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By M. Vallée

Several reviews of mineral project performance in the past 35 years indicate a pattern of occasional, but recurrent, mining project failures due to shortcomings in geological information and estimation, mineral processing and metallurgical testing, feasibility study objectives and requirements, and project start-up methods. A commitment to quality assurance and continuous improvement methods and to obtaining “ENOUGH DATA, OF APPROPRIATE QUALITY” is essential. Recent international and Canadian proposals for mineral resource and ore reserve definitions have taken a nonprescriptive stance that will undermine the formulation of requirements, guidelines and industry standards for efficient deposit delineation and estimation, and for the determination of project feasibility. To help reduce problems, every feasibility study supporting a mine development and production decision should be based on objectives and methods adequate to reach completion targets similar to the bankers’, as a good business target for a profitable project. In a resource/reserve system, the use of reserve should be restricted to a project that meets required technical, economic and legal feasibility requirements for successful project implementation, and the definitions of these categories should provide explicit limits. Current shortcomings will limit the ability of the Qualified Person to provide “adequate professional practice,” fulfill his/her professional responsibilities to his employer or client and provide adequate information to the investing public. We must take advantage of present opportunities for Setting New Standards for the new Millennium.

Jan 1, 2000

By Marco D. Boscardin, Kenneth A. Pidgeon, Adriane G. Boscardin

"Hollow bar tiebacks can offer an economical alternative to conventional solid bar and strand tieback systems for use in temporary excavation support construction. However, the limitations associated with the installation of hollow bar tiebacks require special attention during design, construction and load testing to verify conformance with conventional performance and proof testing criteria (PTI, 2014). In particular, providing a reliable free length is complicated by the 10-foot (3-m) -long, segmental, couplingto- coupling nature of the free length sheath in the hollow bar system, and addressing the fully grouted annulus of the bond zone and the free length zone at the end of installation are key concerns. In addition, it is often more convenient to install a greater number of more closely spaced, lower capacity tiebacks with the hollow bar system, compared to conventional tiebacks. This paper examines how these issues were addressed for a project involving a 60-foot (18-m) -deep sheet pile excavation through a highway embankment and a 70-foot-deep sheet pile and soldier pile and lagging excavation through a railroad embankment, both supported by a hybrid system of hollow bar tiebacks and hollow bar soil nails. The project involved approximately 300 tiebacks and 400 soil nails.INTRODUCTIONEngineers Construction, Inc. (ECI), constructed a pair of 32-foot (9.8-m) -wide (clear span), 30-foot (9- m) -high (21 feet (6.4 m) above the stream bed), cast-in-place concrete arch culverts as a design-build project for the Vermont Agency of Transportation (VTrans) in East Ryegate, Vermont. The new culverts replaced an existing 8-foot (2.4-m) -wide by 6-foot (1.8-m) -high cast-in-place concrete culvert under US Route 5 (RTE5), and twin, 2-foot (0.6-m) -wide by 5-foot (1.5-m) -high granite block culverts under the Washington County Railroad (WACR) alignment. The culverts convey Manchester Brook eastward, through the embankments for RTE5 and the WACR, on its way to the Connecticut River. The Connecticut River is located approximately 100 feet (30 m) east of the WACR embankment. The existing structures were undersized and backed up water behind the embankments during high flow events; and often trapped debris that flowed down the brook and became clogged. The existing culverts also had cracks and openings that have resulted in the loss of ground into the culverts and the formation of sinkholes in the sides of the embankments. Moreover, the reason for the large cross-sectional dimensions of the culverts was to make them of sufficient size and openness to encourage the migration of fish up the stream to spawn. The culvert through the RTE5 embankment is 144 feet (44 m) long, and the culvert through the WACR embankment is 128 feet (39 m) long, with a 57-foot (17.4-m) -long by 32–foot (9.8- m) -wide by 17-foot (5.2-m) -deep 10 feet (3 m) deep above the stream bed) open channel section between the two culverts. A plan view of the culvert alignment is presented in Figure 1."

Jan 1, 2016

By Y. P. Lu

PET/kaolin nanocomposites were prepared with melt blending and the structure of the composites was characterized through IR techniques. The results showed that there is stable chemical bonding between PET and kaolin. In addition, the dispersion condition of nanokaolin was observed by means of SEM and TEM. As a result, the thickness of the dispersed nanokaolin particles in PET matrix is mainly from 20mm to 200nm, and the nanosized particles congregate to some extent in the samples. In addition, it was found the kaolin particles almost homogeneously dispersed in the PET matrix, without preferential orientation because of the shear effect due to melt blending. Furthermore, the mechanical properties of PET/kaolin nanocomposites are dependent on the modification efficiency of nanokaolin. With the poor efficiency, the nanokaolin particles tend to aggregate at a high content and have a bad interfacial compability between nanokaolin and PET matrix, which lead to stress concentration, so the mechanical property descends. Experiments of different contents of modified nanokalin indicated that the intensity of PET/kaolin nanocomposites decreased firstly, then increased, and then decreased, with the nanokaolin content of 4 to 5 percent, the rupture stress of the composites showed a maximum value, which was higher than that of pure PET. On one hand, nanokaolin decreases the function among PET macromolecules, which will decline the mechanical properties, on the other hand, the piece structure of kaolinite improves the intensity of the nanocomposite. When the nanokaolin content is low, the former has the dominant effect on mechanical property, while the latter will play a leading role with the content increasing. But if the nanokaolin content still increases, the agglomeration and stress concentration will be obvious.

Jan 1, 2014

By Phillip J. Maddex

Transportation is a major part of yours in the industrial minerals industry. Whereas federal income taxes merely take 50 per cent of your firms profits, transportation cost may take 50 per cent of the gross realization - selling price plus transportation - on your product, f. o. b. customers plant.

Jan 1, 1969

RISKGATE is an interactive online risk management system developed by the Minerals Industry Safety and Health Centre (MISHC; University of Queensland) to maximise health and safety performance in the mining industry through implementing continual improvement in management of major unwanted events. A comprehensive knowledge base has been captured for risk management of tyres, collisions, fires, isolation, strata underground, ground control open cut, explosions, explosives, manual tasks and slips/trips/falls. This will be extended to outburst, coal burst and bumps, interface displays and controls, tailings dams and inrush in 2013. RISKGATE presents substantive and leading edge controls to assist industry stakeholders in the design, management and reporting of organisational and regulatory compliance requirements. From a broader industry perspective, RISKGATE provides an environment for knowledge capture and knowledge exchange to drive innovation and best practice in the identification, assessment and management of risk. By capturing operational knowledge from industry experts, RISKGATE provides a cumulative corporate memory at a time of high personnel turnover in the coal industry. All major Australian mining companies are contributing topic experts to this broad industry initiative. In the first 24 months, nine coal mining companies nominated over 80 different experts who contributed over 400 days of individual time to the knowledge capture workshops. RISKGATE is the largest single Australian Coal Association Research Program (ACARP) occupational health and safety (OHS) initiative to date.

Aug 1, 2013

By F. E. Cash

The Holmes Safety Association , organized and named in honor of the late Dr. Joseph A. Holmes , first director of the United States Bureau of Mines , has for its object the prevention cf accidents , the improvement of health conditions at work, in the home , and in public places , and the promotion of the general welfare of its members . As a means of preventing accidents and advancing health and safety , the Holmes Safety Association disseminates information , gives instructions on subjects related to safety , and promotes first -aid and other forms of protective and accident - prevention training . This organization is intended to work and cooperate in the closest possible way with existing mine or plant safety organizations in conducting educational , social , and recreational activities for the promotion of health , safety , and efficiency .

Jan 1, 1929

By Xiang Li, Xibing Li

It is paramount that the stability of rock slopes be correctly accounted for under diverse operating and environmental conditions. Owing to different sources of uncertainty entailed in such stability problems, conventional deterministic approach through the calculation of a factor of safety (FOS) cannot reflect quantified uncertainties explicitly and sufficiently. Thus it is highly desirable to invoke the reliability approach to consider uncertainties in a systematic manner. Nowadays, the current design standards have an increasing tendency to ensure rock slope stability by pre-defining a target reliability index (or target probability of failure), viz., the reliability level of a rock slope is pre-set as a target to be satisfied. In such a situation and considering the fact that the FOS used as an indicator of slope performance still has a very wide acceptance, we focus on proposing an inverse-reliability-based methodology which aims at developing a two-fold indicator strategy, i.e., using the FOS and reliability together to deal with slope stability problems. The basic idea behind it is to utilize a so-called inverse first-order reliability method (IFORM) to directly calibrate the FOS provided the target reliability index has been given. In this way, the calibration scheme relating the FOS can be rationally done by not only incorporating uncertainties, but also satisfying a desired level of the prescribed reliability. Based on this, to make the IFORM computationally feasible and also reduce its computational cost, we introduce the response surface method (RSM) to generate a surrogate for the FOS-based limit state function (LSF), considering the lengthy and complicated form of the FOS in some recognized methods (e.g., within the framework of limit equilibrium). Distinguished from the existing RSMs that potential inadequacies may arise, we present an RSM based on a hybrid approach combining support vector machine (SVM; used as a regression technique) and uniform design (UD; pertaining to experimental design). Using a representative example of rock slope stability problem, we demonstrate the feasibility and validity of the developed methodology, during which the associated sensitivity study and further discussion are also performed. By dint of such a methodology, we can establish a link between the conventional deterministic approach and the reliability approach, where a logical and realistic framework is provided, for cases achieving the specified reliability, to assist in selecting the FOS which remains adequate for rock slope stability even in the face of uncertainty.

Jan 1, 2015

By João Paulo Meneguelli Campos

O objetivo deste trabalho foi validar o modelo proposto por Kasuya et al para prever as durezas máximas da zona termicamente afetada (ZTA) em juntas soldadas de um aço com médio teor de carbono através de ensaios empíricos. Para isto, se faz necessário o cálculo da energia de soldagem, quando foram testados modelos apresentados por Marques e Modenesi e também o modelo proposto por Perdigão. As juntas soldadas foram produzidas usando chapas de aço SAE 1045 com espessura de 12,7 mm como material base, chanfro de 70º e arame sólido do tipo ER70S-6. Para mudar as condições de resfriamento das juntas soldadas, foram testadas variações nos parâmetros de soldagem, tais como: energia de soldagem, taxa de resfriamento e temperaturas de pré-aquecimento e interpasses. Foram feitos experimentos com e sem pré-aquecimento e testados pós-aquecimento e alívio de tensões. As amostras da zona fundida e da ZTA tiveram as durezas medidas e foram analisadas por meio de microscopia eletrônica de varredura. Em linhas gerais, os resultados empíricos para a dureza na ZTA seguem a mesma tendência prevista pelo modelo de Kasuya et al, mas observam-se desvios na proporcionalidade validando a equação parcialmente para o material estudado. Também foi possível constatar que para o cálculo da energia de soldagem são adequados os modelos propostos por Perdigão e Marques e Modenesi.

Aug 17, 2017

By Paul M. Tyler

FOR the same reason that water is not missed until the well runs dry, the roles of many industrial minerals in wartime are often overlooked. In contrast to the growing shortages of many metals, our supplies of most nonmetallic minerals are limited only by our machinery for taking them from the ground and by our processing facilities. With few exceptions, the demand for increased supplies has been met without fanfare or delay. Only Brazilian quartz crystals, certain kinds of mica, and, latterly, industrial diamonds are on the so-called strategic list, although asbestos, beryl, corundum, cryolite, fluorspar, crucible-grade graphite, ilmenite, iodine, kyanite, monazite, nitrates, rutile, and zircon have caused more concern among those responsible for procurement and are included in our preclusive buying programs. Such specialties are needed urgently, but they are far less important in the over-all picture than the more abundant minerals.

Jan 1, 1942

By Q. J. Liu

The flotation circuit and the reagents of the all-sliming flotation about low grade and hard operation on zinc oxide ore are researched in the paper. The results indicated that there are many types of zinc minerals in this ore, and the composition is very complex. They include hemimorphite, smithsonite, hydrozincite and so on. The ore is seriously sliming. In light of the ore properties, three kinds of flowsheets have tested. They are gravity concentration (cleaning tables), flotation, combined process of gravity concentration and flotation. The test showed that the recovery of zinc is only 17.08% in the gravity separation. In combined process of gravity separation and flotation, the recovery of zinc concentrate is close to 70%. But the flow-sheet is complex and hard to control in the production. The floatation circuit is feasible. In the test, it pay attention to investigate the new combined reagent which is used in selective all?sliming flotation process. The effects of slime are eliminated by the multi-loop treatment of middling. In flotation, the final recovery of concentrate is 88.76%; the grade is 29.50%. The recovery of physical ore is 93%; and the recovery of -10mm fraction is more than 65%.

Jan 1, 2014

By M Norbert, D O’Connor

The mainline running tunnels for Legacy Way comprise two tunnel boring machine (TBM) driven tunnels. Both TBM drives commenced at the Launch Portal adjacent the Mt Coot-tha Road. Excessive surface settlement arising from tunnelling would have had a significant impact to the road infrastructure. The geological structure above the tunnel springline is a mixture of fill, residual soil and weak rock. Given the combination of low ground cover and weak ground materials, along with the use of an open face TBM, an oversize pipe umbrella system has been installed above the tunnels. This pipe umbrella system is similar to that commonly adopted in conventional mined excavation support in soft ground except that the steel pipes are substantially larger in geometry and filled with concrete. It is acknowledged that similar systems with oversize pipe umbrella have been adopted elsewhere in the world in other projects. These systems often comprise of a full arch formed by conjoining oversize steel pipes (in contact only). By aligning the pipes in contact, the arching behaviour of the steel pipe would have been enhanced. However, this poses a degree of construction difficulty due to excavation and installation method of the pipes. The Legacy Way pipe umbrella system only consists of a partial arch at the tunnel crown and each pipe is spaced approximately 1200 mm apart with 900 mm diameter pipe, leaving a gap of approximately 300 mm between pipes. A reinforced concrete portal block was used to support the exposed ends of the pipes.This paper reviews the design analysis, the recorded deflections from the pipe umbrellas and surface monitoring during TBM launch and revisits the analysis using the newly available RS3 program, from Rocscience for 3D analysis of geotechnical structures.CITATION:Norbert, M and O’Connor, D, 2014. Starting the journey – launching of the Legacy Way open face tunnel boring machines in mixed face ground conditions, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 307–314 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By Susan Rafalko, Mike Walker, John Sankey, Sherif Aziz, Alex Potter-Weight, Mary Nodine, Frederic Masse

"After several successful projects on the Garden State Parkway and New Jersey Turnpike for support of single-stage MSE (Mechanically Stabilized Earth) walls using rigid inclusions (Controlled Modulus Columns) as an alternate to two-stage MSE walls and surcharge, the Bass River Bridge Widening project presented additional challenges in terms of soil conditions and height of embankment that created opportunities for the design-build ground improvement contractor and its MSE wall-designing partner to enhance their design and construction methods. The specialist contractor decided, in association with the wall system supplier, to perform an independent large scale instrumented test area on the project to demonstrate the ability of the design techniques to model the behavior of the system, as well as the capacity of the rigid inclusions to provide the necessary bearing capacity and settlement control to allow the construction of the highway without any consolidation period. This paper presents a detailed description of the design of the ground improvement system and MSE wall system, as well as the results and conclusions of the monitoring data gathered on the large scale test program. The combination of rigid inclusion ground improvement technologies, such as the CMC system, together with an MSE wall system allows for the rapid and economical construction of high embankment without waiting for a surcharge and consolidation period or the necessity to use a two-stage wall system. In-depth understanding of the design techniques and advantages of this combination will be provided and should be beneficial for any geotechnical engineer or owner looking for innovative solutions to save both time and cost on their projects.1. IntroductionAs development continues on sites with poor ground conditions throughout the world, conventional MSE walls remain a flexible design solution; however, construction of MSE walls in combination with ground improvement is becoming more frequent where extreme differential and/or total settlement prevail due to soft ground conditions. Various techniques have been used in the past in such conditions (e.g. conventional surcharge, staged construction, or two-stage MSE walls), even though these design solutions have typically involved longer waiting times for settlement to occur. As a result, conventional MSE wall design has been combined with a variety of ground improvement techniques consisting of rigid inclusions for an economical and efficient solution with the potential to accelerate construction and limit long term settlement. For the particular subject of this paper, the specialist contractor (Menard) proposed to use CMCs (Controlled Modulus Columns) to support the highest part of the MSE wall. CMCs are grouted displacement rigid inclusions installed in a grid-like pattern using a displacement auger. Before the CMCs are installed, a working platform may first need to be placed to allow equipment to move around the site depending on the ground conditions. Following the CMC ground improvement, an LTP (Load Transfer Platform) is installed prior to the construction of the MSE wall."

Jan 1, 2015

By Mateus Alves Segundo Paulino

No estudo de escórias de fornos elétricos a arco (FEA), o sistema CaO-SiO2-MgOFeO se destaca em importância quando os temas são a proteção aos refratários básicos e a produção de ‘escória espumante’. A importância da obtenção da escória espumante no FEA reside no fato reconhecido de que ela traz diversas vantagens para a produção de aço, tais como: economia considerável de energia elétrica, proteção de painéis, redução de ruído, redução no consumo de eletrodos, etc. Levando-se em conta que diversos fatores ligados à composição química são de grande importância na produção e estabilidade de bolhas de CO, neste trabalho diferentes diagramas de fase são produzidos como ferramentas para a previsão da composição das escórias mais favoráveis para a formação da espuma. São consideradas na investigação algumas características relevantes encontradas no FEA tais como: basicidade da escória, temperatura de 1.600°C e teores de FeO e MgO variáveis (que refletem os diversos níveis de oxidação do banho).

Jul 30, 2018

By Thomas L. Ochs

The Bureau of Mines is investigating the fundamental behavior of electric arcs in electric furnace operations. The electric arc is a poorly understood phenomenon. If the arc in a steelmaking furnace can be more carefully controlled, it should be possible to increase heat transfer to the melt, reducing both electrical and acoustical noise. As a first step toward a better understanding of the are, voltage and current signals from operating furnaces were analyzed. The results of the initial analysis show that instrumentation used in monitoring and controlling furnaces, such as meters and strip-chart recorders, gives incomplete or erroneous information to the operator and therefore leads to less than optimal control. Advanced instrumentation and analysis techniques, such as the waveform analysis used in these investigations, can improve the understanding of operation and the control of electric furnaces. This report describes the instrumentation and the numerical analysis methods used and compares these methods with standard metering and recording techniques.

Jan 1, 1986

By I Swane, R Rait, A Robertson

Geochemical assessment of mine waste materials prior to commencement of a proposed mining operation is a fundamental component of mine feasibility studies and the regulatory approvals process. Static and kinetic geochemical test methodologies are widely used to predict the geochemical nature of mine waste materials and to develop strategies for managing potentially æhostileÆ materials. These data can also be integrated with data from other fundamental studies such as hydrogeology to predict specific environmental outcomes and potential impacts at mine closure and post-closure.A case study is presented for a proposed open pit gold mine in Mongolia, which illustrates how geochemical, hydrogeological and groundwater quality data can be used as part of a geochemical modelling process to predict the final pit lake water quality over time. A series of static and kinetic test geochemical test programs were completed and acquired data integrated with hydrogeological and groundwater quality data provided by the proponent. A widely used geochemical modelling program (PHREEQC) was used to develop the geochemical model and predict water chemistry in the pit void after mine closure. Sensitivity analyses were completed to explore the effects on the model output of groundwater to leachate water ratio, pit wall rock type and climate.Modelling has indicated that pit void water should be pH circum-neutral at mine closure and should remain within Mongolian and World Bank water quality guideline limits under the modelled simulation most likely to occur in the field. Final void water salinity is expected to increase eight fold over 14 years after end of mine life due to a continuous flux of salts (particularly sulfate salts) into the pit lake whilst the pit lake volume will remain relatively constant due to evaporation and a slow recharge rate. Dissolved metal and sulfate salt concentrations in pit water are also predicted to increase over time and could be moderately elevated compared to applied water quality guideline values. Some of the metal concentrations, however, may be lower as these would be expected to precipitate at circum-neutral pH and greater. Recommended additional assessment work on the project when mining commences includes determining the magnitude of adsorption and co-precipitation of metals occurring in the pit void water/sludge system.CITATION:Robertson, A, Rait, R and Swane, I, 2013. Geochemical assessment of mine waste materials and prediction of final pit lake water quality at a proposed gold mine in Mongolia, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 165-170 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By Zabetakis M. G.

This Bureau of Mines report presents a brief summary of the explosion trends in United States coal mines for the past 160 years. These trends show that in spite of the overall improvements in mine safety, the number of fatalities from ignitions of methane has actually increased in recent years. Suggestions are made of procedures that can be utilized to reverse this trend.

Jan 1, 1973

By Wojciech Szczepiński, Dominik Gächter

In early 2020, the construction phase began for the new complex of buildings for Radium Hospital in Oslo – the leading facility for cancer treatment in Norway. Settlements in the surrounding area, caused by pore pressure changes, allowed for the introduction of an alternative solution for the construction of the excavation pit. The presence of solid bedrock and sensitive clay – the same material that causes major landslides in the Scandinavia – in the excavation pit, lead to a combination of techniques, which were never applied in Norway before. For the stabilization of the clay Dry Deep Soil Mixing was applied to allow safe execution of the geotechnical works. Interlocking Bored Piles with footbolts and Jet Grouting columns, in combination with anchors, provided the retaining structure for the excavation pit. Rock injections were performed to avoid any ground water ingress into the pit. Underpinning of fully operational, adjacent buildings was carried out with jet grouting columns. These works were performed from the basement of the hospital and the ‘ACI – Acoustic Column Inspector’ was used to ensure proper installation of 2 m diameter columns to a maximum depth of 25 m. The buildings were later founded on Steel Core Piles, the most common pile type in Scandinavia.

Oct 1, 2021

By Dominik Gächter, Wojciech Szczepiñski

In early 2020, the construction phase began for the new complex of buildings for Radium Hospital in Oslo – the leading facility for cancer treatment in Norway. Settlements in the surrounding area, caused by pore pressure changes, allowed for the introduction of an alternative solution for the construction of the excavation pit. The presence of solid bedrock and sensitive clay – the same material that causes major landslides in the Scandinavia – in the excavation pit, lead to a combination of techniques, which were never applied in Norway before. For the stabilization of the clay Dry Deep Soil Mixing was applied to allow safe execution of the geotechnical works. Interlocking Bored Piles with footbolts and Jet Grouting columns, in combination with anchors, provided the retaining structure for the excavation pit. Rock injections were performed to avoid any ground water ingress into the pit. Underpinning of fully operational, adjacent buildings was carried out with jet grouting columns. These works were performed from the basement of the hospital and the ‘ACI – Acoustic Column Inspector’ was used to ensure proper installation of 2 m diameter columns to a maximum depth of 25 m. The buildings were later founded on Steel Core Piles, the most common pile type in Scandinavia.

Sep 8, 2021

By K. Mayhew, R. Bruce, A. Heidel, G. P. Demopoulos

"Teck and Aurubis are working together to commercialize a technology for the processing of copper arsenic sulphide concentrates that is economic and sustainable with regards to the environment and community. The pressure hydrometallurgical approach is a desirable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. A test work program was carried out where a range of copper concentrates with varying arsenic grades was processed under CESL leach conditions. This paper discusses the stability character (in terms of arsenic) of the resulting residues and their mineralogy. The basic ferric arsenate sulphate phase (BFAS; otherwise known as type 2) was identified as the main arsenic carrier. All CESL residues demonstrated high stability (<1 mg/L As) through a range of aggressive (pH and ORP) environmental leach conditions.INTRODUCTIONArsenic deportment and control in the copper industry needs an integrated approach involving each stage of the value chain, i.e. exploration, mine operation, refining process and mine closure. Teck Resources Limited (Teck), Canada’s largest diversified mining company and Aurubis, Europe’s largest copper producer, have formed a partnership to advance the application of CESL copper-gold technology for the development of high arsenic bearing copper resources (Bruce et al., 2011).Among the options for arsenic control in the metallurgical treatment of copper concentrates is the precipitation of ferric arsenate, which is widely accepted as the most suitable method for stabilizing arsenic (Ferron and Wang, 2003). The pressure hydrometallurgical approach to processing arsenic bearing copper concentrates is a favorable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. Under CESL pressure leaching conditions (150 °C, 1380 kPa) high copper extraction and arsenic (V) fixation is possible.Within the pressure leach autoclave, arsenate and ferric iron react to form scorodite type phases. The precipitate formed under CESL conditions is dependent on the Fe (III) /As (V) ratio and the tenor of cations and anions, particularly excess sulphate (Gomez et al., 2011a). Previous studies on CESL residues have found arsenic to be present as crystalline scorodite (FeAsO4.2H2O) (Bruce et al., 2011), basic ferric arsenate sulphate (BFAS: Fe(AsO4)1-x(SO4)x(OH)x·(1-x)H2O, where 0.3<x<0.7), and/or arsenate adsorbed on to hematite (Gomez et al. 2011b). Although not a focus of previous work, scorodite was the predominant precipitate formed when the concentrate Fe/As was <1.5 (Mayhew et al., 2010), and BFAS was the predominant precipitate when the concentrate Fe/As was >10 (Gomez et al. 2011b)."

Jan 1, 2012

By William Hume-Rothery

MR. CHAIRMAN, LADIES AND GENTLEMEN: I need not say how much I appreciate the honor of being asked to lecture to you, and how much I would thank you for your kind invitation. It is encouraging to feel that the abnormal restrictions of the war have been relaxed sufficiently to allow a free exchange of scientists between our two countries, and I hope that some of you will be persuaded to go to England, and to visit us at Oxford, so that I may repay a little of the kindness I have received from you. As this is one of the first lectures since the end of the war, I have thought it well to describe some of the advances in the theory of alloys which were made in the years between the two World Wars. From the point of view of theoretical science, these years have been of outstanding interest in the history of metallurgy. They have been years in which the development of new and more accurate experimental methods has led to the revelation of many new facts. At the same time, the theoretical developments have enabled some of these facts to be viewed as parts of a general scheme, and we may say that some of the foundations of metallurgical science have been laid. This work was naturally stopped by the Second World War, and it can therefore be reviewed as one definite stage in the development of our Science. To illustrate the new advances, I shall deal mainly with the alloys of copper and silver, since these have revealed many of the general principles. SOLID SOLUTION At the beginning of our period, the first steps in X-ray crystal analysis had been taken, and copper had been found to crystallize in the face-centered cubic structure (Fig I). The determination of this structure naturally was of immense importance in the understanding of our subject, because it meant that we were at last in a position to appreciate the underlying structure out of which the crystal of copper was built. The earlier science of metallography had shown that in many alloys of copper the addition of a second metal in not too large proportions resulted in the formation of a homogeneous alloy which was regarded as a solid solution of the one metal in copper. Fig 2, for example, shows the so-called equilibrium diagram of the copper-zinc alloys, and here you will see that there is a solid solution of zinc in copper extending to something of the order 35 to 40 at. pct zinc.

Jan 1, 1947