplate tectonic events cause intraplate deformation which in turn controls the subsidence/uplift and sedimentation histories of the basins. Interplate events are thus responsible for creating, deforming and destroying sedimentary basins and the associated petroleum and mineral systems. The basins of northern Australia show remarkable similarities in the successions of volcanic and sedimentary deposits. Unconforrnities of regional or sometimes only local extent have been mapped between the major sedimentary sequences and it is predicted that interplate tectonic events corresponding to bends or inflections on the APWP directly reflect the processes that have produced these widespread unconformities. These processes are also likely to have controlled the geometry and character of the fluid migration pathways and hence the mineralising events. Palaeomagnetic studies of Proterozoic rocks in sedimentary basins provide a tool for predicting the timing of regional mineralisation events, particularly for low-temperature mineral systems. The techniques, when coupled with systematic regional basin analysis, using petroleum exploration techniques, may identify a number of new mineral 'plays' in northern Australia. Prominent inflections in the APWP occur at approximately 1700, 1670, 1650, 1600, 1540, and 1480 Ma. Each of these may be related to a regional compressional deformation, important mineralising event, or significant change in style and type of sedimentation. Most appear to be associated with magnetic overprints. Some of the inflections between 1400 and 540 Ma may also mark significant events in the evolution of Meso- and Neoproterozoic basins. Further work is required to correlate inflections in the APWP with alteration events in order to understand their regional significance.

Jan 1, 1994

At 9.45 pm on Thursday, 12 July 1962 glass began to flow in an endless stream from a massive melting tank in a new Whangarei factory and a vital new industry was born û right on schedule. It wasn't good glass. It was ridged. It cracked. It rippled. It obstinately refused to emerge upstairs in the cutting room in one solid continuous sheet. But all through the night, drawing speeds were adjusted, temperatures changed. And on Friday morning, at 8:30, it finally came through as sheet û not perfect as yet, but sheet glass all the same. The rest is only a matter of time. Unfortunately, the buoyant enthusiasm displayed by the founders of the sheet glass industry in New Zealand, and the technical expertise of their European consultants, failed to bring the glass quality up to commercially acceptable standards and within six months, the company was in receivership. Taking over the role of producing New Zealand's sheet glass requirements, New Zealand Window Glass Company was formed as a partnership between two companies with long experience in sheet glass manufacture û Pilkington Brothers (NZ) Limited and Australian Consolidated Industries Limited. This paper sets out to identify the raw material requirements and controls necessary for the successful manufacture of sheet glass, and the availability and supply of suitable materials for use at Whangarei.

Jan 1, 1978

By L Lorenzen, C Aldrich

In this paper, a neurofuzzy model is proposed for the development of an explanatory model of an industrial gold leach circuit based on historic plant data. A regression tree was used to partition the data in the predictor variable space and the structure of the tree was used as a basis for the derivation of fuzzy rules that could be integrated into a fuzzy expert system useful for operator decision support or process control. The position and shape of the membership functions were optimised with a backpropagation algorithm in a neural network framework. The approach yielded a significantly better explanatory model of the gold losses in the plant than comparable linear models. Although a regression tree could perform somewhat better in accounting for the variance of the dissolved gold losses, the tree was less robust than the fuzzy model.

Jan 1, 2007

By A S. M A Haseeb

Zircon is the second in abundance among the heavy minerals occurring in the beach sand along the coastal belt of Bangladesh. In this study a detailed characterisation of Bangladesh zircon extracted at the pilot plant of the Bangladesh Atomic Energy Commission at CoxÆs Bazar has been attempted using chemical analysis, X-ray diffraction and optical microscopy. From the chemical analysis it is found that Bangladesh zircon has a purity of 95.88 per cent. The main impurity in Bangladesh zircon is titanium oxide (3.01 per cent). This is followed by iron oxide (0.42 per cent). A number of other oxides are also found. Microscopic study revealed that Bangladesh zircon has an elongated, prismatic shape with pyramidal termination in about half of the grains while the rest are more or less rounded. Some fractured and irregular grains are also found. Bulk sample of Bangladesh zircon in the as-received condition shows a yellowish brown color. However, individual zircon grains are seen to be almost colourless and transparent under polarised light. XRD study confirmed good crystallinity in the sample. Under the microscope it is found that zircon grains constitute 94 per cent while total impurities amount to six per cent in Bangladesh zircon. This result agrees fairly well with the chemical analysis results. Microscopic study identifies oxides of titanium (both rutile and ilmenite) to be the main impurity, in conformity with the findings of chemical analysis. Further, monazite was also identified as an impurity under the microscope. An iron bearing coating is also found on a few zircon grains. Most of the impurities found in Bangladesh zircon exist as discrete minerals.

Jan 1, 2000

The developments in hydrocyclone classification in the milling circuit at Bougainville Copper Limited are discussed. A major change in cyclone size and improve- ments in operating conditions have been made. Test work has been carried out to assess the classification performance of a modified Linatex cyclone, Wemco cyclones and a two stage cycloning circuit. The use of a scalping cyclone, to remove coarse material from the present overflow product for regrind, has also been investigated.

Jan 1, 1978