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By A. Kale

A chlorination pilot plant having capacity to produce 5?10 kg/hr of titanium tetrachloride is in operation at the chlorination facility in Mintek. The bubbling fluid bed chlorination plant can be operated in batch and/or continuous process to study the chlorination kinetics of various feedstocks. The chlorination of titaniferrous ores to produce titanium tetrachloride (TiCl4) was carried out during the commissioning of the pilot plant and also as part of the titanium programme carried out at Mintek. TiCl4 is a basic raw material for producing commercial titanium dioxide pigment and titanium metal. This paper discusses the challenges faced during the commissioning and operation of the chlorination pilot plant. It also discusses the effect on the auxiliary facilities and instrumentation as a result of the harsh operating conditions of +1000°C and use of corrosive gases like chlorine and titanium tetrachloride. It discusses the effect of physico-chemical properties of the titanium tetrachloride and iron chlorides. The effect on the chlorinator refractory lining due to heating and cooling of the chlorinator is also discussed. Besides the special provisions made during the design of the chlorinator, this paper also discusses the operational experience and possible solutions to be implemented in future. Keywords Fluid bed chlorination, titanium ore chlorination, titanium tetrachloride (TiCl4) production using fluid bed technology.

Jan 1, 2011

By Roberto Folchi, Hans Wallin

Having so many norms and technical content of legislation to deal with is a problem that an explo-sives engineer has to face, especially when working at an international level. Each country has its own norms and legislation, sometimes even each other region or state, as if the physics of explo-sions, rock, concrete, and masonry characteristics would change across the borders. Both norms and laws are frequently out of date, being mainly developed at the beginning of the previous century and adjusted, piece by piece, to a technical and political context that is constantly changing, with adjustment being frequently adopted in a hurry, due to a problem arising such as that of internation-al terrorism. Sometime also, norms are not harmonized with those they intend to amend, so required explanations and new adjustments lead to a vicious circle that increases confusion, complexity and depresses the explosive industry.

Jan 1, 2015

By B. Haimson

A new loading apparatus was fabricated and used to conduct true-triaxial compression tests on KTB amphibolite, a crystalline basement rock. Tests in dry jacketed samples reveal that the intermediate principal stress has a significant effect on the onset of dilatancy and on rock strength, contrary to the implicit assumption made by Mohr-type failure criteria. Failure is induced through a shear fracture that dips steeply in the direction of the least principal stress. Experimental results lead to a new generalized strength criterion in terms of all three principal stresses. Unjacketed KTB amphibolite specimens, exposed to confining fluid, are considerably weaker than the jacketed ones, despite the negligible porosity and permeability. Failure is facilitated by several closely spaced subparallel tensile cracks normal to the least stress direction. SEM analysis suggests that microcracks developed upon dilatancy onset are penetrated and extended by the confining fluid, bringing about the unexpected rock failure mechanism at reduced stress levels. Un nouveau dispositif à chargement fut fabriqué et utilisé afin de réaliser un vrai essai de compression tri-axial sur KTB amphibolite, une roche cristalline du sous-sol. Les essais effectués sur échantillons enveloppés et secs révèlent que les contraintes principales intermédiaires affectent considérablement le début de la dilatance et la résistance de la roche, contrairement à la supposition fondée sur le critère de rupture de Mohr. La rupture est produite grâce à une cassure de cisaillement très incliner en direction où la contrainte principale est moindre. Ces résultats expérimentaux indiquent un nouveau critère de rupture général en fonction des trois contraintes principales. Les échantillons de KTB amphibolites sans enveloppe, exposés à un liquide confiné, sont considérablement plus faibles que ceux enveloppés, malgré la porosité et la perméabilité négligeable. La rupture est facilitée par plusieurs fissures de traction adjacentes et sub-parallèles, normales à la plus petite contrainte principale. L’analyse SEM suggère que les micro-fissures développent suivant le début de la dilatance, elles sont pénétrées et agrandies par le liquide confiné, produisant un mécanisme de rupture de roche inattendu, ceci à un niveau de contrainte réduit. Ein neuer Ladungsapparat wurde hergestellt um real - triaxiale Druckfestigkeitsversuche in KTB Amphibolit, einem kristallinen Grundgebirgsgestein, durchzuführen. Messungen in trockenen, bedeckten Proben zeigen that die mittlere Hauptspannung eine bedeutende Wirkung auf das Einsetzen von Dilatanz und auf die Stärke des Gesteins hat, im Gegensatz zu der impliciten Annahme auf Grund von Mohr-ähnlichen Versagungskriterien. Versagen ist induziert durch eine Scherfraktur die sich steil in die Richtung der geringsten Haupspannung nach unten senkt. Messergebnisse führen zu einem neuen, verallgemeinerten Stärke Kriterium dass auf alle drei Hauptspannungen basiert ist. Unbedeckte KTB Amphibolit Proben, die unmittelbar den umgebenden Fluiden ausgesetzt sind, sind wesentlich schwächer als bedeckte, trotz geringfügiger Permeabilität und Porosität. Versagen wird gefördert durch mehrere, nebeneinander liegende, sub-parallele Spannungsbrüche, normal zu der geringsten Spannungsrichtung. SEM Analyse lässt vermuten dass Mikrobrüche, die sich beim Überschreiten der Dilatanzschwelle entwickeln, durch die umgebenden Fluiden fortgepflanzt und weiter verbreitet werden, und unerwartet, auf Grund der reduzierten Spannungswerte, den Versagungsmechanismus des Gesteins einleiten

Jan 1, 2003

The development of information concerning mesothelioma in South Africa started with the 1959 finding of Dr. J. Christopher Wagner of cases of mesothelioma in persons living in the vicinity or working in crocidolite mines in Cape Province. After more than 40 years, the data from South Africa now provide important insights into the differences in mesothelioma risk associated with different asbestos fiber-types. Three case series reports and one analytical report were reviewed in this session. In total, information on 504 proven cases was presented. There were 28% of cases arising from occupational exposure in mining, 35% from non-mining occupations, 23% from environmental exposures; 14% where no exposure was established and 9% where the exposure was unknown. Among the 129 cases for which occupational exposure and asbestos fiber-type were established, 115 cases were associated with occupational exposure to Cape crocidolite; 1 case associated with occupational exposure to Transvaal crocidolite and 9 cases with occupational exposure to amosite (grunerite asbestos) and 4 cases with occupational exposure to mixed fiber-types. There were no cases associated with chrysotile asbestos. There were 33 cases of environmental mesothelioma linked to Cape crocidolite exposure and 2 to exposure to amosite and crocidolite but none to Transvaal amosite alone or to chrysotile. The evidence shows that amosite is capable of causing mesothelioma but that the major risk in South Africa is associated with Cape crocidolite.

Jan 1, 2008

By Peter L. Sheehan, David A. Fawcett, Dennis C. Martin

"Smoky River Coal Limited has successfully completed a major program involving the pattern rock anchoring of a high, steeply dipping footwall slope. The slope dips at approximately 65 to 70 degrees to the north, is benched for the upper 200 feet, is supported with rock anchors for another 240feet, and is unsupported at the pit bottom. In addition to the height and steepness, several structural features including shears, rolls and stratigraphic pinch- outs complicate footwall stability.This paper presents an overview of the project with descriptions of the engineering geology and footwall design, anchor installation, instrumentation and monitoring and a cost summary.IntroductionSmoky River Coal's mines are located in the foothills of the Rocky Mountains near Grande Cache, Alberta, approximately 200 miles west of Edmonton. The Smoky River coal leases were initially developed in the late 1960s and, except for minor shutdowns, have been in continuous operation since 1969 producing a low volatile metallurgical coal, mainly for the export market. Initial coal production was from underground mines; sur face mining started in 1971, and a large surface mine, No.9 Mine, was opened in 1974. Since that time, a number of open pits have been mined within the No.9 Mine area. Surface mining is by conventional shovel-truck method s with the use of a backhoe for mining the narrow pit bottoms.Coal recovery is mainly from the No.4 seam, which has a typical unstructured thickness of 20 feet. The most attractive opportunities for open-pit mining exist in areas of over thickening of the coal seam in the hinge zones of synclines and anticlines and in dip-slope situations. The mining of the more structurally complex pits and steeply-dipping footwall slopes requires that consideration be given to footwall stability."

Jan 1, 1988

By Melford H. Salsbury

The maximum net return from the sale of ores and concentrates of gold, silver, copper, lead, and zinc accrues to the producer when these mine products are marketed to the best advantage. Data are presented that the producer, especially the small mine operator, can use to survey available markets and make a preliminary estimate of the net return to be expected from an ore, on the basis of typical mill, smelter, and freight schedules. A review of the industry is presented by States in which recent production statistics are given, marketing facilities are discussed, and locations of principal mining districts, custom mills, and smelters are shown. Explanations of treatment processes, ore types, treatment charges, payments for metals, and deductions are given. Published rail and truck freight rates for mine products, based on marketing patterns developed over many years, are listed and explained.

Jan 1, 1964

By V. Bush, T. G. Killingsworth, E. P. Ruffel

Effective and sustained corporate energy management programs are becoming a necessity for energy users as electricity deregulation laws are enacted on a state-by-state basis across the country and environmental regulations pertaining to emissions become more prevalent. The “Total Energy Asset Management” (TEAM) approach has been developed to assist energy end users with the development and implementation of corporate energy management programs designed to reduce energy risks and increase energy cost savings. This paper highlights the ways in which this approach can be applied to the mining industry while minimizing initial program implementation costs and increasing potential program benefits. Nearly the entire mining industry has become very focused on identifying opportunities to reduce costs per unit of yield. The industry as a whole has increasingly faced pricing pressures in large part due to the effects of global competition. The result of international marketplace participation and the emergence of higher efficiency recovery techniques have resulted in flat or even decreased prices for mining products. Thus, opportunities to reduce costs are actually opportunities to gain a competitive edge over similar mining operations. Due to the energy-intensive nature of many mining operations, the costs associated with energy are often a substantial percentage of operating costs. Therefore, it becomes very important to develop the corporate mentality that energy is an asset whose use should be optimized globally. In addition to the cost benefits of the TEAM approach, other benefits may occur such as reductions in facility greenhouse gas emissions.

Jan 1, 2002

By W Dodson, S Dogramaci

Isotopes and hydrochemistry were used to define groundwater flow systems and better understand the hydrogeological setting of the Karijini National Park, which is in the Central Pilbara region adjacent to the Marandoo iron ore mine. Based on the stable isotope composition of the water samples, the data can be divided into two main groups. Groundwater is characterised by depleted dD and d18O, suggesting no significant evaporation effect. Surface water on the other hand is more enriched in dD and d18O due to evaporation. The relatively high concentration of Cl- compared to rainfall and depleted dD and d18O values of groundwater indicate that recharge of the aquifers is occurring during intense rainfall events when rapid infiltration occurs. Evapotranspiration then acts to concentrate ionic species prior to recharge. Relationships between the major ion concentration and catchment area, surficial Tertiary cover and distance between recharge and discharge were identified. The results show that these catchment variables combine to determine unique water chemistry for each sub catchment in Karijini National Park. The TDS concentration of the groundwater in the Marra Mamba Iron Formation that hosts the Marandoo ore body is higher than most of the water bodies surrounding the mining area suggesting significant modification or different recharge mechanisms to that of the Karijini groundwater.

Jan 1, 2009

By A. Frits van Tol, Rodriaan Spruit, Jan H. van Dalen

"Abstract In recent years, there have been major problems with deep excavations in urban areas supported by diaphragm walls. In some cases, like the fatal Nicoll Highway collapse in Singapore the quality of the D-walls was not the cause. However in other projects, like the problems with the major leak in the walls of the Boston Big Dig and with leakage in a few projects in Belgium and The Netherlands was related to poor D-wall quality. Leakage through the D-walls at the joints in deep excavations led in these cases to very serious settlement behind the walls, in the case of the North- South line in Amsterdam, there was severe damage to historical buildings. This paper describes ongoing research that focusses i on acquiring more knowledge on and improvement of D-wall installation, in particular the flow process prior and during casting ii on the detection of anomalies prior to excavation and iii on the composition of the concrete mixture in view of a better and more sustainable concrete quality of D-walls.INTRODUCTIONIn the case of deep excavations in urban areas close to neighbouring buildings, diaphragm walls are one of the best feasible solutions for the retaining structure. Although the costs of D-walls generally exceed the costs of alternative wall solutions, the advantages are decisive in many situations. The main advantages of D-walls are the limited impact of the installation on the built environment, the high stiffness and bearing capacity and the retention of water, even at considerable depths. This makes Dwalls often the preferred solution for deep excavations Sometimes the D-walls are the temporary support while for the final stage a complete concrete box is constructed in the excavation. In many other cases the D-wall has the permanent function of retaining soil as well as groundwater.In the last ten years, there have been major problems with deep excavations in urban areas supported by diaphragm walls. In some cases, like the fatal Nicoll Highway collapse, 2004 , the quality of the Dwalls was not the cause. In other important failures like the collapse of the Archives in Cologne, 2008 and Dubai Infinity Tower Flooding, 2007 a combination of design and quality issues played a role. However, the major leak in the walls of the Boston Big Dig was related to poor D-wall quality (McNichol, 2000). Van Tol et al, (2010) describe a number of case studies in Belgium and the Netherlands, with leakage through the D-walls at stop end joints. In several cases with deep excavations these leakage caused serious surface settlements behind the walls. In the case of the North-South line in Amsterdam, there was severe damage to historical buildings. All these cases have generated considerable additional costs and delays, and subsequently public and political concern. Van Tol et al. (2010) present several possibilities to improve the quality of D-walls.Other disputes related to D-walls deal with the quality of the concrete and the sustainability of D-walls applied as a permanent wall. In particular the porosity of the concrete cover is sometimes problematic."

Jan 1, 2014

By Fookes R. A, Bunch K, Gravitis V. L, Watt J. S

The combustible volatile matter in coal mine roadway dusts (CVM) has been determined using x-ray backscatter techniques. The correlation between x-ray and chemical techniques is reasonably good for the 92 samples from collieries on the Bulli seam, and the maximum error expected at the maximum level of 11· 5 weight per cent CVM permitted in the N.S.W. Coal Mines Regulation Act, 1912, as amended, is about ± 2·5 weight per cent. This x-ray technique can be used only when the combustible volatile content of the coal matter (cvm) varies within a limited range, and a separate calibration is required for each coal seam.Portable equipment based on a radioisotope x-ray source ahd digital ratemeter makes possible simple and rapid analysis, and with adaptation to use in coal mines should lead to much more comprehensive testing- ofroadways and hence improved overall prevention of coal dust explosions.

Jan 1, 1977

By Tom Szynakiewicz

Micropiles are routinely used in the United States for foundation support and underpinning applications. The high capacities achievable with the use of micropiles, combined with specialty rigs for easy installation in low headroom and difficult access areas makes them a good choice for situations often encountered on existing commercial projects. The bond zone of the pile is typically drilled into a competent stratum such as sands, gravels or bedrock. In this paper, the authors will discuss a project where the lack of a shallow ?competent stratum? led the geotechnical contractor to create their own bond zone for the micropiles using jet grouting. Due to problematic clay (CH) soils, the original foundation of a six story office building in west Houston had experienced up to five inches of differential movement in-between the shallow under-reamed shafts. The owner desired a permanent solution to the problem without disturbing the majority of the tenants. The structure was underpinned with a hybrid system of jet grouted micropiles as well as jet grouting alone and the structure was re-leveled using hydraulic equipment to within a 0.25? tolerance. Design, construction and sequencing of the project are discussed in the paper. QA/QC methods are also discussed, including coring for verification of jet grout column diameter as well as a full-scale micropile compressive load test. The structure was successfully re-leveled and the entire project was completed without disturbing any tenants on the floors two through six.

Jan 1, 2008

By Jerry Gagnon, Matt Burr, Dave Evans, Timothy Ellis, Davies Kakengela, Abbas Mirza, Larry Webb, François Leclercq, Andrew Johnston

Lead-based alloys are the primary anodes used in electrowinning from sulphate-based aqueous systems. Lead anode technology has evolved over the years, migrating from pure lead and lead-antimonial alloys to the present day lead-calcium-tin alloys for copper electrowinning and lead-silver alloys for zinc electrowinning. It has also migrated from cast to rolled microstructures in search of improved mechanical properties and higher corrosion resistance. Although great strides have been made in the development of new alloys and production processes, the industry still has unresolved issues related to untimely corrosion which limits anode life and may lead to higher contaminant levels in the metal being produced. Lead anodes corrode because of the difference in the chemical/electrochemical potential across the microstructural features of an anode. Given a very high purity material, we find that the grain boundary areas corrode significantly faster than the rest of the grain. The desire to minimize grain boundary corrosion by a balance of alloying element selection and microstructural design allows the grain boundary area to be engineered. However, operational issues can lead to unexpected corrosion behaviours which we will discuss moving forward. The comments in this work, though directed toward copper electrowinning, can be extended to similar phenomena in other metals electrowon from sulphate media (i.e., zinc, nickel, cobalt, manganese). The lifecycle of electrowinning anodes is dependent upon electrowinning tankhouse operating conditions and maintenance of the anodes, including cleaning and straightening. This paper will focus on the operational aspects of maximizing the utilization of lead electrowinning anodes.

Jan 1, 2015

By G. G. Goble

Significant progress has been made in the past decade in determining the load bearing capacity of pile foundations. Developments in the means of prediction of pile capacity as limited by soil strength have been substantial, particularly in the use of dynamic methods. The use of currently available equipment, analytical procedures, and practices in the field, will often produce material economies on a job by allowing increased loads with proven factors of safety. This approach justifies the minimum number of piles required for a safe foundation in a wide range of job sizes and soil conditions. To avoid exposing the reader to excessive detail in the body of this paper, technical topics have been covered more thoroughly in several appendices. I. Wave Equation Analysis of Piles Appendix A II. Dynamic Monitoring and the Pile Driving Analyzer Appendix B III. Case Method Capacity Calculation Appendix C IV. Case Pile Wave Analysis Program Appendix D 1 Preliminary Analysis In designing driven pile foundations, there must be a close relationship between design, construction control procedures, driving practices, and the size of the job. Small commercial buildings or residences involving loads that are only a fraction of the pile capacities do not justify the expense of detailed design processes or elaborate construction controls. Nevertheless, some preliminary analysis of the job requirements and a limited subsurface investigation must be made to understand existing conditions and the possible foundation solutions. In other words, it is necessary to determine that driven piling is the best overall choice of foundation.

Jan 1, 1988

By Ning Shi

This paper suggests an alternative design approach for an innovative shovel dipper, for use in ground conditions where cutting of virgin ground rather than scooping of blasted material is required. Not only does the new design have an optimized dimension ratio (width:height:depth) and attachment arrangement (angle, position), but also a non-linear pro¯le in 2D and 3D. The approach is based on the simulation of a shovel's duty cycle to verify a pilot dipper model. In order to achieve a realistic simulation that could be used to evaluate a dipper design, the model is e®ectively a descriptor of actual shovel activity under soft ground conditions. The shovel geometry, motion and operation, with an emphasis on digging and dumping kinematics and dynamics are the principal elements of the simulation. The simulation considers a fresh face location, repeating tucking, digging and dumping swing motions within the geometric range of the machine, ending when no more face material remaining within reach without re- positioning. The simulation yields digging force, friction force, trajectory, ¯ll time, ¯ll factor, etc, which may be integrated into two basic considerations: power draw (output) and volume delivered (production), as indicators of dipper performance. The simulation has been used as a tool to modify an existing dipper design, prior to looping further simulation cycles. Ultimately, an optimized or totally-new-concept shape is realized. A prototype dipper as a fractional scale model will be built to verity the performance under actual mining conditions.

May 1, 2004

By Michael L. Boucher

Copper and nickel sulfides occurring in the Duluth Complex of northern Minnesota were examined at the Bureau of Mines, A microscopic study was undertaken to determine the mineralogy and paragenesis of the ore minerals. Eighty-two samples were taken from one deep diamond drill core located near Babbitt, Minn. Modal analyses are presented for the Duluth Complex rocks and for the are minerals in the major mineralized zone. The major sulfide minerals are chalcopyrite, cubanite, pyrrhotite, troilite, and pentlandite. Results of this investigation suggest that the mineralization is related to the structural features of the enclosing rocks: pores, open fractures, and cavities. The pyrrhotite-troilite-pentlandite assemblage is believed to have formed from an immiscible sulfide melt, probably associated with the troctolitic rocks. Most of it settled to the very porous base of the Duluth Complex, and to the other porous zones near xenoliths; small portions were trapped higher in the section. A later introduction of a copper-rich sulfide melt replaced some of the pyrrhotite-troilite and oxides, and filled in the remaining open spaces and fractures in the Duluth Complex and those of the adjacent footwall rock.

Jan 1, 1975

By M. J. Beus

This paper will describe the research approach being initiated by the Spokane Research Center to assess hazards and design criteria to prevent ground and muck falls in and around ore passes in hard-rock mines. The major goal of this research is to compile detailed information about ore pass processes and hazards, identification and testing of prevention strategies, and development of computer-based measurement and design methods. Recent ore pass failures have underlined the lack of OE pass design capabilities and standards available to both mine engineers and MSHA personnel. Design criteria and ore pass hang-up prevention and remediation strategies will include the effects of internal ore pass loads, blasting to relieve hang-ups, and rock mass stress redistribution and structural interaction from nearby mining. New visualization and three- dimensional analysis methods will be presented as an extension of existing ore pass design and analysis techniques. A sophisticated particle-flow analysis program will be used to simulate the response of various ore pass designs to a wide range of loading conditions driven by rock mass deformation, muck flow, ore pass blockage, and blasting in both nearby stopes and the ore pass. Analysis techniques will be calibrated and design criteria validated at the Spokane ore pass test facility. These tools will serve to reduce research costs by limiting the number of experimental field tests required.

Jan 1, 1996

By L. Li

The backfilling of underground stopes is a common practice throughout the mining industry. The stresses imposed by the backfill on the surrounding rock mass need to be assessed because of their influence on ground stability and on the hydro-geochemical response of the fill material. There is, however, a complex interaction between the relatively soft backfill and the much stiffer adjacent rock mass. In recent years, the authors have presented results from investigations conducted on stress distributions (obtained numerically and analytically) in and around backfilled stopes with (sub)vertical walls. In this paper, the influence of stope inclination and of backfill properties is evaluated. Results indicate that, in general, the vertical and horizontal stresses in inclined stopes are close to, but somewhat smaller than the stresses in vertical stopes. Nonetheless, significant differences can be observed in some cases, especially for the vertical stress along the inclined central line and along the hanging wall. It is further shown that neglecting deformability in limit equilibrium analyses is an acceptable assumption. However, Poisson?s ratio and the dilatancy angle, usually neglected in limit equilibrium analyses, may have significant effect on the stress distribution. Results also confirm that the backfill strength parameters (cohesion and friction angle) are critical factors required to properly evaluate the stress distribution, at least within a certain range of parameter values.

May 1, 2007

By Darrell L. Beddard

The Loma Prieta earthquake occurred on October 17, 1989 at 5:04 PM, Pacific Daylight Time. It measured 7.1 in magnitude and was felt from Los Angeles north to the Oregon state line and east to western Nevada. The epicenter of the earthquake was located along the San Andreas Fault, in the Southern Santa Cruz Mountains just north of the City of Watsonville, California. It was the largest earthquake to occur in the San Francisco Bay area since the 1906 earthquake. A total of 87 aftershocks of Magnitude 3.0 or larger were recorded within 21 days after the seismic event. As a result of this earthquake thirteen State-owned and five locally-owned bridges were closed to traffic. Three of the most publicized State-owned structures closed to traffic were Struve Slough Bridge, San Francisco-Oakland Bay Bridge and Cypress Street Viaduct. Struve Slough Bridge was twin slab bridges that collapsed and were rebuilt and open to traffic three months after the earthquake. San Francisco-Oakland Bay Bridge experienced collapse of upper and lower spans at Pier 9 and was reopened to traffic one month after the earthquake. The Cypress Street Viaduct experienced collapse of 48 bents that resulted in the upper roadway falling onto the lower roadway.

Jan 1, 1995

By Luis Alberto Medina

La característica principal de la composición de un cuerpo mineralizado es la heterogeneidad, dado que sus elementos no son iguales. En ese sentido, la prueba de heterogeneidad en el mineral de Cerro Verde, es una guía para la geología, mina, metalurgia y laboratorio químico, que busca optimizar los protocolos de muestreo y minimizar errores en las muestras tales como: Error Fundamental; Error de Segregación, generado por una muestra o submuestra cuando es cuarteada; Error de Extracción, generado por una muestra pequeña o insignificante colectada o tomada, y Error de Preparación, producido por la pérdida excesiva de finos. De acuerdo al estudio, el presente trabajo señala que la heterogeneidad de cobre total, cobre soluble en ácido y cobre soluble en cianuro, desarrollada para el mineral de Cerro Verde, es baja, lo que permite un manejo operacional sencillo para el muestreo con protocolos más simples, mientras que el parámetro más heterogéneo es el cobre soluble en cianuro y el protocolo podría ser afectado en el error fundamental.

Sep 13, 2001

The point of the anode effect on carbon anodes of dcfincd surface area. during electrolytic decomposition of alumina dissolved in molten fluorides. has been determined from current-voltage curves. The reproducibility and accuracy was found to be better for cell voltage than anode current density. Results have been obtained for the effect of alumina concentration temperature and carbon type. The point of the anode effect was strongly dependent on both the alumina concentration and the carbon type. For high alumina concentrations it has been found that the anode effect approaches reversibility. From these results it is concluded that co-evolution of CO, and CF. occurs prior to the onset of the anode effect. The anode effect results when the CF, content becomes sufficiently high for the melt not to wet the electrode surface and is maintained because of the slow desorption of CF, and the high electrode potential that results.

Jan 1, 1967