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By John F. Papp

The Bureau of Mines has sampled microstructure of low-pressure flat flames by mass spectrometer for normal methane-oxygen-argon and for methane-oxygen-argon-bromotrifluoromethane flames. The physical and chemical phenomena, and the method of analysis of mole fraction data to evaluate net reaction rates are here considered in detail. Included is a computer program listing with output on one flame. Chemical species considered are CH4 , CO, CO2, H, H20, OH, Ar, H2, O2 , O, H2CO, CH3 , CF3Br, HF, HBr, Br, CH3Br, HCO, F2CO, CH2 CF2 , H02.

Jan 1, 1975

On December 16, the General Services Administration (GSA) suspended weekly sales of surplus silver from the national defense stockpile because Congress approved the Defense Appropriation Act, which contained an amendment to halt silver sales. The amendment, introduced by Senator James A. McClure (R., Idaho), prohibits sales for 6 months while the impact of the sales and alternative methods of disposal are evaluated. The GSA sold 2 million troy ounces since sales started October 14. 46.5 million troy ounces were authorized to be sold during this fiscal year and an additional 58.6 million troy ounces were authorized to be sold over the following two fiscal years. The stockpile held 139.5 million troy ounces of silver when sales began in October. Brush Wellman, Inc., a vertically integrated producer of beryllium products announced plans to modify its Delta, Utah beryllium concentrate processing facility to utilize beryllium concentrates containing as little as 7% beryllium oxide. The company plans to invest $2.5 million for this modification with completion expected in mid-1983. Implementation of this plan to consume lower grade beryllium minerals will significantly increase world reserves of beryllium concentrates.

Jan 1, 1981

By Leonard Obert

THE CRACKING AND POPPING of rock, often heard by men working underground, for years has been interpreted as a warning of danger and unstable ground. However, not until 1939 was it discovered that rock under stress generates subaudible and sometimes audible seismic disturbances (referred to as "micro-seismims" 4), which can be detected with the use of a suitable seismic apparatus. Since that date laboratory and field investigations have been in progress to ascertain to what extent this phenomenon can be utilized to detect, localize, and determine the magnitude of areas of instability in and around mine openings and to predict if and when failure will occur. These investigations have included a determination of the types of problems to which the method is applicable and the effect of rock type, geological defects, such as joints, fractures, faults, and other uncontrollable factors, on the reliability of results. Six reports have been prepared covering the investigations conducted between 1940 and 1952 (4-9). 5 These reports describe some of the characteristics of micro-seismims, as determined from both laboratory and field tests; the equipment used to pick up and record micro-seismims; the general test procedure and method of analyzing results; and applications of the method to specific mining problems.

Jan 1, 1957

By H. R. Babitzke

To develop alloys suitable for use at elevated temperatures, columbium and tantalum were combined with tungsten, hafnium, vanadium, zirconium, and titanium, and the resulting alloys were evaluated with respect to fabricability, hardness, Electrical resistivity, strength at elevated temperatures, oxidation resistance, and bend transition. Of the 23 compositions tested, Cb-2OHf-5W-10Ti exhibited superior high-temperature properties. A recrystallized sample of this alloy was fabricable at room temperature, had a strength of 44,000 psi at 1,200° C, and had an oxidation rate of only 7.7 mg/cm2/hr at 1,000° C.

Jan 1, 1966

Provide a rapid, reliable means of warning underground miners of a fire or other emergency. Approach An ultalow-frequency electromagnetic signaling system was designed, breadboarded, and tested at various under around mines. How It Works Current fire warning systems for underground mines, such as stench, audible alarms, and messengers, arc slow, unreliable, and seldom achieve total mine coverage. An ultralow-frequency electromagnetic fire warning alarm system with true through-the-earth signaling capabilities was developed to solve these problems. The system was originally designed for high-back room-and-pillar mines where stench systems are unusable due to the low velocity of mine air flow. However, the system has an application to all underground mines.

Jan 1, 1988

By Nicholas Kyriazi

A joint effort by the U.S. Bureau of Mines and the U.S. Mine Safety and Health Administration (MSHA) was undertaken to determine how well self-contained self-rescuers (SCSR's), deployed in accordance with Federal regulations (30 CFR 75.1714), survived the underground environment with regard to both impact damage and aging. This report presents findings regarding laboratory-tested SCSR's from 1982 through 1990. The SCSR's were tested on human subjects and on a breathing and metabolic simulator (BMS). These results indicate that most of the apparatus, if they pass their inspection criteria, perform as expected except for units with manufacturing defects or design deficiencies. However, when the apparatus are carried in and out of the mine daily and stored at the working section, they may suffer abuse. Physical signs of abuse, unless extremely obvious, are frequently not detected by the miners or mine operators. This poses a potential danger to a user in an emergency. Recommendations include improved training in inspection procedures.

Jan 1, 2010

By Martin Hertzberg

The concept of limit burning velocities is being used to formulate a quantitative theory of flammability limits. Competing and complicating processes dissipate power from a combustion wave and quench propagation at some characteristically low limit velocity. Two earlier reports dealt with process (a), natural convection (RI 8127); and with process (b), conductive-convective wall losses (RI 8469). This report considers process (c), radiative losses, and process (d), selective diffusional demixing. The limit burning velocity for radiative losses is [(SU)c ~ e cp] It is normally not a significant process for premixed gas flames; however, for laminar flame propagation in a gravity-free environment, it is the only loss process present. Accordingly, limit velocities at zero gravity should be much lower than on earth, and premixed gases should be flammable over wider composition ranges. For highly emissive dusts, soot, or ash-forming flames, radiative losses are significant even under normal gravity conditions. Selective diffusional demixing is a complication that manifests itself in the form of cellular flame structures and wide gaps in composition between upward and downward propagation limits. It induces a burning velocity shift (?Su)d, causing the flame to behave as though it were richer or leaner than its initial composition, depending on whether the fuel or the oxidizer mole¬cule has the higher diffusivity. A simple pertubation analysis shows that the process generates stable cellular flames whenever [dsu] > 0, where ci is the concentration of the reactant with the higher diffusivity. The same analysis indicates that at the opposite stoichiometry, where [dcu] < 0, laminar structures are stabilized. A simple formula for the diameter of cellular flames is derived, which predicts that dcell should vary inversely with the product of the diffusivity difference Di -DJ, and the burning velocity slope [dc ]. Those predictions are in good agreement with the available data. Buoyancy forces for upward propagation induce flame front curvature, and hence buoyancy and selective diffusion are mutually supportive in upward propagation. Thus large gaps in composition between upward and downward limits are present in those composition domains where cellular flames are stable.

Jan 1, 1981

By J. G. Kirby

According to the Bureau of Mines annual survey, as of January 1, 1954 there were 337 refineries with a total daily crude-oil throughput capacity of 8,006,897 barrels. The total daily capacity increased 368,236 barrels during the year while the total number of refineries declined 6. The capacity of the average refinery to process crude oil therefore increased during 1953 from 22,270 barrels to 23,759. With the exception of the Texas Inland, all refining districts reported gains in the installed capacity for the year, the largest being the Louisiana Gulf Coast with an increase of 20 percent. A total of 397,500 barrels of additional crude oil capacity was reported as under construction January 1, 1954. Accounting for 129,500 barrels of this total are facilities for 3 new refineries in North Dakota, 2 in Washington and I each in Ohio and Utah. Equipment being installed to replace existing units, totaled 180,750 barrels daily.

Jan 1, 1954

By John Nagy, Austin R. Cooper, Murray Jacobson

Data obtained in the Bureau's study of dust explosions of 313 elemental metals , alloys , catalysts , and ores comprising 54 types of material are summarized . Information is given on ignition temperature , spark energy for ignition , minimum explosion concentration , explosion pressure , rate of pressure rise , and in some instances , the admixed inert dust and oxygen concentration in an atmosphere required to prevent ignition of dust dispersions . The effects of particle diameter on explosibility and pyrophoricity are also discussed .

Jan 1, 1964

By Gerhard Braüner

The report gives a review of the methods of predicting mine subsidence; these methods are used particularly in European coalfields. The methods are subdivided into two groups, based on mathematical expressions either for the trough profile or for the influence of infinitesimal extraction elements. The fundamental relationships common to all methods described herein are the principles of superposition and of equivalent extraction areas. The involved parameters are derived from field observations. For calculating horizontal displacements, their relation to the slope of the subsidence profile is applied. The time-dependent development of the subsidence process is characterized by the empirical "time factor." Modifications for the case of inclined strata are considered. A brief review of experimental and theoretical model investigations is given.

Jan 1, 1973

By Ted C. Briggs

Twenty-two compressibility runs were made with helium over the temperature range -5° to 80° C and at pressures to 800 atmospheres. A Burnett apparatus was used. Data from the runs were fitted to a fourth degree polynomial equation of state in the pressure and a weighting factor of Pr-3/4 was used. All data for a particular isotherm were treated simultaneously. A temperature function was found to represent the parameters B and C. Compressibility factors determined by this investigation are believed to be accurate to better than 0.05 percent.

Jan 1, 1970

By John B. Knaebel

Hammer machines are now widely used for underground sampling and exploration. Their application to such work can be divided into two classes - sampling and testing with ordinary drilling equipment to shallow depths of 22 feet or less, and "long hole" drilling with heavy machines and special equipment to depths of as much as 250 feet or more. In the first category hammer drills are employed for either of two distinct purposes: first, as a means of checking the results of grab or cut samples or, in certain types of ore deposits, as a substitute for these methods; and second, as a method of sampling the ground 5 to 20 feet beyond existing faces and thus aiding in the control of stoping operations or in the direction of development headings, as the case may be. The deep-hole drill, in the second category, has proved to be a valuable adjunct to the old established methods of exploring, end developing ore, provided it is employed under natural conditions to which it is suited, handled by men thoroughly familiar with the technique of its operations, and used with its possibilities and limitations clearly understood.

Jan 1, 1932

By H. C. Miller

The success of any project in which gas is injected into oil-producing sands to increase the current rate or the economic ultimate production of oil or in which surplus gas from oil producing operations is stored temporarily in reservoir sands that have been wholly or partly depleted of their producible oil depends mainly upon an understanding of the underground movements of oil, water, and injected gas and the ability to control their speed and direction of migration through the reservoir sands. Many operators believe that injected gas always travels up the structure and drives oil to wells structurally higher than the injection wells, because the specific gravity of the injected gas is less than that of the fluid substances in the formation. Consequently, many injection wells are located on the flanks of oil-bearing structures with the idea of utilizing the energy of the injected gas to drive the oil to producing wells higher on the structure. It is true, under certain conditions of pressure and fluid depletion of the reservoir sands, that injected gas will move in an up-structure direction, but the theory that injected gas always moves up the structure is based on an erroneous conception of the laws that pertain to the expansion of gases. By definition, "a gas is distinguished by its property of infinite expansion and is limited in volume only by the walls of the vessel which contains it."3 The expansion of gas that is injected into reservoir sands also is limited by "walls" that surround the space influenced by the injected gas. The walls of the majority of undrilled or virgin oil-bearing reservoirs in California are the impervious shales overlying and underlying the productive strata and the "dams" or effective barriers of edge water around the rims of the reservoirs. When gas is injected into the sands of a producing reservoir, regardless of the location of the injection well on the structure or the degree of depletion of oil from the sands, one of the walls which confine the gas in the structure about the injection well is fluid. This wall will be edge water in a nearly depleted reservoir, where the drainage cones or regions of reduced pressure about injection and producing wells intersect; and, where there is no interference of drainage cones and the injection well is structurally above the edge water, the wall will be oil. In some producing reservoirs bottom water may be the lower wall of the space that confines the gas about injection wells, but the effect of bottom water on limiting the expansion of gas is the same as if the water was not present and impervious formation separated the producing from the underlying nonproducing strata. Therefore, since compressed gas always seeks regions of reduced pressure and its final volume is limited only by formation and fluid barriers and since the force exerted by the gas under pressure is equal in all directions, the course of migration of injected gas in reservoir sands in California and the

Jan 1, 1932

By O. C. Blade

This report on the properties of motor fuels sold through service stations in the United states was made in accordance with a cooperative agreement between the American Petroleum Institute and the Bureau of Mines of the United states Department of the Interiors This paper is a continuation of a series made in cooperation with the Coordinating Fuel Research (CFR) Committee of the Coordinating Research Council (CRC), Inc. The first of this series of reports presented data on motor gasolines sold during the winter of 1935-36, and succeeding reports described motor gasolines sold during the summers and winters to and including the summer of 1941.£1 No reports were made on motor gasolines sold during the winter of 1941-42 and during the summer of 1942. However, starting with the winter of 1942-43, the semiannual reports were resumed

Jan 1, 1949

By ALICE V. Petar

Among the rarest of the rare metals are four that are linked together by a common historical background as well as by chemical relationship. With the excep- tion of indium, these metals are likewise characterized by the patriotic nature of the names given them by their discoverers. The existence of gallium, germanium, and scandium, was predicted by the Russian cherist, D. I. Mendeleeff some time prior to their discovery; and these elements might well have been overlooked, had not the search been stimulated by the urge to confirm the scientific hypothesis of their existence. Nowhare found in sufficient quantities to attract attention, these little known elemente are nevertheless widely distributed in the earth's crust. So far they are found commercially mostly in the sulphide ores of zinc and must be considered as being largely curiosities of the zinc smelter. Recent progress in electrolytic zinc refining, however, now gives promise that the way may be open for the recovery of these very rare metals in larger quantities-- possibly in quantities sufficient to permit of their finding commercial utilization.

Nov 1, 1930

By E. K. Stanek

This report contains results of two major efforts related to electrical transients on mine electrical power systems. The first area concerns the use of digital computers to model mine electrical power systems and predict transients or duplicate field recordings of transients. Two existing general purpose circuit analysis programs were used. The first was the TRW Engineering System Simulator or TESS. The second was Electronic Circuit Analysis Program or ECAP. TESS proved to be superior to ECAP in several important characteristics, including system size limitations and modeling nonlinear elements. The second major topic covered in this report is the evaluation of commercially available surge suppression devices. These devices were found to be quite acceptable and guidelines for the selection and placement of surge suppressors were included. The final important item is a listing of the worst-case transients, from a design point of view, for ac and de utilization systems and ac distribution systems.

Jan 1, 1979

By Robert H. Bedford

As a result of the Bureau&apos;s general survey of quicksilver deposits in California, the Guadalupe mine area was among those chosen for exploration. Exploration, such as that at the Guadalupe, was aimed primarily at maintaining or increasing production of quicksilver during the critical wartime period. The project as originally planned contemplated sampling the dumps and prospecting some promising surface exposures by bulldozer trenches. Salvage was the objective in the first case and new ore in the second. Later, a program. of diamond drilling was added, designed to add both to ore reserves and to geological information. This report summarizes the history, notes the location and physical features, mentions property and ownership, and presents a brief description of the mine. The geology is outlined, and the work done by the Bureau of Mines is explained and supplemented with accompanying maps. The work involved repairing 1-1/4 miles of roads; bulldozing 13 trenches by removing 2,345 cubic yards of dumps to provide for sampling; digging and sampling 9,284 linear feet of hand trenches, digging and sampling numerous test pits; and drilling 7 diamond-drill holes, totaling 1,000 feet. A total of 419 samples, including 10 percent check samples, were taken. Exploration work in California at the time of this project was under the direction of Spangler Ricker, supervising engineer of the California field office, the late Robert Bedford was in charge of the fieldwork on this project.

Jan 1, 1950

By D. Harrington

"In at least three out of every four working faces in metal mines there is no attempt made to cause air circulation other than by use of compressed air, and in at least nine cases out of ten the compressed air is released merely by opening, or partly opening, the valve and allowing the compressed air to escape through open air hose used to convey the compressed air to the drilling machines. Usually no blowers are in use during periods of drilling, as the exhaust from the drill provides cool, comparatively fresh air for the driller; however, in some instances, the compressed-air line is provided with a tea connection, which permits taking air for the drill from one side of the tee, and air for ventilation through a separate hose used as a blower, simultaneously with drilling.Table 1 contains temperature and humidity data as to compressed-air blowers from open end of air hose at 36 working places in eleven metal mines of four States, embracing the mining of gold, silver, copper, lead and zinc ores, and at horizons ranging from 500 feet below the surface to as low as 4900 feet.It is noticed that the ordinary air surrounding the worker at the face gives an average wet bulb temperature of 81.7° F. for the 36 working faces, with 84.7° F. dry bulb and 87.2 per cent relative humidity. The average wet bulb tem¬perature of 36 readings at these working faces of compressed air at the end of the,hose as the air issues from the hose was 67.4° F., or 14.3 degrees lower than the average wet bulb readings of the air of the working places; however, the average dry bulb temperature of the 36 readings of compressed air as it issued from the end of the hose was 79.7° F., or only 5 degrees less than that of the general air (84.7°); the relative humidity was 51.1 per cent as against 87.2 per cent for the surrounding air. Readings were taken in five raises, seven crosscuts, ten drifts and 14 stopes.It will be noted that the velocity or movement of the general atmosphere at each of the entire 36 working faces, was found to be practically imperceptible; this might readily be inferred since compressed air is rarely used on blowers if there is adequate circulation of the general air of the place. Where rook temperatures could be obtained readily, they are shown; it is noticeable that the dry bulb temperature of the air of the working place varies little from the rock temperature, and that the dry bulb temperature of the compressed air as it issues from end of air hose varies only a few degrees from the temperature of the surrounding rock; in some instances the dry bulb temperature of the compressed air as it issued from the end of the air hose was higher than the rock temperature or the dry bulb temperature of the surrounding air."

May 1, 1921

By R. P. Bush

The U.S. Bureau of Mines performed Cu exchange capacity (CuEe) tests on Ca and Na mont-morillonites and attapulgite clays. Mathematical models were developed from the data that the CuEe&apos;s are derived from for each clay as a function of pH, Cu concentration, and the concentrations of metal ions, which compete with Cu for exchange sites. An analysis was made of the impact of competing ions on Cu losses due to ion exchange. The results show that the CuEC&apos;s of clays, and hence Cu losses, are decreased by the presence of competing ions, and that AI and Mg have the largest impact of those cat-ions normally present in Cu leaching solutions.

Jan 1, 2010

By Bertha R. Klahold

"In response to numerous inquiries regarding tests and analyses of minerals and related inorganic materials; Bureau of Mines Information Circular 6999, ""Laboratories That Make Fire Assays, Analyses, and Tests on Ores, Minerals, Metals and Other Inorganic Substances,"" by C. W. Davis and M. W. von Bernewitz, was published .in 1938 and revised in 1939 (I. C. 6999R). In this paper on analytical and testing laboratories, the original text has been rewritten and expanded, and a table has been added, in which are listed laboratories prepared to offer a number of special testing services in addition to ordinary assays and chemical analyses. The arrangement of laboratories on, a geographical basis has been maintained.This circular is compiled as a public service, and none of the laboratories listed herein is recommended over any other,These lists were compiled from questionnaires sent to organizations whose work is connected with mineral and metallurgical testing. The response in general was very satisfactory, and the author takes this opportunity to express her appreciation to the officers of the listed laboratories for their cooperation.Acknowledgment is also made of the valuable assistance of the members of the technical staff particularly Morris Slaving/ of the Eastern Experiment Station of the Bureau of Mines at College Park, Md., in the preparation of the questionnaire and technical descriptions.Many mineral samples are sent to government agencies in the National Capital with the request that they be assayed or chemically analyzed. It should be emphasized that there is no place in Washington D. C. where assays and quantitative analyses are made for the public b the Federal Government.Virtually all of the States maintain a bureau of mines, a geological survey, or some similar organization, frequently at the State University, where minerals found by residents of the State will be identified free of charge. Usually, a charge is made for assays. Specific tests, as on clays, are made by some of these offices.The Federal Bureau of Mines, although it attempts to avoid duplication of services rendered by State Bureaus, is always glad to give advice as to prospective markets. It does not compete with private assayers and chemists, but with respect to samples sent to its field laboratories, it does offer to identify them as far as this can be done by inspection and simple optical and chemical tests. This examination is usually sufficient to indicate whether the material has commercial value, or at least if the expense of an assay would be warranted. Except in connection with its own technical investigations, no assays or other special tests are made by the Bureau of Mines.The Federal Geological Survey and the National Museum also make simple tests of specimens as a public service. Neither of these bureaus nor the Bureau of Mines, however, can afford to render such services on long suites of specimens submitted by mineral dealers, well drillers, or others, when such work can be done regularly by commercial concerns."

Oct 1, 1949