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By E. W. Dean

The Bureau of Mines is engaged in the work of obtaining data regarding the physical and chemical properties of typical crude oils from the various producing fields of the, United" States. Preliminary reports have been published that cover the eastern fields* and the' Rocky Mountain districts.** Since the appearance of these, reports: it has been suggested that certain additional data. I regarding the samples would be of practical value. It was believed that a knowledge of the viscosity of crude oil was desirable, particularly in connection with the design and operation of pipe lines. In accordance with this suggestion, the authors have made viscosity tests upon as many of the samples of the two series as wore still available for examination. Determinations were made at temperatures of 70° and 100°F., and in addition the oils were Subjected to the A. S. T M, pour-test*** to as certain the lowest temperatures at which they remain in a fluid condition.

Jan 1, 1921

By L. A. Haas

The feasibility of removing sulfur dioxide by carbon monoxide reduction in a fixed-bed catalytic reactor was investigated by the Bureau of Mines. The reduction rate of sulfur dioxide with carbon monoxide was significantly dependent upon the iron and alumina content of the mixed catalyst. Maximum catalytic activity was obtained with about 40 percent iron-alumina mixture with a nominal gas mixture of 10 percent carbon monoxide, 5 percent sulfur dioxide, and the balance nitrogen. The synergistic effect of this catalyst mixture was explained by a dual reaction site mechanism, with both iron and alumina augmenting their specific sites at their interparticle contacts. The catalytic activity also increased with decreasing catalyst pellet size. With O.7-mm pellets, the entire pellet appeared to be catalytically active in a 2-gram catalyst bed. The apparent activation energy of the reaction was 18.3 kcal per mole in the temperature range of 350° to 600° C. Carbonyl sulfide (COS) was produced by the interaction of carbon monoxide and sulfur. The amount decreased with decreasing CO concentration. The ratio of COS formed per SO2 removed reached a maximum at about 400° C. The reaction rate appeared to be independent of S02 concentration in the range of 0.2 to 16 percent. The rate, however, increased directly with the CO concentration in the range of 5 to 20 percent. The presence of CO2 (<15 percent) had no appreciable effect on the rate. However, not over 0.5 percent oxygen could be tolerated. This method appears feasible for removing S02 from waste gas if the oxygen is removed prior to the catalytic S02 reduction process.

Jan 1, 1971

By T. F. Anstett

The Bureau of Mines investigated the availability of platinum from known major deposits in market economy countries. Fifteen of these deposits contain demonstrated resources totaling 302 million troy ounces of platinum. Detailed geologic, engineering, and cost evaluations were performed on each deposit to determine its potential for platinum production. There are large amounts of demonstrated platinum potentially available from market economy deposits that were not analyzed owing to lack of adequate data or to technological limitations. These include 297 million troy ounces contained in the UG2 and Platreef of the Bushveld Complex, South Africa. This analysis indicates that about 11 0 million troy ounces (2.3 million ounces annually) of platinum are potentially available at the January 1980 producer price of $420 per troy ounce, nearly all from South Africa. An additional 85 million troy ounces occurring in Zimbabwean deposits would become available only through more than a quadrupling of that price. In order to meet projected world demand of 3.5 million troy ounces in 1990, platinum price may have to increase. Only one domestic deposit, the Salmon River in Alaska, is capable of producing platinum at $420 per troy ounce. Regardless of price, at assumed production capacities, domestic deposits could supply less than 10 percent of annual U.S. requirements.

Jan 1, 1982

Cement kiln dust (CKD) is a waste product generated at the rate of 4 to 12 million tons per year in the United States. The dust has considerable resource potential as a neutralizer for coal mine waste effluents and as a lime substitute in the agriculture and construction industries. However, little information has been published on the composition and characteristics of CKD, and a concern arose over the potential environmental effects of the waste when an analysis of a single sample from West Germany revealed lead and zinc concentrations of 5,620 µg/g and 16,200 µg/g, respectively. To assess the hazardous waste potential of CKD,

Jan 1, 1983

By Ben A. Kornhauser

Petroleum production was the principal component of the mineral industry, followed by cement production and some salt output. The French Central Fund for Economics Cooperation loaned $9.15 million2 to the Communauté Electrique du Benin (CEB), which served Benin and Togo, toward financing the construction of a dam on the Mono River at Nangbeto, Togo. The dam was to supply hydroelectric power to reduce the energy dependence of the two countries and to irrigate crops. Nine other international financial organizations, including the International Bank for Reconstruction and Development (World Bank). the African Development Bank, the Arab Bank for African Economic Development, and the French Aid and Cooperation Fund, contributed to the estimated $140 million cost of the dam. The CEB also was to contribute to the financing. Contracts amounting to $60 million already had been awarded to West German and Canadian firms. The dam was expected to be completed in 1987.

Jan 1, 1986

By P. D. Laverty

The U.S. Bureau of Mines treated mixed and contaminated super alloy scrap by pyrometallurgical and hydrometallurgical methods to separate and recover metal values. Best results were obtained by leaching Zn-treated or atomized scrap with HCI-02 at 9SO C and 50 psig 02&apos; This resulted in dissolving approxi-mately 98 pet of the AI, Co, Cr, Cu, Fe, Mn, Ni, and Zn while rejecting over 98 pct of the Mo, Nb, Ta, Ti, W, and Zr as an insoluble refractory residue. Chlorine was successfully substituted for HCI to leach Zn-treated scrap but was unsuccessful for leaching atomized scrap. The leaching solution was treated by pH adjustment and hydrothermal precipitation at 2000 C for 4 h to remove AI, Cr, Fe, and other contaminants as a filterable precipitate. Recovery of Co and Ni would be accomplished by solvent extraction and e1ectrowinning. Chromium recovery as a ferroalloy was demonstrated.

Jan 1, 1989

By Willard L. Hunter

The separation of tantalum and columbium by solvent extraction was under-taken as part of the Bureau of Mines research program to improve methods for extracting, separating, and reducing these elements to metal. The diethyl ketone aqueous HCl-HF system was one of several systems studied to determine the effect of metal and acid concentrations in aqueous solutions upon the transfer of tantalum and columbium into selected ketones. The tantalum-columbium oxide mixture used in this investigation was obtained by chemical extraction from Geomines slag. The investigation showed that tantalum 99.4 percent pure and columbium 97.2 percent pure can be produced by the selective transfer of tantalum into diethyl ketone from a solution of 2-N HF and 1-N HC1. The relatively low acid concentration necessary for tantalum transfer and the excellent selectivity of the system recommend its use for the separation of tantalum and columbium.

Jan 1, 1961

By A. Z. Dimitroff

An improvised rock- dust disseminator, consisting of a 10-gallon galvanized metal milk can that dispenses rock dust in return air currents by the injection of compressed air has reduced the float dust explosion hazards at the Koehler coal mine, Koehler, N. Mex.

Jan 1, 1965

By F. N. Kissell

The Bureau of Mines has successfully used sulfur hexafluoride (SF6) as a tracer gas to measure mine air flows under conditions where conventional methods have failed. SF6 was employed experimentally to measure accurately recirculation of return into intake air caused by leakage through an old stoped area, to check for potential leakage from an adjacent mine, to trace 10,000 cfm of “lost” air from an intake airway, and to measure transit air time through uranium mines. It proved useful as a means of accurately measuring airflow volumes in airways of large cross section and very low flow velocity, and in determining the recirculation resulting from underground cooling plants.

Jan 1, 1974

By Suzann C. Ambrosio

Crude petroleum, the only commercially exploited mineral resource in Cameroon, continued to dominate developments in the mineral industry sector. International mining concerns have expressed interest in developing Cameroon&apos;s bauxite and iron and steel potentials. Domestically, the mineral industry focused on production of fertilisers for agricultural development, infrastructure construction, and hydrocarbon development, through the nearly self-sufficient production of fertilizer materials, cement, and crude oil. The mineral sector contributed 5.6% to the estimated 1981 gross domestic product (GDP) of $6.5 billion.2 Petroleum exports accounted for approximately 4.5% of the 1981 GDP and exceeded coffee and cocoa exports for the second consecutive year. The trade gap widened during the fiscal year ending on July 80, 1981, owing to a 21% increase in exports and a 25% increase in imports. Offsetting these balance-of-payments difficulties, typical of developing countries&apos; early economic stages, were increases in foreign exchange reserves to $71 trillion by May 1983.

Jan 1, 1983

Reduce injury to people or damage to equipment when a scheduled production blast is detonated. Approach The essential elements of an effective blast area security system were identified through case studies of five mining operations where the blast area guarding practices were considered to be superior to those generally found in the industry. These elements were used in making recommendations for improved blast area safeguarding practices. Background The blast area security system is a means by which the mine operator prevents injury to people or damage to equipment when blasting is performed. Analysis of blasting accidents showed that most blasting accidents occur during scheduled blasting and are due to inadequate blast-site security. Factors contributing to the system&apos;s breakdown are failure to clear the blast zone, inadequate guarding. and failure of personnel to follow instructions, retreat to a safe location, and/or take adequate cover. Mine personnel, visitors and even trespassers can inadvertently wander into a blasting zone unless proper procedures exist to ensure that all personnel are cleared from the blast zone and kept safely away until after blasting IS completed. Statistics show that the blaster is the miner most frequently injured In these accidents.

Jan 1, 1986

By Deno M. Pappas, Christopher Mark, Eric R. Bauer

During 1998-99, groundfall incidents resulted in 27 fatalities and were responsible for over 70% of all deaths in U.S. underground coal mines. To obtain a better understanding of where and why these incidents occurred, a comprehensive analysis of ground fall injuries and fatalities was conducted. The first portion of the study examined various factors associated with roof and rib fall injuries and reportable roof fall noninjuries that occurred during 1995-98. The study found that the room-and-pillar mining method has twice the groundfall incident rate than the longwall method. Mine locations with high groundfall rates seem to correlate to regions where there is a higher concentration of problematic coalbeds. For example, the Illinois Basin has very high groundfall rates, which can be traced back to several key coalbeds-Kentucky No. 13, Herrin/No. 6/Kentucky No. 11, and Springfield No. 5/Kentucky No. 9. High rib fall rates were found in mines located in thick seams. Groundfall rates were found to be 30% to 40% higher during the months of July through September, possibly due to high humidity that may cause the shale mine roof to deteriorate. The second part of the study examined the root causes of failure by reviewing all groundfall fatality reports for 1996-99. Primary and secondary hazard factors were assigned to each groundfall incident. The primaryf actors resulting in these groundfall fatalities were pillar extraction, traveling under unsupported roof, skin failure, construction, longwall faces, intersections, and geologic discontinuities. Defining prominent ground control incident trends and hazards will identify areas where additional study is needed and where innovative solutions need to be developed to reduce these severe occupational hazards.

Jan 10, 2000

By Charles C. Boley

The Bureau of Mines dried and carbonized two wood wastes, one softwood (redwood) and one hardwood (oak), using continuous, vertical entrainment techniques previously developed for use with coal. It was demonstrated that these techniques are readily applicable to wood waste and that appreciable changes in the yields of carbonization products can be obtained by varying operating conditions. A limited amount of experimental work was done on briquetting the charcoals. Firm briquets were formed with oak charcoal, although greater quantities of starch binder than used commercially for kiln-produced charcoal were required. Redwood charcoal did not briquet successfully under the test conditions employed.

Jan 1, 1969

Improve the safety, reliability and overall effectiveness of mine stench warning systems and to provide a means of remote control stench injector operation. Approach Industrial gas odorants were analyzed for their suitability for use in mine stench warning systems. A prototype stench injector capable of precise flowrate control was designed, fabricated, and tested using the odorant chosen as having the most favorable properties. Based on the results of the field tests, a second generation injector was developed. The second generation unit features optional remote control operation, and in addition, is simpler to refill and is less expensive than the original injector. A complete second generation system, consisting of two manually operated injectors and one remote controlled injector was in-mine tested through actual mine fire drills. How It Works Ethyl mercaptan mixed with Freon is the predominant stench agent used in the U.S. underground metal and nonmetal mines. However ethyl mercaptan&apos;s toxicity,

Jan 1, 1982

By A. F. Colombo

In an effort to maintain an adequate supply of iron to meet national economic and strategic needs, the Bureau of Mines, U.S. Department of the Interior, is conducting research on methods for beneficiating the oxidized taconite resources located on the western Mesabi range in Minnesota, thus expanding domestic iron ore reserves. The selective flocculation and cationic flotation process was investigated in a pilot plant using an ore feed rate of 410 kg/hr (900 1b/hr) and 88 percent recycled water. Lime and a cationic flocculant were used to clarify the waste slurries treated in the water reclamation circuit. An oxidized taconite assaying approximately 36 percent Fe yielded concentrates averaging 63.5 percent Fe and 4.3 percent SiO2 and having an average iron recovery of 84.4 percent. The estimated reagent cost per tonne of concentrate was approximately $1.10. In an attempt to recover more of the iron lost in the flotation tailing, wet high-intensity magnetic (WHIM) separation was incorporated in the pilot plant circuit. The flotation concentrate grades obtained from beneficiation circuits with and without WHIM scavenging were similar, but when WHIM separation was used the overall iron recovery was increased by 2 to 9.5 percent, depending on the iron assay of the flotation tailing.

Jan 1, 1978

By Verne E. Hooker

Stress relief measurements were made at three underground test sites associated with the Henderson project, American Metal Climax, located in the rugged, mountainous region between Loveland Pass and Berthoud Pass on the Continental Divide in Colorado. Sufficient data were obtained to determine the three-dimensional stress ellipsoid for each site. The measurements were made at hole depths greater than one diameter of the mined opening; thus, calculated stresses are representative of premining in situ conditions. The vertical components of stress are in good agreement with overburden depth including the influence of mountain topography. Horizontal components of stress substantially increase with depth. These components are believed to be influenced by stresses presumably of tectonic origin. The largest measured principal stress was 5,900 psi at a depth of 3.708 feet. The predominant orientation of maximum principal stress for the determinations at greatest depth is in the NW-SE quadrants.

Jan 1, 1972

Avoid accidents that can occur when applying belt dressing from an aerosol can, particularly when can pressure has dropped or when spraying against wind. Approach Use a garde-type sprayer. How It Works Commercially available garden-type sprayers can be used for applying conveyor belt dressing from 12 feet away, or more. Pressure is easily raised and maintained at about 50 psi. Most sprayers have a hand pump, but a battery-powered cordless model is also available. Garden-type sprayers are available in various sizes from 11/2 to 18 gallons, with the larger models wheel mounted. The 3-gallon model evaluated by the Bureau has a shoulder carrying strap, which gives additional safety advantages. Use of the strap frees both hands for climbing ladders or holding onto catwalk rails. When spraying, one hand can remain on a handhold to lessen the chances of touching a moving belt.

Jan 1, 1980

By Fred N. Kissell

Methane-flow and pressure data taken from a mine in the Pocahontas No. 3 coalbed are compared with flow rates from lump coal obtained in laboratory experiments. From this, it is concluded that the main source of gas is the intact coalbed rather than a "crushed zone" near the working face. The permeability and sorption capacity of the intact coalbed are calculated and gas emission rates are theoretically accounted for.

Jan 1, 1972

By Jami M. Girard

INTRODUCTION Slope stability accidents are one of the leading causes of fatalities at U.S. surface mining operations. The Spokane Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) is currently conducting research to reduce the fatalities associated with slope failures and other unexpected failures of ground. The purpose of this paper is to introduce various warning signs of slope instability so operators are better able to recognize hazards. The most common slope monitoring equipment and practical methods of installation are discussed as well as the limitations of these systems. CONSEQUENCES OF SLOPE FAILURES Unexpected movement of ground causes the potential to endanger lives, demolish equipment, or destroy property. Between 1995 and 2001 (2nd quarter), 34 fatalities were caused by ground instability. This accounts for approximately 15% of all surface mine fatalities (Figure 1). These figures include fatalities classified by the Mine Safety and Health Administration (MSHA) as “fall of face or highwall,” “powered haulage,” “equipment,” and other MSHA accident categories, where the primary cause of the accident was unanticipated movement of the ground. This includes fatalities resulting from bench and highwall failures, rock falls, waste dump and stockpile failures, and the collapse of unknown underground workings. [ ]

By Kenneth O. Bennington

This investigation is part of the Bureau of Mines research effort directed at advancing mineral technology and minimizing energy requirements for extractive metallurgy. The emplacement of the primary minerals petalite (LiAlSi4010) and spodumene (LiAlSi206) in the lithium pegmatites is examined on the basis of their Gibbs energies of formation determined from lithium metastltcate and oxides, using a series of proposed reactions. The reaction between spodumene, quartz, and petalite (LiAlSi206 + 25i02 [=] LiAlSi4010) apparently does not take place in nature but may be proved experimentally.

Jan 1, 1982