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By M. J. Mullikin, J. B. Conway

for use in describing combined first- and second-stage creep data. In the above ?o represents the instantaneous strain on loading, ?t the limit of transient creep, ?S the steady-state creep rate, t the time, and ? a constant leading to the exhaustion rate of transient creep. It was noted that this equation was similar in form to that proposed originally2 by McVetty. This type of equation was also suggested by Andrade and Aboav3 in studies of the shear strain of cadmium. Calculation of the constants ?o, ?t, ?, and ?s, in Eq. [ l] is somewhat involved due to the slight complexity of this relationship. In the paper by Garofalo a computer approach based on a least-squares analysis was recommended. Such an approach involves a trial and error solution but when a computer facility is available the difficulties in this calculation are of little consequence. It does mean however that the evaluation of this type of equation would become quite tedious if computer facilities were not available. Some recent studies have identified a fairly straightforward method for calculating the constants in the Garofalo equation. While not leading to a least-squares evaluation the approach is accurate and is recom-

Jan 1, 1967

By E. C. Rien

When the electrical system for a surface or open pit mine is designed, four major considerations should be satisfied in the following order: safety, reliability, flexibility, and cost. Careful planning initially will make expansion for future growth economical as well as possible without extended shutdown of operations. Electrical requirements in surface and open pit mining can be divided into three categories: main substation, plant power, and pit distribution. These systems are integral to each other, but will be dealt with separately here. 11.2-1. Main Substation. A main substation for a mining operation may vary from a 500 kva transformer supplying 480-v power to motor-driven pumps and conveyors, to a 50,000 kva substation serving a large beneficiation plant or a large strip mining operation. Regardless of size, it should be designed with the realization that a failure of the main substation will totally shut down the operation (Fig. 11.2-1.). Location of a main substation usually is a compromise between expense of running the incoming high-voltage transmission lines and the voltage drop of long secondary runs. Based on a geological survey for immediate and future areas of excavation, the main substation should be located as near to the center of load as possible. The site should be out of the blasting area, readily accessible to authorized personnel, and situated where prevailing winds will keep it free from dust or snow. DISCONNECTS AND OVERLOAD PROTECTION. The main substation should have a primary disconnecting device-either a pole top gang-operated switch and fuses of adequate interrupting capacity or, preferably, an oil circuit breaker with properly coordinated relay protection.

Jan 1, 1968

By Stein Wennberg, Snorre Tessem

INTRODUCTION The mine is situated in the middle of Norway 150 km north of the town Trondheim. The iron ore deposits were discovered in 1906 and have been continuously mined since. The first owner was A/S Nordiske Grubekompagni. In 1912 Fosdalens Bergverks-Aktieselskab was established; since World War II it has been a wholly state-owned company. The location is advantageous, with mining facilities, ore dressing plant and stockpile situated near the northern head of the Trondheimsf jord. The iron ore always occurs in Ordovician lavas and sediments, now altered to greenschists, keratophyres and limestone. The ore bearing zone is 150 km long. The deposits consist of two parallel linear ore bodies lying one above the other in the same stratigraphic horizon which dips 70' to the south. The upper body is 50-100 m high, the lower one 250 m high, while the distance between the two bodies in the East mine varies between 20 and 60 m. The ore width varies between 5 and 8 m. The ore bodies strike WSW and plunge between 10' and 15" in this direction. To date continuous ore has either been worked or opened up along a total strike length of 10 km. Until 1969 all ore was mined in the western part of the deposit called the Western mine. In the spring of 1969 production started in a new mine, the Eastern mine. The ore bodies in this new mine are geologically the same as in the old mine, but they have been displaced 700 m downwards along a major fault in the Fosdalen valley.

Jan 1, 1981

By Joseph L. Gillson

YOUR speaker has long sought an opportunity to review the many differences between the subject matter called economic geology and the duties of a practicing economic geologist. As the subject was taught in my student days, professors teaching courses in economic geology paid little attention to what we now call industrial minerals. Certainly they were not concerned with problems involving production and marketing, but only with the origin of such mineral deposits as the Stassfurt potash deposits; with other evaporites, such as salt, gypsum, and Chilean nitrate; with the possible modes of formation of sulfur in salt domes; and the causes of asbestiform mineralization. Of course, much time and thought was given to the mineral identification and sequence of deposition of the minerals in pegmatites. The fact that such deposits actually produced commercial feldspar, mica, beryl, and lithium minerals for sale in industry was of minor importance. These observations lead us to pause to inquire, perhaps facetiously, what is and what is not to be included in the science of economic geology?

Jan 5, 1957

By R. Fahn

Bentonites are best suited for the preparation of acid activated clays with efficient adsorption properties. They are weathering products of acid volcanic ashes and natural deposits are spread worldwide. The main constituent of bentonite is aluminum hydrosilicate montmorillonite with a high ability to swell. Physical and Chemical Properties of Montmorillonite The clay mineral montmorillonite is named after its place of discovery, near Montmorillon in southern France. The structure of this clay is shown in [Fig. 1]. The montmorillonite crystal consists of about 15-20 silicate plates. Each silicate plate is composed of three layers. The central one is formed by aluminum or by ferric hydrate octahedrons, the two outer ones consist of silicon dioxide tetrahedrons. In the presence of water, the montmorillonite crystal swells and water molecules become deposited between individual silicate layers. Two types of natural bentonites are known: the Western type, which is a natural sodium bentonite (high swelling grade), and the Southern type, an alkaline earth or calcium bentonite (low swelling grade). Southern bentonites have efficient adsorption properties of their own. They are called natural active earths or fullers earths. Acid Treatment of Bentonite Under the influence of a mineral acid, the exchangeable alkaline earth ions of bentonite are substituted by hydrogen ions. Moreover, depending on the acid concentration, temperature, pressure, and reaction time, a more or less pronounced leaching process takes place. Thereby Al-, Fe-, and Mg-ions are extracted from the octahedron layers. This results in a change in the crystalline structure of montmorillonite and in an increase of its specific surface area and porosity, as shown in [Fig. 2].

Jan 1, 1983

By Ingersoll Olmsted

These ores are of two classes, Bessemer and non-Bessemer, existing in separate, though adjoining, beds. Both are carbonates, with small admixtures of oxides and other combinations. To prepare them for market they are roasted in kilns, which have already been described by Mr. John Birkinbine at the Troy Meeting, October, 1883 (Trans., xii., 378). Concerning their size, arrangement, etc., I need, therefore, only repeat that they are 60 feet in height; have wrought-iron shells 24 feet in diameter; are lined with fire-brick, and supported by cast-iron mantel and columns.

Jan 1, 1889

By W. H. Jr. Meyer

Although an aerial photograph is not a map, most of the information that is necessary for compiling a map is recorded in the photograph provided some form of radial-line method is used to determine the true position of images. The slotted-templet method, which is based on the well-established radial-line principle, has made it possible to construct accurate mosaic maps at a cost comparable with that formerly charged for the average mosaic. It makes possible the securing of these results with far less ground control, which is always expensive. It has expanded widely the possible use of aerial photographs for mapping. ALTHOUGH a vertical or oblique aerial photograph is not a map, most of the information that is necessary for compiling a map is recorded in the photograph. Some ground controls or data are needed, the number and accuracy to be governed by the mapping method to be used and the scale and final accuracy desired in the finished map.

Jan 1, 1939

By Douglas Baker

Zinc concentrates assaying approximately 54% zinc and 30% sulfur are roasted in a suspension type roaster to yield a zinc oxide calcine assaying about 65% zinc and 0.40% sulfur. This calcine is the feed material to the sulfuric acid leaching section of an Electrolytic Zinc Plant. The SO2 gases resulting from the elimination of sulfur from the concentrates are passed through a waste heat boiler for the generation of high pressure steam, cleaned by a baghouse, and delivered to the humidifying tower of a sulfuric acid plant system. The gases are then treated in a mist precipitator for final fume removal and then converted to sulfur trioxide in a three pass contact system using vanadium pentoxide catalyst for the manufacture of sulfuric acid. Waste heat steam is used to power the steam turbine which drives the acid plant blower.

Jan 1, 1970

By R. S. Rickard

Chemical processing of ores has gained new im¬petus in recent years. The reasons are many. They range from the need to process ores that are difficult to beneficiate to the avoidance of pollution. Although many think of chemical processing as a hydrometallurgical operation there are other techniques. An example is chlorination. Chlorination, although examined and discarded by many investigators, is again being considered as a means of extracting uranium1, treatment of silver-lead ores2, and the recovery of base metals from pyrite cinder and ores3. Segregation roasting of copper and nickel ores, a process similar to chlorination, is another chemical treatment being revived.

Jan 1, 1970

By Harold Cook

Discussion of the paper of HAROLD EARLE COOK, presented at the New York meeting, February, 1916, and printed in Bulletin No. 110, February, 1916, pp. 375 to 400. ALBERT SAUVEUR, Cambridge, Mass.-I think we must all agree with Lieutenant-Commander Cook when he says that there is a great deal of room for improvement in the annealing of steel castings and that better results would be attained if the annealing were conducted in closer agreement with scientific requirements. Whether even a carefully annealed steel casting can ever be made the equal of a steel forging of good quality is still a debatable question. Nevertheless, we all realize that very greatly improved results can be attained by careful annealing. Lieutenant-Commander Cook refers to some requirements calling for annealing steel castings above the Ac1 point. He is undoubtedly right where he says that this should be the Ac3 point. Take, for example, a steel casting containing, say, 0.35 per cent. of carbon, having a very coarse structure made up of coarsely crystalline ferrite. If this is heated just above the Ac1 point the ferrite remains, of course, just as it was before, while the pearlite is converted into a solid solution, austenite. Upon cooling, all this austenite is again converted into pearlite, or sorbite, while the coarse structure of the ferrite remains unchanged and the annealing has accomplished very little. It is therefore surprising that the requirement of annealing above the Ac1 point should appear, in these specifications.

Jan 5, 1916

By F. R. Jones

T Tahawus, N. Y., National Lead Co. operates the MacIntyre development. Here the world's largest titanium mine produces 5200 long tons of ore per day and pours 8000 long tons of waste rock over its dumps. Concentrated ilmenite is sent by rail to National Lead Co. pigment plants, and a second product, magnetite, is sold to steel producers in raw form or is agglomerated and shipped as sinter. Several earlier attempts had been made to produce iron from the deposits, which have been known since 1826. These attempts failed, chiefly because of titanium impurity. In 1941 the present owners re-established the operation for production of war-scarce ilmenite, and the impurity became the main product.

May 1, 1956

By W. Rostoker

PART of a program of research on the Ti-A1 system1 involved a study of the lattice parameters of the titanium-rich a solid solution, which has a hexagonal close-packed structure. For this work, a 14 cm Debye-Scherrer powder camera and filtered CuK, radiation was used. For each pattern, the parameters were calculated by a least squares solution of the five strongest high angle lines. This provides an accuracy of i0.005A or better. The results are shown graphically in Fig. 1. It will be seen that an unusual change of slope occurs in the curve for the C parameter at high aluminum contents. Such anomalous changes in slope have been recorded by RaynorV or several magnesium-rich solid solutions. The effects were interpreted in terms of a special contribution to the lattice distortion due to factors of electronic origin predicted by Jones." Jones' theory, in substance, suggested that an unusually large expansion of the lattice would begin when the electron per atom concentration in the alloy was increased to a value at which an overlap just began from one Brillouin zone to another. Con-

Jan 1, 1953

By F. E Turton

THE town of Rancagua, at the junction of the state and Braden Copper Co. railroads, is located 82 km south of Santiago, the capital of Chile. From Rancagua 70 km to the east, situated in the Andes at an elevation of 7000 ft, is the town of Sewell, the location of a millsite. Two and one half km east of Sewell by underground railroad at an elevation of 7500 to 10,000 ft is the Teniente ore-body. The history of El Teniente dates from the eighteenth century, when according to legend a Spanish lieutenant, or teniente, a fugitive from justice, escaped to the Andes and camped at what afterwards became known as the Mineral El Teniente. This man reputedly discovered a vein of high grade copper ore. The first official records date from 1819, when some exploitation was begun, and continue until 1870. The orebody was large and of relatively low grade and was beyond the capabilities of the small groups attempting to operate it. No effort was made to erect a concentrator until William Braden became interested in the property. In 1901 Mr. Braden promoted the necessary capital for the first practical exploitation of the ore-body. Barton Sewell and E. W. Nash, both of the

Jan 1, 1953

By D. I. Cameron

A graphical method has been developed and tested for separating the effects of grain boundary and lattice diffusion in polycrystalline materials. The method is based on the assumptions that for unidirectional diffusion from a plane source of radioactive material, the penetration of activity far into the specimen from the source is due solely to grain-boundary effects, and 2) pure grain-boundary penetration is described by a linear plot of log activity vs the perpendicular distance x from the source. The former is based on the fact that at any temperature the grain-boundary diffusion coefficient is always very large relative to the lattice diffusion coefficient; and the latter is based on the derivation of Fisher.1 Using these criteria along with appropriate penetration data (in this case, data for the diffusion of Cb95 in pressed and sintered UO2) one first plots the data as log activity vs x2 and as log activity vs x, as shown by curves 1 and 2, respectively, in Fig. 1. A tangent line to curve 2 for large x (curve 3) is then transferred to the x2 plot as curve 4. The subtraction of curve 4 from curve 1 yields curve 5 which represents only lattice diffusion and may therefore be related to the diffusion coefficient by using the appropriate solution to Fick's second law. It should be noted that the method has inherent inaccuracies for small and large values of x2 and only the subtraction at intermediate values can be used. For the illustrated specimen the calculated diffusion coefficient is 3.4 X 10-11 sq cm per sec at 1445°C while data using a single crystal of UO2 at the same temperature yielded a value of 2.9 x 10-11 sq cm per sec.2 The same method of subtracting grain-boundary diffusion effects to obtain lattice diffusion coefficients has been successfully used to determine self-diffusion coefficients of Th230 in polycrystal- line thoria.

Jan 1, 1962

By F. E. Turton

THE town of Rancagua, at the junction of the state and Braden Copper Co. railroads, is located 82 km south of Santiago, the capital of Chile. From Rancagua 70 km to the east, situated in the Andes at an elevation of 7000 ft, is the town of Sewell, the location of a millsite. Two and one half km east of Sewell by underground railroad at an elevation of 7500 to 10,000 ft is the Teniente ore-body. The history of El Teniente dates from the eighteenth century, when according to legend a Spanish lieutenant, or teniente, a fugitive from justice, escaped to the Andes and camped at what afterwards became known as the Mineral El Teniente. This man reputedly discovered a vein of high grade copper ore. The first official records date from 1819, when some exploitation was begun, and continue until 1870. The orebody was large and of relatively low grade and was beyond the capabilities of the small groups attempting to operate it. No effort was made to erect a concentrator until William Braden became interested in the property. In 1901 Mr. Braden promoted the necessary capital for the first practical exploitation of the ore-body. Barton Sewell and E. W. Nash, both of the

Jan 1, 1953

E. A. HOLBROOK,*Urbana, Ill.-To those who have followed the development of powdered coal two questions often occur. First, as to the moisture in the coal. In Illinois we recognize that the bituminous coals contain about 12 to 15 per cent. of what we call "contained moisture," that is, the moisture is present in the coal although this may appear absolutely dry and dusty. In addition, the surface moisture may be present in any amount. I would like to ask what is the relative effect of these two forms of moisture upon the work of pulverizing. Does Mr. Collins refer to the contained moisture or to the surface moisture in estimating the degree to which the coal must be dried? H. R. COLLINS.-In the lignite coals, of which this country possesses a great deal and is beginning to develop them to considerable extent, the "contained" or "combined" moisture does not .trouble us; we have no difficulty in reducing lignites to a high degree of fineness. But when dealing with bituminous, sub-bituminous, or semi-bituminous, we, prefer to reduce the combined moisture as well as the hydroscopic moisture as far as possible. We have recently put into operation, at a plant, furnaces and boilers consuming the lignite from northern New Mexico, which contains between 4 and 5 per cent. moisture as we pulverize and burn it. The evaporating efficiencies under the boilers have been so remarkable that we wish to check the results half a dozen times before quoting them. We have also just started two boilers at the Garfield smelter, and have obtained the same high efficiencies.

Jan 11, 1918

By Sukeyuki Mori, Kinjiro Aso, Tsuyoshi Hara, Hisao Okamoto

A theoretical calculation of the electro-osmotic circulation of liquid in a rectangular micro-electro-phoresis cell was presented by Smoluchowski (1921) and Komagata (1933). According to their theories, the velocity of liquid changes with depth such that the velocity distribution may be represented by a symmetrical parabola in the cell. Their theories appear contrary to the results of our experiments which show that the velocity distribution curve is represented by a symmetrical parabola whose symmetrical axis is displaced from the center line of the cell. A similar phenomenon had been suggested by Lane and White in 1937 based on the latter's theory which seemingly was incomplete. By using methods of measuring electrophoretic velocities based on the above three theories, serious errors are obvious. We are thus proposing a unified theory for determining the electrophoretic velocity of mineral particles in a rectangular cell. The equations of Smoluchowski, Komagata and White can be derived from our theory as special cases. On the basis of our theory, we are proposing an improved method of determining the precise electrophoretic velocity of mineral particles based solely on the coefficients of the velocity distribution curve. In our experiments, this method gives satisfactory results. We determined the relation between the zeta-potential and pH value of suspension for several minerals.

Jan 1, 1980

By Murray F. Hawkins

One problem of reservoir engineering is the early estimation of the size of newly discovered reservoirs. Often these reservoirs are the expansion type in which sizeable pressure drops occur incident to the production of small fractions of the oil reserve, above the bubble point, and a material balance equation may be solved to find the reserve. The early form of this equation' considered only the compressibility of the oil. Later Hall2 showed that the compressible nature of the formation rock is a significant factor in production above the bubble point, and he presented a new equation which includes a formation (rock) compressibility term. This note presents a further extension of the material balance equation as applied to volumetric, unsat-urated reservoirs above the bubble point by including a term for the presence and compressible nature of the interstitial water. DERIVATION OF EQUATION During a decline in average reservoir pressure, ?p ?p, — p1 the initial reservoir volume V,, will decrease to some value V, due to the reduction in pore volume as a result of a decline in the hydrostatic pressure within the formation, and v, = V,, [l — cr ?p]......(1) The formation compressibility c, is expressed in terms of change in pore volume per unit pore volume per psi. Simultaneously the connate water within the formation expands from an original volume V,, = S,V,, to a new volume V,, V, = s,v,, [I + c,npl.....(2) The difference [Vp — V,] is the hydrocarbon pore volume at pressure p and may be equated to the volume of the remaining oil, or [N — N,] B, = V,,, [I - C~A;] - S,.Vpi [l + cwnjl.........(3) But the initial oil in place in terms of the initial reservoir volume, connate water, and formation volume factor is Ilividing Equation 3 by Equation 4 eliminates V,, to give,

Jan 1, 1956

By Fred P. Dewey

Although coke is the acknowledged metallurgical fuel, and has been extensively used in this country for more than thirty years, yet the facts on record in regard to its physical properties are exceedingly meagre; and this is also true, but in a less degree, of its chemical composition. An investigation is being carried on in the National Museum which is intended to supply, so far as may be, this deficiency, and through the kindness of Professor Baird, Director of the Museum, I am permitted to present to the Institute a summary of a portion of the results already obtained. So far as I am aware, the credit for the first systematic investigation of the physical properties of coke belongs to Mr. John Fulton, Mining Engineer of Cambria Iron Co. The results of this investigation have been published in Report L, Second Geological Survey, Pennsylvania, 1875, and in a pamphlet setting forth the advantages of the Connellsville coke, the latter published also by the " Virginias"* His results are not altogether free from experimental errors, and the assumption that "the specific gravities of coke and water are very nearly alike "- is scarcely warranted. It has seemed to me, therefore, desirable to make an independent investigation of the physical properties of coke on a plan somewhat different from that adopted by Mr. Fulton. This is the investigation now being carried on at the National Museum.

Jan 1, 1884

By Eugene H. Cowles

Now that a determined public effort is being made on this side of the Atlantic to create a steel ship-building industry, the materials that are demanded for this purpose assume a new interest to the American metallurgist. In the past, the uses of metals in this country have been almost exclusively connected with the land, while in England their application to marine purposes has been equal in importance to that on shore. In the future the same should be the case here. This is the reason for bringing a somewhat nautical or rather naval topic before a body the chief interests of which are supposed to lie in the mines and mountains of the interior of the country. A modern war-ship or " ocean-grayhound" (like the City of Paris) is an epitome of philosophy and human skill. In her graceful lines we have, as Ruskin might quaintly say, a " builded geometry ;" while in her wonderful machinery for motion, offensive and defensive, we have the summation of the ideas of a host of students who have, at one time or another, during the course of a hundred years of her evolution, contributed their intellectual mites to render her a thing of beauty and of power. Notwithstanding her present perfection, the modern ship contains room for further improvement. One of the most important things about her is the propeller. This active member is of more impor-

Jan 1, 1890