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By C. E. Birchenall, H. M. Schadel

Vapor pressure of silver over silver-gold alloys has been measured over a range of temperatures for four compositions. Orifice effusion has been compared with electromotive force measurement as a means for determining thermodynamic activities in these solid metallic alloys. Correlated activity coefficients are given for silver-gold alloys for the temperature range 200' to 1000°C. SOUND development of a technique for the measurement of some property of matter requires a comparison with other recognized procedures which have been used to measure the same property. Such a check is especially useful if the assumptions on which the applications stand are basically different for the two methods. Agreement in the results tends to confirm both sets of assumptions. The electromotive force method for determining thermodynamic activities depends upon the reversibility of the electrode processes and a knowledge of the valence states involved. The orifice effusion technique of determining vapor pressures requires that certain mean free path conditions be met, that the state of association of the vapor be known, and that efficient collection of vapors be maintained. Thus the requirements are quite different in nature. Although procedures often exist by which the fulfillment of these conditions may be tested internally, agreement of thermodynamic activities for a single system obtained by both methods constitutes a more severe test of the assumptions. The binary alloy system silver-gold is excellent for this purpose for several series of emf measure-

Jan 1, 1954

By Elmer R. Kaiser

Cooperative research is an established and important activity of modern business by which whole industries can advance on a broad front. The economy of jointly sponsored research as well as the limited research talent available direct attention to the advisability of projects in which a number of companies participate. After outlining the growth of industrial research, the paper discusses one successful method for organizing and financing group research programs. A systematic procedure is advocated by which engineers and scientists can bring to management practical plans for cooperative research and development programs.

Jan 3, 1950

By D. G. Brubaker

IN the history of geophysical exploration by the electromagnetic method many procedures and types of equipment have been used. Source arrangements for surveying on the ground have included long wires grounded at both ends, large loops laid on the ground, small horizontal loops, and vertical loops of moderate to small sizes. Receivers have ranged from simple direction-finding coils to combinations of coils and a bridge circuit to measure quantities related to both amplitude and phase of the received signal. Primary considerations in choosing a survey method are effectiveness, speed, and economy. In work on the ground in which locating and out- lining conducting bodies is the objective, methods using a vertical coil and a simple direction-finder have been found the most satisfactory. Mason1 and his associates applied such a method by setting up a vertical source loop, fed with low frequency alternating current by an engine-generator set. With a direction-finding receiver they surveyed lines along the ground in the plane of the loop, taking measurements at each station of the azimuth and inclination of the magnetic field direction. Deviations of this direction from the normal direction, that is, from horizontal and perpendicular to the traverse line, indicated a conducting body. Recent advances in design of light-weight generating equipment have encouraged using this and similar methods.

Jan 7, 1957

By G. J. Wolga, W. W. Tyler, A. C. Wilson

THE physical properties of uranium have been reviewed by Katz and Rabinowitch.1 Their review includes thermal conductivity data for ternperatures above 375°K. Recently, Mendelssohn and Rosenberg' have published data on the thermal conductivity of uranium from 2" to 20°K. Our measuremerits indicate the temperature dependence of the thermal conductivity in the temperature interval from 20" to 300°K. Electrical resistivity and thermoelectric power were measured on the same sample. The material studied was normal uranium which had been heated at 700°C in a lead bath for 10 min and then quenched in a water bath held at 50°C. From this material a rod M in. in diameter and 2 1/2 in. long was machined. Two 0.040 in. holes were drilled into the rod 1 3/4 in. apart. Copper-constantan thermocouples for temperature and potential measurements were soldered to copper pins which were pressed tightly into these holes. Details of the equipment and experimental techniques used in making the measurements have been described elsewhere." Fig. 1 shows micrographs of a section of the sample studied. Fig. la was taken with unpolarized light and shows impurity inclusions, probably uranium carbide. Fig. lb, showing the same field, was taken with polarized light and gives some indication of the grain size and twinning within the grains. Experimental Results Thermal conductivity and electrical resistivity data are shown in Fig. 2. Table I shows values of

Jan 1, 1954

By Barton K. Cross, Ronald J. Sparks

The question of' providing training for miners in the United States has been answered by Public Law 95-164, which stipulates not only that the mine operator will provide training, but generally how much and what material will be covered. At an operation employing 500 miners, the eight-hour refresher training requirement will necessitate an annual investment of over two man-years in labor, a figure that does not include the time spent in training new hires and job transfers. Such an investment can and should be cost effective, while catering to miners' needs.

Jan 6, 1979

Uranium, the object of a quarter billion-dollar search in the US during 1977, is a ubiquitous element rarely found in economic concentrations. It originates in magmas as a large tetravalent ion, the size of which restricts it from the crystal lattices of many rockforming minerals. Instead, according to United States Mineral Resources (US Geological Survey Professional Paper 820) as the magma crystallizes, a portion of the uranium is deposited as an intergranular film on rock forming minerals, enters accessory minerals, or forms its own minerals. The remaining uranium becomes concentrated in magmatic differentiates, where it forms minerals in pegmatites and veins.

Jan 10, 1978

By Murray F. Hawkins, Marion L. Kimmel

sage' appears to have been the first (1933) to design a rolling ball viscosimeter for the express purpose of measuring the viscosity of oils with natural gas in solution, i.e., under reservoir conditions. In 1940 Hocott and Buckley' further refined the rolling ball instrument in both design and method of operation, and their instrument, known as the Humble type, was the forerunner of present day viscosimeters used in petroleum production and research laboratories. They also initiated the technique of charging the viscosimeter with a sample directly from a bottom hole sampler. In 1948 the committee on engineering research 01 the Petroleum Division of the AIME in Part 3 (1) of

Jan 1, 1955

By L. M. Clarebrough, A. K. Head, G. W. West, M. E. Hargreaves

RECENTLY Welber and Webelerl reported that during the annealing of fatigued copper no energy was released, but that energy was absorbed in the range of temperature 250" to 400°C. In view of the fact that strain hardening occurs during the fatigue of copper, this result was surprising and it seemed desirable to check the measurements. This note describes measurements made by a different technique which indicates that energy is stored during the fatigue of copper. Two test bars with gage length ¾ in. in diameter and 6 in. long were machined from OFHC copper and annealed in vacuum for 1 hr at 600°C. These were fatigued to fracture in an Avery pulsator at a frequency of 2000 cycles per min. The first specimen fractured after 0.25x10 cycles under a push-pull

Jan 1, 1956

By R. L. Tobie

Handling and storing ore at transfer points underground are encountered frequently. An ideal solution to these troubles is probably still to be found, but at the Mather mine "B" shaft a method incorporating scraping trenches has been developed giving better service, from the standpoint of safety and simplicity, than obtained from other schemes. When shaft pockets are used for storage, the size of the ground opening required to assure capacity is often prohibitive, and shaft depth below the last level can become excessive, particularly if a crushing station is used. Also, if the material being handled contains large amounts of wet fines, it is difficult, if not impossible, to hold the material with regular chute gates. In order to remedy these problems Cleveland-Cliffs' Mather "B" has utilized three types of trenches. Types I and I1 are now in service and the third is under construction.

Jan 4, 1955

By S. G. Malghan, J. P. Van Dillen

Some uranium minerals are paramagnetic and hence are amenable to concentration by high gradient magnetic separation (HGMS). This paper describes effects of the HGMS parameters-pulp velocity, field strength, matrix loading, and magnetic field gradient-on the product recovery and grade. Unsatisfactory separation of uranium minerals by HGMS is related to ore-specific properties, such as lack of liberation, fine dissemination of uranium minerals, uniform distribution of magnetic minerals throughout the ore matrix, and interference of fine-sized slimes. Experimental techniques to identify and resolve some of these problems are outlined.

Jan 1, 1984

The Students' Organization of the Michigan College of Mines was recognized as an Affiliated Student Society by the Board of Directors of the Institute, at a meeting held on April 28, 1916. At the College of Mines, University of Washington, 30 students and instructors took part in the annual spring excursion early in April. Studies were made of the new reverberatory and casting furnaces at the Tacoma smelter, the Du Pont powder works located on Puget Sound and the Britannia Mining and Smelting Company's mine and mills on Howe Sound, near Vancouver, B.C. The Britannia mills are using Hancock jigs, Burchart tables and Minerals Separation flotation cells to effect a high recovery on low-grade chalcopyrite ore. The Mining Club, University of. Wisconsin, elected the following officers for the second semester of the present school year: J. G. SKIRM, President, H. L. RAU, Vice President, T. C. SHERWOOD, JR., Secretary-Treasurer, H. E. HODGSON, Mucker, , F. M. WOLVERTON, Assistant Mucker. Theo. C. SHERWOOD, Jr., Secretary.

Jan 6, 1916

By L. L. Anderson, R. E. Wood, W. H. Wiser

Western bituminous coal can be processed to low sulfur liquid fuels by fast reactions. A process (LEFCO) under development at the University of Utah uses coal and catalyst under hydrogen pressure to convert 60 to 70%of the coal matter to fuel liquids and gases. Coals have been processed in small diameter (less than %in.) tubes and at reaction residence times of less than 10 secs. Effects of process variables on the yield and quality of products have been studied. General features of the process and the properties and characteristics of the products produced are presented. Special features of the process that distinguish it from other liquefaction processes under development are also discussed.

Jan 1, 1977

By Mario L. Villa

During the year 1941, there was another increase in the production of oil in Argentina, to which the fields in the Comodoro Rivadavia zone in the Territory of Chubut and those of the Provinces of Salta and Mendoza all contributed. The total production for this period reached 22,013,472 bbl., which represents an increase of 6.8 per cent over that of 20,609,538 bbl. in the preceding year. This result is again attributable to the Government oil company, the Yacimientos Petroliferos Fiscales, which had a total production of 14,006,559 bbl. representing an increase of 1,531,904 bbl., or 12.3 per cent over that of the 12,474,655 bbl. of the year before. The other companies

Jan 1, 1942

By Michael Richings

Although the role of slope stability has not changed, there have been changes in the mining industry which affect the geotechnician engaged in slope stability studies. The deposits currently being mined or evaluated are technically difficult , capital intensive, and economically marginal. In addition, many mining companies are now either controlled by oil companies or are financing projects through bank loans. The mining investor or decision maker is, therefore, often more sophisticated financially, but less sophisticated in mining terms. The impact of these changes will be to force the geo- technician and mining engineer to attempt to quantify risk and financial implications of a slope design. In conclusion, this paper outlines several questions which mining engineers should be asking those engaged in geotechnical studies and indicates the necessity for the mining engineer and geotechnician to work together and quantify the financial risk associated with a geotechnical design.

Jan 1, 1983

By Erwin J. Durrer

The development of planning in the petroleum industry is de- scribed and the current status analyzed. Worldwide transportation networks led to corporate models which caused a differentiation between operations research and planning groups. Ranking of projects solely by ROI proved infeasible because of the diversified nature of the industry. Qualitative elements such as synergism with ongoing operations and the external socio-economic environment had to be included, leading to business plans based on scenarios of possible futures and stressing growth-opportunities over cash-flow rich mature product lines. In addition, decision analysis is finding applications in large capital, high uncertainty situations such as planning for synthetic fuel development.

Jan 1, 1977

By Mario L. Villa

During the year 1941, there was another increase in the production of oil in Argentina, to which the fields in the Comodoro Rivadavia zone in the Territory of Chubut and those of the Provinces of Salta and Mendoza all contributed. The total production for this period reached 22,013,472 bbl., which represents an increase of 6.8 per cent over that of 20,609,538 bbl. in the preceding year. This result is again attributable to the Government oil company, the Yacimientos Petroliferos Fiscales, which had a total production of 14,006,559 bbl. representing an increase of 1,531,904 bbl., or 12.3 per cent over that of the 12,474,655 bbl. of the year before. The other companies

Jan 1, 1942

By G. K. Dumbauld, B. E. Morgan

A satisfactory well-cementing composition must retain its fluidity long enough to be pumped into Place; then it must develop within a reasonable length of time sufficient strength and impermeability to anchor the casing in position and to form an effective seal between the casing and the formations. These properties may be evaluated by pumpability, strength (compressive or tensile), and permeability tests. Laboratory test procedures for the determination of pumpability time and strength development have been outlined previously and are readily available,1 but a satisfactory and convenient laboratory procedure for the measurement of the permeability of set cement has not been developed heretofore. some permeability data have been obtained previously by passing air through dried cement specimens.2 such a procedure is unsatisfactory because the drying of set cement alters it physical and chemical properties and subjects it to conditions dissimilar to well conditions. A more realistic method would be one wherein the cement remains water-saturated durin

Jan 1, 1952

By B. Heide, A. Bergrnann

The Meggen mine and the concentrator plant of the Sachtleben Bergbau GmbH are located in the southern part of the Ruhr district of the Federal Republic of Germany. The mine has been in operation for more than 100 years, but the concentrator described in this paper was started up in January 1963. The Meggen orebody is of sedimentary origin and occurs in a zone of limestones, graywacke and shales of Devonian age. The average thickness of the deposit is 3 meters and due to an intense folding of the area, the mineralized zone dips steeply at 80º towards the north.

Jan 6, 1973

By K. E. Beu

THE integrated intensity X-ray method of meas-uring retained austenite concentrations in hardened plain carbon or low alloy steels as proposed by Averbach and Cohen1,2 has the advantages of being a highly sensitive and precise quantitative method. The various phases of this method have been studied and several modifications have been developed which aid not only in reducing the time required per determination, but which also increase the possible accuracy of the method. A fundamental step in the original calculation procedure is to plot V.A(?) curves for austenite and martensite and to obtain VM/VA ratios from these curves.' In taking this ratio the absorption factor A (8) drops out since it is constant for a. given diffraction angle 8. The reason for eliminating A(?) in this manner is because it is apparently assumed

Jan 1, 1953

By R. W. Heins, N. Street

Recently Hiller1 reported results on the impairment of the strength of quartz glass rods through wetting, indicating that there was general agreement with the prediction of the Griffith formula in that for the liquids used the rods were weakest in water i.e. the liquid which probably had the greatest free energy of immersion. The Griffith equation predicts that the tensile stress necessary to propagate a crack of length c is where ? is the interfacial free energy, E Young's modulus. Since for a solid immersed in a liquid of surface tension ?L and contact angle 8 at the solid-liquid-gas contact, ?s - ?SL = ?L cos ? where ?s is the surface free energy of the solid. Hence comparison between ?L cos 0 and strength impairment should be possible. In a study of the usefulness of the Kuznetsov pendulum2 as a means of studying rock drillability we have determined the effects of various liquids on the pendulum hardness of Bavarian limestone. The pendulum used had diamond points (Burgess Vibro-graver), a period of 1.14 sec and a total on sample weight of 1191 g. The decline of the pendulum oscillations was recorded by a light beam on light sensitive paper carried on a kymograph. Rehbinder's expression relating hardness to amplitude attenuation as a function of time can be written In A = - (1/H) t + In Ao where A, A, = amplitude at time t and initial amplitude respectively, H = hardness parameter, and t = time. The line of best fit to the experimental points was determined using the IBM 7090 electronic computer, the computer also gave A, by extrapolation to zero time. The results for the various liquids tested are given in Table I and Fig. 1. The limestone surfaces were highly polished before testing and each reported hardness value represents the average of at least ten separate determinations of the pendulum decline curve. On each newly prepared surface the water value was again determined (also

Jan 1, 1964