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By Herbert R. Babitzke

As part of a project to develop refractory metal alloys suitable for high-temperature structural applications, the Bureau of Mines applied solid solution and precipitation-hardening techniques to columbium and tantalum alloys. Thirty-three alloys were evaluated to determine their formability, strength, and oxidation resistance. Three alloys had tensile strengths near 40,000 psi at 1,200° C: Cb-1N-5W-5V-10Hf (No.4), Cb-15Hf-5W-0.5B (No. 31), and Cb-15Hf-SW-IB (No. 32). Oxidation resistance of the high-strength alloys was good. Alloy4 gained only 34 mg/cm2 at 1,200° C, and 21 mg/cm2 at 1,000° C in 2 hours. Hot forming was done without any protection from oxidation.

Jan 1, 1968

By Wesley A. Grosh

The Vest nickel prospect, in Floyd County, Va., was discovered about 25 years ago. Limited exploration of the deposit had indicated some appreciable nickel mineralization in the sulfide ore. The property was examined on March 9, 1943, by an engineer of the Bureau of Mines in company with C. W. Vest, owner of the property. A limited exploration program was recommended. Two holes totaling 320 feet were diamond-drilled in January 1944. Drilling indicated the sulfides are sparsely disseminated. The only nickel values of interest were at the old prospect shaft.

Jan 1, 1949

By D. Harrington

The occurrence of dusts in underground workings creates many difficult and, in some instances, contradictory and conflicting problems for workers, operators, and all others interested in health and safety in mining and tunneling. Moreover, there are many misconceptions both as to the actual effect of most dusts which may be encountered in underground work and as to remedial or alleviating measures. Although the harmfulness of mine dusts to health of miners has been mentioned by man; writers in ancient times, much of our really authentic knowledge of the effect of underground dusts upon health or safety in both coal and metal mines has been pained during the past 30 or 35 years. There has been, however, a considerable amount of generalizing from some local condition or occurrence or theory rather than arriving at conclusions after extended studies and observations made not only in mines and tunnels but also in town, camps, and plants, and comprising date on as many different mining and tunneling localities, conditions, etc., as could be secured with reasonable expenditure of time or money. This paper dives sortie observations based on the writer's 30 odd years of experience in and around both coal and metal mines, including approximately 20 years? close study of dust disease with detailed surveys and reports on dust occurrence and effects in considerably more than 100 mines in probably 20 States of the Union. The observatio are those of an engineer and in many respects conflict the with "going" ideas of doctors, pathologists, and others who have written on dust disease. Were the word dust is used in this p: per in connection with respiratory disease, it refers to solid particles which float or can float in the air breathed by workers. Although these particles are usually dry, they may be wet; in general, their dimensions are so small as to be invisible to the nailed eye. Dusts in coal mines which may be involved in the initiation or extension of explosions, are generally thought to be those which are smaller than 20-mesh in size but chiefly finer than 20-mesh; coal-mine dusts which are harmful to health of workers have essentially the same general physical characteristics as other dusts, but usually consist of smaller particles.

Jan 1, 1936

By Michael S. Miller

In 1986 and 1987, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied the 550-acre Carson-Iceberg Wilderness Study Area (NV-030-532), in order to evaluate its identified mineral resources. The Wilderness Study Area is located in Alpine County, CA, 11 mi southeast of Markleeville, CA. Tertiary volcanic and granitic rocks, as well as alluvium, underlie the area. Hydrothermal alteration and faulting have affected some rocks; argillic, silicic, and limonitic alteration are found, particularly near faults. No mineral resources were identified in the Wilderness Study Area. The area has one small pit and no mines or claims. Samples from the Wilderness Study Area and vicinity contained uneconomic amounts of gold, silver, copper, lead, zinc, mercury, arsenic, and molybdenum. Mineral occurrences are too small and low grade to be of interest within the foreseeable future.

Jan 1, 1988

By J. Croeni

The search for new alloys for application in the atomic energy field had prompted investigation of zirconium-rare earth metal alloys by the Federal Bureau of Mines. In this instance the zirconium-dysprosium system was investigated by melting point, thermal analysis, resistivity, X-ray and metallographic methods. Results indicate a single eutectic system with a peritectoid reaction occurring at 890° C. The eutectic isotherm extends from 30 to 95-percent dysprosium at 1,280° C. Eutectic composition is located at approximately 70 percent dysprosium. Solid solubility of dysprosium in both alpha and beta zirconium is extensive. The extent of solid solubility of zirconium in dysprosium has not been determined. Although zirconium rich alloys exhibit a significant increase in hardness, they can be cold worked extensively. These alloys also appear adaptable to solution heat treatment. Additional investigations concerning corrosion resistance and other mechanical properties are necessary for satisfactory evaluation of these alloys. The superior corrosion resistance of zirconium and the nuclear cross-section characteristics of the rare earth metals have stimulated alloy investigations using zirconium as a base metal. Alloys combining these characteristics present a possible substitute for hafnium as a control rod material. In this particular study dysprosium was chosen as the alloying element, and several series of alloys were used to establish the equilibrium diagram.

Jan 1, 1960

By Philip C. Tully

The Bureau of Mines, in a continuing effort to improve processes and methods of helium purification, has developed a differential distillation method for removing helium-3 from helium-4. Differential distillation at 4.2 to 1.6 K was used to reduce the helium-3 in helium-4 from about 200 to less than 1 part per billion. The results from four stills ranging in size from 1 to 25 liters are reported. The method has the potential to be adapted to commercial-scale separations.

Jan 1, 1975

By Irving Hartmann

Several recent ignitions of firedamp - a mixture of methane and air - in American coal mines have been attributed to frictional heating when hard rocks were struck while cutting and drilling coal seams. Although none of these ignitions caused severe explosions, they call attention to a problem that can become increasingly significant as mechanized mining is developed further. The power in and rapid release of energy from high-speed machinery has increased the rates of advance into virgin coal creating many problems. Unforeseen faults and hard mineral inclusions may be encountered; coal brought down in this way is finer in size; more gas is released from the seam; it is frequently more difficult to provide adequate ventilation at the' face; and new roof-support problems must be solved. In particular, continuous mining machines (also known as continuous miners) greatly increase the frequency of contact between cutter bits and minerals. In view of these conditions, it may be expected that more gas ignitions will occur as a result of frictional heating unless the situation is understood and remedial measures are introduced. The problem of frictional heating is not new in coal mining. In Europe, particularly in England, it has been a concern for more than a century. During the last 15 to 20 years frictional ignitions have been a major cuase of explosions in British mines. Explanations for the greater number of such ignitions in England may be the special character of the coal measure strata, the mining methods, the rate of gas emission and possibly its composition, and less effective ventilation near the face. To reduce the ignition hazard, considerable laboratory and field research has been conducted, particularly by the Safety in Mines Research Establishment, Ministry of Fuel and Power of Great Britain. Much of the information presented in this report has been drawn from these studies.

Jan 1, 1955

Prevention of coal-mine explosions depends largely upon thorough knowledge of the causes that initiate explosions. A review of coal-mine explosions in one geographical area when supplemented by nationwide data of similar nature, should serve as a guide for the adoption of measures for explosion prevention. Explosions in bituminous-coal mines of the United States during the 10 years ended December 31, 1932, ranked third in the causes of fatal accidents and constituted 16.1 percent of all fatal accidents in bituminous mines. Kentucky now ranks fourth in coal output in the coal-producing States of this country; a study of the coal-mine explosions in this state will be of definite interest locally among coal-mining people, as well as to those in the coal-mining industry who are concerned in preventing coal-mine explosions. This circular reviews gas and dust explosions in Kentucky coal mines to show their hazards, to point out the influence of certain factors in causing explosions, and to indicate the effectiveness of preventive measures.

Jan 1, 1934

By R. G. Sandberg

Many gold-bearing ores throughout the Western United States contain small quantities of mercury. The presence of mercury not only decreases the gold-loading capacity of the activated carbon, but complicates the fire refining of cathodes and creates a potential health hazard. The Bureau of Mines investigated methods to limit mercury extraction during gold ore leaching and to remove mercury from cyanide leach solu-tions. Mercury dissolution was reduced from 40 to 10 pct by decreasing NaCN concentration from 20 lb to 0.34 lb per ton of solution at a pH of <11. When 0.1 lb CaS per ton of ore was added to a leach slurry, mer-cury extraction was reduced from 27 to 0.4 pct. Less than 0.5 pct of the mercury was solubilized when <0.1 lb CaS per ton of are, along with lime and NaCN, was added to a simulated grinding circuit.

Jan 1, 1984

By D. A. Baker

This report describes the elemental characterization of chromite and related materials at the Bureau of Mines, Albany Research Center. Analytical methods for determining the major constituents, representing extensive experience, refinement, and development, are described and fully annotated. This presentation should allow other laboratories to use these methods and obtain comparable results with a minimum of time needed for familiarization with individual methods.

Jan 1, 1990

By Lewis C. Karrick

In studying the destructive distillation or pyrolysis of oil shales, the primary consideration is to determine the effects of heat on the organic components of the shale. The impracticability of separating these organic components, collectively known as "kerogen", from the mineral matter with which they are associated renders the problem extremely complex. The behavior of the kerogan in the shale while undergoing the heating process is probably different from that of the same kerogen if it could be isolated and treated under similar temperature conditions, and in fact the results of actual distillations have shown that the physical properties of the mineral matter in the shale may be the cause of much variation in the products of retorting. It must be remembered that the inorganic .material of the shale is a heterogeneous mixture of minerals solidified into a very close-grained compact mass. This mineral mass has a thermal conductivity different from that of the kerogen, thus complicating the problem of even distribution of heat. Furthermore, the temperatures of dehydration of gypsum end some; hydrous silicates are included within the temperature range of the shale distillation, These minerals are frequently present in the shales; and the evolution of water vapors from them will affect the partial pressures of the hydrocarbon vapors evolved from the kerogen, probably tending toward, the improvement of the quality of the oil distillates. Carbonates and sulphides which are also frequently present begin to decompose within this range of temperature, and the gases produced from them may alter the chemical constitution of the oils produced from the kerogen.

Jan 1, 1922

By Nicholas Kyriazi

The Bureau of Mines has been developing breathing and metabolic simulator technology since 1970. Breathing simulation has been widely achieved throughout the world and used in the testing of open-circuit breathing apparatus, but satisfactory metabolism simulation has not been achieved. This situation required that the testing of closed-circuit breathing apparatus, which are the only type used in mines, be done using human test subjects. The goal was a machine that could accurately simulate both the breathing and the metabolic functions of a human being for testing of closed-circuit breathing apparatus. The advantages of using such a machine instead of a human being for testing respiratory protective devices lie in its ability to quantify metabolic input, its repeatability, and the lack of a need to deal with the vagaries of human subjects. This report will describe the breathing and metabolic simulators that have been developed and used by the Bureau over the past 15 yr.

Jan 1, 1986

By E. J. Kloos

This publication lists devices approved jointly by the Secretary of Interior and the Secretary of Health, Education, and Welfare, as of May 24, 1972, under provisions of Section 11.2, Part 11, Subchapter B of Chapter 1, Title 30, Code of Federal Regulations (37 F.R. 6244, March 25, 1972), for use in mines as respiratory protection in oxygen-deficient atmospheres, and in gases, vapors, dusts, fumes, and mists. Included are self-contained breathing apparatus, gas masks, and supplied-air, dust, fume, mist, and chemical-cartridge respirators. Names and addresses of manufacturers appear in the appendix.

Jan 1, 1972

By Clete R. Stephan, Mark J. Schultz, William A. Slivensky, Eric S. Weiss, Kenneth W. Jackson

he Pittsburgh Research Center (PRC)~ and the Mine Safety and Health Administration (MSHA) are participating in a research program to evaluate the strength characteristics and air leakage resistance of seals and water trap designs for use in underground coal mines. This program is being conducted at PRC&apos;s Lake Lynn Laboratory near Fairchance, Fayette County, PA. Seals designed with a 40-cm-thick polymer (polyurethane) and aggregate core between two dry-stacked (no mortar) concrete block walls (coated on out by sides) withstood a 138-kPa pressure pulse while maintaining acceptable air leakage rates. Similar seal designs utilizing a 97-cm-thick, 91-kg/m7-density, polymer-only core did not survive; however, a 5 1 -cm-thick, 203-kg/mi-density, polymer-only core seal successfully withstood the explosion pressures. Evaluations of cellular concrete seal designs have shown that a two-pour slurry injection technique did not adversely affect the strength of the 1.2-m-thick seals when subjected to a 138-kPa pressure pulse. Two seal designs utilizing low-density cementitious block have also been evaluated with successful results. In addition to seal strength tests, various 15- and 30-cm-diam U-shaped water trap pipes and a water trough design were evaluated under explosion conditions and were shown to be inadequate when evaluated under worst-case conditions. Simple modifications to the various water trap designs were successfu1 in preventing the passage of explosion flame through the trap.

Jan 4, 1996

By F. E. Cash

Among petroleum refinery employees and officials throughout the United States there has been marked effort to reduce accident frequency and severity. For the interest and benefit of refineries both in Louisiana and in other petroleum-refining States it has been possible to obtain from five refineries, representing 70 per cent of the production of Louisiana, tae accident experience for the past 3 to 6 years. The companies concerned have requested that their names be not used. For tide reason the four plants listed and discussed are designated as refineries A, E, C, and D. The size of the plant as regards largest to smallest number of employees is indicated by the alphabetical order.

Jan 1, 1933

By A. B. Clayton

The Bumpus Cove area is in Unicoi County, Tenn., about 9 miles south of Jonesboro and 5 miles northwest of Erwin. Iron and lead ores were mined in the Bumpus Cove area before the American Revolution. The production of those metals continued intermittently until 1916. In 1850 this area was the most important producer of iron in the South. In 1911 several carloads of zinc ore was recovered from old dumps and shipped to Missouri smelters. In 1913 systematic mining of zinc ores was begun and continued until 1916. After that year, mining again became sporadic and continued so until discontinued in 1943.

Jan 1, 1949

By Michael A. Trevits

During the time period from 1990-2007, there were 1601 reportable fires that occurred in the U.S. mining industry (an average of 89 fires per year). The leading causes of U.S. mine fires include flame cutting and welding operations, frictional heating and ignitions, electrical shorts, mobile equipment malfunctions, and spontaneous combustion. The National Institute for Occupational Safety and Health (NIOSH) is conducting a program of research addressing metal/nonmetal and coal mine fire prevention, detection, management and suppression. In the metal/nonmetal area, work was focused on technology transfer and training, and research to reduce the number of mobile equipment fires and their hazards. In the coal arena, research is underway to determine the root cause of cutting and welding-related fires and to evaluate the effects of ventilation schemes relative to the spontaneous combustion risk in longwall mines. Relative to fire management, research is ongoing on remote mine seal installation and remote mine fire suppression technologies. Finally, research is continuing to develop comprehensive and usable smoke management techniques and to develop mine fire growth models, propagation, and suppression. This paper presents a summary of some of the mine fire research and provides an overview of the next phase of the NIOSH mine fire research program.

Jan 1, 2010

By Guy A. Johnson

Despite the use of warning alarms to alert miners to the backward movement of large mining equipment, miners still are injured too frequently in backup accidents. Currently approved backup alarm technology consists of continuous sounding alarm systems. New technology has developed a warning system that initiates an alarm only if there is an object close behind the vehicle. This advancement eliminates constant exposure to the alarm because a warning is given only in case of a potential collision. Adoption of this development can improve safety and reduce damage, especially for front-end loaders (FEL&apos;s). It will also eliminate a source of nuisance noise in urban and residential areas. This Bureau of Mines report describes the general characteristics of infrared (IR) light, ultrasonic wave, and Doppler radar technology as used for backup alarms, and reviews the testing of the most promising detection devices.

Jan 1, 1986

By Charles D. Litton

Laboratory experiments were conducted to determine the responses of a prototype smoke detector and a commercially available photoelectric smoke detector to smoke particles generated from various combustion sources. The prototype smoke detector combines optical scattering measurements with ionization chamber measurements in order to reduce/eliminate nuisance alarms due to the presence of airborne dusts or diesel exhaust particles. The commercially available smoke detector is designed for use in harsh environments where airborne dust represents a major problem due to both nuisance alarms and detector contamination. In the experiments, the responses of the two detectors were measured when exposed to smoke particles from the exhaust of a diesel engine and from a variety of fire sources, including wood, coal, styrene butadiene rubber, and No. 2 diesel fuel. For the solid fuels, data were obtained for both smoldering and flaming combustions. This report describes the experiments, their results, and the use of these results as they apply to early-warning fire sensors capable of the rapid and reliable detection of fires in atmospheres that may or may not be contaminated by either airborne dust or the products produced from diesel engines.

Jan 1, 2008

By H. Kenworthy

[Experimental studies were made to develop a laboratory technique for direct removal of cadmium and germanium from sphalerite concentrates. Cadmium- and germanium-bearing concentrates from the Illinois-Kentucky fluorspar field were sound to be, amenable to an inert atmosphere fuming process for removing these two moats in the form of gaseous sulfides. Treating the condensed fume by pyrometallurgical methods upgraded the material end provided a means of partly separating the constituents. Cadmium was concentrated about 35:1 arid germanium about 300:1. The extractive investigations were supplemented by vapor-pressure studies on the sulfides of germanium to obtain fundamental data for larger scale laboratory conditioning and control when treating the zinc concentrates. Vapor-pressure curves were developed for synthesized monosulfide and disulfide The results of these- investigations indicate the possibility of significantly increasing the recovery of cadmium from zinc concentrates. Comparison with present recovery of germanium cannot be made, since commercial recovery data arc not available.]

Jan 1, 1956