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By R. F. Abernethy

A modified Unterzaucher method was applied to the direct determination of oxygen in coal. Coal samples were pyrolyzed in a nitrogen atmosphere, and the gaseous oxygen compounds liberated were converted to carbon monoxide by a platinized-carbon catalyst at 9000 C. After passing over heated copper and through a tube containing soda-asbestos and magnesium perchlorate, the purified carbon monoxide was oxidized to carbon dioxide by iodine pentoxide--liberating an equivalent amount of iodine. The iodine was titrated with 0.02 ~ sodium thiosulfate; in a few tests the weight of carbon dioxide produced was determined. Direct oxygen determinations of coal included organic oxygen from the coal substance, plus a small quantity of inorganic oxygen derived principally from carbonate minerals and from combined water of silicates in the mineral matter. The influence of mineral matter on the direct oxygen determination was investigated by testing (1) untreated coal, (2) demineralized coal from which most of the mineral matter except pyrite was removed by treatment with hydrofluoric and hydrochloric acids, and (3) coal samples treated with dilute hydrochloric acid.

Jan 1, 1966

By B. J. Scheiner

The Federal Bureau of Mines investigated an electrolytic oxidation procedure for extracting lead, zinc, copper, and silver from lead-zinc concentrates. Concentrates slurried in brine were pumped through the anode compartment of electrolytic cells equipped with selective ion diaphragms. Hydrochloric and hypochlorous acids generated in the anode compartment converted the metal sulfides in the concentrates to soluble metal chlorides, sulfate ion, and elemental sulfur. Metal extractions of 92 to 100 pct were obtained from lead-zinc concentrates at an energy consumption ranging from 1.5 to 5.0 kW-hr/lb metal extracted. Sodium hydroxide was formed in the cathode compartment at a current efficiency of >99 pet. Silver and copper were extracted from refractory tetrahedrite minerals, but the process entailed a relatively high energy consumption. Sealing the top of the diaphragm cell utilized the chlorine more effectively, thereby reducing energy consumption 10 to 50 pct.

Jan 1, 1975

By Alan R. Buehler

A mineral survey of the 67, 110-acre Raven?s Eye WSA (Wilderness Study Area) in the north-central Snake River Plain of Idaho was conducted by the U.S. Bureau of Mines in 1985, at the request of the Bureau of Land Management. The WSA is in Blaine and Lincoln Counties; the northwest corner is about 1 mile east of Carey, 10. A search of county mining claim records indicated that no claims have been located in the WSA. Basaltic lava is the only rock type exposed within the WSA. A platy variety of lava (slab pahoehoe) occurs that is produced from other lava fields in southern Idaho. The material is marketed as decorative stone, used for wall veneers, and retails for approximately $125/ton. Within the W5A, approximately 18,000 tons of indicated reserves are concentrated in two areas, and a total of 12,000 tons of indicated subeconomic resources were found at six other localities. An additional 10,000 tons of inferred subeconomic resources are unevenly distributed over the remainder of the WSA.

Jan 1, 1986

By R. S. Dean

The principle of explosive crushing depends upon the fact that an expandable substance contained within the pores of a solid body will disrupt such a body upon expansion. Such expansion may be obtained by the detonation of an explosive or by the sudden release of pressure of a superheated liquid. That this principle of disruption may be applied to minerals rests on the fact that cracks, cleavage planes, and pores exist in all mineral to an extent hardly conceived possible heretofore. Crushing by this method takes advantage of force applied from within the mineral rather than from forces applied from without. The application of a force from within would appear to be more effective. A consideration of the possibilities of such a method for crushing led to some experimental work of a preliminary nature, the results of which are embodied in this paper. No systematic program was followed in the work and the results are, therefore, not final and far from complete. The success attained so far, with the mediocre apparatus available seems to warrant a preliminary report, with the expressed hope that the work may be carried on as well-outline program covering such phases as have been impossible to investigate at this time.

Jan 1, 1931

By John E. Shelton

Flotation tests were conducted on two samples of copper-nickel-bearing ore from the Harriman area near Rockport, Maine. The samples were taken by Roland F. Beers, Inc., for tests in cooperation with the Federal Bureau of Mines. One sample, analyzing 0.38 percent copper and 0.71 percent nickel, was essentially a disseminated pyrrhotite in hypersthene. Pentlandite, chalcopyrite, pyrite, and millerite were intimately associated with the pyrrhotite. Locked series flotation tests on this sample showed that 87.4 and 73.4 percent of the copper and nickel, respectively, could be recovered in a bulk concentrate that analyzed 3.47 percent copper and 5.34 percent nickel. The copper-and nickel-bearing minerals were collected with sulfhydric collectors in an alkaline circuit. Cleaning the concentrate three times with the addition of pH regulators was sufficient to attain the previously stated grades. The second sample had analyses of 0.31 percent copper and 0.85 percent nickel; talc and hypersthene were the main gangue minerals. Bulk sulfide flotation, made while depressing the talc, resulted in a concentrate that analyzed 2.33 percent copper and 4.70 percent nickel at recoveries of 70.0 and 54.4 percent, respectively. Flotation of the talc followed by bulk sulfide flotation resulted in a nickel content greater than 5 percent. A locked-series test showed that 60.7 percent of the copper and 73.7 percent of the nickel could be recovered at grades of 1.29 and 4.85 percent, respectively.

Jan 1, 1961

By W. L. Parker, W. A. Selvig

"Introduction.Powdered or pulverized coal is extensively used as a fuel, the total annual consumption*** in the United States being about 12.000,000 tons, and growing steadily. As the coal is usually pulverized so that 70 per cent or more parses through a 200-mesh sieve, it presents difficulties in sieving, because such finely divided material tends to clog the meshes. A fineness test is desirable in order to judge the efficiency of the pulverizing apparatus, and as an indication of the particle size of the coal being burned.Committee D-5 on Coal and Coke, American Society for Testing Materials, has recognized the desirability' of a standard method for determination of fineness of powdered coal. The Bureau of Mines, in co-operation with this Committee, conducted sieving tests on two standard samples of powdered coal, which are described in this paper. As a result of this work a method for making fineness tests, by band sieving, is recommended as a standard method, while a rapid method, by machine sieving, is given for routine tests.Outline of Investigation.Preliminary trial tests were made by the bureau and tentative methods were formulated for making the sieving tests both by band and by machine.Each of two samples of powdered coal was carefully mixed, and portions were sent to the twelve laboratories mentioned later. These were requested to make duplicate sieving tests on the two standard samples, by the hand-sieving and machine-sieving methods, and to follow the tentative procedure exactly as outlined. All of the laboratories made sieving tests by hand shaking and eight of them made tests by machine shaking."

Nov 1, 1923

By S. J. Pearce

The need for a simple, very sensitive, and accurate method for the determination of benzene in blood and urine vas evident throughout a recent study of chronic benzene (C6H6) poisoning conducted cooperatively by the United States Bureau of Mines, The Barrett Company, and the producers of benzene. A combustion method which will be described in a later publication, and a previously described/ adaptation of Smyth's method were developed and used during that investigation. The adaptation of Smyth's method gave satisfactory results when dealing with exposure conditions that produced chronic poisoning in a comparatively few days, but it was time-consuming; and lacked the accuracy necessary for a study of the absorption, distribution, and fate of benzene in the body during exposure to threshold concentrations of benzene vapor in air. The combustion procedure was satisfactory from the standpoint of sensitivity but was cumbersome, intricate, time-consuming, and required the use of special and somewhat expensive Physical and chemical apparatus. Following the termination of this study of chronic poisoning, possibilities ides for developing better methods occurred, and these have been investigated by the Bureau of Mines with the aid of Relief Works Division personnel microcolorimetric method for the determination of benzene in air has been described recently.6/ The present report deals rich the adaptation of this new colorimetric method to the determination

Jan 1, 1936

By Benjamin W. Haynes

As part of the first-order assessment of potential manganese nodule processing reject waste materials, the Bureau of Mines estimated the physical and chemical characteristics of reject waste materials that would be generated from each of five potential process flowsheets. These processes were chosen because of their economic and technical feasibility for first-generation nodule processing. A brief description of the five processes is given to show process inputs and outputs, The physical characteristics are predicted based on land-based laterite processing where applicable, and where no land-based analog exists, on the basis of process chemistry. The probable chemical characteristics such as element content and compound form are tabulated for each process for 16 elements: As, Ba, Be, Cd, Go, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sb, Se, TI, and Zn. These elements were chosen based on their presence on the toxic substance list of priority pollutants, EP toxicity criteria, and major and minor elements of economic importance (Co, Fe, Mn, and Mo). Physical and chemical analyses as well as results of the EP toxicity test of one industrially supplied pilot plant reject waste material are presented.

Jan 1, 1982

By G. W. Birge, D. E. Wolfson, J. H. Lynch

This report presents all available 900 ° C BM- AGA carbonization and related data for coals from the principal beds of the southwest Virginia field in a form which permits ready comparison of product yields and properties of coals and cokes . Thirty- one channel samples from Buchanan , Dickenson , Russell , Tazewell , and Wise Counties were carbonized at 900 ° C in an 18 - inch - diameter retort . Blending properties of 10 of the coals were studied , and expansion of most of the coals and blends was measured in the Bureau of Mines sole - heated oven . Ash Most of the samples were chemically suitable for metallurgical use in coking blends , and their coking properties generally were satisfactory . content exceeded 10 percent in only three samples , and none of the coals contained more than 1.5 percent sulfur . Dry , mineral - matter - free fixed - carbon content of the coals ranged from 62.1 to 77.5 percent . Expansion behavior varied widely , ranging from 16.8 percent expansion to 27.6 percent contraction .

Jan 1, 1964

By H. L. Riley

This report describes the methods and equipment used by the Watauga Stone Co. to drill and blast limestone in a two-level quarry, and to crush, screen, blend, and load this stone. Power requirements per ton of stone produced are reported. The personnel requirements for individual phases of the operation are tabulated in man-hours per ton of stone produced.

Jan 1, 1963

By C. C. Merrill

Studies were made to determine the amenability of yttrium to fused-salt electrorefining in a controlled atmosphere. Tests were conducted in a LiCl- YCl3 electrolyte system at 710° C. The major variables studied were the YCl3 content of the electrolyte, from l.7 to 13.4 mol percent, and the initial cathode current density, from 410 to 1,630 amperes per square foot. Vacuum distillation was employed to remove salt from the deposited metal. Metallic impurities, except for lithium, could be reduced to near or below their lower analytical limits, ranging from 10 ppm for Cu to 300 ppm for Ta; reduction of oxygen content, however, was accomplished only in metal produced from electrolytes with 5.4 mol percent YCl3 or less. Initial cathode current density had little effect on the purity of the product.

Jan 1, 1967

By J. G. Walters

In 1928, the Coal Carbonization Section of the Federal Bureau of Mines, in cooperation with the American Gas Association, began a survey of the carbonizing properties of American coals. A standard test method for evaluating the carbonizing properties of coals that met the following conditions was developed: To yield products similar to those obtained in commercial operations. To produce yields sufficient to permit analyses and tests of quality. To be laboratory size. To be convenient to operate. To permit reproducible control of test conditions and results. This test method has become known as the Bureau of Mines-American Gas Association (BM-AGA) test (53),3/ and more coals of greater variety have been tested in this apparatus than in any other of similar scale.

Jan 1, 1961

By Wm. F. Netzeband

The purpose of this paper is to present to the operators, in other districts a detailed description of the ruining method used and the results obtained to exploiting one of the zinc-lead deposits of the Kansas-Oklahoma-Missouri district. No. 1. mine is located in the heart of the town of Picher in the extreme northeast corner of Oklahoma. HISTORY The first prospect drilling was done at No. 1 mine late in-1914, and shaft sinking was started early in 1915. Sufficient ore was developed to start construction of the mill in April, 1016, Production begin in August, 1916, and the mine s been producing, except for short periods, to the present time. The property was originally a 40-acre tract, but additional properties have been consolidated with the original one until the mine now covers 200 acres.

Jan 1, 1929

By G. R. Hopkins

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Jan 1, 1927

By H. R. Shell, John L. Miller, M. V. Denny

In the mica research program conducted by the Bureau of Mines at Norris , Tenn . , many micas other than silicon fluorphlogopite have been synthesized . It has been well established since the initiation of the program that synthetic micas are important materials useful for their superior or unique properties as well as substitutes for natural micas . The possibility of controlling the physical properties of synthetic mica by isomorphic substitution of other ions in the fluorphlogopite lattice further emphasizes the importance of these materials . Accurate measurement and reporting of their properties constitute an essential part of the research program . The study of germanium fluorphlogopite is in keeping with the requirements of a comprehensive study on isomorphic substitution , specifically to identify precisely the material -- chemically , structurally , and optically . The X- ray measurements , including indexed powder and single crystal data , with a description of the methods used to obtain these data , are provided . 5 Earlier work on germanium mica by R. A. Hatch et al . (5) gave an estimate of the cell parameters from X - ray powder data , but no attempt was made to index the diffraction pattern or to determine the space group symmetry . Later work by E. A. Schatz and J. C. Withers (9) listed X- ray and optical measurements , but no attempt was made to index the mica or determine its symmetry . Roth (7) found that germanium dioxide having the a - quartz structure , when heated with equimolar percentages of MgO , CaO , Sr0 , or Ba0 at 1,235 ° C , formed ABO3 -type compounds , e.g. MgGe03 isostructural with enstatite (MgSiO3 ) . Geo₂ also has a rutile - type polymorph with Ge ++ ions in octahedral coordination . Germanium was substituted for silicon in the serpentine structure by Roy and Roy (8 ) using hydrothermal techniques . These authors wrote as follows : "The substitution of Ge + for Si + yielded a magnesia - germania serpentine , formed easily in euhedral hexagonal plates which in some instances were visible in the light microscope . Electron micrographs and the sharp X - ray diffraction patterns confirm a plate - like rather than tubular habit . " It has been shown in this investigation that substitution of germanium for silicon in the mica structure is readily accomplished without radically changing the characteristics of the mica . Substitutions in the mica structure take place in three locations : Tetrahedral , octahedral , and interlayer positions . The tetrahedral positions are normally occupied by Sit or by a combination of Sit with Al +3 the most common combination being 2A1 +3 and 6Si +4 · , The octahedral position , which has six - fold coordination in phlogopite , contains a larger cation such as magnesium . In muscovite it contains only 2A1 ions ; therefore , this mica is considered a dioctahedral mica , whereas phlogopite is considered trioctahedral . +3 The interlayer position has twelve - fold coordination with six oxygen ions from each of two adjacent tetrahedral silica layers . This is the cleavage plane of the mica and commonly contains the largest cation in the mica structure (e.g. potassium) .

Jan 1, 1964

By Roy H. Poston

This paper sets forth the mode of ore occurrence, characteristics of ore and country rocks, methods of exploration, development, and. ore extraction, and the costs of underground operation at No. 8 mine of the St. Louis Smelting and Refining Works of the National Lead Co. located near the southern extremity of the Southeast Missouri lead district. The author acknowledges the assistance of E. T. Campbell, geologist, in the preparation of the paragraphs on the geology of the ores. HISTORY The first record of mining in St. Francois County, Mo., concerns more or less shallow semisurface "diggings" which were worked about the year 174-2. In 1864, however, the discovery of the disseminated deposits, the present source of lead, was made on property near the town of Bone Terre. Winslow has estimated the lead-ore production in this county prior to 1869 to be 59,526 tons.3

Jan 1, 1929

By D. A. Paice, A. B. Shimp

Illegitimate loads on a mine dc power distribution system can be detected by measuring a superimposed ac current. To implement such a scheme, a 10-volt, 3-kHz voltage is applied at each dc power substation. By this means, the mine dc power distribution network, consisting of a feeder and trolley wires with a grounded rail return, is caused to serve also as a 3-kHz ac distribution network.

Jan 1, 1975

By H. L. Riley

This report describes the methods and equipment used by the Watauga Stone Co. to drill und blast limestone in a two-level quarry, and to crush, screen, blend, and load this stone. Power requirements per ton of stone produced are reported. The personnel requirements for individual phases of the operation are tabulated in man-hours per ton of stone produced.

Jan 1, 1963

By Steven A. Fechner

The U.S, Bureau of Mines is conducting a four-year (1987-1990) study to assess the mineral resources and mineral development potential of the Valdez Creek Mining District in southcentral Alaska. This study is part of the Bureau's ongoing statewide mining district evaluation program. This report summarizes the Bureau's site specific evaluations of two areas (Tyone and Peters Creek) of the district that were investigated to determine the bedrock sources of gold and PCM in the alluvial gravel of both areas. In the Tyone Creek area, grains of gold (up to 0.0212 oz/yd3) and platinum group minerals (PCM) were recovered from alluvium and weathered conglomerate of the Jurassic Naknek Formation and Tertiary age using placer sampling techniques, Platinum and palladium were detected in the heavy mineral concentrates recovered from placer sampling the alluvium, and Naknek Formation and Tertiary conglomerates. In the Peters Creek area, grains of gold (up to 0.014 oz/yd3) were recovered from the alluvium and Tertiary Sterling Formation conglomerate. The Bureau's evaluations indicated that drainage basins containing conglomerate are the most favorable targets for placer gold and PGM exploration; and Tertiary conglomerate represents a high volume, low grade gold resource.

Jan 1, 2011

By R. V. Ramani, V. T. Burgos, J. A. McClay

General The underground mining environment has traditionally been hostile and as early mines were developed, coal seams with particularly difficult natural conditions were bypassed in favor of those more easily exploited. Barring the discovery of new and novel sources of energy, the depletion of petroleum and natural gas reserves will eventually force the United States back to the use of coal as its primary energy source. Figure 1 illustrates the trend away from coal which has taken place over the past half century. Today, the demand for coal requires a re-evaluation of all coal seams to meet the needs of the energy market. Difficult mining conditions may result in an increase in the consumption of roof control materials, require greater investment in pumping and ventilation systems, and increase the need for in-depth engineering of far greater safety in production plans. They may also cause delays in mine development and curtail production, all of which combine to drive up the unit production cost. It is reasonable to expect that conditions will continue to deteriorate as current reserves are depleted, thus bringing this factor into greater prominence in the future. For several years now, it has become apparent that in addition to economic objectives, coal companies must set and achieve several concomitant objectives to accomodate society's interest in the conservation of natural resources. Government action to meet this interest has taken the form of two categories of Federal legislation, environmental protection and employee health and safety. The effects of both of these have not been fully evaluated with respect to the total economic picture, although preliminary evidence indicates that an immediate increase in

Jan 1, 1975