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By Mario Luiz Cruz Nascimento

Devido a seu preço competitivo e alta resistência à fluência e à corrosão, atualmente as colunas dos fornos de reforma são confeccionadas com tubos fundidos por centrifugação de aços inoxidáveis austeníticos da classe HP modificados ao nióbio. Apesar de projetadas para uma vida mínima de 100.000 horas em serviço, falham frequentemente devido a intercorrências operacionais que levam ao superaquecimento localizado, designados surtos de temperatura. No presente trabalho, microscopia eletrônica de varredura (MEV) e microanálise por energia dispersiva de raios-X (EDS) foram utilizadas para estudar duas colunas trincadas após um surto de temperatura. Descobriu-se que o NbC reprecipita na morfologia de pequenas partículas nos sítios onde a fase G foi dissolvida durante o surto de temperatura. Desta forma estas partículas servem como marcadores microestruturais da ocorrência do surto.

Aug 17, 2017

By Maurice K. Seguin

It is a difficult task to find enriched soft iron ore deposits in the central part of the Labrador Trough, New Quebec, Canada, when the areas investigated are covered by glacial drift. A qualitative interpretation of either a combined gravity-magnetic-seismic-resistivity survey or gravity-magnetic-seismic or gravity-magnetic-resistivity survey permits (with a low probability level) the detection of iron formations and ore zones as well as their delineation from most of the country rocks. This is possible because most of the altered iron formation underwent a slight increase in density through enrichment and because the accompanying geochemical alteration changed their magnetic properties. In order to increase the chances of success in finding ore bodies when using geophysical methods, different types of correlation were done for many deposits. These are: I) A quantitative correlation of the residual gravity anomaly intensities with the specific gravity, the iron content, the silica content, the porosity factor, and the dimensions of the underlying ore bodies. 2) A quantitative correlation of the ground magnetic intensity relative to a reference lithologic unit with the percentage of Fe.,O, recovery and with the volume ferromagnetic susceptibility. A few discoveries already have been made with this method. The details of the location, the description of the geology, and the history of previous geophysical surveys and their qualitative interpretation have already been given.', ' A very brief paragraph describing the regional and local geology is necessary in order to facilitate the understanding of this paper. The sedimentary iron formations of the Labrador Trough consist of a 700-mile geosynclinal segment composed of tightly folded and faulted Proterozoic sediments, volcanics, and intrusives that are rich in mineral deposits. The complex sequence rests unconformably on the basement of Archean granitic gneisses. The direct-shipping iron deposits are scattered along a northwest-trending strip, 5 to 10 miles wide and some 60 miles long in the facies rich in iron oxides and preferentially in localities where the original sedimentary environment favorized the deposition of a large concentration of magnetite associated with chert by physicochemical processes, e.g., oxidation-reduction potential, pH, temperature, pressure. Once leached of its silica and/or iron carbonate content and enriched with secondary a-hematite (occasionally goethite), this original magnetite associated with some primary hematite makes the blue direct-shipping ore which constitutes the important ore reserves in this mining district.

Jan 1, 1971

By Tapani Järvinen

Non-ferrous metals and metals in general are considered as being non-renewable natural resources. Metals are needed because of their excellent and irreplaceable properties. The consumption of metals, with the exception of carbon steel, is steadily growing by 1-3 % annually, and that of stainless steel as much as 3-6 %. This is a general trend, which is periodically disturbed by cyclical variations. In recent years so-called "New Economy" has become prominent in the public media and the market value of the traditional industry has been well below its real value and importance. Nevertheless, the modem society requires metals today and also in the future, and the companies using the most modern technology in a responsible way and innovative solutions not only in technology, but also in everything they do will survive. This paper describes the role of Europe as a producer of primary base metals and as a supplier of technologies in the base metals industry. It concentrates on the development and commercialization of technologies and project implementation in the metallurgical industry. As one example ofa European approach to these matters the paper presents Outokumpu's response to the future challenges in the base metals industry. Outokumpu Oyj is one of the leading metals and technology companies in the world of stainless steel, copper, zinc, and sales of technology in metals and minerals businesses. Outokumpu applies its knowledge of metals and processing to generate value for its customers and shareholder. Everything we do, we do in an economically, environmentally and socially responsible way.

Jan 1, 2003

By Charles E. Weaver

During the past few years there has been considerable activity in prospecting for oil and gas in several parts of western washington. From time to time seepages of oil or emanations of gas have been reported from various places. Several companies have been organized for the purpose of drilling, but only a part of these have actually begun operations. In certain localities very small seepages of oil occur, but up to the present time no oil or gas in commercial quantities has been obtained. In order to determine the conditions which may be favorable or unfavorable to the occurrence of petroleum it becomes necessary to know the character and extent of the geological formations in which such deposits might occur. In other regions where producing wells have been developed it is possible to know what formations contain the oil and what structural conditions influence its concentration in reservoirs or zones. It is usually possible to determine those strata which contained the materials from which the petroleum may have been derived and also the position and distribution of the more porous sandstone belts into which it may have collected. Detailed stratigraphic surveys may even determine the depth at which a certain known oil-bearing zone may be tapped at any particular place. It is also possible to recognize those formations which are presumably barren of oil, as well as those which are absolutely so. In new regions far distant from any of those which are now producing or have produced in the past, it becomes absolutely impossible to foretell whether oil may exist in commercial quantities or not. Assuming that such deposits do exist, it is extremely difficult to predict at what depth the produciqg zone or zones occur. However, in prospecting in a new and unexplored region, use should be made of such laws as have been found to govern the occurrence of petroleum deposits in other well-developed fields. Such deposits in their world-wide distribution are found almost exclusively associated with sedimentary rocks. Areas composed predominatingly of igneous and metamorphosed rocks are to be rcgarded as extremely unfavorable localities for the occurrence of commercial deposits of oil or gas. Assuming that such oil deposits are

Jan 1, 1916

By C. C. Griggs

From its inception, a limestone quarry or mine should be under the direction of a capable engineer. Before it becomes a reality, he should outlinc the future results, plan the most economical methods for moving the materials and the most efficient equipment, and pilot the undertaking along the narrow pathway of success, avoiding the pitfalls of uneconomical production and the precipitous walls of scanty profits. Inspection of successful limestone properties shows that all have had difficult engineering problems, the solution of which have required keen engineering ability. In approaching a subject of this nature, it is logical to follow the progress of the limestone operation from its inception to the end, as reflecting the engineering required. There are four major divisions: Investigation, equipment, development, and operation. Investigation On the reliability of the engineer's estimates and the soundness of his judgment depend the success or failure of the enterprise. When one visits a prosperous concern, realizes that the limestone is of a constant chemical composition, sees the mechanical devices installed, and watches the output leave the plant in trains of railroad cars or fleets of vessels, he may overlook the fact that in the remote past this great creation was born in some man's brain and evolved through competent engineering. Many factors must be considered before a promoter could procure the money necessary to launch such an enterprise, for a conservative banker will only recommend a successful producer while the promoter must provide funds on his own and his engineer's judgment. An engineering investigation must be made preliminary to expenditure for actual operation, which, for a limestone deposit, would' naturally embrace such subjects as : ' Readily available. 1. Tonnage available........ Possibly available. Chemical analysis.

Jan 1, 1925

By William C. Peters

The Alpine-Himalayan system, the only major active tectonic belt mainly exposed in a continental mass, is of increasing interest to exploration geologists as well as to theoreticians. Answers to the broader problems of plate tectonics are being sought in this intricate system where the geosynclinal concept was born and where the geotectonic cycle was first applied to metallogeny. The search is all the more intense because it involves scientists from more than a dozen countries with a stimulating variety in perspective. The international Geodynamics Project has allocated the Alpine-Himalayan system to two separate study groups with one directing its attention to the Alpine-Mediterranean region and the other giving consideration to the Himalayan region. This geographic division is accepted in this paper, with remarks being confined to the former and to the west of boundary zone between the European-Asian and the Southeast Asian plates as envisioned by Dewey and Bird (1970). The region is well-mapped in some parts and it includes some of the most intensely-studied geology, most classic mines, and newest orebody discoveries. Within the region, an Alpine-age copper-molybdenum metallogenic belt extends from Rumania to Pakistan. The belt can be considered in terms of plate tectonics, and there is the possibility of using plate tectonics concepts in exploration.

Jan 1, 1973

By Christine Wenzl, Christoph Wagner, Christoph Sagadin, Stefan Luidold

Corrosion mechanisms have been investigated between MgO refractory substrates and synthetic FeNi slags. The materials taken into consideration comprised a simple synthetically mixed slag with specific oxides of slags from a ferroalloy producer. The MgO refractory substrates with the slag specimens on it were heated in a hot stage microscope to two different characteristic temperatures, 1350 and 1650 °C. The experiments proceeded under a controlled gas atmosphere that simulates the relevant process conditions. The corrosion mechanisms of each system were determined by SEM analyses. The obtained results showed that slag corrosion is dominating with a pronounced partial dissolution of refractory. It was also observed that iron oxide present in the slag diffused into the coarse refractory grains forming the relative low melting magnesia wuestite. Finally,the comparison of these findings with those predicted by thermodynamic calculation (FactSage) indicated the corrosion mechanisms and draw implications for improving the refractory performance and lifetime.

Mar 1, 2017

By Luane Isquierdo Ferreira Holanda, Lucio Fabio Cassiano Nascimento, Luis Henrique Leme Louro, Sérgio Neves Monteiro, Alaelson Vieira Gomes, Édio Pereira Lima Júnior

In the present study,we used natural fibers malva (Urenalobata, Linn) in 0, 15 and 30 vol.% as reinforcement of epoxy matrix composites to ballistic application. Ballistic efficiency of these composites was assessed by measuring the energy absorbed and residual velocity after impact 9 mm FMJ ammunition projectile, aiming to compare with traditional materials, such as: aramid fabric Kevlar™ used in vests for personal protection. The results showed by visual analysis and scanning electron microscopy (SEM) that the main active failure mechanisms in composites were delamination layers and fiber rupture. In test groups can be seen that the absorbed energy and the residual velocity varies with the fiber percentage used. Compared to aramid there is both a gain in weight and cost of the ballistic armor, which makes the fiber malva a promising material applications involving personal protection against 9 mm caliber ammunition.

Mar 1, 2017

By Richard F. Hewlett

This report describes a comparison of methods for computing grade and tonnage of ore, leach, and waste material for a mined-out portion of the Silver Bell Oxide porphyry copper deposit, and these computed values are compared with the actual tonnage of these classes of material produced during mining operations. Comparisons with production records have been made by using both exploration drill-hole assays and development blast-hole assays. The polygonal method is the most accurate for this deposit, because it more closely represents the lateral mineral distribution in the deposit. This is demonstrated by plots of the total-copper assay distributions of the development blast-hole assays for a specific bench. The investigation also shows that the smaller vertical assay interval (based on a 5-foot vertical churn-drill-hole sample) yields a more accurate estimate of both grade and tonnage than the 40-foot composite assay interval (based on the average of eight 5-foot assay values). This can be attributed to the fact that selective mining within a bench can separate out much of the waste and leach material that is included as ore in the 40-foot composite assay computations.

Jan 1, 1970

By Dachun Liu, Xuepeng Li

Smelting-acid leaching process is a way to treat high-content arsenic containing copper dust. However, smelting makes a low recovery of valuable metals and acid-leaching produces large amounts of arsenic-iron slag. Arsenic sulphuration volatilization at low temperature was studied, followed by pressure leaching to selectively recover Cu, Zn, and In from copper smelting dust while minimizing arsenic contamination.

Mar 1, 2017

By T. E. Swigart

In the production of oil end gas, engineering methods have been applied less than in any other branch of the oil industry. While refineries, gasoline plants, pipe-line and other transportation systems, and even drilling wells to a great extent, take advantage of engineering skill, the tendency has been to assume that the handling of producing wells is merely a mechanical and routine matter. At present few companies employ engineers to study oil and gas production methods with a view of increasing the general efficiency of recovery, but in vie, of the advancement in other lines of the petroleum industry by the application of engineering principles, does it not seem likely that the production branch may benefit also by engineering studies? Engineering applied to the handling of producing wells falls under two general headings, - first, the efficient handling of wells from the time of their inception in order to obtain the greatest possible ultimate production, and, second, the rehabilitation of old properties that have been handled carelessly in their early lives. To date, the engineering work that has been done on oil production problems falls mostly in the second class. For example, the use of vacuum and the application of compressed air have proved successful in some instances in stimulating wells of low gas pressure. These methods are costly to apply and are adapted to small wells in which the gas is almost exhausted, or in which the original gas pressure is negligible. The experiments described in this paper fall under the first heading, as they were made with an idea of learning toe probable extent to which the gas production of an oil well can be curtailed while gas in the sand is still plentiful, and thus saved for doing work during the later period of a well's life. Because of the scope of the experiments, this paper does not include a discussion of back pressure on flowing wells or for purposes other than cutting down the gas produced with each barrel of oil.

Jan 1, 1922

By B. D. H. Knights, M. A. W. Bryson

Flotation of PGM ores, specifically UG-2, presents a number of technical challenges. These centre on the prevalence of chromite. Subject to over-grinding, chromite is primarily recovered to the flotation product through entrainment. This is of unique concern as it must be kept below a threshold for downstream smelting, with significant operational and monetary penalties being imposed should it exceed this concentration. A number of strategies have been developed to maximise PGM recovery in the presence of this unwanted contaminant. Specialised flowsheets form a vital basis and advanced control algorithms further enhance PGM recovery while minimising the recovery of chromite. Advances in Mineral Processing Science and Technology Proceedings of the 48th Annual Conference of Metallurgists of CIM Sudbury, Ontario, Canada Edited by

Jan 1, 2009

By Nasri Munfah

Long Island Rail Road’s (LIRR) service to New York City is limited to Penn Station on the West Side of Manhattan, which is operating at its practical capacity for the commuter railroad. This situation imposes serious considerations for future growth and limits the destination of many Long Island commuters. The East Side Access Project will provide a connection of the LIRR to the landmark Grand Central Terminal (GCT)on the East Side of Manhattan. The construction of the connection will require significant tunneling and underground work utilizing a variety of construction techniques. In Queens, the connection will require five soft ground tunnels using pressurized face tunnel boring machine. In Manhattan, the connection will require a series of rock tunnels and caverns connecting to two deep large station caverns under GCT to accommodate eight tracks with four platforms in a stacked configuration. The caverns housing train rooms are connected to the lower level of GCT where a large concourse will be provided. With a budget of $4.3 Billion, The East Side Access Project is the largest transportation project ever undertaken in New York City. This paper provides an overview of the project, discusses its environmental and the engineering challenges, and provides an insight into the design development to date.

Jan 1, 2001

By W. D. Guo, Y. M. Zhu, B. B. Luo

The main chemical constituents of waste cooking oil are higher fatty acid glycerides, which can be used to produce anionic fatty acids for most non-sulfide flotation. However, using the mixed fatty acids (MFA) produced by waste cooking oil as collectors directly, the flotation effect is usually not satisfactory, especially at lower temperature or room temperature. There are very rare systematic studies about the reason for poor flotation performance of waste cooking oil. This study aims to investigate the flotation and adsorption characteristic of different types of fatty acids in waste cooking oil to find out what kind of fatty acids results in the poor flotation performance. This will provide technical supports and theoretical guidance for the waste cooking oil application in the field of mineral processing. In this study, MFA were produced from the waste cooking oil, and then separated into saturated fatty acids (SFA) as well as unsaturated fatty acids (UFA), which possessing different flotation properties. The properties of the MFA, SFA and UFA were analyzed by iodine value, melting point measurement, Fourier transform infrared (FT-IR) spectroscopy and quartz micro-flotation tests. The results showed that UFA was composed of fatty acids containing group—(CH=CH—CH2)n—, having an iodine value of up to 162.90, a melting point as low as -17.3 ? and stronger low-temperature floatability. In contrast, the SFA was made up with saturated fatty acids and a few oleic acids, with an iodine value of 48.97 and a melting point of 38.8 ?. SFA had shown poor collectability and required a flotation temperature higher than 35 ?. The results of zeta potential measurements, solution chemistry calculation and FT-IR spectra revealed that both UFA and SFA can be adsorbed on the quartz surface activated by CaCl2 via the chemical and hydrogen bonding. The reason MFA having a poor flotation performance is the SFA has an extremely high melting point which affecting the dissolution of the dispersion.

Jan 1, 2018

By D. J. Miller

Environmental considerations are extremely important in planning and carrying out mergers, acquisitions and real estate transfers. It is not inconceivable that potential or actual environmental liabilities could exceed the targeted company's net worth or the book value of the real estate of interest. It is therefore essential that an environmental due diligence investigation (DDI) be performed to quantify environmental liabilities before sales, mergers or acquisitions. This paper will discuss general procedures used in environmental due diligence investigations. The emphasis will be placed on mergers and acquisitions. It should be pointed out that the procedures discussed in this paper are general and must be modified to fit each particular merger or acquisition under consideration.

Jan 1, 1988

By J. M. Clark

(Wilkes-Barre Meeting, June, 1911.) For some years past, those interested in the development of the increasingly important mining industry of Canada, have urged the adoption by the Dominion Parliament of a federal mining-law, which would have the force and stability of statutory enactment. At present, placer-mining in the Yukon Territory, is governed by the Yukon Placer Mining Act. All other mining under federal jurisdiction is governed by 'Orders in Council and Ministerial Regulations. In the earlier stages of development, it is perhaps a matter of necessity that these important matters should be so dealt with; but it is now felt that the time has come when mining-rights in the extensive regions under federal control should be put on a permanent basis, -and that any changes required from time to time should be made only after full and open discussion in Parliament. A short sketch will suffice to indicate how vast and varied the interests affected really are. When the Dominion of Canada was constituted by the Imperial Statute known as the British North America Act of 1867 (which came into force by proclamation on July 1 of that year), it comprised only the present Provinces of Ontario, Quebec, Nova Scotia, and New Brunswick; but provision was made for the inclusion of Newfoundland, Prince Edward Island, British Columbia, Rupert's Land, and the North West Territories. Subsequently Rupert's Land and the North West Territories were acquired, the 'Crown Colonies of British Columbia and * SECRETARY'S NOTE.-Mr. Clark, an eminent Canadian lawyer, and joint author of the treatise on "The Law of Mines in Canada," has been requested by the Do¬minion Government to prepare a Federal mining-law, and presents this paper, by invitation of the Council, in order to obtain, if possible, useful suggestions from members of the Institute.-R. W. R.

Apr 1, 1911

By Jetson Lemos Ferreira

O presente estudo teve por objetivo verificar a independência tanto da Curva Limite de Tensão (CLT), quanto da Curva Limite de Deformação Plástica Efetiva (CLDPE) em relação à trajetória de deformação. Para tal, foram utilizadas Curvas Limite de Conformação (CLC) de aço livre de intersticiais (Interstitial Free - IF), determinadas, primeiramente, por meio de trajetórias lineares e, posteriormente, por trajetórias bi-lineares estabelecidas por níveis de pré-deformação nos modos de tração uniaxial e estiramento biaxial simétrico. As previsões da CLT e da CLDPE, calculadas a partir das deformações limites da CLC convencional em trajetórias lineares e bi-lineares, mostraram-se independentes em relação à trajetória de deformação. Entretanto, verificou-se que o critério de escoamento adotado tem grande influência na forma e posição destas curvas limites.

Aug 17, 2017

By João Batista Ferreira Neto

A escória de aciaria pode ser uma alternativa como mistura para o cimento portland, substituindo parcialmente a escória de alto-forno. Um processo pirometalúrgico tem sido desenvolvido para promover a modificação química da escória de aciaria LD. Os experimentos foram realizados através da refusão de 300 kg de escória de aciaria LD, seguido de sua modificação no estado líquido. Essas escórias foram resfriadas com o uso de esferas metálicas. Análises de fluorescência de raios–X (FRX) e microscopia eletrônica de varredura (MEV) das escórias revelaram uma relação entre composição química, condição de resfriamento e a formação de fases cristalina ou vítrea. As amostras de cimento foram obtidas através da mistura de 25% de escória modificada e 75% de cimento Portland, resultando em mais de 280 J/g de calor de hidratação acumulado em 72h, expansão abaixo de 0,1% em ensaio em autoclave e resistências à compressão acima de 42 MPa com 28 dias. O processo mostra potencial para ser aplicado no tratamento de escória de aciaria LD.

Aug 17, 2017

By E. Scheepers

Within a phosphorus producing submerged arc furnace it was found that the continuous fluctuation of the furnace between a flowrate-driven state (high throughput) and a thermodynamic-driven state (low throughput) caused both techniques to have similar overall, predictive abilities and resulted in a linear, ARX-type, adaptive prediction model as the model of choice. Secondly, this pre-diction model was developed, tested and then shown to have a reasonable, 8-hour-ahead predictive accuracy (R2, coefficient of determination) of 30% (±6%) on future Pslag values. This inherent relationship exists because, at the precise moment of a Pslag prediction, the furnace already contains the metallurgical memory (input variables to the linear model) needed to ensure that some predictive possibilities will always exists - all as a result of the long residence times in the furnace. Residence time, however, is not a directly adjustable variable but rather a fully dependent variable and a function of an array of interconnected and interactive variables. In fact, this applies to virtually all input variables, reemphasising the importance of innate metallurgical memory. Thirdly, predictive control possibilities were explored by simulating the set-points of two fully independent variables used by operators to control the process: the ratio of fixed carbon-to-P2O5 and the ratio of silica gravel-to-pellets. This linear, predictive control model showed only a slight improvement with an 8-hour-ahead predictive accuracy of 35% (±7%). This highlights how ineffective current adjustments are in optimally steering the process and how difficult even incremental improvements in feed-forward and predictive control can be. Finally, it is shown that fundamental design-, sampling- and process restrictions currently associated with the process will always limit the predictive and especially control accuracy or meaningfulness of any dynamic model. These restrictions include the size of the furnace resulting in long residence times, 8-hours sampling intervals, an extremely complex and interactive process and a 16% spatial analyses variation on the Pslag values ? the very value that the model is to predict. The point is made that, given the current status quo, even the perfect dynamic prediction model can not improve on an 8-hour-ahead prediction of 30% (±6%). This barrier can only be pierced with e.g. tidier and more frequent sampling regimes and other upfront capital investments, a decision that becomes a cost accounting exercise and that can only be taken by the management structure. An investment demanding ever-increasing attention is CFD software and it?s potential to shed more light on the complex interactions within the furnace.

Jan 1, 2014

By M. Sunkpal, K. C. Kocsis

"An underground environment with high air temperature and humidity conditions generated from various heat and moisture sources can significantly affect the thermoregulation processes of the human body. This can lead to a series of heat-related illnesses such as heat exhaustion, heat cramps and heat stroke. The majority of the metabolic energy of a mine worker results in the production of heat. If the human body is to maintain thermal equilibrium, then this metabolic heat must be transferred to the ambient surroundings at the same rate. The heat loss from the human body occurs through a combination of heat transfer processes, such as respiratory heat exchange, convection, radiation and evaporation. If the heat loss from the human body to the ambient surroundings is less than the metabolic heat produced, the excess will be accumulated within the human body, which will result in a rise in the core and skin temperatures. This can ultimately lead to a heat-related illness or a combination of heat-related illnesses. This paper aims to discuss major heat-related issues and provide an overview of various mine ventilation and cooling systems, which can be employed to overcome high levels of heat and humidity in underground mines. In this paper, the effects of heat exposure on the health, safety and productivity of the mine workers are also highlighted. IntroductionMining in the United States remains one of the most hazardous industries, despite significant reductions in fatal injuries over the last century (Coleman and Kerkering, 2007; Saleh and Cummings 2011; Jacklitsch, Musolin and Kim, 2016). Occupational health hazards within the mining industry include hazards that are physical, such as traumatic injury or hearing loss; chemical, such as silica or diesel particulate matter; biological; ergonomic; and psychological (Donoghue, 2004; Saleh and Cummings, 2011). The effects of some of these hazards can be diagnosed immediately, while many, like black-lung and silicosis, will have long-term effects on the health, safety and life quality of mine workers (Donoghue, 2004; National Institute for Occupational Safety and Health, NIOSH, 2000). Among these hazards, exposure to heat and humidity can significantly affect the safety, health and productivity of mine workers, particularly in deep and hot underground mines (Roghanchi, Sunkpal and Kocsis, 2015). Short-term acute heat exposures can cause a rise in the core temperature of the human body, which can result in a heat-related illness or combination of heat-related illnesses. Adverse long-term chronic heat exposure can generate serious occupational heat-related illnesses, such as cardiovascular diseases, mental health problems and chronic kidney diseases. High core body temperatures coupled with dehydration can generate negative behavioral effects such as physical fatigue, irritability, lethargy, impaired judgment, loss of dexterity and loss of concentration (Xiang et al., 2014)"

Jan 9, 2017