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By S. J. Ramokgopa

The development of the modern State and the growth of capitalism involves a complex process of interaction between cross-cutting structural dimension: first between politics and economics and, second, between market and hierarchy. Central to such developments are political economies of scale. Mineral specialization in the Third World developed within the framework of an international extension on oligopolistic structure of the advanced capitalist economies of Western Europe and North America. Up to the late 1960s, the world mineral and metallurgical industry was closely controlled by a handful of Western mining and industrial groups. To the extent that, foreign control of the mining sector was seen in the Third World producing countries both as the essence of foreign domination and as its major symbol. In some newly industrializing countries, the State took a more direct role in tying the economy and society together. Central to this process was the growth of large-scale finance capital. From early 1959to the mid-1970s, metal consumption in industrial countries expanded well beyond their domestic mineral endowments. And a free access to Third World minerals was a major element of the economic dynamism of these countries throughout that period. With the change in the characteristics of international investment, Africa has become less important as an outlet for capital exports of European countries. Actually, the African continent now receives only a very minor share of direct foreign investments of Western enterprises. International political economy is concerned first of all with the relationship between the economic and political domains across territorial boundaries. Second, attention should be drawn to the role of the State as the focus of decision-making in a system of competitive States, that is in turn, interdependent with a trans-national market economy in which mining and metallurgy are essential activities that affect the politics of the State, and how this in turn, rebounds on the politics of the international system. Understanding the role of the State must go beyond the glib pronouncements on the ?national interest?. How, and whose interest, the ?national interest? is determined, is precisely the problem. This implies a third theoretical problem that must be addressed: the linkage between the domestic and international domains (or levels of analysis), given that political-economic processes clearly cut across the lines of political decision-making constituted by the institutional structures of the State. Situating the State and economic interests within this vast ?state-society? complex that we call the global order will be a crucial problem for any theoretical approach that involves mining and metallurgy.

Jan 1, 2002

By J. H. Potgieter

The method used to assess the reactivity of lime was evaluated to gauge it usefulness as a quality control tool. The effect of particle sizes, different lime and water masses for a fixed s:l ratio and the same for various s:l ratios on the reactivity values obtained, were investigated. An attempt to introduce the amount of grit produced during the slaking reaction as an additional measure of limeís quality and reactivity, proved to be unsuccessful. It was also found that the relative amount of lime slaked during the different tests was independent of the reactivity value of the lime. The investigation confirmed the usefulness of the accepted test procedure as are liable method to measure the reactivity of lime, despite various reservations expressed from a theoretical point of view.

Jan 1, 2002

By M. F. Handley

Sequential grid mining has been employed as the primary mining strategy at the AngloGold West Wits Elandsrand Mine since the inception of stoping operations from the sub-vertical shaft system in 1988. Little has been published on sequential grid mining as a mining strategy since, and the purpose of this paper is to describe sequential grid mining, its history, its implementation at Elandsrand, and the outcome to date. The results obtained using sequential grid mining have been evaluated from seismic data, productivity statistics, and rock related accident statistics. Comparisons with neighbouring mines namely Western Deep Levels and Deelkraal, have been made to substantiate the improved conditions observed at Elandsrand, and to compare sequential grid mining directly with longwall mining in similar conditions and at similar depths. Sequential grid mMining is shown to be cost-effective, more flexible, and safer than long wall mining in similar conditions, at least on the Ventersdorp Contact Reef in the western part of the Carletonville Goldfield. More work is necessary to establish it as the favoured mining strategy at depths exceeding 3000 metres, and for reefs other than the Ventersdorp Contact Reef.

Jan 1, 2000

By A. Burger Pintér

To be meaningful the sharing of ideas about the National Environmental Management Act (NEMA) and social issues within the context of Mining and Metallurgy (M&M) requires an honest scrutiny of the M&M/social environment relationship, both past and present. It is not a secret that this relationship has been and is fraught with difficulties. Thus from all perspectives (M&M, society and environmental and social consultants) such a dissection, that highlights the realities, both good and bad, is uncomfortable. For this section of the colloquium to have any value, the honest but difficult approach needs to be taken.

Jan 1, 2000

By H. Willenberg, J. S. Coggan

ABSTRACT: Although individually both continuum and discontinuum numerical analyses provide useful means to analyze rock slope stability problems, complex failures typically involve mechanisms related to both existing discontinuities (i.e. discontinuum) and deformation and brittle fracture of intact rock (i.e. continuum). One such example is the 1991 Randa rockslide in the southwestern Swiss Alps, where failure involved several complex mechanisms, which require the consideration of progressive failure and rock mass strength degradation. This paper presents results from a series of hybrid finite-/discrete-element models directed towards the explicit modelling of brittle fracturing in natural rock slopes, enabling the modelling of progressive failure, from initiation, through to the development of catastrophic failure, transport and deposition. RÉSUMÉ: Si les modélisations numériques de type continu ou discontinu fournissent des outils utiles pour l’analyse de problèmes de stabilité de pentes rocheuses, elles montrent de sérieuses limitations lorsque des mécanismes de rupture complexes impliquent des processus liés autant aux discontinuités préexistantes qu’au développement progressif de nouvelles fractures. Ceci se retrouve typiquement dans l’exemple de l’éboulement de 1991 à Randa dans les Alpes suisses du sud-ouest, où la rupture a impliqué plusieurs mécanismes complexes nécessitant la prise en considération de la fracturation progressive ainsi que de la dégradation de la résistance des masses rocheuses. Cet article présente des résultats provisoires d'une série de modèles hybrides orientés vers la modélisation explicite de la fracturation de pentes naturelles, permettant la modélisation de fractures progressive de leur initiation jusqu’à leur développement, leur rupture catastrophique, leur transport et leur déposition. ZUSAMMENFASSUNG: Obwohl numerische Kontinuum- und Diskontinuum-Berechnungen einzeln nützliche Ergebnisse zur Stabilitätsanalyse von Felshängen liefern, sind komplexe Felsrutschungen typischerweise mit Mechanismen verbunden, die sowohl durch bestehende Trennflächen (s.a. Diskontinuum-Ansatz) als auch durch die Deformation und das Versagen intakter Felsbereiche (s.a. Kontinuum-Ansatz) bedingt werden. Ein Beispiel für einen solchen Sachverhalt ist der Bergsturz von Randa 1991 im südwestlichen Teil der Schweizer Alpen, bei dem die Rutschung mehrere komplexe Mechanismen umfasste, so dass “progressive failure” und Verminderung der Gebirgsfestigkeit in Betracht gezogen werden müssen. Dieser Artikel beschreibt vorläufige Ergebnisse einer Reihe von hybriden Modellrechnungen (Finite-/Diskrete-Elemente). Diese haben zum Ziel, explizit das bruchhafte Versagen natürlicher Felshänge zu modellieren, wobei das progressives Versagen im ganzen modelliert wird, von der Anfangsphase über die Entwicklung zum katastrophalen Versagen und den Transport und die Ablagerung der Rutschmassen.

Jan 1, 2003

By M. Hermanus, N. Coulson, N. Pillay

"SynopsisThis paper assesses the effectiveness of the Mine Occupational Health and Safety Leading Practice Adoption System (MOSH) and its potential to improve mine health and safety in South African mines. Developed by the Chamber of Mines, which represents the majority of the country's large scale mining employers, MOSH was devised to accelerate progress towards achieving health and safety milestones, which were set by tripartite agreement in 2003. The paper documents and builds on the findings of a study conducted by the Centre for Sustainability in Mining and Industry (CSMI) in 2011 that evaluated MOSH strategy, structures, and process of implementation.The study found that MOSH operated across the mining sector, was directed and dominated by experts and, despite best efforts to include other stakeholders, was led by employers. Statutory worker health and safety representatives and structures were not integrated into the complex change process developed by MOSH. The Mine Health and Safety Inspectorate (MHSI) and organized labour were ambivalent about direct involvement in MOSH and preferred regulatory measures to enforce the participation of mines. MOSH interventions were not targeted at mines with a poor health and safety record, and MOSH lacked a baseline from which to track impacts on sector-wide health and safety performance. The leading practices most widely adopted by mines were designed to improve, rather than fundamentally alter, existing practice. Although the depth of engagement with MOSH among stakeholders and on mine sites varied, mining companies, labour representatives, and the Mine Health and Safety Inspectorate (MHSI) saw the programme as significant.IntroductionIn 2011, the Chamber of Mines commissioned the Centre for Sustainability in Mining and Industry (CSMI) to evaluate the progress and effectiveness of the rollout of the Mine Occupational Health and Safety Leading Practice Adoption System (MOSH). CSMI, based in the School of Mining Engineering at the University of the Witwatersrand, is an independent research centre conducting health and safety research relevant to all major stakeholders in the mining sector. The purpose of the evaluation was to identify the factors that enabled or hampered the adoption of new technologies or practices. The timing of the evaluation, two years before the deadline for the 2013 safety and health milestones, allowed time for adjustments to be made. This paper summarizes the results of the evaluation and includes further analysis and discussion of the nature of the programme and the conditions that act to advance it or it hold back."

Jan 1, 2015

By K. I. Afewu

A modified approach to the implementation of Gy?s sampling theory is discussed and used to design a procedure for sampling crushed gold ore feed to metallurgical process plants. The approach involves calibration of certain ore-specific parameters. These parameters were calibrated for two different crushed gold ores en route to grinding mills in process plants. The model predictions were compared with the predictions from Gy?s original model. Far smaller masses of samples are required by the modified model than by Gy?s model at the same relative variance. The representativeness of the sampling procedure if normally distributed errors are assumed was also calculated. These procedures and evaluations lead to significant savings on cost of handling and preparation of the samples and to a quantifiable degree of confidence in the analytical results for the process plant.

Jan 1, 1998

By L. Li

The performance of microemulsified diesel and conventional diesel collectors in coal flotation was compared by flotation indicators, including combustible recovery, ash content of the clean coal, and the flotation index. An efficient separation with lower dosage was obtained using the microemulsified diesel collector. Under optimum separation conditions, the microemulsion consumption was 100 g/t less compared with diesel. The saving in diesel consumption using the microemulsion reached about 70%, disregarding the consumption of the surfactant and cosurfactant. Frothing tests showed that the frother dosage was decreased by using the microemulsion collector, because of the surfactant and cosurfactant added during preparation. The microemulsified diesel collector is superior to the conventional diesel collector in terms of diesel consumption and separation efficiency, but the selectivity requires further improvement. Keywords froth flotation, microemulsified collector, coal.

Nov 1, 2013

Existing processes for the recovery of platinum group metals (PGM) from UG-2 ores place stringent requirements with regard to chromite content upon feed material to the plant. An alternative hydrometallurgical process for which this is not an issue is proposed that involves reductive roasting of the ore followed by leaching with HCl/chlorine, ion exchange, and recovery of PGM from the ion exchange eluate by reduction. Problems associated with leaching of PGM are discussed and results of laboratory testwork for each of the process steps are given.

Jan 1, 2004

By M. S. M. Aljuhani

In this paper, one of the human factors that affect productivity in an underground gold mine in Saudi Arabia was investigated and analysed for the purpose of improving productivity. The human factor that was investigated is labour utilization and labour productivity. In the selected mine, labourer?s performances were measured carefully. It was found that in this mine, workers spend only 65% of the shift time in a productive work, and they spend 35% of the shift time in non-productive activities. As a result, recommendations were presented to enhance productivity in the selected underground gold mine by enhancing labour utilization.

Jan 1, 2002

By D. E. Ng?andu

The experience of Mufulira concentrator, of the Zambia Consolidated Copper Mines Limited, with underground mine drainage water, which is used in milling operations is discussed. It is shown that the underground mine water has a deleterious effect on flotation performance. The adverse effect of the underground water was successfully negated by adding lime into the primary ball mills and increasing the pH of the slurry, from a ?natural? pH of 8 to the flotation pH of 10.5. Traditionally, the pH modifier, quicklime, had been added downstream of the milling. Changing the lime addition point further reduced lime consumption by 50%,?a key issue as lime accounted for over 60% of the Mufulira flotation reagent costs. The nature of the effect of the underground water at Mufulira, particularly the sensitivity of the flotation to the pH at which the milling was conducted, characterized galvanic interaction. A large-scale plant situation is presented in which the desired electro-chemical response in the flotation was achieved, by a deliberate manipulation of the milling environment. The experience provides practical testimony of a more fundamental role for the milling process, other than the mere physical preparation, i.e. size reduction and liberation, of mineral particles prior to flotation.

Jan 1, 2001

By S. Sakurai

We discuss the mechanical characteristics of underground structures that are subjected to vertical oscillations. Under such circumstances - expected when an earthquake rupture occurs very close to highly developed urban areas - the conventional seismic analysis, which mainly considers horizontal shear oscillations, may not be fully valid. Our analysis, based on the elastic wave theory, shows the effects of vertical disturbances and the generation mechanism of the unique damage patterns observed on the occasion of the 1995 Hyogo-ken Nanbu (Kobe) Earthquake. Wir diskutieren über die mechanischen Eigenschaften der unterirdischen Strukturen, die sich vertikalen Schwingungen aussetzen. Unter solchen Umständen - erwartet, wann ein Erdbebenabbruch sehr nah an hochentwickelten städtischen Bereichen geschieht - kann die herkömmliche seismische Analyse, die sich hauptsächlich horizontale Schubbewegungen überlegt, möglicherweise nicht völlig gültig sein. Unsere Analyse, basiert auf der elastischen Wellentheorie, zeigt die Effekte der vertikalen Bewegungen und den Erzeugungsmechanismus der einzigartigen Beschädigungsmuster, die anläßlich des 1995 Kobe Erdbebens beobachtet wurden. Nous discutons les caractéristiques mécaniques des structures souterraines qui s’exposent aux oscillations verticales. Dans ces conditions - s’attendent quand une rupture de tremblement de terre se produit tout près des secteurs urbains fortement développés - l’analyse séismique conventionnelle, qui considère principalement des oscillations horizontales de cisaillement, peut ne pas être entièrement efficace. Notre analyse, qui est basée sur la théorie des vagues élastiques, montre les effets des mouvements verticaux et le mécanisme de génération des modèles uniques de dommages, que nous avons observés à l’occasion du tremblement de terre 1995 de Kobe.

Jan 1, 2003

By S. N. Opperman

Testwork at Goedehoop Colliery showed that fine coal, essentially?150 microns can be successfully beneficiated using froth flotation. Both conventional and column flotation were tested. It was found that the traditional stirred tank type of flotation machines used in conventional flotation produced the best recovery of fine coal. After extensive testwork it was decided to develop a flotation machine on Goedehoop Colliery that would combine stirred tank and quiescent column technology. It was thought that this design would give the best combination of recovery and selectivity. The Multicell was developed and is producing results acceptable for Witbank coal flotation. Keywords: Multicell, Witbank coal flotation, froth, stirred tank, quiescent column.

Jan 1, 2002

By Marco Barla, Mariacristina Bonini, Giovanni Barla

ABSTRACT: The paper describes the characterisation studies of Tectonised Clay Shales at laboratory and in situ scale. The interest relates to tunnelling under squeezing and swelling conditions, in Italy, along the Apennines. The results of monitoring during full face excavation are presented in conjunction with numerical modelling. RESUME: Cet article présente la caractérisation, à l'échelle du laboratoire et in situ, des Argiles Chaotiques. L'attention est portée sur le creusement, dans ces milieux gonflants, des tunnels, dans les zones montagneuses des Appennini, en Italie. Enfin, on présentera les résultats de la modélisation numérique et la comparaison de ces derniers avec les mesures effectuées in situ. KURZFASSUNG: Die Arbeit beschreibt die Charakterisierungsstudien von tektonisierten Schiefertonen, sowohl im Labor als auch vor Ort. Das Interesse gilt dem Tunnelbau unter Quetsch- und Schwellbedingungen in Italien entlang der Apenninen. Die Überwachungsergebnisse des ganzflächigen Ausbruchs werden mit numerischen Modellen präsentiert.

Jan 1, 2003

By F. H. Cornet, D. Ask, O. Stephansson

We have conducted a stress analysis of overcoring stress measurements undertaken at the Zedex Test Site (ZTS) in the Äspö HRL, Sweden. Two different types of overcoring cells have been used at the site: the 9-gauge Borre Probe (CSIR-type) and the 12-gauge CSIRO HI cell. Inversion programs based on the least-squares criterion were developed and calibrated. The primary and secondary stress field in the ZTS were back-calculated using strain data from individual cells as well as from combining data from both cells. We propose that the combination of strain data from the two cells significantly improves the determination of the stress field. A striking result is the good agreement between the re-analysed overcoring data and the existing hydraulic fracturing data. The deviations for the horizontal stresses between the re-analyzed overcoring data and the existing hydraulic fracturing data are approximately 3 MPa. The deviation in the orientation of maximum horizontal stress is approximately 10-20°. Nous avons analysé les résultats de mesures de contrainte par surcarottage réalisées sur le site Zedex, du laboratoire souterrain HRL d’Aspö, en suède. Deux types de cellule de mesure ont été utilisés sur ce site : la cellule à 9 jauges (du type CSIR) et la cellule à 12 jauges (du type CSIRO HI). Un programme d’inversion mettant en œuvre une norme par moindres carrés a été développé et validé. Les champs de contrainte primaires et secondaires du site Zedex ont été évalués d’une part en considérant chaque mesure isolément, d’autre part en intégrant l’ensemble des données de déformation dans une inversion unique. Nos résultats suggèrent que l‘association des diverses mesures dans une intégration unique améliore nettement la détermination du champ de contrainte. Un résultat intéressant est le bon accord entre ces nouveaux résultats et les résultats des mesures par fracturation hydraulique. Les écarts sur l’amplitude des contraintes horizontales est de l’ordre de 3 Mpa, les écarts sur les orientations de l’ordre de 10-20°. Auf dem Zedex Test Gelände im Äspö Festgesteinslabor (HRL) wurde eine Spannungsanalyse mittels Overcoring Spannungsmessungen durchgeführt. Hierzu wurden zwei verschiedene Methoden verwendet: das 9-kanal Borre Gerät (CSIR- Ausführung) und die 12-Kanal CSIRO HI Zelle. Inversionsprogramme, die auf dem “least-squares”- Kriterium basieren, wurden entwickelt und kalibriert. Das primäre und sekundäre Spannungsfeld des Zedex Test Geländes wurde sowohl aus Verformungsdaten individueller Zellen als auch aus Kombination beider Zellen ermittelt. Wir nehmen an, daß die Kombination der Messergebnisse beider Geräte die Bestimmung des Spannungsfeldes signifikant verbessert. Überzeugender Beweis hierfür ist die gute Übereinstimmung der überprüften Overcoring Daten und Ergebnisse aus existierenden Hydraulic Fracturing Versuchen. Die Abweichungen der horizontalen Spannungen aus beiden Datensätzen ist etwa 3 MPa und Abweichungen der Orientierung der größten Horizontalspannung liegen bei etwa 10-20°.

Jan 1, 2003

By M. K. Elmouttie, G. V. Poropat

The analysis of structure using joint set statistics is well known. Other data such as the position of discontinuities and the contacts between rock mass units cannot be easily incorporated in simple statistical analysis based on orientation alone. Algorithms to model the structure of rock slopes using measurements of the orientation and position of discontinuities are being developed by CSIRO Exploration and Mining. These algorithms provide a capability to model the structure of a rock slope and estimate the likelihood of the formation of hazardous blocks in existing or proposed rock slopes and identification of the location and size of these blocks. The algorithms provide the basis of structural modelling to identify potential failure mechanisms in rock slopes.

Jan 1, 2006

By U. Singh, E. T. Brown, J. Coxon

The rapid fracturing and deformation that occurs around excavations during rock bursts demand that support and reinforcement systems have both deformability and damping capabilities. The energy demand and supply approach currently used in design is considered to be too simplified to represent adequately the rock burst process and the support and reinforcement system requirements. Momentum change may be a necessary second criterion for the analysis of dynamic loading situations. At the St Ives Gold Mining Company, DE plates made from conveyor belt rubber, and dynamic cables with sliding anchors have been developed and used to improve the dynamic performance of support and reinforcement systems. La fracturation rapide et la déformation qui se produisent autour des excavations lors de coups de terrain demandent que les systèmes d’armature et de support soient déformables et aient une capacité d’amortissement. L’approche basée sur l’énergie actuellement utilisée pour la conception est considérée être trop simplificatrice pour représenter adéquatement les coups de terrain et les paramètres de conception des systèmes d’armature et de support requis. Le changement de quantité de mouvement pourrait être un second critère nécessaire pour l’analyse des cas de charge dynamnique. St Ives Gold Mining Company a développé et utilisé des plaques « DE » constituées de caoutchouc de courroie de convoyeur et des câbles dynamiques avec ancrage coulissant afin d’améliorer la performance dynamique des systèmes d’armature et de support. Die ploetzliche Rissbildung und Verformung, die sich in Baugruben waehrend eines Felseinbruchs ereignet, verlangt Stuetz- und Verstaerkungssysteme, welche verformbare und mildernde Eigenschaften aufweisen. Die derzeitlich gebraeuchliche Methode den Entwurf auf den Energiebedarf und dessen Abdeckung zu basieren, wird als eine unannehmbare Vereinfachung betrachtet, da sie den Felseinbruch und die benoetigten Unterstuetzungs– und Verstaerkungssysteme unzulaenglich darstellt. Die Aenderung der Umstaende kann einen zweiten Ansatz fuer die Analyse der Lastsituation erforderlich machen. Die St.Ives Gold Mining Company hat DE Platten aus Foerderband-Gummi und elastischen Kabeln mit verschiebbaren Verankerung entwickelt und dazu verwendet, die dynamische Kapazitaet der Unterstuetzungs- und Verstaerkungssysteme zu verbessern.

Jan 1, 2003

By J. Szlazak, A. Tor, M. Borowski, N. Szlazak, D. Obracaj

This article presents the analysis of ventilation systems used in dead-end headings, while being drilled, in coal mines. Special emphasis is put on methane and dust hazard. Mathematical model for distribution of methane concentration in a heading is given as well. This model takes into consideration sources of methane emission and change in air flow rate due to leaks in a duct line. Solving equations presented in this article enabled giving dependencies describing distribution of concentration along the heading. On the basis of these dependencies there is a possibility of determining places with higher methane concentration and ways of combating this hazard. Determining the distribution of methane concentration in dead-end headings ventilated by a separate ventilation system is of great importance as far as work safety conditions are concerned. The information obtained may be of use when finding proper places for installing methane sensors. Three kinds of separate ventilation systems were distinguished: forcing, exhaust and overlap. The development in construction of fans and spare parts of a duct line enables using both forcing and exhaust ventilation systems in headings developed by continuous miners, with length above 1000 m, in the conditions of methane, temperature and health-detriment dust hazards.

Jan 1, 2003

By J. D. de V. Louw

Introduction Zircon is a natural occurring mineral and may exhibit natural low level radioactivity. It contains trace levels (90 to120 pCi/g and 110 to 115 pCi/g respectively or 3.3 to 4.4Bq/g and 4.1 to 4.3 Bq/g) of naturally occurring radioactive uranium and thorium. This mineral is often found in a suiteof minerals (rutile, ilmenite and monazite) Due to the overlap in physical properties of monazite (containing 4–7% thorium) with some of the zircon (slight magnetic susceptibility) it often contaminates the zircon, adding to the levels of thorium in the product. Hazards associated with the products from zircon and its processing is inhalation of respirable dust (generated by milling) containing radioactive uranium and thorium which may cause cancer of the lungs. Legislature regulates the transport, use, workplace environment exposure and storage of radioactive material. In America the general regulation for the unlicensed use of low levels of radioactive materials limits the concentration to 500 ppm (U plus Th). Europe (IAEA) specifies a limit of10 Bg/g (Bequerels per gram) on the parents for transport only which is a higher level of U+Th. Companies selling into these markets need to comply with these regulations and certification is therefore required, not only of the major constituents determining the price, but of the U and Th levels as well. Exceeding the limits for U and Th may result in material being returned to the country of origin. However, for the analyst the requirement is to analyse for these elements throughout the production process as well as the analysis of the ‘tails’ that is returned to the mine area. This requires a wide range of concentration to be analysed. Methods of analysis A wide variety of methods exist for the analysis of U and Th in a range of matrices. (Table I) All these methods have been used with varying degrees of success in terms of accuracy. Overall precision for the different techniques varies from 5 to 25% relative. Time to produce results from these methods vary from a few minutes to several days. The Production Chemist is expected to produce between5 and 10 analyses per hour for process control purposes. A suitable technique that fits this requirement is X-Ray Fluorescence. Both Wavelength Dispersive (WDXRF) and Energy Dispersive X-Ray (EDX) instruments are suitable. X-Ray analysis in general has a few major advantages over competitive techniques. •It is fairly simple to set up and interferences are known and easy to correct •It has multi-element analysis capabilities •Clean spectral lines for U and Th (in zircon specifically) •Uncomplicated and easy to measure background •Low detection limits (3 to 5 ppm) •A very high degree of precision •Sample preparation is uncomplicated and fast (pressed powders and fused beads). In Zircon (ZrSiO4) processed sands the matrix is constant(>99% ZrSiO4) and the background is thus essentially constant. A typical set up for the analysis of U and Th by WDXRFis given below: X-Ray Tube Tungsten (W) Target, 2.5 to 3kW operated at 50mA/50kV Crystal LiF200 (or LIF220 for higher resolution) Analytical Lines (2?)U La1,226.14Th La1,227.47 Detector Scintillation Counter Analysis time, depending on the concentration can vary from as little as 20 seconds up to 5 minutes. Standards As with any other comparative technique XRF analysis relies heavily on the quality of the standards used. Assuming proper set-up and operation of the instrumentation as well as consistent sample preparation, accuracy is determined by the quality of the initial calibration standards. A search for the available zircon certified reference materials (CRMs) shows that there are only a few CRMs

Jan 1, 2003

By Y. -J. Park, K. -H. You, Y. -T. Choi, Lee. H. -W.

Many large caverns are being constructed in great depths in Korea mainly for the storage of oil and LPG. These caverns are mostly located near the port where rock conditions are reasonably good. In some instances, the horizontal stress is very high and endangers the stability of the cavern. The purpose of this study is to assess the stability of large caverns excavated in a rock mass with high horizontal stress where Ko value is close to 3. Result shows that stress exerted in the shotcrete at crown exceeds allowable value when the 3rd bench is excavated. Also found is the tensile failure of shotcrete near the boundaries between benches. In Korea werden viele grosse Kaverne fuer Aufbewahrung vom Oel und Fluessiggas in grosser Tiefe gebaut. Am Meisten befinden sich diese Kaverne in der Naehe von Haefen, wo der Fels gute Verhaeltnisse zum Bauen einer Kaverne besitzt. In einigen Faellen ist die Horizontalspannung sehr gross und dadurch wird die Stabilitaet vom Kaverne gefaerdet. Der Zweck dieser Arbeit ist die Stabilitaet des im Fels gebauten grossen Kavernes mit hoher Horiaontalspannung zu schuetzen, wo Ko-Wert sich auf 3 naehrt. Die Ergebnisse zeigen, dass die Spannung im Spritzbeton an der Krone den zulaessigen Wert ueberschreitet, wenn das dritte Bank ausgegraben wird. Im Bereich des Spritzbetons zwischen Baenke wurde das Zugversagen festgestellt. Des larges cavités nombreuses sont en train d’être construites en grand profondeur en Corée prin-cipalement pour le stocage du pétrole et LPG. Ces cavités sont pour la plupart situées près de la porte oú les conditions des roches sont résonablement bons. En quelques cas, la contrainte hori-zontale est trés haute et met en danger la stabilité de la cavité. L’objet de cet étude est d’estimer la stabilité des large cavités excavées dans une masse de roche ayant une haute contrainte horizontale oú la valeur de Ko est proche à 3. Le résultat montre que la contrainte exercée dans le shotcrete à la couronne dépasse la valeur admissible quand le troisième banc est excavé. En plus une faillite en tension du shotcrete près de la frontière entre des bancs est trouvée.

Jan 1, 2003