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By S. Aktas

The present work describes an investigation of a hydrometallurgical process for the recovery of mercury from spent silver oxide button cells. The cell paste was leached in nitric acid to solubilize silver, mercury and zinc. The optimum leaching conditions, in which mercury is entirely converted to Hg2+ ions and, therefore, does not co-precipitate with silver chloride during treatment with potassium chloride solution, were 1.0 M HNO3, 45° C, 1 hour and 200 rpm. After the silver was removed from the solution, mercury was cemented out with zinc powder with an efficiency greater than 99%. In the cementation experiments, the amount of zinc powder, shaking rate, temperature and solution pH were investigated in detail. The mercury recovery (%) increased as the amounts of zinc powder and the temperature were increased. Zinc hydroxide was precipitated from the waste solution by the addition of sodium hydroxide. The Zn(OH)2 precipitate was then converted to zinc oxide. The proposed process is proven to be simple, straightforward and environmentally friendly.

Jan 1, 2011

By M. Soderstrom

In a solvent extraction (SX) plant, stage efficiency calculations are used to determine mixer efficiency. With modern extractants and mixing equipment, it is generally taken for granted that stage efficiencies will be above 95%, but this is not always the case. Dependant on mixer/solution conditions, stage efficiencies can occasionally be low, therefore leading to higher reagent usage. Proper methods to identify when stage efficiency performance is below expectations, and ways to identify if it is an equipment or chemical issue are valuable tools for a plant metallurgist. With these tools and skills an on-site metallurgist can more quickly return their SX plant to proper operation. This paper will discuss methods for analyzing stage efficiency, evaluating factors that may affect stage efficiency, and evaluating the impact of stage efficiency on the overall operation.

Jan 1, 2010

By Frank M. Howell

Creede, one of the younger major mining camps in Colorado, grew spectacularly to a town of eight or ten thousand people in the early 1890's following discovery of rich ore in the Amethyst and Last Chance mines. Gross metal production in gold, silver, lead, copper and zinc rose to a maximum of four million dollars a year in 1893. Annual production dropped to much lower figures and ranged between one hundred and five hundred thousand dollars per year during the period from 1914 to 1940. Production reached a gross of eight hundred thousand to one million dollars per year by the mid-1950's. In the years 1953 to 1957, Steven and Ratté conducted geologic investigations which were carried on as part of a cooperative program of the U. S. Geological Survey and the Colorado Metal Mining Fund Board. In a preliminary report on the Creede District, Steven and Ratté suggested that the Bulldog Mountain Fault Zone appeared to be a favorable structure to prospect. On the basis of that recommendation, augmented by independent work done by Manning W. Cox, the property was acquired, transferred to Bulldog Mountain, Inc. and financed by an O. M. E. loan. Late in 1963 Homestake Mining Company, under a Lease and Option Agreement, backed the venture by furnishing additional funds plus management.

Jan 1, 1969

By A. Singh, C. Da Corte

"South Africa possess the biggest fluorspar reserves in the world followed closely by China. In light of the current commodity downturn this paper explores the use of Dense Media Separation (DMS) as a coarse pre-concentration method for two fluorspar deposits located in South Africa in which the dominant gangue is carbonate present in the form of dolomite and calcite. Heavy Liquid Separation indicated that conventional pre-concentration of the drill core samples from both deposits would result in unacceptably high fluorite CaF2 losses. At a maximum CaF2 loss to floats of 5% the benefit of DMS would be economically marginal and difficult to justify as a conventional pre-concentrator. In light of cashflow constraints, a twin flowsheet was proposed for the sole purposes of upfront cash generation in which the majority (67-77%) of the CaF2 would report to a high grade flotation plant in 38-41% of the mass whilst the rejects would be stockpiled for flotation at a later stage. Considering the proposed twin flowsheet approach the high grade product split was achieved using DMS and this paper documents the challenges encountered and results achieved. INTRODUCTION Fluorspar is the commercial term for the mineral fluorite (calcium fluoride, CaF2). Worldwide production of fluorspar is dominated by four countries namely China, Mexico, Mongolia and South Africa. Although South Africa is the fourth largest producer, it has the largest fluorspar reserves closely followed by China (U.S. Geological Survey, 2017a). Fluorspar is broadly categorized into two grades namely acid grade also referred to as acidspar (>97% CaF2); and sub-acid grade (ceramic and metallurgical grade) commonly referred to as metspar (=97% CaF2). Acid grade fluorspar is used for the production of hydrofluoric acid (HF) which in turn is used for the manufacture of fluorocarbons and semi-conductors in the electronics industry; metal processing; the production of insecticides, herbicides and cleaning detergents, and the manufacture of uranium tetrafluoride used to concentrate the uranium isotope 235 for use as a nuclear fuel (British Geological Survey 2010; Miller 2001). Ceramic grade fluorspar (85-95% CaF2) is used in the ceramic industry as a flux and opacifier in the production of glass and enamels. Ceramic grade fluorspar is also used to make coatings for welding rods and as a flux in the steel industry. Metallurgical grade fluorspar (60-85% CaF2) is primarily used in the steel industry as flux to reduce the melting temperature and remove impurities in steel making. Similarly metallurgical grade fluorspar is also used as flux in cement production to reduce energy consumption (British Geological Survey 2010; Miller 2001)."

Jan 1, 2018

By Robert A. Bauer

Two basic types of subsidence occur in Illinois: pit and sag / trough. Pits develop over mines less than 165 feet deep and where relatively incompetent strata are found over the mines. Sag subsidence is found over mines as shallow as 75 feet and more generally over mines of greater depths. The percentage of subsidence and angles of draw associated with sag subsidence appear to be controlled by the rock properties at each specific site. The percentage of subsidence and angles of draw are smaller where the sites are not affected by geologic structures. An investigation to determine if a time factor based on the time interval from the date of mining to the subsidence events has shown that simple correlations with time, percent extraction, average pillar stresses, and pillar dimensions is not evident in Illinois.

Jan 1, 1982

By J. W. Leonard

Since the interpolation of exploratory data 1 can be no better than sampling procedures, a series of field experiments were conducted in an effort to determine whether hand-cut channel or core washability determinations best represent continuous miner produced run of mine coal. By obtaining a core drilled to within a few feet of channels taken from an underground face and then overmining both locations; core, channels and run-of-mine coal allocations were obtained from a common sample and all allocations were subjected to identical washability determinations. In order to compare results, basic rules2,3 previously anticipated and later published by the writer were employed. The first rule states that "For any full seam washability determination, the sulfur versus ash function for increasing cumulative specific gravity float coal fractions is linear". The second rule states that "For any full seam washability determination, the recovery versus ash function for increasing cumulative specific gravity float coal fractions is logarithmic".

Jan 1, 1988

By R. L. Beatty

The Bond International Gold (BIG) Colosseum Gold Mine was discovered in 1865, but no recorded production occurred until the 1930's, with production approximately 19k9 (615 oz) of gold. The mine was closed in 1942 as a non-essential industry during World War II. The property was acquired by Dallhold Resources in mid 1986. Construction of a 1.1 million Mt carbon-in-pulp, cyanide mill started in November, 1986, and was completed in September, 1987. Minable reserves are estimated to be 9,560,831Mt (10,539,000St), with an average grade of 2.1 g/Mt (0.062 oz/st). This paper describes a general view of process flow and plant equipment, as well as a look at the maintenance and operational problems encountered in the fist six months of operation.

Jan 1, 1989

By Joyce Lappin-Randolph

In 1977, Vertical Crater Retreat (VCR) Mining was developed at the Homestake Mine and by 1983 had become a fully integrated mining method contributing 60% to total underground production. VCR has proven successful for continuous ore blocks exceeding 55,100 tons (50,000 st) with dips greater than 60" and provides a productivity average of 39 tons (35 st) per man shift (tpms) which is 92% greater than Open Cut-and-Fill. Discontinuous ore bodies, small pods, or flat structures not amenable to bulk systems are mined with Mechanized Cut-and-Fill (MCF) and have been able to achieve a 32 tpms (29 st) average productivity. Small, low grade, remnant ore bodies were not economically viable with large scale bulk techniques and couldn't support the development required for a MCF system. As a result, Homestake began researching modified bulk mining methods to increase production rates and maintain safety, while lowering costs. A modified version of VCR with significantly diminished development was prototyped in an effort to reduce initial capital investment and expedite the production phase. This modified method is called Small Block Vertical Crater Retreat (S. B. VCR). Geology The Homestake Gold Mine is located in the northern Black Hills of South Dakota at Lead. Having been active since 1876, it now extends from the surface to the 2,440 m (8000 ft) level underground.

Jan 1, 1987

By P. A. S. Manning

Eastern Jamaica consists predominantly of non-carbonate rocks reaching elevations of over 2200 m. The area is drained by a well established river network which supplies close to 30% of the sand and gravel used by the building and construction sector. Present high extraction rates and slow rates of replenishment will result in early exhaustion of this source of aggregate. A number of volcanic and carbonate rocks are being examined as a possible source of high quality aggregate which meet the requirements for all types of construction. Preliminary evaluations show a dacitic deposit to be the most suitable source for aggregate use.

Jan 1, 1998

By David K. Ingram

The objective of this U.S. Bureau of Mines investigation was to characterize overburden response due to longwall mining. Subsurface strata and surface deformations were monitored during the mining of two adjacent, 900 ft wide longwall panels in southeastern Ohio. The panels were separated by a five entry, four pillar system (about 350 ft wide). The overburden thickness in the study area ranged from 214 to 280 ft, and the extraction thickness averaged 70 in. To delineate the geology of the overburden, six coreholes were drilled along a profile line extending across the two longwall panels. Multi-point borehole extensometers (MPBX) with eight-anchors were installed in six boreholes to measure subsurface displacements. The MPBX units were continuously monitored using a data logger. During the mining of the first panel, displacement occurred in a radiating pattern beginning just above the extracted area in the center of the panel and extending upward and outward towards the surface and margins of the panel. Overburden deformation did not project over the gate road entries. During the mining of the second panel, the MPBX's showed almost simultaneous displacement, indicating that the overburden began to move as a whole unit. Again, overburden deformation was confined to the immediate panel area. At both panels, overburden movement began when the longwall face was approximately 55 ft beyond the line of MPBX boreholes. Moreover, all ground movement was complete when the longwall face was approximately 200 ft beyond the line of MPBX boreholes. This paper discusses the results of the study and identifies the characteristics of overburden deformation.

Jan 1, 1986

By C. J. Hall

An investigation of multi-shaft airflow problems by the author in 1976 (1) was presented in the hope of arousing considerable written comment, but in fact-. only one contribution (2) was forthcoming. The investigation in this paper is taken several stages fur¬ther, because the matter is of major importance in many American hard rock mines with complex networks extending over thousands of meters vertically. The examples used have all been generated thermodynamical¬ly and checked by motive column (denisty) calculations. Dry air has been used to reduce the amount of time spent on the rather complex calculations, but it has been shown (3) that the principals developed apply equally well to air/vapor/water mixtures. Initially the subject is investigated using both thermodynamic and motive column analyses. The latter part of the paper concentrates on a motive column presentation. Both methods are, of course, equally valid and give identical answers to any situation when correctly applied, as is shown in the worked examples.

Jan 1, 1980

By Dan Ifrim

Soft ground tunneling poses major challenges to the underground industry. Most of soft ground tunnels are in highly urbanized areas, often include limited cover, and include a strong trend of increasing diameters. Therefore, soft ground tunneling works can sometimes cause inevitable ground movements and settlements that may lead to damages to adjacent buildings, roads, structures or utilities; many of these being “lifeline” infrastructure assets. Tunneling operations, Tunnel Boring Machine (TBM) advance rates, and face pressure control can significantly increase or decrease such risks, depending on how well the TBM and operational parameters are applied to the ground conditions. Additionally, the risks of impacting existing infrastructure are heightened in many parts of North America because of cobbles and boulders. To date there is no standardized guideline that determines appropriate tunneling rates nor operator’s guidelines, to ensure safe tunnelling in soft ground. The paper analyzes tunneling records from completed soft ground tunnels to determine a relation between ground conditions, tunnel cover, TBM cutters maintenance and TBM advance rates. The records are discussed to draw several mitigation measures to be adopted during tunnelling, to reduce risks of settlements, over excavation or sinkholes.

Jun 13, 2021

By D. W. Gillmore

Numerous orphaned strip mines and old refuse piles scar the landscape, contributing to stream pollution and degradation of the natural environment. Field experiments to reclaim acidic surface-mined spoil and refuse banks with fly ash from bituminous coal-fired powerplants were conducted at several sites in West Virginia. Fly ash served as a neutralizing agent and soil amendment, permitting vegetation of waste lands and disposal of large quantities of ash. Reclamation of land by this method is estimated to cost about $300 per acre of leveled site, depending upon the topography of the land and quality and availability of the fly ash.

Jan 1, 1972

By G. J. Koons, J. L. Uhrie

Field density studies carried out at the Phelps Dodge Chino Mine have found that truck-induced compaction is limited to the upper 2.4 m (8 ft) of an individual lift. Hydraulic properties of material compacted to field densities were determined in a laboratory setting. Saturated flow models were then run, simulating the effect of compacted zones within a stockpile. Modeling shows that compaction can prevent solution flow through large portions of the stockpile. This implies that care must be taken to ensure that ripping is carried out to a depth of at least 2.4 m (8 ft) across the entire stockpile to achieve uniform solution flow. Uniform solution flow will result in maximum leach recovery.

Jan 1, 2002

By Stefan Medel

As a pioneer Herrenknecht started in 2018 to automate the production of tunnel lining segments. Since then, many automation processes became state of the art. Robots cleaning and oiling the moulds, hydraulic units opening and closing them fully independently. Artificial Intelligence (AI) controls the works and ensures the quality requirements. Data management has become a massive tool from a simple data collector towards a control and optimization tool. Sensors controlling concrete maturity and supporting the precast team to optimize the concrete mix. These state of the art and new innovations will be presented in this paper.

Jun 23, 2024

By J. S. Roti

Calcium-based scale precipitation is a common problem in mill reclaim waters. An accumulation of these adherent deposits can result in a rapid reduction in water flow, loss of pump efficiency and eventual interruption in ore production. Heap leach applications can also experience the added problems of plugged sprinkler heads, blinded leach pads and fouled carbon columns when scale control is not maintained. The primary cause of scaling in precious metal recovery is the relative insolubility of calcium carbonate. The presence of the calcium ion and bicarbonate alkalinity is common in almost every water source. If the temperature or pH of the water is allowed to increase, the bicarbonate breaks down to carbonate and combines with calcium by the following reaction: Ca +2 +2HCO3 ? CaCO3 + H2 + CO2

Jan 1, 1986

By Christopher Mark

Sixty years ago, underground coal mining was the most hazardous job in the United States. Roof falls killed about 100 miners every year, more than all other causes put together. Fast forward half a century to 2016, and the first year ever with zero roof fall fatalities. Just three miners were killed by roof falls during the following six years. To understand how this historic goal was achieved, this study analyzed hundreds of roof fall fatality reports covering five decades. It found that the immediate effect of the Federal Coal Mine Health and Safety Act of 1969 (Coal Act) was to reduce the riskiest activities, like needlessly going under unsupported roof. Other hazards, like large roof falls, required technological developments before they were brought under control. Roof control plans, which the U.S. Bureau of Mines had been advocating since the 1920s, fostered the necessary improvements in both the safety culture and the mining technology.

Jun 1, 2024

By Alex Lowson, Dan Tempelis

The Riverside Badlands Tunnel segment of the Metropolitan Water District of Southern California’s Inland Feeder Project, was lined with a segmented concrete primary lining and a welded steel final lining with the annulus filled with Low-Density Cellular Concrete (really a grout). The paper describes a numerical modeling technique that was developed to determine safe grout placement procedures to avoid pipe flotation, and shows the relationship between flotation and the rheology of the liquid grout. Design details of the steel liners are often not well suited to grout placement, and recommendations are given on how to improve this.

Jan 1, 2003

By D. E. Ranta, G. H. Giroux, A. W. Randall, D. A. Barr

Zinc-lead ores of the Pine Point District, Northwest Territories, Canada, are hosted in paleokarst cavities within a Middle Devonian carbonate barrier complex. Of the nearly 100 deposits found, most are irregularly distributed along two main regional stratigraphically controlled trends. The ores, which occur predominantly as open space filling, form deposits most of which average one million tonnes in size with an average grade of 10% combined zinc plus lead. Geological features related to karsting control not only distribution of deposits but also their shape, size and grade. The higher grade ore in these deposits generally occurs in a relatively small core area. Consequently, accuracy of reserve estimation is dependent on drill-hole density and understanding of karst geometry. Several case examples will be reviewed to demonstrate the relationship between shape, size and grade of deposit, geological reserves and drill-hole density, along with a discussion of geological ore reserve estimation methods.

Jan 1, 1992

By J de Cuyper, V. M. Lovell, W. Freyberger

The recovery of apatite from the phoscorite ores occurring in the Transvaal, Republic of South Africa, involves a flotation process that is particularly difficult to characterize from a fundamental point of view. However, the reagents used, (tall oil fatty acid, nonylphenyltetraglycol ether, sodium silicate, and sodium hydroxide) can successfully bring about a separation of apatite from dolomitic calcite, which is the most troublesome gangue component. Recently, it has been demonstrated with some flotation feeds that the addition of certain polysaccharides can improve the flotation significantly. It has been shown that the metallurgy obtained is closely linked to the nature of the froth, and this, in turn, is influenced, often dramatically, by the presence or absence of certain of the reagents. The character of the froth depends less on the inherent frothing ability of these reagents than on the presence or absence of fine mineral particles in the froth, and on their surface characteristics and state of aggregation. The polyglycol ether and the polysacchar- ides have been shown to affect these properties, and it is suggested that a major function of these reagents is to modulate the properties of the fine particles in the pulp, thereby changing the character of the froth and giving rise to improved results.

Jan 1, 1976