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Advanced process and equipment analytics have been around for a while. However, with accessible IT infrastructure and site maturity, it is possible to analyse, monitor, and control processing plants and equipment easily. These various disparate systems provide different reports requiring the involvement of various personnel and attention to different reporting platforms. For efficient harnessing of the systems? capabilities, as well as effective improvement and monitoring of process and equipment, a single point of entry is required. A process and equipment optimization solution was required at a concentrator in South Africa, focussing on the product stream of platinum group metal (PGM) concentrate from the UG2 Reef. The investigation of data to identify strategies for optimization was required to allow visibility into plant operations to guide operators, an easier method to identify process loop problems, identification of imminent equipment failures, and advanced process control to optimize throughput and stability. A collaborative effort between the client and General Electric Intelligent Platforms (GEIP) investigated data-driven solutions to each of the problems. With the focus on process optimization and asset monitoring, as well as equipment monitoring, a combination of approaches was utilized to address the various problem areas that were identified. Each was implemented separately in the control layer of the plant IT infrastructure. The integration was done in a centralized web-based reporting tool that integrated the detailed results from the various solutions. On the process control side, monitoring of control loops was included by calculating performance statistics that were reported daily to identify sub-optimally performing control loops and indicating potential problems. The advanced process control solution for this site includes a surge tank controller, stabilizing flow through the flotation banks, and preventing the surge tank from overflowing or running empty. Equipment monitoring was investigated, for preventative maintenance, by making use of statistical data models to indicate imminent equipment failure. These predicted alarm events included the cause for failure, drilling down, and allowing focus on a specific variable for preventative action. The results included a more stable flow through the mill, with fewer stoppages due to surge tank overflows or running empty. The causes for process drift could be identified and operators could react early. Alarms warning of equipment failure 2½ and 4 months in advance were identified in an offline analysis.

Jan 1, 2012

By N. Wagner, P. den Hoed, J. D. Steenkamp, S. Soqinase

In pyrometallurgical processes, metal oxides are reduced from molten slag through carbothermic reduction. It is of interest to evaluate the reactivity of the carbonaceous materials towards substances such as slag. Characterization techniques such as coal petrography can provide insight into the influence of feed coal properties and how they potentially dictate reductant performance. This study aimed to compare the petrographically determined organic composition of coal to reductant reactivity. Two South African medium-rank C bituminous coals and one anthracite sample were investigated together with high-carbon ferromanganese industrial slag. The reductant reactivity tests were conducted at 1500°C in a muffle furnace to assess the potential of carbonaceous reductant in reacting with the main slag components. SEM-EDS was applied to understand the extent of MnO (and to a lesser extent, SiO2) reduction from the slag. Coal 2, consisting of a greater proportion of vitrinite (59.5 vol% on a mineral matter-free basis and 54.7 vol% including mineral matter) was the most reactive reductant. The anthracite sample, with the highest inert maceral proportions (71.8 vol% including mineral matter and 76.8 vol% on a mineral matter-free basis), was the least reactive reductant.

Feb 6, 2023

By Z. Yang, X. Bian

"The synthesis of 3-hydroxy-2-naphthyl hydroxamic acid (H2O5) as a collector for bastnaesite is described. The flotation performance of H2O5 with respect to bastnaesite was investigated by flotation tests, measurements of the surface adsorption capacity, and polarizing microscopy. The results indicated that H2O5 exhibits superior collecting performance compared with direct flotation recovery of bastnaesite, with recoveries above 90% at pH 8–9. The adsorption mechanism of H2O5 on bastnaesite was studied by solution chemistry analysis and ?-potential tests. The results showed that the adsorption of H2O5 is associated with the types and concentrations of hydrolysis products of rare earth cations on the bastnaesite surface. At pH 8–9, the hydrolysis-dominant components RE(OH)2+ and RE(OH)2 + of the rare earth cations were adsorbed onto the bastnaesite surfaces, which were considered to be the major positive active points and were beneficial to chemical adsorption of the reagents. The pH range of 7–10 was optimum for bastnaesite floatability, and the adsorption of H205 on bastnaesite was by means of chemical adsorption through formation of a five-membered ring chelate. IntroductionThe rare earth elements (REEs) have long been known as ‘industrial gold’ and are widely used in the petroleum, chemical, ceramic, metallurgical, and permanent magnet material industries because of their special physicochemical properties (Chen, 2011; Krishnamurthy and Guptac, 2002; Esquivel, Bohe, and Pasquevich, 2002; Abrahami, Xiao, and Yang, 2015). Demand for REEs is growing in response to continuous advances in science and technology. Currently, most REEs are extracted from bastnaesite ((Ce,La)CO3F) (Chelgani et al., 2015; Yosry, 1990), which is recovered from rare earth ores by flotation. Typically, hydroxamic acids are used as bastnaesite collectors (Xu, 2015; Ren, 1997; Mousumi and Venugopal, 2016). Research into the mechanism of interaction between hydroxamic acids and bastnaesite is important for improving the recoveries of bastnaesite. However, there have been few studies that examine this mechanism."

Jan 1, 2017

By Wm. Bleloch

SYNOPSIS The feasibility of rejection of nitrogen from stack gas by recycling of top-gas with cold-blast 95 to 98 per cent oxygen is assessed. It is concluded that nitrogen could be removed to a level below 3 per cent of the stack-gas using recycled cleaned cold top-gas and 95 to 98 per cent oxygen produced by a single-column air separation plant with liquid-air reflux instead of liquid nigroten reflux. The partial pressure of carbon monoxide in the stack-gas could be doubled without top pressure and the deposition of carbon and reduction of iron oxides by the stack gas could be markedly increased. It is concluded that rate of stock descent could be doubled compared with present-day practice and an iron make of 4400 kg/m 2 of hearth area/hour may be attainable with a working volume of 129 m2/m hearth diameter by this method. Oxygen consumption is estimated at possibly 280 m2 (0.4 t)/t iron made and carbon consumption at possibly 280 kg/t iron. Power consumption for oxygen including auxiliaries is estimated at 304 kWH/t 100 per cent oxygen as 95 to 98 per cent gas. The air separation cycle due to Schuftan is discussed in some detail, and the components of a 1 600 metric ton/day separation plant are briefly discussed. The paper is a theoretical essay.

The following comment has been received from Mr A. D. Osche* on the above paper, which was published in the Journal in October 1977 (vol. 78, no. 3, pp. 51-62). Obituary: T. K. Prentice The Institute records with deep regret the death on 30th January of its senior surviving Past President, Mr Thomas Kennedy Prentice, at the age of 83. Book reviews R. A. Rich, H. D. Holland, and U. Petersen. Hydrothermal uranium deposits. (Developments in Economic Geology, vol. 6). Amsterdam, Elsevier Scientific Publishing Co., 264 pp. with 77 illustrations and diagrams, 30 tables. U.S. $34,75. M. David. Geostatistical ore reserve estimation. Amsterdam, Elsevier Publishing Company, 1977. 364 pp. World mineral industry The Australasian Institute of Mining and Metallurgy is celebrating its sesquicentenary in 1979. A conference will be held in Perth from 13th to 18th August, 1979, as part of the celebrations, the theme being 'Australia's Role in the World Mineral Industry'. Engineering teaching staff UNESCO has extended its technical assistance to the Venezuelan government in the training of engineers to suit the rapidly developing economy of the country. UNESCO vacancy Vacancy for a post of expert under the UNDP. (1) Title of post: Expert in metallurgical engineering. (2) Duty station: Instituto Universitario Politecnico of Ciudad Guyana (Venezuela). Shell Design Awards The annual Shell Design Awards, organized by the Design Institute and sponsored by Shell South Africa (Pty) Ltd, focus attention on achievements in South African design.

Jan 1, 1978

Mixtures of MnO and graphite were reacted under argon at temperatures ranging from 1200 to 1425°C, and the loss in mass of the mixture was recorded continuously. The results showed that the rate of reduction of MnO increased as the temperature increased and the ratio of MnO to C decreased. The effect of the particle size of MnO and of graphite on the rate of reduction at I350°C was very small in the range 63 to 250 µm for MnO and 45 to 355 µm for graphite. The rate of reduction at I350°C was increased markedly by the addition of Na2CO2 and K2CO3, was slightly increased by the addition of Fe2O3, was unaffected by the addition of CaO, MgO, and AI2O., and was decreased by the addition of SiO2. Some CO2 was always present in the effluent gas, and this was taken as evidence that the reduction of MnO occurred by way of CO2 as an intermediate product. The activation energy of the ratecontrolling step was 57,5 kcal, and this was similar to the measured activation energy for the gasification of graphite by CO., namely, 61,S kcal per mole of graphite. A simple kinetic model was derived on the assumption that the gasification of graphite was the ratecontrolling step, and the results over the temperature range 1200 to I425°C, when plotted in the appropriate form, yielded straight lines as predicted by the model.

Jan 1, 1980

By K. H. Berget, V. Andersen, H. Tveit, R. Jensen

This paper presents some of the work carried out in order to improve the tapping process in silicon production, with special focus on the environmental and the safety standards. Some of the modelling work that has been done to improve the understanding of the process is described, together with the resulting implementation to improve tapping standards.

Jan 1, 2014

By K. A. Moxham

The ARM 1100 was described in a paper presented at the 6th International Symposium on Mine Mechanization and Automation in September 2001. It started operation underground at Rowland Shaft in early 2002. This paper covers the results of those trials that resulted in more than 1 100square metres of UG2 being mined.

Jan 1, 2004

By C. T. Connor, O&apos

The fifth University of Cape Town (UC1)/University of Stelenbosch (US) Minerals Processing Symposium was held at the Faculty of Engineering, University of Stelenbosch on Friday, 8th August, 1986. This series was initiated in 1982, the symposia being held alternately in Cape Town and Stelenbosch. The South African Institute of Mining and Metallurgy has kindly agreed to sponsor this event for the next three years. Cokemaking On the initiative of the European Cokemaking Commitee, the First International Cokemaking Congress will be held in Essen (F.R. Germany) from 13th to 19th September, 1987. It is being organized by the Steinkohlenbergbauverein, together with the Verein Deutscher Eisenhitenleute.

Jan 1, 1986

By A. Esterhuizen

Since 2005 Two Rivers Platinum Mine has set out on an initiative to actively monitor and control ground conditions on a daily basis, by making use of borehole cameras and pro-actively amending the support and mining strategies based on day-to-day observations of the hangingwall conditions. Today the borehole camera observations form part of the Rock Engineering Department?s daily function, and the size and frequency of falls of ground and ensuing accident rates have been drastically reduced since implementation of the system. The Two Rivers Platinum fall-of-ground management system aims to support 100% of the possible fallout thickness, based on ongoing data gathering and interpretation, thereby ensuring safety and limiting support cost.

Jan 1, 2014

ENERGY 73 The First International Energy Exhibition will be held in Brussels from 13th to 18th May, 1973. Vllth INTERNATIONAL CONGRESS ON CYBERNETICS This congress will be held in Namur, Belgium, from 10th to 15th September, 1973. GRADUATE SCHOOL OF BUSINESS ADMINISTRATION University of the Witwatersrand The Sixth Executive Development Programme is scheduled to take place from 2nd July to 24th August, 1973. IFAC SYMPOSIUM 1973 Second announcement ofthe International Symposium on AUTOMATIC CONTROL IN MINING MINERALS AND METAL PROCESSING to be held at the University of New South Wales, Sydney, Australia, from 13th to 17th August, 1973. MINERALS AND ENVIRONMENT The effect ofthe mineral industry on the environment and mineral resources The Institution of Mining and Metallurgy, with the co-operation of the Institute of Quarrying and the Institution of Mining Engineers, will hold a Symposium "Minerals and the environment" at the Institution of Electrical Engineers, Savoy Place, from 4th to 7th June, 1974. COLLOQUIUM ON SLlMES DAMS The South African Institute of Mining and Metallurgy have great pleasure in advising members that a two-day colloquium on slimes dams is bei ng arranged for the 14th and 15th November, 1973. INTERNATIONAL SOLVENT EXTRACTION CONFERENCE This conference will be held at Lyon from 8th to 14th September, 1974. Particulars may be obtained from the Secretary: Dr A. Naylor, British Nuclear Fuels Ltd., Windscale and Carder Works, Seascale, Cumberland CA20 IPG, United Kingdom. Competition for Student Members of the South African Institute of Mining and Metallurgy Each year the Institute offers a prize (or prizes should the entries warrant it) of up to RIOO for the best paper or dissertation on a topic appropriate to the interests of the Institute. Proceedings of the Tenth International Symposium on Application of Computer Methods in the Mineral Industry (APCOM) The Proceedings of the APCOM Symposium held in Johannesburg from April 9th to 14th, 1972, have now been published. Members of the Institute may buy the Proceedings at a special price of R12,50 as against the list price of R25,00 to non-members. Verrigtinge van die Tenth International Symposium on Application of Computer Methods in the Mineral Industry (APCOM) Die Verrigtinge van die APCOM Simposium, wat op April 9 tot 14, 1972, in Johannesburg gehou is, is gepubliseer. Lede van die Instituut kan die Verrigtinge teen 'n spesiale prys van R12,50 koop, in teenstelling met die prys van R25,00 vir nie-Iede.

By I. Wayland

Value added blasting is a process methodology that links tasks and processes, with the aim to improve/enhance the technical application of explosives technology and initiating systems, resulting in improved output. The phases and steps of a typical value added blasting intervention are discussed in this paper. Each step having distinct purposes, principles and methodology. The underlying philosophies and process steps of the programme are described for each step. This paper gives an account of projects that have been completed in two Anglo American Gold Mines. This will include a description of the projects that were conducted at Vaal Reefs 8 Shaft and Western Deep Levels South Mine covering: ? The need for blasting improvements ? The approach that was followed ? The result of the programme.

Jan 1, 1999

By R. Sun, R. G. Gillies, R. S. Sanders, J. Schaan

The pipeline transport of paste, backfill or thickened tailings slurries is an important component of the tailings disposal process in many mines around the world. These mixtures contain significant fractions of fine (clay) and coarse (sand) particles, causing them to exhibit non-Newtonian flow behaviour and high frictional pressure gradients. There is often economic incentive to operate these pipelines in the laminar flow regime. Irrefutable evidence has shown that coarse particle settling can occur during the laminar flow of these slurries even when static settling tests show no indication of such behaviour. Previously, a ?rule-of-thumb? minimum frictional pressure gradient of ~1.5 to 2 kPa/m was suggested to ensure effective sand transport, based on the results of tests conducted using viscous Newtonian oils. In this paper, we examine the results of laminar flow tests of non-Newtonian, coarse-particle laden slurries conducted with pipeline loops of 50, 100, 150 and 250 mm in diameter. The results indicate that the ratio of the mean wall shear stress to the mean surficial particle stress is abetter indicator of laminar flow settling tendency than frictional pressure gradient.

Jan 1, 2007

By N. G. Cook, N. C. Joughin, A. J. A. White

The rate of face advance in the gold mines is between 3 and 10 m a month, with a median value of about 5 m a month; it follows that faces are blasted less frequently than is planned. There are many advantages in the use of short holes for stoping to give face advances of from 0,7 to 0,8 m per blast. This has the potential for so increasing the frequency of blasting that monthly rates of face advance could be improved significantly. Cleaning with face scrapers is too slow to permit the maximum achievement of a complete clean, drill, and blast cycle for each shift. Short-hole blasting, combined with the use of mechanical conveyors for face cleaning, offers the possibility of completing two such cycles each day, yielding monthly rates of face advance of up to 35 m. Experiments aimed at developing safe, unitized explosive charges well-suited to produce reliable face advances of 0,7 to 0,8 m per blast under a wide range of gold-mining conditions have been notably successful. A novel method of assessing the effectiveness of a blast based on the percentage of holes that leave socket lengths of 5 cm or less was used. Unitized charges of 60 per cent Ammon gelignite, 600 mm long by 25 mm in diameter, appear to be near optimal. The explosive is de-sensitized to obviate detonation by chance mechanical impact, but requires only a 6D detonator for initiation; it has good water-resistance. Means have been developed for producing these cartridges automatically, but the necessary machines will have to be built specially and the cartridges are not yet available in large numbers. A second experiment by way of an extended pilot production trial using these cartridges in holes 0,9 m long is now under way. Preliminary results indicate that drilling and explosive efficiencies and productivity are well above average, even though face scraping is being used. Unitized charges of this type are likely to prove even more advantageous when mechanical face conveyors come into use.

Jan 1, 1975

Limestone formations in the United States can be subject to relatively high horizontal stresses due to the existence of tectonic loading of the limestone strata. Underground limestone mines use the room-and-pillar method, in which 12- to 18-m-wide rooms are typically excavated. The stability of these excavations can be compromised by the horizontal stress, resulting in a rockfall hazard. Rockfalls are the cause of 15% of all reportable injuries in underground limestone mines. Horizontal stress related damage can occur in the form of guttering along one or more sides of an excavation, roof beam buckling or oval shaped roof falls, with the long axis perpendicular to the major horizontal stress. Numerical analyses show that the pillar layout and orientation of the mine workings have an effect on the horizontal stress distribution within the roof. The effects of high horizontal stresses can be mitigated by orientating the heading development direction parallel to the maximum horizontal stress, reducing the number of cross-cuts and offsetting the cross-cuts to limit the potential lateral extent of horizontal stress related roof falls. The modeling approach described in this paper can be used as a tool to evaluate potential roof failure and optimize the stability of room and pillar layouts.

Jan 1, 2008

By M. K. Matthews

The use of backfill has important environmental control implications which, although frequently overlooked, can be both beneficial and problematical. Where backfill is widely used, the reduction in stope heat load and improved air utilization influence the overall mine ventilation and refrigeration requirements significantly. A programme of work examining in detail all the environmental consequences of backfilling is currently underway at the Environmental Engineering Laboratory of the Research Organization of the Chamber of Mines. This paper gives an overview of the work and presents some findings. In so doing, the environmental implications to be considered when backfilling are highlighted.

Jan 1, 1988

By K. M. Primrose

Electrical tomography has developed rapidly over the last few years in its sophistication and practical use to enable three-dimensional information on the distribution of phases within flowing mixtures to be observed1. This paper reviews the current state of application from the industrial perspective, drawing on applications case studies based on scaling studies in the laboratory right through to installations on plant. In the laboratory, applications have looked at scale-up of mixing2 processes involving gas-liquid and solid-liquid suspensions3 with a particular interest in verifying computational fluid dynamics simulations or in checking scale-up design4,5. In the processing plant, the circumstances are usually bespoke and may range from simple detection of the degree of homogeneity of a flowing mixture through to the need to measurement a sophisticated batch process such as crystallization, sedimentation, filtering and drying. Examples drawn from the chemical and pharmaceutical industries will be presented and related to the benefits that can be gained through application of the method.

Jan 1, 2008

By D. Menne

A comminution model and a quick laboratory milling test procedure are presented. These allow the determination of milling parameters for the - optimization of ball size and pulp density in operating mills estimation of the performance of new feed stocks in an existing mill - estimation of the expected milling performance for a new project. Information on the estimation of the size of mills to deliver specified amounts of comminution energy, and amount of expected ball, rod, and liner wear to allow cost estimates for new projects, is also included.

Jan 1, 1983

COUNCIL The following served on Council during the year under review Office Bearers Dr J. P. Hugo (President), P. W. J. van Rensburg and Professor R. P. Plewman (Vice-Presidents), Professor D. D. Howat (Immediate Past-President), and D. G. Maxwell (Honorary Treasurer). Ordinary Members of Council H. P. Carlisle (until February), R. C. Espley-Jones, G. H. Grange, Dr D. I. Legge, W. W. Malan, J. B. Mudd, Dr R. E. Robinson, Dr M. D. G. Salamon, L. W. P. van den Bosch, D. A. Viljoen (co-opted May 1973), and P. A. von Wielligh. Branch Chairmen A. Bain (Witbank-Middelburg Branch), C. J. Isaac (O.F.S. Branch). Past Presidents Serving on Council R. J. Adamson, M. Barcza, H. Britten, J. K. E. Douglas, R. C. J. Goode, P. Lambooy, Professor J. de V. Lambrechts, Dr J. T. McIntyre, J. F. Reid, and V. C. Robinson. Ten Council meetings were held during the year, with an average attendance of 18, and the standing committees held 29 meetings. MEMBERSHIP Twelve Fellows, ten Members, twenty-one Graduates, eleven Associates, thirty-one Students, and forty-two Company Affiliates were elected during the year. One Member was reinstated. Eight Fellows, two Members, and two Associates were admitted to retired membership. Four Graduates were transferred to Members, one Associate to Member, three Students to Members, one Graduate to Associate, two Students to Graduates, and one Student to Associate. Your Council records with deep regret the death during the year of the following : D. R. Campbell, J. Daniel, M. J. Dennehy, and F. S. C. Rogers (Life Fellows) ; W. T. balling and T. Pryor (Life Members); C. Boocock, W. Drake R. J. Moore, M. P. Pearse, J. M Pike, W. A. Schwezoff, A. I. Suss man, and L. G. S. Wright (Fellows) ; A. F. Chalmers (Member) ; and W. R. Gerry and G. T. Rimmer(Associates). A comparative statement of membership as at 30th June, 1973, and the end of the previous year it shown in the following tabulation: 30th - 30th June, - June, 1972 - 1973 Honorary Life Fellows 5 - 4 Honorary Fellows 13 - 9 Life Fellows 181 - 177 Fellows 541 - 536 Members 479 - 487 Graduates 115 - 128 Associates 182 - 186 Students 162 - 183 Company Affiliates 24 - 64 1 702 - 1 774 JOURNAL The papers that were published in the Journal during the year are listed below: August, 1972 The effects of chromium oxide, iron oxide, and calcium oxide on the liquidus temperatures, viscosities, and electrical conductivities of slags in the system MgO-Al2O3-SiO2, by M. S. Rennie, D. D. Howat, and P. R. Jochens A study of the dust exposure of South African white gold miners, by R. J. Page-Shipp and Elizabeth Harris A forecast of the coal and uranium requirements for electric power generation in South Africa, by E. J. Maunders September, 1972 Mine management by objectives, by A. A. Hazell Some aspects of the deformation behaviour and temperature rise during instantaneous compression loading of high purity aluminium, by H. J. E. Hamel Computer control of flotation at the Ecstall concentrator, by M. P. Amsden, C. Chapman, and M. G. Reading Optimizing the public gains from the exploitation of mineral resources, by A. Azis and J. Zwartendyk October, 1972 Presidential Address: Nuclear energy: its interactions with mining and metallurgy, by J. P. Hugo Presidentsrede: Kernenergie: sy wissel-werkinge met mynbou en metallurgic, deur J. P. Hugo Raise-boring experiences in the gold mines of the Anglo American Corporation Group, by J. W. Wilson and P. C. Graham November, 1972 Materials for winding plant components, by G. T. van Rooyen An analytical solution to the batch-comminution equation, by R. P. King A new approach to the study of human factors in stope productivity, by A. C. Lawrence Fundamental studies of the flotation process: the work of the National Institute for Metallurgy, by N. P. Finkelstein and V. M. Lovell Growing use of deionised water in surface coating techniques, by W. F. Lorch December, 1972 The development and application of a computer system to aid in the planning of production in mines, by F. H. Deist, L. F. Duvel, J. D. Austin, and H. D. Small PERT, and how PERT techniques can be used in modern mine management, by E. J. Boome and A. C. Schmidt A critical comparison of specific cooling power and the wet kata thermometer in hot mining environments, by J. de V. Lambrechts January, 1973 Liquidus temperatures in the Cr-Fe-Si system in the composition range representative of ferrochromium-silicide produced in South Africa, by J. C. M. Wethmar, D. D. Howat, P. R. Jochens, and O. A. W. Strydom Platinoids in the Witwatersrand System, by C. A. Cousins The development of a continuous recording scintillation counter mounted on a cyclometer, by P. D. Teens and D. Visser February, 1973 Computer analysis, modelling, and optimisation of gold recovery plants of the Anglo American Group, by M. I. Brittan and E. J. J. van Vuuren The significance of the mineralogical and surface characteristics of gold grains in the recovery process, by C. E. Feather and G. M. Keen Statistical valuation of diamondiferous deposits, by H. S. Sichel March, 1973 The effect of the reactivity of lime on desulphurisation efficiency in the basic oxygen furnace, by A. A. Hejja, D. D. Howat, and P. R. Jochens A review of real-time particle size analysers, by A. L. Hinde In situ measurements of the surface heat transfer coefficient in underground airways, by K. R. Vest April, 1973 An investigation into the kinetics and mechanisms of the oxidation of iron (II) by oxygen in aqueous chloride solutions, by R. P. Colborn and M. J. Nicol Electric smelting at Rustenburg Platinum Mines Limited of nickel-copper concentrates containing platinum-group metals, by J. C. Mostert and P. N. Roberts Metallurgical considerations in the

Jan 10, 1973

By N. B. Devi

The extraction of Cu(II) from HCl media using Cyanex 923 in kerosene was investigated. The effect of shaking time, aqueous phase acid concentration, extractant concentration, chloride ion concentration, various metal ions (Mn2+, Mg2+, Fe2+, and Ni2+), and temperature on the extraction were studied. Using 0.1 M Cyanex 923 the extraction of Cu(II) was 6.7 per cent from 3 M HCl, which increased up to 78.5 per cent with 6.5 M HCl and then decreased due to acid extraction by the extractant. The maximum extraction (97.5 per cent) was obtained with 1 M Cyanex 923 from 5 M HCl solution. A mathematical model has been developed to describe solvent extraction equllibria over wide ranges of concentration of extractant, acid, and chloride ions. The composition of the extracted species has been predicted on the basis of slope analysis results and extraction equilibrium modelling. The negative values of enthalpy change and entropy change confirm the exothermic formation of the extracted complex.

Jan 1, 2012