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By Philip A. Bucci

The Florida phosphate industry successfully uses froth flotation to concentrate phosphate in: the particle size range of approximately 28 to 150 mesh. However, as recently as 1965, coarse particles in the range of 14 to 28 mesh generally had not been beneficiated by conventional flotation methods at recoveries high enough to be considered adequate. It has been customary to upgrade this coarse material; by "agglomerate flotation" or "skin flotation" using belts, tables or spirals. While these devices have proved commercially effective, their capacities are much lower than those of froth flotation cells. To determine whether coarse phosphate material could be recovered successfully by froth flotation, Armour Agricultural Chemical Company began a series of pilot and plant tests; in April 1965. Objective of the tests was to compare over-all performance of a froth flotation cell design relatively new to the phosphate industry with results from the belt circuit at the Bartow, Fla., plant.

Jan 1, 1966

By Sergio Cattalanl, Francis Chartrand

"The geology and origins of volcanogenic massive sulfide (VMS) deposits in the Abitibi belt of northwestern Quebec have been the subject of discussion since the discovery of the Horne orebodies in Noranda in 1923.The present Noranda version of the VMS model characterizes the ideal deposit as a stratabound, base-metal accumulation that is in close spatial relationship with hydrothermal alteration and stockwork zones, felsic lava domes, coarse phreatic-pyroclastic breccias, and subvolcanic intrusions that characterize vent- and proximal{acies submarine volcanic environments. Deposits tend to occur in a favorable stratigraphic interval within a mining camp, and this is well-documented in the Rouyn-Noranda and Matagami camps.However, in recent years many VMS deposits have been shown to deviate from the ideal Noranda-type. For example, the Ansi/ deposit is characterized by sulphide-bearing alteration zones that extend far above the massive sulfide lenses, and by abundant magnetite immediately underlying massive sulfide. The Horne deposit appears to lack the typical chloritic alteration pipe underlying the massive sulfide lenses, as well as laterally-equivalent exhalite horizons. The Horne and Quemont deposits, besides being the two giants of the camp, are particularly rich in gold, whereas others, such as WaiteAmulet and Millenbach, have low gold values. Finally, some deposits in the Noranda camp, such as the Ansil, Corbet and Mobrun mines, are outside the favorable stratigraphic interval. Therefore, it would appear that part of the key to renewing base metal reserves in northwestern Quebec is the use of evolving descriptive-genetic models that incorporate geological variations like those cited above."

Jan 1, 1990

By R. L. Rough, W. K. Overbey

The Bureau of Mines obtained samples of oil - reservoir rock from wells in Ohio , Pennsylvania , and West Virginia as part of an investigation of the susceptibility of petroleum reservoirs to secondary - recovery techniques . Illustrations and tables showing the geographic and stratigraphic sequence of the cored reservoirs and 40 tables of detailed lithologic descriptions of the reservoirs are presented . Information relevant to geologic surroundings , oilfield history , coring and well logging operations , and reservoir core analyses are referenced throughout the report .

Jun 1, 1970

By Flanelson Maciel Monteiro

Os materiais cerâmicos são essenciais para o desenvolvimento da humanidade. O homem os utiliza para os mais variados fins, desde a confecção de utensílios domésticos até a produção de peças de alto desempenho tecnológico. Neste sentido, são extremamente necessárias à produção de pesquisas científicas para prospectar novos materiais para a indústria cerâmica. As argilas são consideradas o principal componente para fabricação de massas cerâmicas. Para produção de peças de cerâmica branca, revestimentos e outras categorias cerâmicas onde a coloração clara é prioridade, usam-se argilas cauliníticas. Todavia, esse tipo de argila possui pouca ocorrência na esfera terrestre, em comparação com outros tipos, tais como as argilas de coloração vermelha. Por tal motivo, encontrar novas jazidas de argila caulinítica para abastecer à indústria ceramista é extremamente imprescindível. Nesse sentido, objetiva-se com esse trabalho caracterizar uma argila caulinítica proveniente de uma jazida localizada no município de São Gonçalo do Amarante, região metropolitana de Natal-RN. O referido trabalho configura-se como a primeira parte de uma caracterização do material estudado. Sendo reservado para esse artigo os ensaios físicoquímicos e na segunda parte os ensaios tecnológicos. A caracterização fisioquímica foi realizada através das seguintes análises: DRX, FRX, Análise Granulométrica (AG), Dilatometria e ATG/DTG. Os resultados obtidos demostram a viabilidade técnica da utilização do material para fabricação de produtos cerâmicos, tais como: telhas, lajotas, revestimentos e outros materiais cerâmicos.

Oct 30, 2017

"Located on the Big Hole River, three miles from Divide, Montana, and 21.75 miles from Butte.Built in 1899.DAM: Rock-filled wooden crib, 512 ft. long and 57.5 feet high.SPILLWAY: Equipped with flash-boards 189 ft. long, 8 ft. 10 inches high.PENSTOCKS: Two 8 ft. diameter of steel, each branching and supplying two wheels.WHEELS: Four double horizontal, double discharge turbines, made by The James Leffel & Co., 1,000 h-p., 180 r. p. m., direct connected to generators, operating at 60 ft. head. GENERATORS: Four G. E., revolving field, 750 k-w., 180 r. p. m., 800 volt, 3 phase, 60 cycle alternators.EXCITERS: Two water-wheel driven exciters.TRANSFORMERS: 12 250-k-w. G. E. air blast, primary 15,000 volts, Secondary 800 volts.OPERATION: The plant operates essentially as a peak load plant. Except in flood period, there is insufficient water to operate at full load continually. In December its average output is about 500 k-w."

Jan 1, 1913

By C. M. Harrer

This paper describes the location, features, qualities, extent, and potential of iron occurrences and some associative resources -limestone and dolomite, coal, petroleum and natural gas, power, and water - in New Mexico. Reconnaissance investigations were made of 118 iron occurrences to deter-mine their extent, attitude, and potential; character samples were analyzed to determine their quality and impurities; and pioneer metallurgical investigations were made on character samples to present their metallurgical problems. Some factors influencing past and potential iron markets are discussed. The most abundant iron minerals are magnetite and hematite. The higher grade deposits are extensive contact-metamorphic and pyrometasomatic replacements in calcareous Paleozoic rocks associated with intrusives. Low-grade deposits of considerable potential are the extensive Cambrian oolitic hematites of sedimentary origin and the Precambrian magnetite-hematite taconite iron formation. Iron occurs also as extensive colluvial and alluvial concentrations. A wide variety of accessory elements are indicated and these pose metallurgical and economic problems.

Jan 1, 1963

By Cleiton Rodrigues de Vasconcelos, Elizeth Oliveira Alves, Kleber Gonçalves Bezerra Alves

Em virtude da periculosidade do Pó de aciaria (PAE), práticas alternativas, como a reinserção do resíduo no processo produtivo, ou sua incorporação em outros materiais fizeram com que a reciclagem tenha se tornado uma via para este subproduto. O presente trabalho tem como objetivo identificar as áreas de desenvolvimento tecnológico de utilização do PAE, avaliar a potencialidade de reaproveitamento e reciclagem do resíduo oriundo do processo de produção do aço carbono, comparando as características obtidas do PAE analisado com os requisitos indicados através da análise de patentes. O PAE produzido no estado de Pernambuco foi caracterizado pelas técnicas de Fluorescência de raios X (FRX), separação granulométrica via peneiramento, distribuição do tamanho de partículas, Difração de raios X (DRX), Microscopia eletrônica de varredura (MEV) e Espectroscopia por energia dispersiva (EDS). A prospecção tecnológica foi realizada nas bases de patentes europeia EPO e na base nacional de patentes nacional do INPI. As análises realizadas mostraram que o material apresentou aproximadamente 28,5% de suas partículas com granulometria inferior a 53μm, composto em sua maioria por ferro e zinco presentes na forma de óxidos, organizados nas fases franklinita, zincita e magnetita. A baixa granulometria e composição química possibilitam a sua aplicação no campo dos materiais cerâmicos, bem como sua reinserção no processo de fabricação. O resíduo estudado apresentou características similares com os demais resíduos observados nas patentes.

Mar 1, 2019

By F. S. Crawford

Safety devices and guards are often looked upon as the last word in safety by the men around the shop or large industrial plant . However , thorough knowledge of the details of their jobs and of the dangers attending them are even more important . It should be unnecessary for all men to go through the experience of the first man to meet an unknown danger , but that appears to be about the only way by which many learn . Practically every danger connected with the job around a mine , blast furnace , steel mill , foundry , coke oven , cement mill , or other operation , was encountered for the first time by someone , and if he was fairly fortunate he either got hurt or just missed being injured and lived to tell his " budaies " how it happened; he spread the knowledge of that particular danger . Sometimes , but not often , a man can foresee a danger . If he could always be on guard and remember everything he had ever learned and also know everything that had happened to the other fellow , and then let that knowledge keep him aware of the dangers in his own immediate " job , " so that he would work the safe way for both himself and the other fellow , he would have what safety engineers call " safety consciousness . " Being safety conscious is a fine attribute , as it really means knowing all about one's job . A man who is really safety conscious is one of the best and most efficient workmen in the whole plant . The boss wants men of that kindmen who want to learn and who try to learn every little detail about their jobwhere there is danger of spoiling the heat or getting burned by hot metal in a steel plant or of loading rock instead of coal or ore in a mine . Such men know how to do whatever job they are on easily and with the least amount of hard work and at the same time get it done as quickly as possible with safety . A man who is safety conscious has to nearly all intents and purposes developed eyes in the back of his head , if he is in a big mill where there if something going on all around him . These eyes are not real eyes , but they are what might be termed a sixth sense which he has developed by his experience in the mill as well as in other dangerous work which he may have done before in other plants . There may be occasions when a man's safety consciousness will leave him for just a short time ; this is likely to happen when he is thinking about a quarrel he had with his wife which has not been cleared up happily , or perhaps when he has bought too many things on installment and with sickness at home

Apr 1, 1931

By F. Dinter, C. McGregor, Q. G. Reynolds, L. Hockaday

The necessity of reducing greenhouse gas emissions to limit the impact of anthropogenic climate change means that all industrial processes should investigate their options towards decarbonization. Iron, steelmaking, aluminium, and cement production produce the most industrial emissions. Although most research focuses on decarbonizing these industries, minerals processing industries must be decarbonized to achieve net zero emissions goals by 2050. Incorporating renewable energy sources and avoiding the combustion of fossil fuels are two ways to reduce greenhouse gas emissions. This paper reports on the results from a dynamic process model developed to investigate the feasibility of concentrating solar thermal pretreatment of manganese ores to pretreat carbonate-rich manganese ores for increased ferromanganese smelter productivity and reduced greenhouse gas emissions. The results indicate that pretreated ores reduce the energy requirement for smelting significantly for some ores and lowers total carbon dioxide emissions by 13 to 19% compared to the traditional smelting route. A high-level economic evaluation shows that solar thermal treatment is financially viable for low cryptomelane, high braunite ore that is common in the Kalahari Manganese Field.

Dec 11, 2024

By Henry C. Meeves

The Bureau of Mines investigated the silver production potential of the Leadville (California) mining district, Lake County, Colo., in 1966-67. The mining history of the district, the ground conditions encountered in mining, and the mine-support methods used are reviewed. The drainage problem is discussed in detail. An initial objective was to establish the existence of potential silver resources minable by low-cost open-pit methods, particularly in the silver-bearing manganese halos surrounding the major deposits. The report concludes that under present conditions, development of the deposits in the area is not economically feasible; however, a pioneer rotary noncore drilling program demonstrated that this type of exploration is technically feasible. Potential reserves of silver and associated metals are estimated. Possible mining methods for recovery of the reserves are discussed. Future production possibilities from the various subareas of the district are analysed, considering optimum operating size. Consolidation of small individual holdings for unit operation is recommended. Type of operation, amount of rehabilitation, size and type of concentrating plants required, drainage and other mining problems, and metal price trends are discussed as they bear on economic feasibility of development.

Jan 1, 1970

By Marcos Meyer Machado

A determinação de características microestruturais como base de controle de qualidade tem demonstrado cada vez mais a sua importância nos processos de aglomeração de minério de ferro. A linha de pesquisa do presente trabalho envolveu o desenvolvimento de técnicas de embutimento de pelotas seccionadas em resina condutora, de desbaste e polimento da superfície das amostras e emprego do microscópio eletrônico de varredura em conjunto com a técnica de Electron Backscattering Difraction. Por meio das técnicas empregadas de microscopia baseadas em parâmetros cristalográficos específicos, foram obtidas ilustrações forescatter e mapas de fases minerais ferríticas, silicatos e óxido de ferro que caracterizam a microestrutura de pelotas tratadas termicamente em forno piloto. O desenvolvimento desta metodologia promove subsídios para estabelecer futuramente uma relação das estruturas observadas em escala microscópica com as propriedades reconhecidas e mapeadas no produto final.

Aug 17, 2017

By A. G. Loomis

METHODS for measuring relative permeability as a valid function of saturation were compared by the. Bureau of Mines, using core samples from representative oil-productive California formations, from the Bartlesville sand in Oklahoma, and from synthetic samples. Measurements for gas-oil systems were made by steady-state dynamic, unsteady-state displacement and two stationary-phase methods. Measurements for water-oil systems were made by the unsteady-state displacement method. As the ratio rather than individual relative permeabilities is measured by the last method, three methods for calculating individual relative permeabilites from their measured ratio were compared for gas-oil systems and two methods for water-oil systems. Errors arising from capillary discontinuities, such as the end effect and stabilized-zone flow, are discussed and evaluated; possible errors rocs arising from turbulant flow are also examined. The inapplicability of non-steady-state methods for water-oil systems that are not definitely oil-wet is discussed in detail. Measurements of relative permeability to both gas and oil can be made quickly and accurately by the steady-state dynamic method when rates of flow of the two phases are sufficient to minimize the capillary discontinuity at the outflow end of the sample. At such rates relative permeability-saturation measurements are essentially independent of the rate of flow. The steady-state method wits modified by a dispersion section at the inflow end of the sample acid designated tie dispersed-feed method.

Jan 1, 1962

By A. Ghadyani

This investigation was undertaken to assess the possibility of ash and sulfur removal by microbial action of high sulfur-content coal. Thiobacillus ferrooxidans and Thiobacillus thiooxidans have been used for biodesulfurization of coal. Feed samples were provided from Tabas coal mine located in Yazd province, Iran. The sample contained 28.80% ash and 2.30% sulfur. Flotation tests were implemented to optimize the effective parameters in these cells which were constant during bio-flotation tests. According to the results, obtained from various tests using Taguchi orthogonal array design (L27), the values of optimized parameters were pH at 7, 1000 g/t gas oil as a collector, 10% solid content, 15 min conditioning time, 100 g/t MIBC as a frother and 800 rev/min rotor speed. Bio-flotation tests are carried out by means of laboratory double discharge cell and mesophilic bacteria as depressant reagent using above mentioned optimized parameters. The bio-flotation experiments were conducted based on a Taguchi orthogonal array design (L9) with four variables (bacteria type, bacteria count, rotor speed of mixer and bio-conditioning time). The collected data was analyzed by using DX7.0, Minitab14.0 and WinRobust1.02 softwares for evaluation the effect of each parameter on the optimization criteria. Considering the highest combustible recovery and the lowest ash and sulfur content, the value of optimized bacteria type, bacteria count, rotor speed of mixer and bio-conditioning time were Thiobacillus ferrooxidans, 5×107 cells/g(coal), 100 rev/min and 20 min respectively. Under this condition, ash and sulfur content and combustible recovery were predicted 12.39%, 2.08% and 82.03% respectively.

Sep 1, 2012

By Lois G. Schwarz

I did a project (Sungai Piah) as a consultant to your firm in Malaysia, where we were faced with a similar situation as sketched out in your question. The following is what we did for the grouting of the primary holes, which were both located upstream of the plug as well as downstream: We used a hydrophobic MDI based semi-rigid polyurethane prepolymer in the first phase of the grouting operation when grouting under water flow conditions. Then in the second phase and also for the contact grouting we used a two component water compatible polyurethane elastomer. And then for deeper formation grouting, when all the water flow had been stemmed in the vicinity of the plug, we used a regular (balanced stable) cement based grout. So it may not exactly answer your question, but we first used hydrophobic grout because it is very efficient to grout a formation through which water flows. We didn't stop all the leaks day-lighting downstream of the plug or all water running through the formation near the plug, but the flow of water through the rock formation adjacent to the plug was reduced by 99.9%, after completing the urethane grouting. This facilitated the placement of cement based suspension grouts without wash-out.

Feb 10, 2003

By R Dunne, J Dodd, J Snyder, F Roberto

Energy costs are steadily increasing worldwide while the availability and quality of water are becoming contentious issues between the users (municipalities/households, agriculture, manufacturing and mining). Refractory gold ore treatment - pressure oxidation, biological oxidation and roasting (ultra-fine grinding, or UFG, will not be discussed here as this process only reduces the particle size of the feed prior to cyanidation) - requires substantially more energy and water quantity and quality are vastly different compared to the standard and simple flow sheets used for treating non-refractory ores This paper will provide an overview of the energy and water requirements for treating refractory gold ores, a topic which does not appear to have been considered previously in the literature.CITATION:Roberto, F, Snyder, J, Dodd, J and Dunne, R, 2013. Energy and water requirements in the treatment of refractory gold ores, in Proceedings World Gold 2013 , pp 527-532 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By T. C. Cheng, G. P. Demopoulos

It is the object of this paper to discuss various options for improving the hematite process in terms of increased throughput hence lower capital cost and production of saleable quality hematite. With reference to increasing the throughput of the process, it has now been determined via the analysis of Akita Zinc Co's continuous industrial autoclave performance data that the process kinetics is limited by the rate of the hydrolytic precipitation reaction. By correlating the hydrolytic precipitation rate to supersaturation ratio, it is shown that accelerated kinetics can be achieved via the following measures: (1) in-situ neutralization with addition of zinc calcine; (2) elevation of temperature; and (3) dilution of feed; of which, the first one was retained for further evaluation. According to presented estimates, addition of calcine, amounting to only 2.6% of the total zinc calcine processed, can allow for shortening the retention time by at least 50%. Such drastic shortening of retention time may be either used to increase the throughput of a given autoclave circuit or alternatively to release autoclave capacity for clean hematite production. Hydrothermal treatment of the crude hematite product proved effective in producing clean hematite as according to laboratory tests, hence allowing the sulphur content of hematite to be reduced from around 4% to less than 1%. A conceptual flowsheet incorporating in-situ neutralization for accelerated kinetics with hydrothermal upgrading of crude hematite without sacrificing production capacity and with minimum upset of the plant's water balance is described.

Jan 1, 2004

By Richard Quirk

This report describes methods and techniques employed by The Glidden Co. of Cleveland, Ohio, in explorating an ilmenite-bearing sand deposit in Ocean County, New Jersey, during 1960 to determine ore reserve potential and the feasibility of mining and establishing a milling plant on the property for the production of ilmenite concentrate. The property covered approximately 1,250 acres. Comprehensive sampling by water-jet drilling indicated the deposit averaged 20 feet in thickness and contained 4.5 percent heavy minerals, of which 80 to 85 percent was ilmenite and leucoxene. Average depth of the water table as determined by auger boring was 16.8 feet. Pilot plant tests indicated that circular concentrators in combination with spiral concentrators would recover at least 80 percent of the heavy mineral content of the sands. It was estimated that sufficient ore reserve tonnage had been developed to supply the company's Baltimore chemicals division, pigments department, with a suitable grade ilmenite concentrate for a period of 20 years at the present rate of pigments production. The property was designated as Lakehurst mine and plans are in progress for mining development and plant construction.

Jan 1, 1963

By A. Romero, M. Carvalho, D. L. Millar

"The number of underground mines replacing diesel by battery powered mobile equipment is growing worldwide. The latter produces locally zero emissions and less heat, improving air quality in the working areas, and can potentially reduce energy costs due to lower ventilation requirements and in the face of higher fuel prices. However, there is a lack of systematic approaches to evaluate the potential economic benefit of switching from diesel mobile technologies to electric ones. This paper presents a method to answer the question of whether a mine with known operating conditions should invest in battery-powered electric equipment to reduce its total costs. Furthermore, this method provides the optimal number of electric and diesel equipment in relationship with their impact on the ventilation system and the total costs of running the mine from the energy perspective. A case study of an underground mine in Northern Ontario (Canada) is presented to validate the method proposed. The scenarios studied include the specific climatic conditions of the region, and the possibility to use heat recovery for the ventilation system. Overall, results show that the use of electric mobile plants is cost competitive, especially so when electricity cost can be lowered through load-shedding strategies.INTRODUCTIONOf the multiple advantages of using electrical vehicles (EV) underground in mining, the potential increase in air quality and comfort is the most significant (Paraszczak, Svedlund, Fytas, and Laflamme, 2014). Until recently, fully battery-powered electrical underground heavy duty machinery (i.e., loaders or trucks) were not available, so that tethered and trolley assisted vehicles were the only electric alternatives to diesel powered vehicles (Bétournay et al., 2011). Today, several commercial battery-based alternatives are available (General Electric Fairchild, 2015; RDH Mining Equipment, 2015; Paraszczak et al., 2014). Operational details can be found in Ewing (2015). The main battery technology used (Lithium Iron Phosphate, LiFePO4, or LFP) was already anticipated in Bétournay et al. (2011) as a good candidate for these types of vehicles. More details on these batteries, along with state of the art and future perspectives can be found in Zubi, Dufo-López, Carvalho, and Pasaoglu, (2018)."

Jan 1, 2019

By J. Wallace Gwynn

Salt from Great Salt Lake was probably used by the Native Americans prior to the Jim Bridger Expedition to the lake in 1824-25, and was used by the region's early explorers and trappers after that time. From the arrival of the Mormon pioneers in 1847, salt has been produced from Great Salt Lake, starting first with the collection of crude salt from along its shores, and later by boiling down the lake's brine to obtain crystalline salt. Since these early beginnings, salt production from the lake has become a substantial commercial enterprise. Since the early 1960s, research and development have led to the economic production of potassium sulfate, magnesium metal, chlorine gas, magnesium chloride products, and nutritional supplements. Many of the salt-production techniques and equipment that were developed prior to 1964 are still being used today. Sodium sulfate has been produced, but is no longer marketed. Morton Salt, Cargill Salt, and IMC Salt currently extract sodium chloride, which is precipitated during the early stages of evaporation when the brine concentration reaches saturation, or about 26 to 27 percent total dissolved solids. Magnesium Corporation of America produces magnesium metal and chlorine gas, and IMC Kalium Ogden Corporation produces potassium sulfate, as well as magnesium chloride brine and flake products. These salt, gaseous, and metallic products are processed from the sodium-chloride-saturated, high-magnesium-chloride brines, and from the potassium and magnesium salts that are precipitated from the lake brine after it has been further concentrated. One obstacle to salt production is the fluctuating level of Great Salt Lake. In 1983, the lake level began a dramatic rise from an elevation of 4,200 feet (1,280.16 m) to its historic high of 4.211.85 feet (1,283.77 m) in 1986-87 (uncorrected USGS provisional lake-level records). The State of Utah employed flood-control measures, including breaching the Southern Pacific Railroad causeway in 1984, and pumping lake water to a shallow basin west of the lake in 1987. During the high-water years, the lake's mineral-extraction industries faced many challenges including the need to raise dikes to prevent flooding of facilities, broken dikes which resulted in the inundation of solar ponds, and dealing with the lake's greatly reduced brine salinities which resulted in lower annual salt and concentrated-brine production. The years following the record-high lake levels have been a time of adaptation, innovation, and change for Great Salt Lake industries. After its solar ponds were flooded in 1986, AMAX, Inc. built a new solar-pond complex near Knolls, and used the concentrated brines from the West Pond, generated by the State's West Desert Pumping Project. Great Salt Lake Minerals built a 21-mile-long (33.8 km) open, underwater canal, called the Behrens Trench, to convey concentrated brines from a new, remote solar pond on the west side of the lake to the east side of the lake, to help increase its production of sulfate-of-potash. There were also numerous changes in corporate ownership and production-facility locations.

Jan 1, 2001

By Tetsuya Uda

Our recent achievements of rare earth separation technique[1,2] and new process idea for rare earth magnet recycling[3] are reviewed, (1) Binary chloride mixtures of rare earths were separated by a new selective reduction-vacuum distillation process. According to our experimental results, apparent separation factors were 8.1 for the Pr-Nd chloride mixture and 570 for the Nd-Sm chloride mixture. These values are much higher than conventional solvent extraction methods. (2) A study of recycling process of magnet sludge was carried out. The rare earths in the neodymium magnet sludge were extracted by chlorination with FeCI2, An activated carbon was used as a de-oxidation reagent Metallic iron in the sludge was not chlorinated because the iron monochloride is not stable, The extracted rare earth chlorides were easily separated from Fe-alloy and the excess of FeCh by vacuum distillation, 96 % of neodymium and 94 % of dysprosium in the sludge were extraeted into chloride phase, By the vacuum distillation, a mixture of neodymium and dysprosium trichlorides of 99.2 % purity was recovered, On the other hand, the rare earth chlorides can be converted to the corresponding oxides by a pyrohydrolysis reaction accompanied by a formation of HCl gas, The HCI gas can chlorinate metallic iron to FeCh, Therefore, a new recycling process for rare earth magnet waste can be realized as a chlorine circulation type process. During the process, only carbon and water are consumed and there are no toxic pollutants, Moreover, the obtained rare earth oxide can be directly used as raw material in the conventional oxide electrolysis process,

Jan 1, 2003