Search Documents

By Rodney H. Sergent

After being forgotten or ignored for nearly 100 years, the ability of bromine chemistry to extract gold from ore has been rediscovered. While bromine chemistry is similar to chlorine, there are some important differences. Bromine in its elemental form is a dense, fuming, red liquid. Elemental chlorine is a gas and requires a substantial amount of equipment to handle, store and deliver to solution. Bromine has an advantage in its ability to rapidly and completely oxidize heavy metals to water soluble halide salts. The first patent for use of bromine chemistry for gold extraction was issued in 1881 (1). By 1895, work done in Colorado concluded well roasted ores required approximately 1-1/2 lbs/ton of elemental bromine for superior extraction of metals (2)). At that time, bromine was deemed to be cost effective vs. chlorine even though it was more expensive on a pound basis than chlorine. The advent of cyanide technology virtually eliminated both chlorine and bromine from consideration for leaching of ores. Cyanide was so inexpensive that it made deposits requiring unique technologies unattractive for mining. Only since the deregulation of gold price has bromine/chlorine technology been considered for those ores not amenable to cyanide. While chlorine has found its way into the pretreatment steps, bromine is just beginning to realize its niche in the marketplace.

Jan 1, 1998

By K. P. Unrug, E. Thompson, S. Nandy

The method of coal pillar design involves primarily two aspects: the geometry of the pillar and the strength of the coal. However, the strength of the coal has to be emphasized with respect to the entire pillar dimension rather than isolated strength values of coal samples taken and measured from different locations. As of now, the presently applied pillar design systems do not specify clearly what the coal sample strength really represents. The intention of this paper is to introduce the concept of seam strength as opposed to the current practice of using coal strength as a prime design criteria in the formulation of pillar calculations. Seams are most often composed of multiple layers of coal, partings, and bone in various configurations, changing within the vertical section of the seam even in relatively close locations. The difference in strength between the weakest and strongest component of the coal seam could be as much as five times or more. An experimental approach based on multiple uniaxial compressive strength tests performed on coal samples from the Coalburg and Warfield seams from eastern Kentucky was undertaken. Analysis of the results led to the conclusion that for pillar dimension calculations, both the weighted mean of the seam strength and the strength of the weakest stratum should be considered, rather than the relatively vague aspect of coal strength. The design of pillar dimensions based on the aforemen¬tioned criteria should assure a more realistic design performance.

Jan 1, 1987

By Thomas E. Weyand, Wolfgang Baum

PMET is engaged in the development of reuse operations for process wastes from the natural resources industry. Most of the current remediation practices with mining wastes are concentrated on stabilization techniques. Once stabilized, valuable resources are no longer readily available for recovery and reuse. Additionally, stabilized materials, unless protected from weathering influences, pose lingering liability for the generator.

Jan 1, 1992

By Edward J. Zeigler, John T. Miller

INTRODUCTION Construction of Phase I, Section A, of the Baltimore Region Rapid Transit System required that six underground stations be built using a cut and cover excavation technique. For five of these stations, soldier piles, used as support of excavation, were installed with tip elevations well below the bottom of the excavation. However, in the case of the sixth subway station, the Mondawmin Station, soldier piles were installed only through soil and decomposed rock, with the tips of the piles being stopped well above the bottom of the excavation in partially decomposed rock. Below the tips of the soldier piles, and below a cut slope where piles were not installed, the sides of the excavation consisted of partially weathered and fresh rock and were supported by a combination of rock bolts, wire mesh and shotcrete. An extensive installation of geotechnical instrumentation permitted detailed monitoring of horizontal and vertical movements of the soldier piles and the walls of the excavation. Preliminary studies indicated that the excavation support system selected for the Mondawmin Station would have several advantages over a conventional system consisting of soldier piles extending to the bottom of the excavation, braced with prestressed struts. These advantages included lower cost of installation, a decreased time required for installation, and a more open excavation for the contractor during construction of the station. The Mondawmin Station is situated in the northwestern quadrant of Baltimore City, approximately 6.4 km (4 miles) from the center of the City. The station lies midway in a project 12.9 km (8 miles) long identified as Phase I, Section A, of the Baltimore Region Rapid Transit

Jan 1, 1981

By W. S. Fyfe

Gold is mobilized or made soluble under all crustal conditions given appropriate fluid chemistry with molecules which complex gold. In the surface environment chloride, thiosulphate and a host of organics may mobilize gold. In the epithermal range bisulphide appears effective as shown by the classic studies in the Taupo volcanic zone of New Zealand. In the high grade metamorphic to igneous ranges little is know but it appears that gas molecules in the system CO2 -CO-H20-S-C1 can do the job. Precipitation may occur by changes in P-T-EL-pH or boiling where such changes influence the liquid concentration. Of the known regimes information is good for epithermal systems, poor for surface lateritic environments, inadequate for high-T systems. Gold is often concentrated in bio-systems both living and dead. The influence of biosystems is little appreciated. There is a great potential for the discovery of new types of gold deposits and in particular, gold in weathering environments, gold in very high-T environments, gold in strike-slip faults and thrust regimes, and gold as a by-product in materials like coal and other organic debris. By the year 2500 we may find our noble metal resources in the asteroids.

Jan 1, 1987

By Jorge Martinez

The Muck Valley Hydroelectric Project in Northeastern California required construction of a 3.65 meter tunnel through 6,623 meters of mixed volcanic flow deposits within a critical time frame. As Engineer and Construction Manager for the Project, Morrison-Knudsen Engineers invited bids for both Drill and Blast as well as Tunnel Boring Machine methods, selecting a contractor proposing a TBM designed and built specifically for this project which could excavate a wide variety of materials and maintain acceptable progress rates to complete the work within schedule. Tunnel lining as required included shotcrete with metal fibers and full circle concrete.

Jan 1, 1989

By Jacques L. Mauboussin

The EUROPEAN ORGANIZATION for NUCLEAR RESEARCH (CERN) has undertaken the construction of a LARGE ELECTRON POSITRON COLLIDER (LEP), near GENEVA (Switzerland). The facility includes the main 27 km long tunnelled ring, 18 shafts, 20 experimental caverns and many auxiliary galleries. Roughly 800 000 cu.m were excavated in the molasse at 50-140 m depths, using roadheaders for caverns and auxiliary tunnels and 3 WIRTH, 4.5 m diameter, fullface TBMs for the main circular tunnel. Each TBM performs 25-30 m/day. Provisory lining behind them uses either precast concrete elements or shotcrete. Works a e being carried out by a joint-venture of European contractors led by FOUGEROLLE (France).

Jan 1, 1987

By Thomas E. Krakowski

INTRODUCTION This paper presents a method of calculation of internal moments and thrusts in tunnel liners of any material. The method is intended for hand calculation, but as it is numerical in nature it can be programmed for use in computers. The information required for design or analysis is presumed active internal and external pressures, the effective moment of inertia and cross-sectional area of the tunnel liner, the liner's modulus of elasticity, and the coefficient of subgrade reaction of the material surrounding the tunnel. Starting with active external and internal pressures and following the procedure described herein using the structural properties of the liner and surrounding medium, external passive reactions and internal moments and thrusts are calculated. The method is intended for use by design engineers. GENERAL Experience has shown that flexible tunnel liners have less internal bending stresses than those calculated using classical structural theory applied to free-standing arches. In fact, liners which are very flexible in relation to the surrounding soil or rock have virtually no bending moments when compared to free-standing arches supporting equal active loads. In order for this phenomenon to occur, the original active pressure diagram must be "modified" by additional external reactions (passive pressures) from the surrounding material, so that the thrust line within the lining follows the centroid of the tunnel arch more closely than that of a similar free-standing arch. These passive pressures are reactions developed through outward deflection of the tunnel liner. Thus, the outward moving portions of a

Jan 1, 1979

By Keith J. Henley, Nicholas C. Clarke, Paul Sauter

A detailed investigation of the stability in cyanide solutions of native gold and gold-silver tellurides in a flotation concentrate from the Golden Mile, Kalgoorlie, has been undertaken to assess whether leaching under different conditions can be used to quantify the distribution of Au between native gold and gold-silver tellurides, as suggested by, for example, Chryssoulis and Cabri (1990). The leaching was carried out on +20 µm native gold and gold-silver tellurides separated from a high-grade flotation concentrate and then diluted with barren quartz. The material leached assayed 270 ppm Au and 118 ppm Te and the leach conditions used were:- Stage 1: Leaching in dilute cyanide (0 .1 % ) at pH 9 .5 for 24 hours to dissolve native gold but not gold-silver tel­lurides. Stage 2: Leaching the residue from Stage 1 in strong cyanide (2%) and pH 12.5 for 96 hours to dissolve gold-silver tellurides.

Jan 1, 1995

By Brian Hester

Many Third World African countries are well-endowed with minerals - especially gold and diamonds - while only a few have important base metal deposits. For decades since colonial rule, political and economic conditions discouraged interest by Western capital. Influence from Soviet Bloc countries, however, has declined with the move toward multi-party rule. And the left wing orientation, once widely favored by Third World African countries, has almost disappeared. With International Monetary Fund (IMF) encouragement, these Third World African countries now encourage representational government and solicit western finance to expand their industries. Mining is especially encouraged. The North American mining industry is following the same trail as other capital intensive industries and looking abroad for opportunities. The Prospectors and Developers Association of Canada released figures that show exploration expenditures in that country were halved between 1987 and 1990. Figures for the United States are not so easily found but every indication points to a downward trend. While total annual expenditures on US exploration by corporations as a group are either declining or remaining constant, expenditures away from North America is increasing. Gold exploration expenditures in 1991 by the major companies tracked by Minerals Economics Group were less in the United States than for Latin America and the Southwest Pacific combined. The same study showed as much was spent in the Republic of South Africa and "Other" areas combined as in the United States. Expenditures by major corporations in these "Other" areas amount to only 5.2% of their total budget. Third World Africa is a major component of these "Other" areas.

Jan 1, 1993

By John T. MacWaters, George H. Milly

INTRODUCTION This paper describes operational procedures and instrumentation which were developed to implement a patented method of detecting and locating uranium ore bodies. All equipment was designed for accurate and reliable use under difficult field conditions. Data resulting from these developments, some of which are incorporated in a companion paper for this conference*, have contributed to our understanding, of the nature and significance of naturally-occurring radon exposures. Further applications of these techniques may prove useful in studying anthropogenic radon in evaluating the significance of variability in radon flux, or in taking proper account of the contribution of natural radon to ambient radon concentrations, particularly in mineralized regions. OPERATIONAL PROCEDURES The uranium search technique employed by GEOMET begins with a [reconnaissance mode], which utilizes a series of ambient air filter samples taken from a moving or standing vehicle to detect anamalous concentrations of radon. These samples are normally taken at night under stable (temperature inversion) or neutral atmospheric conditions, to avoid the rapid dispersion of the radon clouds typical of daytime turbulent conditions. Radon daughters formed by the decay of radon quickly attach to ambient aerosol particles and are captured on the surface of a membrane filter during a five-minute sampling period. The filter is placed in a portable alpha scintillation counter, and a five-minute count is started at a preset time after the completion of the sampling period. This count is followed immediately by a second five-minute count to enable determination of the cloud age, based on consideration of the relative half-lives of the initial radon daughters. With the use of tables computed from the mathematics of the uranium decay process, and with the measured radon background accounted for, the first and second counts are used to estimate the time which has elapsed since the pure radon initially emanated from the earth's surface. This cloud age, combined with wind speed and direction measurements made at the beginning and end of each sample, as well as with an understanding of the effects of local terrain features on wind trajectory, provides an estimate of the Probable location of the source. In practice the reconnaissance mode involves one vehicle with a single operator to take the five-minute samples, moving or standing, along any available roads or trails in the area to be covered. Under the usual nighttime stable conditions the cool air flows downslope and downvalley, and the operator will pay special attention to locations along the axes and confluences of the natural downflow patterns. These facilitate sampling of large air drainage areas. Successful detection of sources of radon based on high concentrations of radon daughters, and substantiated by evidence of "fresh" clouds, are frequently made on the basis of a relatively few samples taken judiciously by an experienced operator during a reconnaissance. At this point he has a choice: he can continue to cover the designated reconnaissance area, leaving the localization of any anomalous radon detections to await the ranking of detections by priority, or he can continue with localization of the detected source, either alone or by radioing for another vehicle to assist in triangulation operations. Localization of a source involves skillful and experienced use of the continuously collected data on concentration, age, and wind speed and direction, together with knowledge of the terrain from observation and contour maps, and exploitation of the available roads. Since age ratios are dependent solely on proximity of the source and wind speed, decreasing [cloud ages] based on statistically significant increasing age ratios represent the most useful. information in localization. The [magnitude of the concentration] of radon daughter products is also useful; however, it may vary widely for a variety of reasons during sampling for a localization, thus making this a secondary parameter for localization. Large values of concentration are of course useful; typical results for successful detection of a strong anomaly would yield alpha counts ranging from 10 to 25 times background values. These counts are convertible to ambient radon concentrations by appropriate consideration of the decay process. Successful localizations of radon sources using this procedure with ambient atmospheric measurements normally will narrow a source location to within an area ranging in size from less than a quarter of a square mile to at most a square mile, and frequently give information on the probable shape of the source (in plan view) on the earth's surface. Judicious use of this procedure could undoubtedly provide finer localization, but the coarser results just described are adequate for this Phase of GEOMET's uranium exploration procedures.

Jan 1, 1981

By Ken Criley, Marc E. Orman

Identifying the optimum ultimate height for heap leaching ore requires the consideration of a number of competing factors. A primary limitation is the reduction in the permeability of the ore with increasing heap heights. At low permeabilities the heap can blind off, cause serious ponding and runoff, and become very difficult to rinse at closure. The authors present a laboratory methodology that has been successfully used on several projects to identify the maximum height for controlling heap permeability.

Jan 1, 1996

By A. Perelli Cippo, R. Granata, D. A. Bruce

During the last few years, significant advances continue to have been made in aspects of grouting technologies used for ground treatment in advance of tunnelling. In permeation grouting, fundamental researches have continued into improving the penetrability characteristics of cement-based grouts. The twin advantages of field regrinding normal grouts to reduce cement particle sizes, and incorporating special additives into stable grouts, are now being systematically exploited in major soft ground tunnelling projects in Europe. The methodologies of jet grouting continue to be developed with special attention being paid to qa/qc issues, reducing unit production costs, and improving predictive capabilities for subsequent settlements.

Jan 1, 1993

By J. J. Robertson, D. M. Polizzotti

Cement is used as an established agglomerating agent in gold heap leaching operations to maintain heap permeability and prevent migration of fines. In addition to agglomeration, cement provides protective alkalinity control. However, the amount of cement needed for agglomeration is usually very different from the amount necessary for pH control. As a result, cement is usually added in excess. Overdose of cement can result in reduced gold recovery and/or lengthy detoxification. Betz Laboratories has identified polymeric agents that provide the benefits of cement without negatively impacting gold recovery when used alone or with lime. Independent laboratory tests also strongly suggest that the polymer/lime system can significantly reduce heap detoxification time.

Jan 1, 1992

By Paul C. Schmall, Arthur B. Corwin, Hugh S. Lacy, Derek Maishman

For reasons of hydraulic design and constructability, water supply tunnel systems are often located relatively deep, in competent rock. Where the rock lies below a thick cover of water bearing soils, artificial ground freezing offers a low risk, cost-effective method of constructing access shafts. Several examples, in Kansas City, MO and in Brooklyn and Queens, NY, illustrate the use of freezing to provide structural support and ground water exclusion. In the case histories presented, the shafts range from 6m to 12m (20 to 40 ft) in diameter and soils vary from clays to boulder beds with depths in excess of 73m (240 ft) to competent bedrock. Where tunnels for infrastructure are designed to be driven in rock, vertical access may encounter a considerable thickness of overburden soils with groundwater. In such cases, shaft sinking problems are analogous to those confronted by mining engineers over 100 years ago. At that time, newly developed refrigeration machines were set to freeze the ground water and stabilize running sands. Although modern technology has refined our efforts, the basic features of the ground freezing to be described here are the same as those used in the last century. Vertical holes drilled on a circle surrounding the shaft site are equipped with leak-free steelpipes through which a refrigerated brine is circulated. In this manner, a frozen cylinder, seated in rock, is formed when the earth freezes between adjacent pipes. Shaft excavations take place inside a self-supporting, ground-water excluding structure. For mines, no better method of sinking production shafts through deepwater-bearing ground has yet been established. Indeed, major deposits of coal, potash, and salt would have remained inaccessible to this day were it not for the continued use of artificial ground freezing. If mine shaft freezing became relatively commonplace, early applications to civil engineering were few. Mussche and Waddington (1946) mention only five projects between 1892 and 1935; three of these relate to subway or vehicular tunnels in Paris, Antwerp, and (the most extensive) at five locations of the Moscow Metropolitan Railway development. In the United States, the method was used to spectacular effect in 1936, freezing about 3,000 cubic yards of silt to stop a slide

Jan 1, 1999

By Dan Slyter

This paper prov ides comparisons be­tween Merrill-Crowe and Carbon Adsorption pl Rnts 11sed for Pree ious Metal Heap Leach Operations. During the first stage of mine devel­opement, the question arises as to type of gold recovery circuit to be employed, Car­bon or Zinc. Several important factors to consider in answering this question are: Au/Ag ratio Solution grades Daily plant production Plant throughput required Plant gold inventories

Jan 1, 1992

By Robert F. Baker

Neanderthal technology is a harsh and inaccurate way to describe modern underground construction and mining practices, but such an exaggeration helps to focus on a major problem or wasted opportunity of modern society. Why is it not safer to excavate in the underground? Why are the working conditions still so unfavorable? Why are urban freeways, shopping malls, warehouses, power plants, sewage disposal treatment plants, and similar facilities still constructed on the surface of the ground--because it is a better location? On the contrary, if underground technology made full use of existing knowledge, underground resources and space would be much more effectively used. And why is the technology so inadequate? Certainly, researchers and practitioners are aware of the shortcomings and are equally aware of problems that have to be overcome. One of the most important reasons has to do with the type of policy goals that society has set in the past. Policy makers may have agreed that improvements would be desirable but no serious commitments have been made--that is, there has been no major allocation of resources to advance these technologies. And yet, to bring about significant changes will require significant time and resources. The resources that are needed are far in excess of what industry can afford to invest, particularly since the pay-off may be far in the future. So the problem reverts to society in general. As long as society is willing to tolerate the present costs and safety requirements for recovering minerals and for constructing underground facilities, then the changes will be slow in coming. Until such time as society sees and desires the benefits

Jan 1, 1974

By Steven A. Moreno

Geochemical returns from commercial analytical laboratories are often delayed because of postal and other bulk distribution inefficiencies. Consequently, minerals exploration programs are handicapped due to insufficient time for treatment, analysis, and diagnosis of the data. The minerals industry lacks a system for rapid transmission of geochemical data which allows immediate entry into statistical and plotting routines. Over the past three years, Houston International Minerals Corporation (HIMCO) has developed a computer-based system to receive, treat, and distribute geochemical data. In the past two years, Bondar-Clegg (Denver) and Chemex (Vancouver) have developed systems to transmit' data directly to HIMCO via the world-wide Boeing Computer Services (BCS) network. The main benefits to HIMCO have been ten less days for reporting turnaround, ten less days for keypunching, less data handling, accuracy. The benefits to the laboratories have been improved in-house data management, reporting, and HIMCO's increased geochemical activity.

Jan 1, 1982

By D. Forbes

The results of a fundamental study involving zeta-potential and turbidity determinations of solid suspensions are discussed. Illustrations of how these results are utilized to design field applications of solid-grade polymers to clarify mine-drainage water are presented. Operational and economical advantages are examined.

Jan 1, 1997

By Drupad B. Desai, James G. Gallanes

A key component of the Inland Feeder Project is the Riverside Badlands Tunnel, a7.9-mile stretch subjected to high internal and external hydraulic pressures passing beneath highly eroded hills in a semi rural environment. The tunnel presented significant design and management challenges to the project team. This paper describes the formula for project success used to manage the design of this complex pressure tunnel, from team member selection to the completion of all contract documents, on schedule and below budget. The project team dealt with sensitive regional and local community issues and won the trust of the community. The team included participation by senior management and recognized experts from inception to finish. The team worked diligently to build quality into design and adopted a claims avoidance approach to management and preparation of documents.

Jan 1, 1997