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By Arthur M. Hartstein

The Bureau of Mines through contract with Ultrasystems, Inc., obtained gram per gram data of products formed on thermal oxidative degradation of selected compositions, both under dynamic and static conditions. Four broad classes of materials were studied! Polyvinyl chloride compositions, neoprene compositions, rigid urethane foams, and variously treated woods. Whenever possible, comparisons between pure components and composites were attempted. Thermogravimetric and differential thermal analyses were performed to gain understanding of the processes occurring and to explore the feasibility of using these analyses as a method of material identification. The toxic products detected and quantitated included HC1, H2S, CO, S02, CS2,COS, HCOOH, CH3COOH, formaldehyde, acrolein, C 6H6, chloroprene, chloroethanol, benzyl chloride, aniline, and furfural.

Jan 1, 1974

By J. D. Noll

The Mine Safety and Health Administration (MSHA) has promulgated rules to limit the exposure of metal/nonmetal underground miners to diesel particulate matter (DPM). These rules have resulted in many types of control tech­nologies being implemented including diesel particulate filters (DPF). The passive type DPF is the most desirable because it requires little maintenance and it regenerates while the vehicle is operating. One problem with passive DPFs is that many vehicles cannot develop the sustained exhaust temperatures needed to initiate DPF regeneration, and thus it is required that the DPF be catalyzed to decrease the temperature needed for regeneration. In some past studies, such catalyzed filters have been shown to cause an increase in the nitrogen dioxide concentrations in the exhaust, resulting in a potential health hazard. In this study, a lightly catalyzed DPF along with a fuel-born catalyst were employed to help reduce the DPM emissions from a 980F loader used for cleanup in a stone mine. After 30 days of use, the filter continued to regenerate successfully at the exhaust temperatures generated by this loader, substantially reduced DPM concentrations emitted in the exhaust, and did not cause a measurable increase in nitrogen dioxide levels that could be attributed to the device.

Jan 1, 2009

By Kevin Michael, David C. Byrne

In previous issue of Spectrum (October 1999, 16/4), a system of measuring the attenuation provided by insert-type hearing protectors was described, That report described experiences using the FitCheck (Michael & Associates, Inc.) system in a pilot project involving the steel industry during 1998.[ ]

Decrease dust concentra¬tions of longwall face workers by keeping them up¬wind of the headgate stage loader and crusher. Approach Direct the face airflow from tailgate-to-headgate, the direction of coal transport. How It Works Ventilation is the primary method of dust control on longwall faces, and the most effective ventilation control is to put workers upwind of dust sources. Recent ad¬vances in longwall dust sampling by the Bureau have shown that on some faces, the headgate crusher and transfer points are signifi¬cant sources of dust -some¬times making up more than half of the total dust to which the face workers are exposed. Also, when the air is coursed from head-to-tail, the relative velocity between the air and moving coal on the face conveyor can cause dust entrainment from the conveyor, particularly if the coal is dry. On the faces where these dust sources are a signifi¬cant problem, they may be eliminated by coursing the air from tailgate-to-headgate, provided that the mine roof is stable enough to permit the necessary intake of the tailgate along with an aux¬iliary intake at the headgate.

Jan 1, 1982

By C. M. McCulloch

A series of geological surveys were completed in six coal mines in connection with a Bureau of Mines research program on methane control. The aim of these surveys was twofold: First, to study the overall geology of the coalbed, and second to use the resulting data to evaluate the influence of the geological characteristics of the coalbed on safe and efficient coal extraction. This report explains the advantages of geologic maps and fence diagrams in coal mining, and how the knowledge gained from such geologic investigations of mines can help control many underground problems.

Jan 1, 1975

By F. Garcia, J. Cervik

The cross-measure borehole technique has been shown by the Bureau of Mines to be an effective method of controlling methane liberated by fracturing the roof strata in longwall gobs where overburden is less than 750 ft (229 m). Boreholes are drilled into roof strata before mining operations affect the roof strata. Longwall mining fractures the roof strata and releases methane from source beds. Surface exhausters or vacuum pumps are used to draw the gas to the surface through an underground pipeline and vertical exhaust hole. The captured methane is thus prevented from entering the mine's ventilation system. About 71 pct of the methane produced by longwall mining in the Lower Kittanning Coalbed was captured by the cross-measure boreholes. Borehole spacing is an important factor affecting the performance of the technique. Interference tests and measurements of methane flows in return air indicate borehole spacing in the Lower Kittanning Coalbed should be limited to about 200 ft (61 m) except on the first 600 ft (183 m) of the longwall, where spacing should be reduced to about 100 ft (30 m) to capture the large quantities of methane released when the first large roof fall occurs. Comparisons between measured and calculated gas pressure differentials on boreholes indicate borehole length can be reduced from 280 to 140 ft (85 to 43 m), which reduces drilling costs significantly. Additional experimentation is necessary to verify the calculations.

Jan 1, 1985

By D. A. Wilson

A process was developed on a laboratory scale in which a solid waste byproduct from refining of secondary lead was converted into three valuable products. Roasted lead blast furnace matte was leached with water to recover copper. This was followed by brine leaching to recover lead. Residues were finally smelted to yield pig iron. Copper was precipitated as cement copper and the lead product obtained was a mixture of pure 3PbO.PbC12.xH20 and Pb(OH)C1. Copper recovery was 89 percent and lead recovery was 96 percent.

Jan 1, 1967

Provide the technology to remotely control a thin¬-seam continuous mining machine from a safe location hundreds of feet outby the working face in an underground room-and-pillar mine. Background and Approach Hard-wired or radio remote control of continuous mining machine has been commercially available since the early 1970's. This type of remote control, in low and high coal seams, situates the machine operator offboard, but within direct view of the underground coal face, Although positioned under supported roof, the operator can still be exposed to face area hazards that include roof-rib falls, dust, methane explosions, and equipment congestion. The U.S. Bureau of Mines approach has been to put the operator into a protected compartment at a location away from the working face. Since 1979, the Bureau has investigated innovative methods to better protect face area workers in under¬ground room-and-pillar mines. In 1989, the Bureau demonstrated an offboard, computer-based remote con¬trol system in a West Virginia highwall mining operation that stationed the operator hundreds of feet away from the working face. In late 1992, much of this technology, plus improvements, Was used to demonstrate, on the surface, how a thin-scam continuous mining machine could be remotely controlled 200 feet from the machine in a 36-inch working height.

Jan 1, 1992

By A. Mayton, A. Brien, W. Porter, O&apos

In 2004, management at Unimin's Gleason, TN operation began implementing ergonomic interventions specifically targeted to reduce risk of musculoskeletal injuries (MSIs). Together with corporate and site management, Unimin identified work site hazards and began to modify work practices/equipment. Some interventions were relatively simple and were implemented immediately. Others, like improvements to a mobile shredder, were more complex but were eventually resolved through a participatory approach with employees, management, manufacturers and NIOSH. This paper discusses ergonomic interventions that were successfully implemented using a bottom-up approach to reducing the risk of injury.

Reduce longwall shearer operators' dust exposures by more effectively suppressing the dust generated by the upwind cutting drum. Approach Direct more of the shearer water supply to the upwind drum, thus reducing the shearer operator's exposure to respirable dust while making more efficient use of water. How Proportioning Permits More Efficient Use of Water On most longwall mining operations, the cutting action of the shearer drums is the primary source of dust. Al-though the amount of dust generated is directly related to the amount of coal and rock cut by the drum, the exposure or the shearer operators to dust depends more on their work position relative to the upwind drum. When cutting with the airflow, the upwind drum, cutting bottom coal and floor rock, is the primary generator of dust reaching the operators. The lead drum is downwind of both shearer operators and is thus of less concern. (See diagram). When cutting against the airflow, the lead drum is upwind-taking a full cut, including roof rock-and both shearer operators may be exposed to very high levels of respirable dust. Currently, water sprays mounted on the cutting drum provide the most effective method of controlling dust from longwall shearer drums, and all longwall mining operations use some type of bit flushing or cavity filling water spray system on the cutting drums. Bureau surveys of longwall operations, conducted as part of its research program to reduce respirable dust, have indicated that six longwalls with better than average compliance records use higher than normal water flowrates to the cutting drums. The average water flow to the shearers at these six operations was approximately 60 gpm-about 50 percent more water than is normally supplied to double-drum longwall shearers.

Jan 1, 1982

By Donald O. Capstick

A mineral survey of a 13,525-acre portion of the 21,875-acre Owyhee Canyon Wilderness Study Area in northern Nevada was conducted by the U.S. Bureau of Mines in 1984. Two samples from sand and gravel deposits in the study area contained minor placer gold typical of the Owyhee River area. The gold-bearing gravels are too low grade or of insufficient volume to support commercial placer mining operations. The sand and gravel deposits might have minor local construction uses.

Jan 1, 1986

By J. Torma-Krajewski, M. Lehman

In 2005, NIOSH and Badger Mining Corporation entered a partnership to implement ergonomic interventions, including a systematic process, to address exposures to risk factors that may result in musculoskeletal disorders or other types of injuries/illnesses. As a result of this partnership, an ergonomics process was integrated with the existing safety and health program to promote an on-going application of ergonomic principles, and over 40 task-specific interventions were implemented during the first year of the process. This paper presents details of the process integration, and several examples of task-specific interventions that reduced exposures to risk factors.

By Richard J. Bielicki

Poor mixing of methane and air at coal mine working faces causes fluctuating methane concentrations. If these fluctuations are large enough, methane levels can periodically exceed safe limits, even though the time average methane concentration may be satisfactory. Concentration fluctuations measured underground can result both from variations in methane emission rate and poor mixing. The present paper reports on a statistical analysis of fluctuations at a constant methane emission rate, that is, on fluctuations due only to poor mixing. A full-scale model of a working face was used. Both peak heights and elapsed times between peaks were evaluated. Good mixing was indicated by normal, Poisson, and exponential distributions while poor or incomplete mixing was indicated by log-normal or gamma distributions.

Jan 1, 1974

Reduce longwall intake contamination by controlling respirable dust generated by the stage loader. Approach Install a water-powered scrubber on the stage loader immediately outby the crusher. Dusty air from the crusher is drawn through the scrubber and a clean air discharge is delivered into the primary face airflow. How It Works The contamination of intake air is a significant dust control problem often overlooked on many longwall faces. This dust source contributes to the full shift dust exposure of all face personnel, and thus can significantly affect compliance with Federal regulations. Several sources contribute to contamination; however, dust generated by the stage loader crusher is the single largest source. The breaking action of the crusher generates a tremendous quantity of dust, which mixes with the primary ventilation airstream and is carried down the entire length of the longwall face. The installation of a water-powered scrubber (see diagram) has proven effective in controlling crusher-generated dust. The scrubber is mounted immediately outby the crusher. A duct is placed over the scrubber intake and attached to a flanged opening over the crusher discharge. In

Jan 1, 1982

By Ann G. Kim

The Bureau of Mines investigated factors that influence the formation of methane and other hydrocarbon gases in coal, which is an integral part of the coalification process. Coalification begins with a biogenetic stage in which plant debris decomposes and peat is formed; methane and CO2 are the predominant gases produced during this stage. During the diagenetic stage of coalification hydrogen and the hydrocarbon gases methane, ethane, ethylene, propane, propylene, butene, iso-and normal butane, and pentane are formed by dissociation of the organic material. Methane may also be produced by a secondary reaction of hydrogen with unsaturates or by the reduction of CO2. The gas contained in coalbeds is a mixture of methane, C2 through C5 alkanes, CO2, O2, N2, H2, and He; its heating value is equivalent to that of natural gas. The gas content of coal depends on many variables, but an empirical relationship between adsorptive capacity, rank, and depth has been observed.

Jan 1, 1978

By P. A. Bloom

Arsenic-containing flue dusts are currently being stockpiled by several nonferrous smelters in the United States. These stockpiles are a source of environmental concern since the dusts can be transported by wind and contain water-soluble arsenic. The stockpiles also represent an alternate source of metals. To provide a quality environment, the Bureau of Mines investigated a process to make environmentally acceptable the discard of arsenic obtained from the treatment of arsenical flue dust. The process includes (1) leaching arsenic from a lead smelter copper dross flue dust, (2) fixing arsenic as an insoluble compound, and (3) recovering other metal values. Overall results of acid-leaching tests on lead-smelter flue dusts showed that H2S04 dissolved 80 to 90 percent of the As, Zn, and Cd, and up to 86 percent of the In. Pb, Ag, and Au remain in the residue, which can be recycled to the smelter. Indium was recovered from the strong acid leach solution by solvent extraction; arsenic was fixed in a stable form by precipitation with Fe2(S04)3 and CaO or CaC03.

Jan 1, 1982

By W. M. Merritts, Charles Findlay, Stephen Krickovic

Methane emission rates were studied in a Pittsburgh coalbed mine in northern West Virginia. A fullface boring-type continuous miner, equipped with a methane monitor, was used in the development of a set of eight main headings, one side of which was near old workings; the other side abutted virgin coal. Two air splits ventilated the section. Air volumes and methane percentages were recorded, and time studies of the miner were made during five consecutive operating days, during which a complete cycle of mining the headings and one line of related breakthroughs was accomplished. Methane emission rates increased significantly as mining progressed from the side near old mine workings toward the virgin area, and generally increased with coal extract ion. Mining in the heading immediately adjacent to virgin coal was interrupted quite frequently, owing to excessive methane concentrations at the face, despite adequate air volumes and acceptable methane concentrations in the immediate return airway.

Aug 1, 1970

By Walter W. Fisher

A kinetic investigation of copper cementation in a revolving drum was undertaken by the Bureau of Mines to explore the effects of a porous copper deposit attached to the iron surface and a fluidized slurry of copper particles surrounding the iron precipitant. The rate of cementation was found to be significantly enhanced by the increased cathodic areas provided by a porous copper deposit or the presence of a fluidized bed of copper particles contacting the iron precipitant. The cementation rate was found to be retarded by increased ionic strength, low pH, and the presence of oxygen. The cementation reaction was first order with respect to precipitant surface area. Copper cementation on iron is visualized to occur by two basic mechanisms. Precipitation may occur through a series of shorted electrochemical cells, whereby cupric ion precipitates on a growing cathodic copper deposit, or, deposition may occur via a fluidized cathode of copper particles contacting the ion precipitant.

Jan 1, 1976

By C. E. Jordan

The Bureau of Mines conducted laboratory studies on methods to increase the recovery of brine from slime produced by operating potash plants. The slime was comprised of 80 percent brine saturated with KCl and NaCl, and 20 percent solids. A variety of settling techniques, filtration methods, continuous centrifugation, and novel processing techniques were investigated. Vacuum filtration recovered 6S percent of the brine at 47 gallons of brine per square foot per day. Pressure filtration, on the other hand, recovered 74 percent of the brine at 40.9 gallons of brine per square foot per day. Centrifugation in a 6-inch-diameter continuous decanter-type separator resulted in 42 percent recovery of the brine at a treatment rate of 542 gallons of brine per day. Vertical drains proved to be the most promising novel debrining technique investigated. With this method, 45 percent of the brine was recovered in 3 days.

Jan 1, 1977

By D. E. Kirby

In the preparation of beryllium-copper alloys by fused-salt electrolysis, beryllium was electrowon from beryllium oxide dissolved in fluoride electrolytes and deposited on copper cathodes. At 880° to 1,030° C, deposition was on solid cathodes. Beryllium deposited on the copper, forming a liquid alloy that dripped from the cathode. Dripping alloys containing 3 to 4 weight-percent beryllium were produced with as high as 90 percent cathode current efficiency, by electrolysis at 910°.C. To prepare alloys of higher beryllium content, attempts were made at depositing beryllium on liquid copper cathodes. These efforts were generally unsuccessful, although alloys containing as much as 12 percent beryllium were prepared by this method. At temperatures of 1,100° to 1,300° C, requisite to maintaining beryllium-copper compositions as liquids, the beryllium reacted with cell structures.

Jan 1, 1972