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By S. Maluadzi, D. Rocchi, S. Luyckx, S. S. Potgieter-Vermaak, C. Machio, J. H. Potgieter

The aim of this work was to compare the corrosion behaviour of thermal spray WC ? based coatings before and after annealing. X-ray diffraction (XRD) was used to determine the phases present in the coatings at various stages. The corrosion resistance of the coatings was measured using electrochemical and immersion corrosion tests. The results obtained from electrochemical corrosion (quantified by corrosion current density) and immersion corrosion tests showed that annealing appears to decrease the corrosion resistance of the coatings. From the XRD results it was determined that the phases that corroded preferentially were cobalt (Co), eta (Co6W6C) and W2C. Keywords: Corrosion, thermal spray, coatings, hardmetals.

Jan 1, 2006

By M. I. Brittan

SYNOPSIS The key reactions of the copper segregation process have been studied with a view to establishing the kinetics of the system. The investigation was carried out using two refractory copper ores from the Zambian Copperbelt in a small-scale, fluidized bed, chloridization reactor. The rate of chloridization of the copper in the ores is compared with the rate of volatilization of the cuprous chloride produced and with the rate of reduction of the cuprous chloride to form segregated metallic copper. In conjunction with available data on the rate of production of hydrogen chloride in a segregation system and with due regard to the conditions applicable in a TORCO reactor, it is concluded that the chloridization reaction is the major rate limiting step of the process. Factors influencing the rate of this extraction step and aspects of its mechanism are examined. The findings have confirmed the validity of the existing theory of segregation and provide insight as to the viability of the system of reactions involved in the copper segregation phenomenon. Experimental results which relate to observations made in the course of TORCO plant operation and segregation studies are discussed.

By K. G. Tshilombo

It should be possible to use an oxygen probe to follow iron removal during converting, if local equilibrium is established between iron in the matte and the iron oxides in the fayalitic slag. The oxygen activity is expected to increase strongly as the iron content of the matte decreases (and the iron activity in the matte drops) while the iron oxide activity in the slag remains constant. To test this idea, oxygen activities were measured in synthetic mattes (made up of mixture of Cu2S, FeS and Ni3S2) when in contact with silica saturated SiO2-FeO slags, and silica and (initially) magnetite saturated SiO2-FeO-Fe3O4slags. The measurements were performed on laboratory scale at 1250°C, using an oxygen probe consisting of a stabilized zirconia electrolyte and Fe/FeO reference, and containing the sample in a silica crucible. Electrical contact to the matte was by means of a platinum wire. The measured oxygen activity was sensitive to the iron content of the matte, and insensitive to the composition of the gas atmosphere over the melt. The measured oxygen activity was generally close to that predicted by Fact Sage calculations. This indicates that such oxygen activity measurements could be useful to monitor iron removal during converting of nickel-copper-iron mattes.

Jan 1, 2006

The Federation of Societies of Professional Engineers Our Institute is a member of the Federation and, to give members some idea of the work of the latter body, a few notes are submitted from the Federation's annual report for the year ended June 1973.

Jan 2, 1974

Papers of Interest The following papers may be of interest to members. APCOM The Thirteenth International Symposium on the Application of Operation Research and Computer Techniques for Decision Making in the Mineral Industries will be held at the Technical University CIausthaI, Federal Republic of Germany, from 6th to 11th October, 1975.

Jan 1, 1975

By J. Palarski

Long waling is used in most Polish coal seams, with backfilling to support the roof, to create an artificial hanging wall to prevent movement if the rockmass, and to eliminate the fire hazard in abandoned mine workings. This paper discusses the results if tests conducted on 7 different backfill mixtures, and gives equations for the estimation if the flow if backfill slurries through gravitational pipelines.

Jan 1, 1994

By F. van Heerden

The paper sketches the. management of the various phases in a cost-reimbursable, plus-fee contract. which is claimed to be the most flexible of all contracts. In this type of contract, the contractor is reimbursed for all the direct costs Incurred, plus a percentage fee to cover his profit (or overheads and profit). The client usually reserves the right to approve all drawings, equipment purchases. contract awards, technical specifications. project cheques and change orders.

Jan 1, 1982

By H. T. Clausen

This paper gives a brief review of the main environmental and ecological problems of slimes dams, both those created in the immediate vicinity of the dams and those influencing the region or catchment. Methods of dealing with these problems and influences on existing dams are described. The difficulties encountered in the growing of grass on steep slopes are explained, and, after an analysis of the conditions, a plea is made for flatter slopes on the sides of dams.

Jan 12, 1973

The South African Institute for Mining and Metallurgy celebrated its 95th anniversary with a banquet at The Carlton on Friday, 2nd June, 1989. This event was attended by 600 people, including the Presidents of AS&TS, constituent societies, and other kindred bodies, together with members and their guests. The guest speaker was Mr Muray Hofmeyr, Chairman of the Johannesburg Consolidated Investment Company Limited, who gave an interesting and thought-provoking talk entitled 'Will we still be the best in the year 2001'

Jan 1, 1989

By J. K. E. Douglas

Brigadier Ralph Shelton Griffin Stokes D.S.O., C.B.E., M.C., who died in England on 24th February, 1979, at the age of 96 years, was one of the most colourful personalities in South African mining history. After the South African War, in which he served as a trooper, he joined the Crown Reef Mine as an assistant assayer (1902), and was to serve the mines of the Corner House Group intermittently for the next 57 years until his retirement in 1959.

Jan 1, 1979

The FSPE Award for Services to the Engineering Profession was awarded to Or Francis George Hill at a ceremony held in January of this year by the Federation of Societies of Professional Engineers. The following is an abridged version of the citation made by Professor A.N. Brown, President of FSPE, and of Or Hill?s reply. Achievements. It is indeed fitting that such a distinguished group of people have gathered on this special occasion to honour and pay tribute to Or Pinkey Hill

Jan 1, 1988

By D. D. Marsden

The paper briefly outlines the history of the successful development of vegetating techniques for mine-residue deposits. It seeks to place on record the major roles played by M.J. Mrost, who initiated and systematically developed the concept, and W.H. Cook, who continued the trials and successfully directed a stupendous large-scale project. The vegetating techniques currently practised are outlined, and it is concluded that vegetating is still the only surface-stabilizing technique of any significance that is employed throughout the world.

Jan 1, 1987

By J. J. S. de Beer, F. Hunter, A. F. Neethling

SYNOPSIS The paper describes the rib-pillar extraction method now used at Sigma Colliery in the Orange Free State. In this method, access roadways (with a high safety factor) are developed into a block of coal suitable for total extraction; pillars that have a low safety factor are then formed and extracted immediately. The method, together with the current practices of labour management, has resulted in better utilization of the coal resources and capital, increased production and labour productivity, and improved safety.

Jan 1, 1991

By E. L. Atkinson, G. W. Leach

The paper discusses the reasons for the introduction of load-haul-dump (LHD) units into Greenside Colliery, and the circumstances leading to the replacement of conventional mechanized equipment on a trial basis in the mining operations on No. 2, 4, and 5 seams. An outline is given of the factors governing the selection and introduction of these units into coal mining, and the associated mining and engineering aspects involved in the optimization of their use. Operating statistics comparing the performance of conventional and LHD equipment are included.

Jan 1, 1979

By R. M. Göktan

A theoretical comparison is made between point-attack and wedge-shaped picks in regard to their cutting efficiencies in coals having different strength characteristics. With specific energy as a criterion of cutting efficiency, it is shown that a mathematical expression can be derived for the assessment of the relative performances of these two groups of picks as a function of coal-strength parameters and pick-tip angle. The ratio of tensile to compressive strength of coal is found to play a significant role in the determination of relative cutting efficiencies, lower ratios favouring the use of point-attack picks.

Jan 1, 1992

By B. J. Ralph, I. J. Corrans, B. Harris

In the first section, a brief background to the practical and theoretical aspects of bacterial leaching is presented. Descriptions are given of present and potential methods for exploiting bacterial leaching in metal-winning. In the second section, the results of recent research are presented. The aim of this work was to obtain a greater understanding of the mechanism of bacterial leaching of sulphide minerals. Bacteria were observed to catalyse leaching reactions by oxidising ferrous ions to ferric ions, by removing protective films at the mineral surface and by depolarising cathodic areas.

By A. J. Jager, G. R. Adams

The pattern of mining-induced fractures ahead of stope faces in deep-level gold mines, as revealed by petroscopic observations, is described. It is shown that there are zones of fractured and unfractured rock ahead of the face, which are about I m wide and continue as discrete entities for at least 12 m parallel to the face and at least 5 m vertically. These zones do not form continuously as mining progresses, but develop from time to time, leaving a solid zone between the fractured zones. The maximum depth of fracturing ahead of the face depends on the rate of energy release.

Jan 1, 1980

By A. B. Stewart, I. J. Barker

Traditionally it has commonly been believed that the only problem with inductive reactance in a submerged-arc furnace is that it leads to difficulties with the electricity supply as a result of the Iow power factor. This paper sets out to show that inductive reactance can also give rise to the following problems in the metallurgical operation of a furnace: (i) dead and live phases (fairly well known in openarc furnaces), (ii) lack of sensitivity to electrode movement, (iii) interactions between electrodes. These problems increase with increasing inductive reactance relative to resistance, and thus they increase with furnace size. Each of these effects is discussed in detail, and suggestions are made for their alleviation.

Jan 1, 1980

By R. C. Urquhart, W. P. Channon, D. D. Howat

Discussion: The mode of current transfer between electrode and slag in the submBerged-arc furnace by w. P. CHANNON, R. C. URQUHART, and D. D. HOWAT J. MEINTJES I have read the paper with much interest, and I should like to make a few observations. (I) The experimental work deals with resistance heating by an electrode immersed in a slag... AUTHORS' REPLY We thank Mr Meintjes for his critical analysis and helpful comments arising out of his study of our paper. Possibly we should emphasize at the outset that our experiments all related to the conditions in which the lower portion of the electrode was immersed in molten slag. We believe, however,

Jan 12, 1974

Measurements of the rates of penetration at various throttle air pressures are presented as a function of thrust for three different rockdrills when drilling quartzites with strengths of 45 000 lb/in2 and 39 000 lb/in2, The rate of penetration at optimum thrust is shown to agree well with the predictions of theory and curves of air consumption as a function of throttle air pressure are presented. Man-held machines are shown to be under-thrusted at throttle air pressures above 40 lb/in2g. Measurements of bit wear as a function of distance drilled are presented graphically and discussed in terms of the theory developed in Part 1.