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By Dudley L. Davis, E. C. Peterson

Introduction The Darwin District is 30 miles east of Olancha which is 220 miles north from Los z4ngeles via U. S. Highway No. 6. The ore deposits occur in the Darwin hills that have been elevated above the Darwin plateau by typical basin and range-type faults. Some of these faults have been active quite recently as shown by the displacemerit of Quaternary (?) basalt flows and the rejuvenation of erosion in Darwin wash. The ore bodies occur as fissure fillings and replacement of favorable beddings in a thick series of Paleozoic limestones, dolomites, shales and quartzites. Rich oxidized lead-silver ores were dis'Overed in the early seventies. BY 1875, Darwin had a population Of about 5000, and by 1880 several small mills and smelters had been built. Early exhaustion of surface ores, the isolated location of the district, and fluctuation Of metal prices caused intermittent operations until World War 11. The district production is estimated at about $3,000,000 prior to 1900 and perhaps $4,000,000 between 1900 and 1945 when Anaconda purchased the major producing mines. 'or the Past two Years, daily production has averaged 75 tons of direct shipping and 150 tons of milling-grade ore. At present, 300 tons of mixed oxide and sulphide ore are treated by flotation, the oxidized lead minerals being activated by addition of sodium sulphide after galena and sphalerite have been recovered from the circuit. Extraction averages 85 pct of the lead, 80 pct of the silver, and about 33 Pct Of the zinc in a bulk concentrate. The mill is designed so that minor changes permit selective flotation of pyritic lead-zinc ores encountered at depth. General Geology The oldest rocks in the Darwin hills are a series of Paleozoic limestones, dolomites, shales and quartzites probably pennsyl-vanian in age. These rocks have been intruded on the Rest by the Coso granite batholith and on the east by a granodiorite stock. Numerous sills and dikes grading from orthoclase granite to gabbro are exposed in the underground workings. The sedimentary rocks have been considerably folded and faulted, the most prominent structure being a northwest pitching anticlinal fold, the crest of which lies just west of the ridge line of the Darwin hills, The east limb of this fold has been intruded by the granodiorite stock and east of the stock the sediments show several closely spaced anticlines and synclines. The minor flexures on the west flank of the major fold are structurally important in localizing the ore in the Defiance and Essex mines of the Darwin group. There are three principal systems of faulting and fissuring, most of which are post-intrusive and premineral in age, with minor amounts of postmineral movement. The Darwin tear fault is the largest, most persistent fault in the district. It strikes N 60 to 75°W, dips steeply south and is traceable for about 10 miles. It is a normal

Jan 1, 1949

By G. S. Scott

The Bureau of Mines is engaged in research to assess the hazards associated with the handling, storage, and use of combustible gases, vapors, and. liquids encountered in mines and in industry. As a part of this general pro-gram, numerous limits of flammability and ignition temperatures are being investigated for a wide variety of combustible materials, and methods are being developed to minimize the explosion hazards of these combustibles. The Bureau receives numerous requests for information on the explosion hazards of specified combustible mixtures under various conditions of use. This information circular has been prepared to assist those who may have similar requests. Destined primarily for the layman with a limited technical knowledge of the subject, it considers rather briefly the numerous factors that enter into the general problem of gaseous explosions and their prevention.

Jan 1, 1951

By W. C. Meyer

The concept of using powdered coal-in-oil-mixtures (COM) as a composite fuel to conserve oil resources and relieve import supply problems is being vigorously promoted by the Department of Energy via the sponsoring of various demonstration units (1). The idea of COM as a useful alternative fuel has been explored on and off for over 100 years (2). The approach must be capable of grinding, mixing, storing, and combusting COM with presumably only minor equipment changes on oil-fired boilers. DOE estimates that 56 000 m3 of oil (350 000 barrels) could be spared daily if a 50-50 COM was used to generate electricity. Of course, the ability of COM suppliers to prepare and deliver a stable suspension of COM at reasonable economic costs must be achieved if the concept is to be successful. This report reviews the various methods used to attain stable coal-oil mixtures. Various physical-chemical principles associated with each method of stabilization are also discussed.

Jan 1, 1981

By E. R. Cole

This Bureau of Mines investigation was prompted by the need forr a stable anode for electrowinning metals, particularly zinc and copper, from acid solutions. The polarization behavior of Pb-Ag (1 pct Ag) anodes in H2SO4 and fluoride solutions was determined as the first step in the development of such an anode. A Luggin capillary, dc power supply, high-impedance voltmeter, and other equipment standard to an electrochemical laboratory were used in this study. It was determined that during polarization, a relatively hard, stable coating of Pb02 was formed on the surface of the lead-silver anode and the rate of formation of this coating was considerably enhanced by the presence of fluoride ions in solution. Subsequent investigations at the Bureau of Mines Rolla Research Center resulted in the development of a Pb02-coated titanium (Pb02-Ti) anode. Results of this effort were presented in Bureau of Mines Report of Investigations 8111. Additional data resulting from extensive testing of the Pb02-Ti anodes, as well as process improvements and innovations, are included in this report. The anodes were considered generally unsatisfactory for zinc electrowinning because of lower conductivity, higher oxygen overvoltages, and shorter in-cell life as compared with the Pb-Ag anodes now being used in industry. However, the PbO2-Ti anodes were used successfully to oxidize waste chromium solutions and to electrowin copper.

Jan 1, 1981

By E. D. Gardner

The mine of the Eureka Standard Consolidated dining Co. is at Dividend, Utah, in the Tintic mining district. It is operated under the same management and controlled by the Antic Standard Mining Co.; the two properties adjoin each other. The Eureka Standard is worked through a vertical shaft; the ore is mined by a stringer-set-and-fill method. One hundred and thirty men were employed in April 1933. The normal daily tonnage is 100 tons; the ore is shipped to the smelter at Garfield, Utah.

Jan 1, 1935

By L. L. Sirois

Because segments of the Canadian mineral-based economy are dependent totally or in part on foreign sources of certain minerals, their well-being may well be affected by inability to obtain these minerals. Where such dependency exists, it is therefore important that contingency plans be available to counteract possible price increases or lack of supplies by means of technology, developed well in advance of any pending crisis . Canada is vulnerable to possible future real or artificial shortages of certain foreign-produced mineral commodities, and science and technology can provide information for the development of policies for counteracting efforts by foreign exporters to control prices or limit supplies.

Jan 1, 1977

By E. D. Eastman

There are three researches upon the specific heat of water vapor by the method of explosion that are sufficiently advanced in technique and suitable in plan to justify careful study of their results , with the double purpose of fixing the best available experimental values and indicating the attainable accuracy of the method. These three researches comprise the work of Pier , Bjerrum , and Siegel.5 The work of earlier date than Pier's suffers from obvious inaccuracy of measurement , while the experiments more recent than Siegel's , such as those of Womersley6 , of Bone and his collaborators , and of Maxwell and Wheeler , 8 are for the most part not well designed for the accurate determination of the heat capacities in question . Some of the errors to which they are especially subject have been discussed by David and by David and Thorp.

Sep 1, 1930

By Joseph E. Pogue

THAT the domestic consumption of gasoline displays a marked seasonal variation, with a low in the winter and a high in the summer, is well known. It is logical to expect that the nature of the variation has itself been undergoing a change as a result of improvement in roads, general employment of closed cars; and growth of mass haulage; but so far as I am aware the change in seasonal variation has never been investigated and measured. It is the purpose of this paper to present the method and results of such an investigation undertaken as a contribution to the technique of planning operating schedules now so prominent in connection with the functioning of the industry under a Federal quota system. For the method employed I am in-debted to the suggestions and help of Frederick R. Macaulay', who kindly looked over the work sheets; and credit is due Barnabas Bryan, Jr., for assisting in the computations and the graphic work. Ideas for the approach to the problem were also derived from an article by Aryness Joy, and Woodulief Thomas of the Division of Research and Statistics of the Federal Reserve Board*-.

Jan 1, 1934

By Shuoshi Lu

The Cu-Co ore studied here belongs to the oxide type. The oxidation rates of copper and cobalt are69.30% and 78.78%, respectively. The content of Cu in ROM is 1.34% and that of Co is 0.096%. The ore contains 4.64% carbon.Based on the process mineralogy and previous metallurgy tests, the principalprocess flow-sheet of ?grinding fines 80% -0.074mm, sulphide flotation followed by oxide flotation, and flash flotation for oxides? has been determined.The handling of carbon is determined through tests. The depressant PNL-1 depressed carbon effectively, improved the recovery of sulphide minerals and reduced the reagents consumption.The operation of the flow-sheet was also changed to better at the same time. Keywords: Cu-Co oxide ore, process mineralogy, carbon depression, efficient depressant of carbon

Sep 1, 2012

By M. Dupuis

It has been previously demonstrated [1,2] that using selective collector bar rodding has a big impact on the uniformity of the current density at the top surface of the cathode block and hence on the intensity of the horizontal current in the metal pad, The present study investigates the impact of using selective collector bar rodding on the MHD stability of a 500 kA aluminium electrolysis cell, For this purpose the recently developed MHD package for the aluminium reduction cell time dependent behavior is used.

Jan 1, 2005

By Rodrigo Seara Martins

Foram realizados testes industriais com cerca de uma tonelada de pó fluxante com teor de flúor da ordem de 1,0%, denominado ultrabaixo teor de flúor (UBF). O testes foram realizados em 29 corridas de aços com baixo teor de carbono acalmados ao alumínio (AA BC) na Aciaria 2 da Usiminas em Ipatinga. Ao longo do processamento industrial, os dados operacionais foram analisados, coletadas amostras para avaliação das propriedades físico-químicas da escória líquida e as válvulas submersas foram separadas para medir a taxa de desgaste. Tanto as caracterizações realizadas quanto o desempenho industrial evidenciaram que as propriedades relativas à taxa de fusão, lubrificação e cristalização estão de acordo com as necessidades operacionais para a produção de aços AA BC. Por fim, os resultados de desgaste da válvula submersa mostram um ganho significativo com o uso do pó fluxante UBF. A taxa média de desgaste foi aproximadamente 40% inferior à obtida com o uso do pó fluxante comercial (teor de flúor na ordem de 7,5%).

Aug 17, 2017

By H. Huang, R. N. Gow

"The reactivity of an enargite mineral electrode was investigated spectroelectrochemically under conditions typically found in alkaline sulfide leach solutions, with pH 11-13 and Na2S additions of 50 and 250 gL-1. A bulk enargite electrode was cycled between 0 and -1,000 mV for each set of solution conditions. Raman spectroscopy was used to determine and compare surface formations against species in mass-balanced EH-pH diagrams generated using STABCAL. Previously, it was determined that arsenic could be selectively leached under alkaline conditions at an average solution potential of -300mV, across the pH range 11-13. Operating under such conditions allowed for the selective leaching of arsenic with elemental sulfur formation. From several of the voltammograms obtained during this current testing, the formation of elemental sulfur appeared at increasingly reducing conditions with increasing sulfide concentration. At high concentrations, copper started to dissolve, possibly as a bisulfide complex, reducing the selectivity of the leach, unlike previous studies. However, the presence of the higher sulfide concentration is also anticipated to prevent passivation by consuming any surface formation of elemental sulfur. This study provides insight into the operating parameters of alkaline sulfide leaching in regards to the selectivity of arsenic leaching, as well as guidance for control of reagents and solution potential and, of course, the need for water treatment afterwards.IntroductionEnvironmental limitations on the pyrometallurgical processing of arsenic-bearing concentrates have forced operations to consider other solutions. Attempts to hydrometallurgically process enargite (Cu3AsS4) fall into two categories: the co-dissolution of arsenic and copper under acidic conditions, and the selective leaching of arsenic under basic conditions. The authors believe that the selective leaching of arsenic is more amenable because it produces a solid copper phase, preferably chalcocite (Cu2S) or covellite (CuS) that could then be processed using conventional methods already in place in the copper and gold industries. Potential leaching methods include alkaline sulfide leaching (Achimovicovica et al., 1999; Anderson and Twidwell, 2008a,b; Tongamp et al., 2009 and 2010), hypochlorite leaching (Vinals et al., 2003; Curreli et al., 2005; Mihaljovic et al., 2007), ammoniacal leaching (Gajam and Raghavan, 1983), and acid leaching (Gow et al., 2014b) with or without fine grinding to mechanically activate the enargite surface and increase normally slow leach reaction kinetics (Achimovicova et al., 1999; Balaz et al., 2000; Balaz and Achimovicova, 2006). In this study, the reactivity of enargite under alkaline sulfide leach conditions was examined."

Jan 1, 2015

By Isabela Santana de Oliveira

O aço inoxidável 304L pode apresentar uma característica particular: transformações de fase induzidas por deformação, o efeito TRIP (Transformation Induced Plasticity) que possui embasamento na transformação martensítica. Neste trabalho propõe-se analisar o perfil de formação de martensita em corpos de prova submetidos a ensaio CLC (Curva Limite de Conformação), segundo o método Marciniak, nas regiões junto à trinca e distantes da mesma através de uma sonda portátil de um ferritoscópio. Utilizando técnicas de difração de Raios-X (DRX) e ensaios de dureza Vickers pode-se correlacionar a evolução microestrutural e valores de dureza nessas mesmas regiões ao grau de encruamento da austenita e a formação de martensita.

Aug 7, 2018

By Bráulio Salumão de Oliveira

A participação do petróleo e gás natural na matriz energética mundial aumenta gradativamente a cada ano. Em estimativas para as próximas duas décadas, tais fontes continuarão a figurar entre as principais na participação em suprir a demanda por energia mundial. Para que seja tecnicamente e economicamente viável a exploração destes recursos, são necessários utilizar produtos e processos inovadores que, por sua vez, exigem evolução da pesquisa e desenvolvimento de novos materiais e processos. Este estudo objetivou analisar o desenvolvimento tecnológico de ligas ferrosas para os produtos tubulares utilizados nesse mercado, através da elaboração de indicadores a partir de documentos de patentes indexados na base Derwent Innovations Index entre 1995 e 2014. Foram elaborados indicadores de evolução temporal, de identificação dos elementos de liga, das tecnologias em processamento dos produtos e das propriedades requeridas além de comparativos entre principais desenvolvedores e seus mercados de interesse. O número de documentos de patentes sobre o tema aumentou significativamente durante o período estudado. Foram notados países com destaque no número de depósitos de patentes, porém com pouca expressão de pedidos fora de seu território. Os principais titulares são empresas japonesas embora a China tenha apresentado a maior tendência de crescimento de depósitos no tema.

Aug 16, 2017

"Virtual reality, a 3D computer-generated environment, has become a recognized delivery system for many forms of education. This paper describes the application of virtual reality to mineral processing education. An interactive mineral processing visualization module developed at the University of New South Wales, Australia, provides users with an overview of a base-metal concentrator and details about how the mined ore progresses through stages in processing. The module also involves developing instructional based plant layouts and flowsheets in the virtual environment. These assist the user in understanding the essential components of the base-metal concentrator.RÉSUMÉ La réalité virtuelle (RV), un environnement en 3D généré par ordinateur, est devenue un système de prestation reconnu pour diverses formes d’éducation. Cet article décrit l’application de la réalité virtuelle à l’éducation dans le domaine de la minéralurgie. Un module interactif de visualisation du traitement des minerais développé par l’université de Nouvelle-Galles du Sud, en Australie, offre aux utilisateurs une vision d’ensemble d’un concentrateur de métaux communs ainsi que des détails concernant la progression du minerai extrait à travers les différentes étapes de traitement. Ce module implique également le développement de schémas de réalisation et de traitement didactiques dans l’environnement virtuel, lesquels schémas aident les utilisateurs à appréhender les composantes essentielles d’un concentrateur de métaux communsINTRODUCTIONVirtual reality (VR) is the creation of an artificial environment that is experienced through sights and sounds provided by a computer (Squelch, 2001). The simulated environment is achieved through technologies such as 3D graphics, audio feedback, and special peripheral devices to produce interactive environments.Virtual reality has been used in diverse fields including medicine (Riener & Harder, 2012), entertainment (Hsu, 2011), military (Manojlovich, Prasithsangaree, Hughes, Chen, & Lewis, 2003), manufacturing (Zimmermann, 2008; Jiang, 2011), and chemical processing (Squires, Andersen, Reklaitis, Jayakumar, & Carmichael, 1992; Schofield, Lester, & Wilson, 2005). Virtual reality is also becoming the recognized delivery system for education in many fields, including engineering (Bell & Fogler, 1996, 1998; Shin, 2002). For example, VR laboratories have been designed and developed to teach users fundamental features of heterogeneous catalytic mechanisms and absorption columns (Bell & Fogler, 1995), the multi-phase and multi-component blast furnace iron-making process (Babich & Senk, 2009), and to guide users to identify various safety measures while working in a real laboratory (Bell & Fogler, 1996)."

Jan 1, 2017

By Kasimcan Koruk, Julian M. Ortiz

Building a geological model is important in resource estimation, as it defines the extent of domains for estimation. Geological models are built by assigning a domain to the samples, based on logging of different features related to lithology, alteration, and mineralization. Then, the extent of these domains is determined using geometric or geostatistical tools. However, these models should account for uncertainty, since the actual extent of these domains is not known and must be extrapolated from the labelled samples. With the availability of geochemical datasets and machine learning techniques, employing multiple variables to build resource models should be considered. This article proposes a two-step machine learning approach with an ensemble implementation to define geological domains and their uncertainties. First, an unsupervised binary clustering method labels the geochemical samples into two domains. These labelled samples are used to inform a geological domain model built by support vector classification. This application is repeated with subsets of variables and subsets of samples, leading to an ensemble learning method. Weak models are produced with each subset of samples and variables, and combined to devise a stronger learner. The final model accounts for uncertainties thanks to the ensemble implementation. The proposed workflow is demonstrated on a dataset from a porphyry copper deposit, applied hierarchically to define four domains. Performance is comparable with traditional methods, but provides the advantage of allowing domain knowledge in the selection of the variables, and generates domain boundaries that can be controlled in terms of their continuity and smoothness.

Oct 11, 2023

By Jelena Milinovic, Sofia Martins, Anna Lichtschlag, Sven Petersen, Fernando J. A. S. Barriga, Bramley Murton, Adeline Dutrieux

"The active TAG hydrothermal mound is one of the largest and better studied. Due to its size (one of the largest, known so far, in the Atlantic Ocean) and concentration of specific economic valuable elements, it might be considered for future exploitation due the increasing demand for raw materials. However, the discovery of several large inactive sulfide mounds, some partially buried under sediments may relieve this pressure. Exploration for such occurrences can, together with geophysical exploration tools, be accomplished by mineralogical and geochemical studies of those sediments.INTRODUCTION AND GEOLOGICAL SETTINGThis study reports the results from sediment samples collected during the Meteor M127 cruise on the TAG hydrothermal area in 2016. The Trans-Atlantic Geotraverse (TAG) hydrothermal field (Mid-Atlantic Ridge, 26°08’N) is located 2.4 km east of the main rift valley at depths of about 3650 m. The TAG hydrothermal field stands as an example of a massive sulfide deposit on a low-spreading ridge associated with an active detachment fault (Humphris et al., 2015).Associated with the TAG hydrothermal field are metalliferous sediments/deposits that can reach several meters in thickness (Metz et al., 1988). These sediments/deposits can be formed by hydrothermal plume fall out (buoyant and nonbuoyant), massive wasting of hydrothermal edifices (sulfide mounds and chimneys) and authigenic mineralization (Gurvich, 2006). By studying the grain size, mineralogy and geochemistry of the sediments it is possible to identify each type of sediments and find their proximal or distal distribution. The location of the gravity cores studied here is distributed along sediment ponds near inactive hydrothermal mounds [Three mounds area (B)], actively venting low-temperature mound [Shimmering mound (A) and Mir zone (D)] and an area of sediment accumulation [Central area (C)] (Rona et al., 1993) (see Figure 1)."

Jan 1, 2017

By Jun Lu, Min Chen, Wei-jian Su, Jian-zhong Luo, Yu-tao Lei

"In the case of treating phosphatizing wastewater containing zinc, zinc had an impact on the solution chemistry, especially on pH. Fe2(SO4)3 and CaCl2 were used as precipitators to remove phosphate from zincic phosphatizing wastewater and the optimum pH was investigated. Zinc ion had a significant effect on the optimum pH. The optimum pH ranges were 12.10(inlet concentration of 15.67mg/L, outlet concentration of 9.53mg/L), 3.04-5.50(inlet concentration of 11.97mg/L, outlet concentration of 0.44-0.26mg/L), and more than 10.72(inlet concentration of 12.24mg/L, outlet concentration of less than 0.47mg/L) under the conditions without precipitator, with Fe2(SO4)3 and with CaCl2 respectively.Introduction Phosphate coating is commonly used for protective coating of machine elements. Including oil removal by caustic washing, rust removal by acid washing, phosphatization and inactivation, the phosphatization process produces wastewater containing inorganic salt of high concentration, especially the phosphate, beyond the environmental standards and polluting environment seriously. What’s more, the wastewater from zincic phosphatizing technology also contains another pollutant, zinc. At present, Chemical Precipitation (CP) and Biological Nutrient Removal (BNR) are two of most common technologies of phosphate removal. BNR, such as A/O, A2/O and UCT technology, is suited for wastewater containing organ phosphorus of low concentration and CP for wastewater with phosphate of high concentration [1]. Researches on CP treating wastewater containing phosphate of high concentration, mainly focus on adding quantity of precipitators[2-5] and coagulants[2-4] and the choice of technologies[3-9]."

Jan 1, 2008

By Musa D. Manzi, Raymond J. Durrheim, Richard T. Masethe

An investigation into the source mechanism of mining-induced seismic activity plays a vital role in understanding the various modes of failure observed in the underground deep-level South African mining environment. The seismic events data for this study was captured by the mine-wide seismic system operating at Kloof Gold Mine. This system comprises 40 4.5 Hz tri-axial geophones sampling at 6 kHz installed at locations that surround the stopes mining the Ventersdorp Contact Reef (VCR), Main Reef (MR) and Kloof Reef (KR). A set of 103,753 mining-related seismic events (-3.0≤ ML ≤2.7) that occurred during 2017 and 2018 was selected for this study. The mining depth of these seismic events ranges from 1600 – 4200 m; most located close to stopes mining the VCR ore body. The main criteria used to select a subset of events for detailed analysis were the number of stations that recorded the seismic event and the azimuthal distribution of the sensors.

Apr 26, 2022

By Fazel G. Jahromi, Ahmad Ghahremaninezhad

Enargite (Cu3AsS4) is a major complex copper mineral and often is a carrier of invisible gold particles. Pyrometallurgical treatment of enargite is challenging due to the arsenic release to the environment. Hydrometallurgical treatment, on the other hand, appears to be a promising alternative for enargite processing. In an atmospheric enargite leaching process both the copper and arsenic from the mineral can be leached into a sulphuric acid solution and the arsenic can be simultaneously precipitated as ferric arsenate. The unlocked gold in the residue then can be recovered in a subsequent cyanidation circuit. The downside of the atmospheric enargite leaching in sulphate solutions is the slow leaching kinetics. In this study the effective parameters of the atmospheric enargite leaching process in ferric chloride media were investigated. All the experiments were carried out at temperatures below 100 °C. The process parameters that were investigated in this study included ferric, chloride, sulphate and cuprous concentrations, temperature, mixing rate and leaching slurry pulp density. It was found that the copper recovery rate increases with the addition of cupric chloride and also with raising the temperature. The highest leaching kinetics and the highest overall copper recoveries were achieved when cupric was initially added to the leach solution and at 90 ºC.

Jan 1, 2015