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Thermal Processing of Petroleum Fly Ash for Vanadium Recovery

Sep 13, 2010

By Jensen B

The investigation of the explosion characteristics of nine Bowen Basin (Central Queensland) dust samples in a suitable coal dust explosion chamber using a new dust concentration probe provides several advances in the area of coal dust explosibility testing. The 20 litre explosion chamber, of novel design, uses rotation of the main body of the chamber together with air jets for dust dispersion, and allows testing of different types of explosion initiators and analysis of the explosion characteristics of coal dust/methane mixtures of varying concentrations.A new development was a dielectric dust probe for the measurement of coal dust concentration. A capacitive micrometry technique was successfully adapted to measure dust concentration. The system uses a ratio-transformer bridge for measurement of small changes in a capacitive probe designed to sample a representative volume. The device is accurate, and is capable of operating in the hostile environment within the explosion chamber.The explosion chamber and dust probe characterise the explosive potential of coal dust samples by determination of the dust lean limit concentration in varying mixture with methane. Plots of lean limit points obtained in this way present an explosion curve for each sample which indicates the potential of the coal dust/methane to explode under the conditions of initiation in the chamber. The explosion curve obtained for each sample presents a unique signature that appears to reflect the physical and chemical characteristics of the dust.The results from this series of laboratory experiments appear to provide a useful index and indicate potential areas of interest for future research.

Jan 1, 1991

Coal seam methane (CSM) is an æunconventionalÆ gas resource that is becoming an important energy resource for Australia, especially along the eastern seaboard. It has been conventionally believed that methane in high rank coals was exclusively derived from thermocatalytic processes during decomposition of coal at elevated temperatures. However, recent re-interpretations of gas composition and isotope data have indicated that microbial methane generation may be one of the main processes responsible for the accumulation of commercially producible methane in some coals. In low rank (æbrownÆ and sub-bituminous) coals, methane (CH4) is mainly generated by microbial activity at low temperatures. The amount of this biogenic gas generated and accumulated in low rank coals depends largely on the rate of burial and depth. Most low rank coals are æunder-saturatedÆ with respect to their maximum gas sorption capacity. In contrast, high rank coals may be highly saturated due to extensive gas generation from both thermogenic and secondary biogenic processes. However, in basins where secondary biogenic gases have not replenished the thermogenic gas lost during basin uplift, the coals will be æunder-saturatedÆ. In many basins around the world, high CSM producing zones appear to contain secondary biogenic CH4 generated by microbes transported in meteoric water recharge through permeable coal seams. Biogenic CH4 generation requires the activity of a consortium of anaerobic respiring microorganisms, fermentative bacteria and acetogenic bacteria to break down complex organic molecules to simpler molecules having one or two carbon atoms, which enables methanogenic archaea to generate CH4. The two main methanogenic pathways in the generation of secondary biogenic gas from coal are aceticlastic reaction and carbon dioxide (CO2) reduction. In eastern Australian coals CO2 reduction appears to be the main process. The types of microbes that are directly involved in these processes are unknown because they have not yet been isolated from the coal seams. The CSIRO is currently investigating the processes of biogenic gas generation in Australian coals. Potential may exist to introduce appropriate microbes into deep coal seams to enhance methane saturation levels, gas sorption capacities and permeabilities.

Jan 1, 2004

With increasing depth of mining, geotech nical factors assume increasing importance in the design and operation of open pit coal mines. Dragline strip mines are particularly sensitive to stability conditions since the draoline is a relatively inflexible machine, particularly in relation to its limited dump- ing radius for overburden disposal. Geotechnical factors relevant to strip mine design include: 1. spoil pile stability 2. wall stability 3. floor stability 4. excavation characteristics 5. groundwater conditions A basic geotechnical investigation pro- gram for new mine feasibility studies is described. This includes: 1. terrain evaluation 2. geotechnical drilling and logging 3. geophysical logging 4. materials testing 5. seismic refraction traversing 6. groundwater studies Such a program will give an overall geotech- nical assessment of the site and highlight any areas which may require further, more detailed Investigations

Jan 1, 1981

Recent mineral exploration successes in the Proterozoic rocks of the Mount Isa Inlier are unprecedented in the regionÆs history. This new era of discovery, particularly for æblindÆ deposits, owes its origin to perseverance and advances in geoscience and exploration techniques, notably geophysics. Prospective host rocks outcrop over more than 50 000 km2 of the Mount Isa Inlier and extend a further 100 000 km2 below cover. They contain major deposits of copper, lead, zinc, silver and phosphate (Georgina Basin) and significant deposits of gold, uranium and cobalt. The discovery in 1923 of silver, lead and zinc at Mount Isa established the regionÆs world-class mineral potential. Since 1990, major orebodies have been discovered at Cannington (silver-lead-zinc), Century (zinclead-silver), Ernest Henry and Osborne (copper-gold) and extensions to known deposits at Dugald River and George Fisher (zinc-lead-silver), and Esperanza (copper). This success is of global significance and reflects a prospectivity upgrade since widespread copper mineralisation was discovered and mined in the Cloncurry district a century ago.

Jan 1, 1998

By Erepan P. C

Flash flotation technology was introduced by Outokumpu in 1985. Considerable success was achieved in other plants with similar operations to OTML. Conclusions from site visits and amenability tests performed on plant samples were that the OTML

Jan 1, 1997

Recognition is the most important aspect in the use of breccias as an exploration tool. Ore-hosting breccias occur in a wide variety of environ-ments, shapes, compositions and characteristics, but generally present favorable loci for the deposition of ore mineralization in epithermal, porphyry copper-gold-molybdenum, massive sulfide, carbonate-hosted, sedimentary lead-zinc deposits and others.

Jan 1, 1990

By B F. J Kelly

Multiple-point simulation is a family of methods used to generate conditional facies simulations that present the same spatial dependence as a user-defined training image. The main advantage of using a training image is the easy integration of geological concepts in numerical subsurface models. The strength of multiple-point methods is that it allows making the best use of geological expertise when data are too sparse for inferring a model of spatial continuity. However, despite being appealing to geologists, the multiple-point methods are often not used in practice due to the difficulty of building complex 3D training images that contain realistic features.A new framework for multiple-point simulation is presented that involves small and simple training images. The main idea is to use random transformations to expand the range of structures available in the simple training image. The training image is not regarded any more as a global conceptual geological model, but rather a basic structural element of the subsurface. Complex geological structures are obtained, whose spatial structure can be parameterised by adjusting the statistics of the random transformations, based on field data or geological context. In most cases, such parameterisation is possible by adjusting two numbers only. One advantage is that the training images are so simple that they can be easily built even in 3D. The method allows building 3D models that reproduce shapes corresponding to a desired prior geological concept and are in phase with different types of field observations, such as orientation, facies or geophysical measurements. The flexibility of the approach allows for naturally integrating different types of data. This is demonstrated on an example involving seismic data assimilation. Examples where complex 3D folded structures are built from a simple training image and a few orientation data are shown.

Sep 26, 2011

By Taylor R. N

Flow simulations have been performed on the flash-smelting burners currently used at KNS. This paper presents studies of the heat transfer between gas and particles at the burner exit. Gas and particle temperatures, velocity and concentration profiles of the two-phase flow are calculated by the mathematical model. The predicted gas temperatures have been favourably compared against values measured by thermocouples placed near the burners in the flash furnace. The predicted particle temperatures are also reasonable when compared with the measured temperatures.

Jan 1, 1992

By Denholm W. T

The SMELT-2 package is specifically designed to perform on-line simulation of smelting processes. This paper describes its application to the simulation of continuous matte converting followed by reductive slag cleaning in SIROSMELT reactors. The matte, containing 50% Cu is assumed to be produced at the rate of 20 tph in a continuous matte smelting furnace such as an Outokumpu Flash Furnace, Noranda or Sirosmelt reactor. Two alternative fluxing strategies in the converter are examined, namely: ò conventional silicate slags, ò calcium ferrite slags, and the flow sheets associated with each strategy are discussed. A regular solution model is used in the present study to account for the variations in the activity coefficients of components in the slag.

Jan 1, 1989

By Chander S

Properties of surface films on chalcopyrite and pyrite differ due to variations in the mechanism of oxidation of the two minerals. In the case of chalcopyrite the first step in the oxidation is the release of iron as ferric ions, which hydrolyse depending upon conditions prevalent in solution. The iron oxide/hydroxide layer formed by hydrolysis of ferric ions is quite porous and easily detachable from the surface of chalcopyrite. When the surface oxide layer is detached a sulphur-rich layer is exposed making chalcopyrite hydrophobic. The thickness and properties of the sulphur-rich layer determine its flotation response, both in the absence and presence of collectors. In the case of pyrite, on the other hand, iron is released as ferrous ions which require much higher pHs to hydrolyse. These ions remain adsorbed on the surface of pyrite making the surface hydrophilic. When the iron species are complexed with chelating agents such as ethylene diamine tetra acetic acid, pyrite was hydrophobic. Siderite forms in the presence of carbonate ions, which might be present in several flotation systems. Siderite nucleated on isolated sites at the surface. The presence of such a precipitate is likely to influence the interaction of pyrite with various reagents thereby altering its flotation behavior. To determine the mechanism of oxidation, kinetics of oxidation of chalcopyrite and pyrite was studied using several electrochemical techniques, namely, cyclic voltammetry, polarisation and impedance spectroscopy. Floatability of the minerals was investigated by measurement of contact angles on mineral electrodes and by Halimond tube flotation. Impedance spectroscopy was especially useful for estimating various properties of surface film for both the minerals. Properties such as charge transfer resistance, porosity, and capacitances of the surface films on the two minerals are compared under several conditions of oxidation. These properties were found to be a strong function of the rate and the extent of oxidation.

Jan 1, 1993

The Fosterville goldfield, situated 25 km east of Bendigo, Victoria was at its peak between 1894-1910 with some 47 600 ounces produced (Figure 1). Since that time intermittent mining and tailings retreatment was undertaken until Bendigo Gold Associates delineated a viable resource and commenced an open cut heap leaching operation in early 1991. Unfortunately they encountered financial difficulties and Perseverance Exploration purchased the mine in April 1992. Perseverance operated a successful heap leach operation nearby Nagambie, 100 km east of Fosterville. Based on its acquired heap leaching experience, Perseverance Exploration was able to instigate operational changes to create a successful small gold heap leach operation. The major change was the using of the original multi-use leach pad as a single-use leach pad. The available data allows for a comparison of the two operating systems.

Jan 1, 1994

Legislation up to the early 1950s prevented the mechanical extraction of pillars. The mines operating at that time had formed extensive areas of pillars. When permission for the mechanical extraction was gazetted, conventional equipment was employed for pillar extraction and generally using hand mining systems. The mid-fifty's saw the of continuous miners. These machines eliminated the disadvantages of conventional equipment and the necessity for multiple working places. Some new layouts for panels emerged; however, actual extraction methods of pillars still followed closely that of hand mining. During the early sixty's the extraction of standing or new formed pillars was undertaken by the "open-end lift" or a "split and lift" method.

Jan 1, 1974

Five types of mineral resource were known in the sedimentary cover of the oceans and seas floors prior to the 1980's :1) hydrocarbon fields including some very large zones of oil and gas accumulation; 2) "Red Sea" type thermal oozes with increased concentrations of noble metals; 3) ferromanganese nodules; 4) concentrations of metallic sulphides ("Black Smokers"); and 5) cobalt-bearing ferromanganese crusts on the summits and slopes of seamounts. Since then, the so called "White Smokers", containing sulphides of copper and zinc, have been discovered. The ore horizons (manganese, copper, nickel and other metals) of the sedimentary cover of deep-sea basins comprise a sixth type of mineral resource in the oceans. These horizons have not only a theoretical, but also a principal economic significance

Jan 1, 1995

By V Pere

A geotechnical data management system has been developed to manage drillhole and mapping data generated from in house and consultant administered field programs. This system comprises a data collection interface with integrated validation, processing and reporting functionality. Development of the database required careful consideration of how and what geotechnical information is gathered in the field, a clear understanding of the interdependency of the parameters, and the outputs required to support geotechnical design.The acQuire Geoscientific Information Management System was selected as the preferred software to support the process because of its ability to easily manage data from capture in the field through to quality reviews and ultimately into reports. Initially only geotechnical logging of diamond core was considered, subsequently the system has been expanded to support additional geotechnical data sources such as laboratory test results, traverse and window mapping data. This paper focuses on the core logging data acquisition, validation, analysis and presentation of data.The acQuire Geoscientific Information Management System has proven to be a robust platform for the capture, interrogation, and reporting of geotechnical data. Data entry objects have been created to manage seven different areas of geotechnical data collection ranging from core logging to mapping to automated reports for falls of ground.

Aug 22, 2011

Swedish sulphide mining is presented. Dry filling is described. Fill properties with and without cement addings are dis- cussed in relation to various studies in la- boratory and in situ.

Jan 1, 1973

Methane is present in varying degrees in nearly all underground coal mining operations. At mixtures with air near 5-15% it is explosive and consequently since it is not usual for these levels of contamination to be reached in the general body of a mine ventilation system it is not unusual to experience it in specific places. On longwall faces the most used power loader is the shearer machine and because of its general shape, situation and operation it is likely that all the factors which are required to cause a frictional ignition can be present. This paper makes a general appreciation of the causes of these ignitions and methods which are and have been used to control these situations on and around these machines.

Jan 1, 1981

The paper poses certain questions relating to mine design aspects of deep shaft pillars. It then explores these questions in relation to Western Deep Levels (South) where a sub-shaft system is to be sunk to 4 000 metres below surface to exploit two narrow tabular reefs in the down dip extension of the mine workings. After brief discussion of some broad considerations, the findings of a major rock mechanics investigation are reviewed. Some overall conclusions as well as the outcomes of separate studies of the anticipated behaviour of shaft pillars on each of the two reef horizons are outlined. The effect of this behaviour on the barrels of the shafts in the system and on the associated shaft excavations and in-pillar development is Cnnctdarcrl

Jan 1, 1986

By Osborn G

The bulk flotation behaviour of an industrial rougher bank has been determined with a view to characterising the size iepend ent behaviour of the identifiable nineral groups present. A relatively simple flotation model, based on first order kinetics and the assumption of perfect mixers in series ias been used to provide a fit to the operation of the cells. The adequacy of the model is discussed in relation to the characteristics of the ore and the size iependancy of the parameters. It is shown that improved fits are possible if the model accounts explicitly for this size dependancy and demonstrated how the model may be of use in prediction of the grade recovery relationships for different operating conditions as an aid to plant optimisation.

Jan 1, 1986

The overall systems approach to blast furnace aerodynamics is explored including the time and spatial inter-relationships that exist between the furnace lines, tuyeres, burden characteristics, distributor capabilities and furnace operating practice. Attention is called to the time dependent, three dimensional aspects of blast furnace aerodynamics and to the existence of several zones within a furnace where the flow characteristics are different. Changes in furnace operating practice to take further advantage of fully beneficiated burdens including formed coke are discussed from a practical viewpoint. Lessons learned in a variety of shaft furnaces used for other purposes are discussed insofar as they have a bearing on aerodynamics in an iron blast furnace. Questions are raised about the penetration of hot blast in large furnaces. Operating practices and.proposed solutions are evaluated where tuyeres over iron and slag notches are restricted or plugged. Opportunities are presented for using on-line hierarchical computer systems with adaptive tuning algorithms to provide non-linear control of changing process conditions in real time. This will make it possible for the blast furnace operator to optimise a variety of interrelated paramaters, each with different response times. Potential increases in productivity, fuel savings and improved quality control are believed to be within reach.

Jan 1, 1975