Search Documents

By E. Manev

Thin aqueous equilibrium film studies and surface tension measurements on a mixed surfactant system consisting of polyethylene oxide (a model frother) and potassium ethyl xanthate (a model collector) enable the interaction between the two surfactants at the air/solution interface to be elucidated. For the film containing the non-ionic frother, the interface was charged and addition of low concentrations of xanthate acted as a common electrolyte and reduced the thickness of the film inducing rupture. However, at high xanthate collector concentrations, the negative charge xanthate was found to interact with the non-ionic and caused a build-up of negative charge at the air/solution. Higher frother concentrations were necessary to produce non-rupturing thin films upon increasing the xanthate concentration.

Jan 1, 1992

By Brett P. Spigarelli

"To meet the growing need for CO2 capture and storage technology, Michigan Technological University is studying CO2 capture using alkali-based solvents. The objective of the present study was to find a way to increase the absorption rate of CO2 into an alkali solution without reducing the absorption capacity of the solution. One approach to increasing absorption rate is to use a surfactant to chemically alter the gas bubble size. The surfactant chosen for the study was a neutral-charge polypropylene glycol methyl ether (PPGME) with a molecular weight of 200. Experiments were conducted to study the absorption rate of CO2 at varying surfactant concentrations. Results showed that as the concentration of PPGME increased in solution, the absorption rate also increased. The CO2 absorption rate increased from 3.45 x 10-3 mol/min CO2 at 0g/L PPGME to 3.92 x 10-3 mol/min CO2 at 0.48 g/L PPGME. This amounted to a 14% increase in the CO2 absorption rate with no decrease in the absorption capacity of the solution. IntroductionChemical absorption using an amine solvent is currently the most mature carbon capture and storage technology available. Amines are advantageous in that they have a fast CO2 absorption rate, which leads to a high CO2 removal efficiency. However, amine absorption has some considerable drawbacks, such as high energy requirements, high equipment corrosion rates, amine degradation in the presence of oxygen, high waste generation and a large increase in plant footprint if new equipment is constructed (Herzog and Golomb, 2004; D’Alessandro et al., 2010). Due to these drawbacks, Michigan Technological University (MTU) is studying CO2 absorption using alkali-based solvents, which address the above disadvantages of amine solvents."

Jan 1, 2015

By J. Morris, R. Sellaro

El petrodiesel es un colector común para la flotación de carbón, pero la partición de compuestos orgánicos de diesel (DRO por sus siglas en inglés) en corrientes de proceso no ha sido ampliamente estudiada. Investigaciones preliminares sugieren que bajo esquemas de dosificación normales los contenidos residuales totales de DRO en aguas de procesos deben estar limitados a la fracción soluble en agua (WSF por sus siglas en inglés) sub-ppm. Es más, los hidrocarburos aromáticos poli-cíclicos (PAH por sus siglas en inglés) debería segmentarse de manera proporcional con los compuestos orgánicos de diesel (DRO). El propósito de este estudio fue confirmar estos resultados en pruebas de flotación realizadas en laboratorio. Se midieron los contenidos totales de DRO Y PAH en aguas asociadas con los flujos o corrientes de concentrados y relaves. Los resultados muestran que las aguas con concentrados tenían de manera consistente mayores cantidades de DRO que las aguas de relaves. Es más, los contenidos de DRO en ambos flujos generalmente se incrementaban con el aumento de la dosis de diesel. De acuerdo con la investigación preliminar, los DRO parecían estar limitados a la fracción soluble en agua (WSF) y los PAH tendían a segmentarse proporcionalmente con los DRO. Bajo condiciones de operación típicas, los DRO residuales no deberían representar una preocupación medioambiental, pero deben evitarse situaciones que permitan una sobredosis significativa de diesel.

Jan 1, 2014

By Harrison R. Cooper

Composition data is needed as input for executing process control and management of particulate separation for flotation control. While requirements for composition data can be satisfied in many cases by manual sampling and analysis, automatic sampling and assay systems are now viewed as justified for all but the simplest or smallest processes. On-stream X-ray fluorescence analysis (XRFA) has satisfied requirements for the main portion of metalliferous sulfide ore flotation processes as XRFA technology evolved in reliability and sophistication from its beginnings in the late 1950's. In recent years, advanced on-stream analysis technologies have reached levels of development suitable for use in process control to increase efficiencies of important processes in mining and minerals industries such as coal fines flotation and industrial minerals beneficiation (particularly phosphate beneficiation) where XRFA methods have been inapplicable. Recent technical developments pertinent to use of advanced technologies as well as improvements to established on-stream composition analysis methods are discussed.

Jan 1, 1989

By Y. H. Chia, P. Somasundaran

Carrier flotation of anatase from clay using coarse calcite is investigated, together with relevant basic properties of the system including aggregation and zeta potential, under different chemical and hydrodynamic conditions The roles of carrier sue and amount also are considered Mechanisms responsible for selective aggregation and flotation are reviewed

Jan 1, 1983

By Alden B. Carpenter

The Dead Sea is the only relatively large body of surface water having bromide concentrations comparable to those in the brines of the Smackover Formation in Arkansas. The Dead Sea, like the Smackover brines, contains a great deal of calcium and is very low in sulfate and iodide. The relationships between potassium, divalent cations, and chloride indicate that over 20 percent of the bromide in the Dead Sea is derived from some source other than by the evaporation of sea water. A similar type of study of the Smackover brines in Arkansas indicates that approximately 60 percent of the bromide has been derived from some source other than sea water. Both the Dead Sea and Smackover brines are very low in iodide suggesting that the excess bromide has not been derived from organic matter. The origin of the excess bromide is probably the same for both of these brines, but the source of this bromide remains unknown.

Jan 1, 1978

By R. F. Al-Fariss

The phosphoric acid industry is expected to develop in Saudi Arabia in the near future. There are three main reasons for expecting this: the discovery of phosphate deposits in the Sirhan-Turayf region, the construction of phosphate fertilizer facilities of the TSP, DAP and NPK plants on the east coast of the country, and the availability of an ample amount of sulfur As a by-product from the petrochemical industries. This study is a part of the research work performed in the chemical engineering department At King Saud University to evaluate the Saudi phosphate rocks for the wet process phosphoric Acid production and to test different flotation methods for the carbonate rich phosphate rock In a laboratory scale flotation cell. Experimental results for the above tests, as well as Beneficiation by calcination, are presented.

Jan 1, 1993

By R. L. Grayson, Y. J. Wang

An application of material requirements planning (MRP) to coal mine inventory control is presented. MRP is an efficient material control system that integrates the production planning and inventory management functions. Net material requirements are determined from the production forecast utilizing bill of material files, the inventory status file, and the purchase order status file. Net requirements are computed for each period in a specified planning horizon, and purchase orders, offset by lead time, are initiated routinely to ensure timely receipt of materials. The MRP system is especially useful in production-inventory systems in which con¬sumption of materials is directly production dependent.

Jan 1, 1987

By Thomas H. Koenning, William E. Bruce

Determination of the state of a mine fire is an important function during firefighting and during rescue and recovery operations. It is imperative that an accurate, up-to-date assessment of fire conditions be available for persons directing such activities in order to avoid unacceptable risk to mine rescue teas and/or fire fighters. Many indicators which consist of ratios of the concentrations of fire gases have been developed over the years for determining the state of a mine fire. Results from numerous gas sample analyses are necessary for determining the trend of the fire. Some indicators are preferred because the influence of sample dilution, a frequent problem, is said to be eliminated. Definitions and examples of indicator6 found to be useful in diagnosing recent western U. S. coal mine fires are presented. Mine gas explosibility is an important subject also requiring rapid assessment. Example explosibility calculations are presented applying one widely used method. Establishing limits for withdrawal of personnel are discussed.

Jan 1, 1987

By E. Topuz, M. J. McPherson, I. M. Konduri

The research is carried out to investigate the flow mechanics and effectiveness of face ventilation using induction fans, as an effort to provide a more efficient alternative to conventional auxiliary duct or brattice ventilation systems. The induction effects and plume longevity of fluid jets are being studied with the help of a plexi-glass model, using water as the fluid medium and creating a system that is dynamically similar to the flow in mine headings. This scaled model represents a typical 1.5m x 6m x 25m heading connecting to a crosscut. Reynolds Number criteria are used to obtain dynamic similarity of the flow in the designed model to simulate real mining conditions. The role of various parameters such as nozzle position in three dimensions, airway roughness, nozzle geometry, and flow rate in the jet are studied. During the laboratory tests, flow visualization techniques, coupled with still and video photography, were employed to identify the flow patterns. The results indicate that in typical coal mine headings, jet fans can produce effective face ventilation for distance up to 30 meters.

Jan 1, 1995

By D. C. White

The Vulture Mine near Wickenburg, Arizona was a major gold producer from 1863 to 1942, having yielded about 11,000 kg Au and 8,000 kg Ag. Gold occurs as coarse native metal and electrum in quartz veins and also finely disseminated within a quartz monzonite sill and its silicified wall rock. The sill is semi-conformable within a Proterozoic volcaniclastic-dominated sequence all dipping north about 35°. Early mining focused on the vein-hosted gold particularly in the immediate hanging wall and footwall of the sill. Later efforts included some open-pitting of the outcropping sill and adjacent altered and mineralized rock. Two sets of post-mineral faults have complicated the orebody geometry.

Jan 1, 1988

By Herman Gill, Dani Delaloye, Madelyn Rubin

The Foothill Tunnel is a remote 16-mile-long untreated drinking water tunnel in the San Francisco Public Utilities Commission’s (SFPUC) Hetch Hetchy Water and Power (HHWP) system. The 14-foot horseshoe shaped tunnel, constructed in the 1920s, is lined intermittently with concrete over approximately 53% of its length, with the balance being unlined rock. After detailed planning, in January of 2020 Mott MacDonald and HHWP staff completed a visual inspection and documented the condition of the tunnel with electronic data collection, photographs, and video with audio recording. The result was a comprehensive condition assessment that identified key areas of the tunnel to monitor.

Jun 13, 2021

By Stanislaw Nawrat, Waclaw Trutwin, Waclaw Dziurznski, Janusz Roszkowski

In recent years attempts have been made to fight open and intensive mine fires by the use of special extinguishers, which are able to produce great volumes of inert gases directed into the fire zone. These extinguishers are derived from turbo-jet engines used in aircrafts and adopted for operations in mine conditions. The purpose of this paper is to draw the attention to a computer simulation method, enabling studies of dynamical behaviour of mine ventilation processes disturbed by open fires, which are also influenced by measures taken during fire fighting actions i.a. the mentioned operating extinguishers. The first part of this paper gives an account of the principles on which the computer simulation program, concerning the non- steady mine ventilation process, the fire as a heat source and the extinguisher as a source of inert gas and moisture has been based. The next part of this paper deals with simplifying assumptions and the subsequent limitations of the derived simulation pro- gram. Finally, from an example of a computer simulation, the results will be presented and relations shown between parameters characterising the ventilation process during the fire fighting action.

Jan 1, 1997

By E. J. Beckman, R. M. Enick, C. Shi

A novel liquid-liquid separation for the recovery of free or liberated gold from mixtures of fine particles was evaluated. Two inexpensive and environmentally benign fluids were selected for the study, water and carbon dioxide. The separation, which is conducted at 295 K and at the vapor pressure of carbon dioxide (6.0 MPa), is based on differences in wettability between the precious metals and other minerals. Contact-angle results indicated that, in the presence of water and liquid CO2, gold is slightly hydrophobic. The addition of CO2-soluble fluoroalkyl thiols or f uoroetherthiols increased the hydrophobicity of gold exposed to water and CO2 to a greater extent than alkylthiols. Minerals, including quartz, pyrite and magnetite, were hydrophilic. During the separation, an aqueous slurry of fine mineral and gold particles was mixed with liquid carbon dioxide. Pure gold particles (-325 mesh) were found to agglomerate at the H2O-CO2 interface. The minerals tended to remain in the aqueous phase. Despite these promising preliminary results, very poor gold recoveries were obtained when applying the procedure to an Australian gravity concentrate. This was attributed to the native gold particles in the concentrate being either too large, agglomerated in slimes or coated with minerals. Although this particular application was unsuccessful, this water-CO2 biphase technique may be applicable for other separations that require the removal of very fine, hydrophobic particles from an aqueous slurry.

Jan 1, 2000

By R. Q. Phillips

INTRODUCTION Since Canada commenced sulphur exports in the early 1960's, the volume of exports has grown steadily and by 1984 Canadian sulphur accounted for 45% of internationally traded sulphur. In 1984 a total of 7.6 million tonnes of Canadian sulphur was shipped to offshore markets and the U.S.A. Total shipments, including domestic sales, were 8.3 million tonnes. With a production of some 5.6 million tonnes, inventory was drawn down by nearly 3 million tonnes in order to keep pace with demand. Since 1979, world consumption has exceeded total world production and Canadian sulphur inventory has played a truly crucial role in balancing world supply and demand. Consequently, by the end of 1984 the Canadian inventory, which stood at 21 million tonnes in 1978, had been almost halved to 12 million tonnes. This inventory, however, is still by far the largest in the world and will continue to play a vital role in the world supply until expected depletion around 1990. Canada is the world's second largest producer of sulphur following the U.S.A.. The Current production level of between 5 and 6 million tonnes per annum is forecast to be maintained to 1990 with only a marginal fall in that production level in the following decade to the year 2000. This will ensure that Canada retains its position as one of the largest producers and most important suppliers of sulphur in the world market well into the future. CANADA AS WORLD SUPPLIER OF SULPHUR Since Canada commenced sulphur exports in the early 19601s, exports have grown steadily. (Figure 1) The rate of growth accelerated in recent years and in 1984 a total of 7.6 million tonnes was sold for export, compared to 3.0 million tonnes in 1975 and less than 1 million tonnes in 1964. World trade in sulphur also increased during this period, from 11 million tonnes in 1975 to 17.0 million tonnes in 1984 (Figure 2). Most of this increase in volume was accounted for by Canada and Poland. As a result, the importance of Canada as world supplier expanded from 28% in 1975 to 45% in 1984. The markets for Canadian sulphur can be divided into two broad categories, i.e., solid and liquid (Figure 3). The solid market is the largest, taking about 70% of Canadian output, virtually all of which is sold offshore. The U.S.A. and the Canadian domestic market take about 20% and 10% respectively, in liquid form. In 1984, (figure 4) total Canadian sulphur sales exceeded 8 million tonnes with offshore export sales at a record 5.8 million tonnes and sales to the U.S. of 1.8 million tonnes. Domestic sales accounted for only 0.7 million tonnes. The general trend for offshore export sales has been upward whereas there has been relative stability in domestic sales. The exceptional growth in offshore sales in the 1970's necessitated considerable capital investments by the industry in order to establish a logistics system capable of handling increasing offshore tonnages. Over 50 sulphur plants are currently operating in Alberta and British Columbia. Some of these are connected by rail, (Figure 5) the balance being generally connected by road. There are currently fourteen of the larger rail-connected plants designated as export plants, and these are equipped with sulphur forming facilities. The long distances between these plants and tidewater terminals in Vancouver is a very significant factor in complex logistics of Canadian offshore sulphur exports (Figure 6). Alberta and B.C. plants are located an average of 1,400 kilometers from tidewater.

Jan 1, 1986

By Larry D. Patts

Section 317(e) of the Federal Coal Mine Health & Safety Act of 1969 directed the Secretary of the Interior to prepare standards under which all working places in a mine shall be illuminated by permissible' lighting while persons are working in such places. Section 317(e) further provides that such Working places shall be illuminated within 18 months after such standards are promulgated. In accordance with this section of the Act, there was published in the Federal Register for December 31,1970 a notice of proposed ru1emaking which prescribed the illumination to be provided in the working p1 aces of underground coal mines. In 1ight of written comments, suggestions, and objections to this proposed ru1emaking, the proposed standards were with-drawn and reproposed in the Federal Register for Wednesday, October 27, 1971. In light of further comments, suggestions, and objections, a public hearing was held on April 4, 1974 and standards were again reproposed and published in the Federal Register for April 1, 1976. Promulgation of the final lighting standards took place on October 1, 1976 which means that the underground coal mining industry must comply with face illumination requirements by April 1, 1978. As mentioned previously, the first proposed ru1emaking for illumination of underground coal mines was published in the Federal Register on October 27, 1971. In early 1972, Consolidation Coal Company (Consol) and the United States Bureau of Mines agreed to a cooperative study of underground face illumination; Conso1 felt that expertise in this field would become increasingly important. Conso1's initial efforts in illumination were aimed at investigati.ng practical lighting systems for underground face equipment. We were concerned with installing unobtrusive lights which provided sufficient face illumination for safety, but at the same time were readily maintainable, electrically reliable, and physically sheltered from damage.

Jan 1, 1977

By M. Tarshan, M. C. Williams, T. P. Meloy

A methodology is presented for the spreadsheet solution of separation processing networks. With the methodology developed, a spreadsheet grid is used to represent networks both with and without recycle loops. In this manner, network solutions are numerically approximated by spreadsheet grid solutions. The methodology was used to explore the ramifications of networks developed by the Chinese for tungsten and molybdenum processing Nonlinear stage-transfer functions for two-component sharp separations can be used.

Jan 1, 1996

By C. Anderson, K. Nikkhah

This paper outlines the role of simulation software in design and operation of a typical metallurgical plant with mineral processing and hydrometallurgical units, to produce concentrate and pure metal. It addresses the role of simulation and mass balance software in the conceptual, feasibility and detailed design stages. It discusses the use of JKSimMet for sizing of mineral processing units, and METSIM and IDEAS for development of energy and mass balances. In detailed design of a plant, the complex interaction and variation in performance of various units makes it difficult to predict overall system performance and availability. Simulation is used to: assess operating strategies that affect surge capacities at various stages compare different ore types and mining strategies that affect concentrate product quality. optimize transportation logistics for raw materials, concentrate and metal products

Jan 1, 2001

By Richard Hogg, Heechan Cho

Investigations of long-time grinding of fine quartz (to about 80% passing 0.35 pm) in a 0.6 liter stirred-media mill are described. Breakage rates and primary breakage distributions have been determined based on extensive characterization of the ground products by laser scattering/diffraction and gas adsorption. The results indicate that, while there is qualitative similarity between the breakage parameters for ultrafine and conventional (coarse) grinding, there are important, quantitative differences. In particular, it is found that primary breakage distributions become significantly narrower in the submicron sizes. The trend can be described using double-truncated log-normal distributions in which both a maximum (breaking) size and a grind limit are specified. The breakage distributions become progressively narrower as the size being broken becomes finer. Breakage rates follow a typical, consistent pattern in which the rate decreases with size according to a simple power law. Further decrease in the rates seems to occur after very long grinding times when the entire mill contents become finer than about 1µm. The effect is explained as a result of changes in the rate/size relationship in the submicron range.

Jan 1, 1995

By J. Stachurski, N. A. Abdel-Khalek

The objective of this investigation was to compare the results of countercurrent, column cell flotation vs. conventional (mechanical) cell flotation for the cleaning of a sulfur ore (-0.5 mm, 27.43% S) and its discrete size fractions. The tests were carried out using diesel oil as a collector and alcohol as a frother. Generally, column flotation produced concentrates of higher grade. For example, column cell flotation produced a nonwashed concentrate of 65.3% S with a recovery of 84.1%. However, conventional cell flotation produced a rougher concentrate of lower grade (57.0% S) and higher recovery (92.5%). At a superficial-wash water velocity of 0.265 cm/sec, the column product grade increased to 76.4% S, with a slightly lower recovery (80.3%). However, a concentrate with a similar recovery but a lower grade (74% S) than that of the washed product was obtained after three cleaning stages with the conventional cell. The column gave superior results for the flotation of fine and ultrafine particles.

Jan 1, 1994