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By John Wulff, H. H. Uhlig

Since its first mention in the literature in the eighteenth century12 the phenomenon of passivity in metals has stimulated much speculation and attendant controversy as to its nature and cause. No one of the numerous theories so far proposed has been generally accepted. ‡ Faraday,' in 1836, associated the passivity of iron with a protective film over the surface of the metal, which materially prevents or slows down reaction with corrosive environments. His theory was that oxidizing acids like nitric acid form an unstable oxygen or oxide layer over the iron surface, which protects the underlying metal from further attack. This concept was simple yet plausible, and without alteration has frequently been assigned in present-day discussions as explanation of the passivity of many metals. With the advent in recent times of stainless steels, it is not surprising that this oxide film theory of passivity proposed by Faraday has been used to explain the phenomenal corrosion resistance of stainless steels and other passive alloys. The passive alloys, such as the chrome-iron alloys, are supposedly covered with a protective oxide film, which forms on exposure of the alloy to air, is extremely stable and self-healing, and accounts for the remarkable resistance of these alloys to corrosion. Within the past few years, several investigators, following the theory of film protection, have attempted to gauge the resistance of the supposed film on steels. Brennert8 and Donker and Dengg9 determined the potential at which a negative ion (e.g., C1-) moving in an electric field reacted with the metal anode, as detected by increased current flow or change in potential of the steel electrode in an electrolytic cell. The potential corresponding to reaction Brennert called the film break-through potential.

Jan 1, 1939

By W. P. Haynes

The Bureau of Mines has been studying a modified steam-iron process using coal-derived producer gas for making either hydrogen plus carbon monoxide or methane. To provide a guide for this experimental study, compositions of equilibrium product gases for the reaction of steam plus carbon dioxide with iron were calculated and are discussed in this report. The calculations, which are described in this report, are based on thermodynamic data in the literature and cover temperatures from 800° to 1,300° K., pressures from 1 to 30 atmospheres, and hydrogen-to-carbon atomic ratios in the gas of 4 to 12. The equilibrium gas compositions are discussed in regard to making hydro-gen, carbon monoxide, and methane in the oxidation step of the modified steam-iron process. From the viewpoint of thermodynamics alone, assuming the reactions reach equilibrium, the discussion considers the effects of temperature, pressure, and composition of feed gas upon the composition of the product gas, the degree of oxidation of the iron, and the possible deposition of carbon. The results indicated the following: (1) Nearly all the carbon can be converted to methane at low temperatures (800° to 900° K.) and high pressures (over 20 atmospheres); (2) to obtain high yields of synthesis gas, high temperatures are required. For example, at 30 atmospheres, a temperature over 1,200° K. is required to convert 60 percent of the steam plus carbon dioxide to hydrogen plus carbon monoxide. Lower temperatures may be used at lower pressures) (3) oxidation of the iron increases with increasing pressure and decreases with increasing temperature; and (4) process conditions favoring carbon deposition were found within the range of variables studied, but it is thermodynamically possible to operate the oxidation process with steam and carbon dioxide outside this range of carbon deposition.

Jan 1, 1961

Table 1.-Salient aluminum statistics (Thousand short tons and thousand dollars) [ ]

Jan 1, 1967

By Victor Bridi Telles

Este trabalho teve por objetivo estudar a redução por hidrogênio de sínteres produzidos com coque e carvão vegetal. Para isso, foram realizados 6 ensaios de sinterização substituindo o coque por carvão vegetal como combustível do processo. As substituições foram de 0%, 8%, 16%, 25%, 50% e 100%. As amostras com substituições de 0%, 50% e 100% foram reduzidas em termobalança, durante 6 horas, em temperatura de 1000°C, utilizando uma mistura de gases contendo Argônio – 10% Hidrogênio. Os resultados mostraram que, para as misturas produzidas, o sínter fabricado com carvão vegetal diminuiu os índices de produção da sinterização e de resistência do sínter. Contudo, o sínter produzido utilizando somente carvão vegetal como combustível, apresentou maior redutibilidade.

Oct 30, 2017

By T. E. Bernard

The CO2-absorbent canisters used in four approved rescue breathing apparatus were investigated. A breathing machine was used to simulate human expiration with gas flow rates of 26, 37, and 48 1/min of 3.5% CO2 in air. The exit gas CO2 concentration, the pressure drop across the canister, and the exit-gas temperature were monitored. The absorbent capacities of the packed-bed canister designs were found to be dependent on flow rate within the range studied, while the capacities of the other designs were less affected. The radial canister had the least resistance to breathing while the complex bed design proved to be the most effective in utilization of the chemical. The overall results indicated that LiOH (lithium hydroxide) has the highest capacity for CO2 absorption among the absorbents tested. It can be used in a simple packed-bed design while maintaining acceptable levels of resistance and exit-gas temperature. Examination of oxygen supply with respect to CO2-absorption capacity suggested that it is desirable to closely match CO2-absorption capacity with the avail-able O2 supply to minimize the size and weight of rescue breathing apparatus.

Jan 1, 1979

By Drain P, Dibdin T. R

THE completion of the Linda incline man and supply haft at the Mount Morgan Gold Mining Oompany's mine led to an investigation of the various safety gears in general use in mining shafts. One of these gears completely fulfilled the necessaryconditions. This paper endeavours to give a description of the man car and safety gears now operating in the before mentioned shaft, together with the main considerations leading to their design and sub equent adoption. Fig 1 diagramatically shows a longitudinal section of this shaft.

Jan 1, 1911

By Eric J. Foell

The Offshore Technology Conference (OTC) was founded in 1969 when a group of scientific and technical societies organized an annual conference and exhibition dedicated to technologies used in the offshore oil, gas and mining industries. Currently, OTC is sponsored by 12 industry organizations and societies. These include: American Association of Petroleum Geologists (AAPG); American Institute of Chemical Engineers (AIChE); American Institute of Mining, Metallurgical, and Petroleum Engineers (AIME); American Society of Civil Engineers (ASCE); ASME International Petroleum Technology Institute; Institute of Electrical and Electronics Engineers/Oceanic Society (IEEE-OES); Marine Technology Society (MTS); Society of Exploration Geophysicists (SEG); Society for Mining, Metallurgy, and Exploration (SME); Society of Naval Architects and Marine Engineers (SNAME); Society of Petroleum Engineers (SPE); and The Minerals, Metals, and Materials Society (TMS). OTC also has two endorsing organizations, the International Association of Drilling Contractors (IADC) and the Petroleum Equipment Suppliers Association (PESA), as well as 6 supporting organizations that include the American Petroleum Institute (API), the Independent Petroleum Association of America (IPAA), the Institute of Marine Engineering, Science, and Technology (IMEST), the International Association of Geophysical Contractors (IAGC), the National Ocean Industries Association (NOIA), and the United Kingdom Offshore Operators Association (UKOOA). From its earliest years, the OTC has been held during the first week of May in Houston, TX, initially at the Albert Thomas Convention Center where OTC?69 drew 4200 attendees and 200 exhibitors. As the conference grew and became established as the world?s foremost event for the development of offshore resources in the fields of drilling, exploration, production, and environmental protection, the venue was changed to the Astrodomain Complex, with technical paper sessions and most exhibits taking place in the Astro Hall. The numbers of attendees and exhibitors varied somewhat over the years, primarily in accordance with the fortunes of the international oil and gas industry. At its height in the early 1980s, OTC registered attendance exceeded 100,000 with more than 2500 exhibitors forcing expansion into the Astro Arena and even the Astrodome.

Jan 1, 2005

By AIME AIME

THE meeting" of the Rare Minerals and Metals Committee was held Monday afternoon, Feb. 17; Donald M. Lidclell, chairman, presiding. The first paper (T. P. 279), "Progress in the Use of Tantalum," by George W. Sears, was read by Mr. Smyth. Dr. Sears' paper contains an interesting summary of the uses, alloys and ores of tantalum and a resume of present method of reduction. The uses of tantalum is based on its extreme rise to the reaction of even the strong mineral acids, its great avidity for the common gases and its capacity for transforming alternating to direct current. Tantalum, as an alloy material, has received considerable study and many alloys have been reported. Among them three types appear to .be most prominent, alloys of high melting point, hard alloys and acid rising alloys. As the estimated quantity of tantalum in the earth's crust is less than that of gold, it must be looked upon as n rare metal. Australia is the greatest producer and the Black Hills of South Dakota produce minor amounts. As the one type of mineral available contains both tantalum and columbium, the extracting and metallurgy of tantalum are difficult chemical processes. Greater simplicity in this and the development of a market for columbium would undoubtedly be of great benefit to the tantalum industry, andl make for a greater use of tantalum produced.

Jan 1, 1930

By Garland Likins

High strain PDA testing has become common for verification of capacity of both driven and bored piles. It is equally applicable to Augered-Cast-in-Place (ACIP) Piles. It also evaluates other aspects of the installation such as integrity. The benefit of high strain dynamic test results for the relatively low cost of the tests compared to conventional static testing has resulted in widespread use. The method is described and specific procedures for testing ACIP piles are outlined. Example results demonstrate the application.

Jan 1, 2000

By Foluke Salgado de Assis

A fibra de juta é uma das fibras com grande potencial para ser aplicada como tecido reforçando compósitos poliméricos Este trabalho avaliou a resistência ao impacto para compósitos de matriz poliéster reforçado tecido de juta. Os corpos de prova foram fabricados com diferentes percentuais de tecido de juta: 0, 10, 20 e 30% em fração volumétrica. O tecido sido de juta foi embebedado com resina poliéster (estado líquido) e curado em temperatura ambiente durante 24 horas. As amostras foram ensaiadas utilizando o pêndulo impacto Izod and a superfície de fratura foi examinada utilizando o microscópio eletrônico de varredura. A resistência ao impacto Izod dos compósitos poliéster-juta cresceu de maneira linear com o aumento da quantidade de tecido de juta. Utilizando 30% de tecido de juta, foi possível obter 83,1 J/m enquanto o poliéster puro (0% de tecido) obteve 21,8 J/m. O bom desempenho do compósito poliéster-juta pode ser associado com a dificuldade de romper o compósito em virtude do tecido de juta, assim como, as trincas produzidas através da interface poliéster/tecido de juta que colaborou com o aumento na absorção de energia durante o ensaio de impacto Izod.

Oct 30, 2017

By D Woolmer

Since January 2019, BHP Olympic Dam have been trialling the use of a drone based LiDAR mapping system for the purpose for surveying stope voids. This new technology utilises Simultaneous Location and Mapping (SLAM) algorithm providing positioning, stability and collision avoidance in GPS denied environments. Implementation of this system utilised underground personnel trained in the equipment’s use. The study’s intention was to evaluate the effectiveness of this equipment versus traditional surveying methods in regards to quality, safety and productivity. The trial results showed a marked improvement in the quality, productivity and personnel safety when conducting surveys. The use of the drone and LiDAR system reduced personnel and equipment requirements for surveys, thus allowing these resources to be deployed elsewhere. The technology’s simple and rapid deployment allowed multiple surveys to be conducted during a 12 hour shift, including ad-hoc work with minimal disruption to underground operations. After the drone’s initial trial, further work was conducted to utilise the Hovermap LiDAR scanner on other platforms to increase utilisation. A mounting system was created allowing the LiDAR to be mounted on a remotely operated loader or vehicle. This enabled drawpoint scans to be taken directly after production completion, resulting in faster stope close outs and drive scans for convergence monitoring. Implementation of the LiDAR system has resulted in improvements in the stope production cycle by reducing delays previously associated with data capture. The increase in the volume and quality of data has also allowed in-depth back-analysis of stopes in new mining areas to be conducted, which have driven improvements in the design process.

Mar 15, 2021

The Bureau of Mines is the engineering arm of the Government for mineral resources. Its mission is to carry out laboratory and field studies that will assure the wise and effective development and use of our Nation's minerals, fuels, and underground domain in order to preserve the security and enhance the welfare of our people. Specifically, studies are directed to the means by which current and emerging demands may be met, the real cost of such achievements, and the assessment of related social and economic factors. Ways are sought to fulfill our material needs in a manner that minimizes occupational hazards to workers in the industry, reduces waste, and ensures that mineral raw materials are supplied and mineral-based products are used and are disposed of efficiently, without objectionable social and environmental costs. The headquarters of the Bureau of Mines is located in Washington, D.C. The Bureau's research and development program, however, is conducted at 19 research centers and laboratories located throughout the United States.

Jan 1, 1971

Jan 1, 1882

By Miklos D. G. Salamon

The laminated model, in conjunction with the seam element method, is expected to be a powerful predictor of subsidence due to coal mining. The fundamental solutions for the model are presented. Numerical approach to determine the roof-to-floor convergence and evaluation of ground movement are discussed. Numerical results and comparisons with field observations are given to illustrate the validity and the potential of the model.

Jan 1, 1986

By N. F. Faria, F. Monteiro, B. O. Taiwo, A. Palangio, D. Fonseca, J. Manuel

This paper explores the interpretation and application of Particle Size Distribution (PSD) curves in optimizing blast design and enhancing downstream operations. The study looks at important factors like D50, D80, fines content, and the uniformity index to show how PSD curves affect the efficiency of different mining processes. The first section of this paper discusses the impact of blast design parameters such as burden, spacing, and explosive energy on the resulting PSD, highlighting their significance for downstream operations like crushing, and material handling. The section concluded that proper alignment of PSD with downstream size classes, like primary crusher inlet sizes, among others, can result in substantial cost reductions and productivity gains. The second part presents a case study from dstgroup aggregate quarry in northern Portugal, utilizing fragmentation analysis to evaluate blast performance and promote continuous improvement. The section specifically examines the effect of stemming material size on blast fragmentation, comparing the impact of using aggregate with a D80 of 12.32 mm versus a D80 of 21.94 mm. The D80 value represents the particle size at which 80% of the stemming material is smaller, making it a critical parameter in evaluating the stemming's effectiveness in confining explosive energy. The drilling and blasting designs were meticulously planned using O-PitDev and O-PitSurface software to ensure accuracy in blast parameters and layout. To assess the fragmentation resulting from these different stemming material sizes, the study utilized WipFrag 4 software. The software allowed for precise measurement of particle size distribution after the blast, as well as a detailed comparison between the two stemming sizes. Results from the analysis indicate that using bigger-sized stemming material led to improved blast confinement, which in turn resulted in better fragmentation compared to the smaller-sized material. The reviewed blast videos demonstrate that the larger aggregate effectively contained the explosive energy within the borehole, thereby reducing premature venting and directing more energy towards breaking the surrounding rock mass. This led to finer fragmentation with D80 = 1240.1 mm, D50 = 685.9, and Dmax = 2580 mm, which is advantageous in downstream operations like crushing and milling. On the other hand, the smaller stemming material (D80 = 21.94 mm) did not confine the explosive energy as efficiently, resulting in coarser fragmentation (D80 = 1327.37 mm, D50 = 750.76, and Dmax = 2370 mm) and reduced overall blast efficiency. These findings highlight the significant influence of stemming material size on blast performance and fragmentation outcomes. 

May 4, 2025

By S. Que

Local community acceptance is a key aspect of planning and managing mining projects, whether through sustainability assessment and reporting or corporate social responsibility programs. However, there has been very little research to understand the determinants of community acceptance. This paper seeks to identify key mine characteristics and demographic factors that influence individual acceptance of mining projects. Six demographic factors and 16 mine characteristics were selected based on literature review. Four of the six demographics factors were confirmed to be significantly (p < 0.05) correlated with people?s attitude of the importance of the mine characteristics. All sixteen mine characteristics are identified as important factors. The most important mining factors are Job opportunities, water shortage or pollution, air pollution and land pollution. Both the mining and control groups have same opinion of 12 mining characteristics and differ on four (infrastructure improvement, labor shortage for other businesses, noise pollution, and mine life). During design and management of mines, this data can be used as a reference. This result will facilitate better choice experiment (survey) design for discrete choice modeling. Such discrete choice models can provide a viable framework for data-driven community engagement and sustainable mine management.

Feb 23, 2014

By W. G. Deeks

CANADIANS are world leaders in marketing metal and mineral products. Noranda Sales Corporation Ltd. is an international metal and mineral product marketing company operating from Toronto and London, England, where it operates a wholly owned sales subsidiary and is a 50% partner in Rudolf Wolff and Company Ltd., a charter member and the largest metal broker on the London Metal Exchange. Noranda Sales employs 97 people, of whom 52 are university trained and professionally competent in international resource product marketing. We market for 19 companies or divisions in the Noranda Group and 39 companies for whom we act as agent, consultant and purchaser of resource production. Our business in 1976 was 1.5 billion dollars carried out in 45 countries and covering 24 products and materials. Today, ownership of most of the mining industry in Canada has transferred back to Canadians, and this is said with the knowledge that a significant part of the Canadian industry has been Canadian owned and managed from its very early days. Noranda Mines Limited is such an example. It was born in 1922 as the result of a copper-gold showing at Noranda, Quebec, discovered by Ed Horne, a prospector, financed with a grubstake by a syndicate mainly composed of New York businessmen. Shortly after the discovery, when the shares of the company had risen, the syndicate was sold to Canadian interests and, since that time, Noranda has been dominantly Canadian owned and certainly Canadian managed. Today, over 90% of Noranda&apos;s shareholders are Canadian, who hold an equivalent percentage of the stock.

Jan 1, 1977

By H. C. Theuerer

GeC14 may be purified by extraction with HCI and chlorine. The process is as effective for the removal of AsCI:, as the more cumbersome distillation methods usually used for this purpose. GERMANIUM for semiconductor use contains impurities at levels no higher than a few parts in ten million. Material of this quality is obtained from highly purified GeC1, by hydrolysis to the oxide and reduction of the oxide in hydrogen. When purifying GeCl,, AsC1, is the most difficult impurity to remove. This is usually accomplished by multiple distillation procedures.1-3 AsC1, may also be removed from GeC1, by extraction with HC1.1-4 Reducing the arsenic to low concentrations is not practicable, however, because of the large number of extractions needed. This paper discusses a new method for the removal of arsenic from GeC1, by extraction with HC1 and chlorine. The method is rapid, leads to little loss of germanium and is at least as efficient as the distillation procedures currently being used. Theory of Extraction Procedures In the simple extraction of GeC1, with HC1, the following reaction occurs ASCl8G8C1 D AsCl3rc1 at equilibrium CA/Cn= K, where K is the distribution coefficient, and C, and C,, are the molar concentrations of AsC13 in HC1 and GeCl,, respectively. The materials balance equation for this reaction is VACA + vncn = VnC,, where V, and Vn are the volumes of HC1 and GeCl4, respectively, and C, is the initial concentration of AsC13 in GeC1,. From this it can be shown that for multiple extractions where C,, is the concentration of AsC13 in GeC14 after n extractions, and r is the ratio of V, to V,,. It is assumed that r is maintained constant, that equilibrium is established during each extraction, and that K is independent of the AsCl3 concentration. By saturating the system with chlorine, the following reaction occurs in the aqueous phase AsCl3 + 4H2O + Cl2 D H5AsO4 + 5HC1 at equilibrium K&apos; = ------------ ai - a4 h2u - aet2 where a is the activity of the various components. The effect of this reaction is to reduce the concentration of the AsC1, in the aqueous layer and, therefore, to promote further extraction of this component from the GeC1, layer. If the arsenic acid remains entirely in the aqueous phase, the net effect of this reaction is to promote the removal of arsenic from the GeC11. The materials balance equation for extraction with HC1 and chlorine with the foregoing reaction is, then, VaCC + VACA + VACn = VnCo where C,. is the molar concentration of H3AsO, in the HC1. With the added assumptions that the activities of AsC13 and H8ASO4 in the aqueous phase are equal to their molar concentrations, it can be shown that for n extractions Cn/Cu = (1/rkK + rK + 1) n where k - K1 a4h2o - acl2/aoncl. It can be seen by comparing Eqs. 1 and 2 that if k is large, the removal of AsC1, by HC1 extraction will be greatly improved by the addition of chlorine. Dilution of the HCI used in the extraction with chlorine would also favor the separation. This, however, would increase the loss of GeCl,, which is undesirable. Experimental Procedure Germanium prepared from oxide of semiconductor purity is n-type with resistivities greater than one ohm-cm. The resistivity is controlled by the donor concentration, which is —lo-: mol pct. Germanium prepared from material with added arsenic will have lower resistivity commensurate with the arsenic concentration. With such material, at arsenic concentrations above 10-1 mol pct the resistivity is controlled by the added arsenic, and effects due to other impurities initially in the oxide are negligible. In this investigation GeO, of semiconductor purity was converted to GeCl,, and -0.01 mol pct As was added. This material was used for the extraction experiments and the purification attained determined by a comparison of the resistivity data for samples of germanium prepared from the initial and purified GeC1,. A method for calculating the arsenic concentration from the resistivity data is discussed later. The details of the experimental procedures used are as follows: Two hundred and thirty cu cm GeC1, were prepared by the solution of GeO, in HC1, followed by

Jan 1, 1957

By Steve Kral

"The Rapid Excavation & Tunneling Conference (RETC) is a world-renowned event that attracts some of the best minds in the global underground construction and tunneling industry. The experts gather at this conference to impart new technologies, discuss challenges to their projects and learn about new technologies that have become available to them.The 2015 RETC will be held June 7-10 at the Sheraton New Orleans, in New Orleans, LA. This biennial conference, of which SME is a sponsor, is expected to attract about 1,400 attendees from around the world. These professionals represent all parts of the global tunneling and underground construction industries - contractors, engineers, owners, consultants and equipment suppliers.More than 110 technical papers in 21 sessions will be presented over two-and-a-half days. Paid attendees will receive a proceedings volume of the conference. The proceedings will also be available from SME. In addition to the technical programming, the accompanying exhibit will include 155 exhibitors occupying 175 booths, providing RETC attendees the opportunity to get a look at the latest in equipment and service technology. Three short courses will be held on the Sunday preceding the start of the show. And there will be plenty of opportunities for attendees to meet and chat during several social activities that are scheduled throughout the conference."

Jan 1, 2014

By Carlos Bermúdez Ortega

El presente texto señala el aspecto geológico de las estructuras más importantes de las minas Orcopampa, perteneciente a la compañía de minas Buenaventura en Castilla, Arequipa. En este sentido, se describe la zona mineralizada, geología estructural, depósitos minerales, texturas, alteración hidrotermal, descripción de las vetas, reservas, yacimientos similares y los prospectos. Asi como se realizan las interpretaciones preliminares del zoneamiento y paragénesis de veta Calera y Santiago Este.

Nov 8, 1982