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By X. N. Hu, X. Shi, V. Vallyathan, N. S. Dalai

"Although silicosis has been studied extensively, the mechanism is still not fully under stood. Experiments do provide evidence that the actions of unique properties of silica surface on the cell membrane are the starting point of silicotic processes. This paper summarizes literature on chemical properties of silica surface, and the effect of particle size on silica toxicity. This paper also discusses the ways in which silica dusts are thought to interact with the cell membrane, with emphasis on freshness, hydrogen bonding, and free-radical interactions.INTRODUCTIONSilicosis is a debilitating pulmonary disease that afflicts persons (miners, foundry workers, ceramic workers, heavy construction workers, etc.) who chronically inhale silica-containing dusts (Schepers, 1960; Silicosis and Silicate Disease Committee, 1988). Since silica is second only to oxygen in weight percentage of the earth's crust (about 28%) and is found in an enormous diversity of minerals, it is natural that silicosis is one of the Major industrial health hazards all over the world. Although silicosis has been studied extensively, the mechanism by which the dusts exert their toxic actions on cells and the processes by which these-actions progress to fibrogenesis are still poorly understood. The biological characteristics of the dusts are largely unknown, although it is suggested that the dust size, shape, surface charge, roughness, surface chemical composition, trace metal content, and crystallinity; dose of silica in the ambient air of the workplace; duration of exposure; genetic variation in exposed sub¬jects; personal respiratory patterns; and presence of any coexisting dis¬ease (such as tuberculosis or rheumatoid arthritis) all influence the ex¬pression of silicosis (Koskinen et al., 1983; Noweir et al., 1980; Raask and Schilling, 1980; Reiser and Last, 1979; Thorne et al., 1985; Wolff et al., 1981). The actual biochemical mechanisms through which these factors operate are still unclear. However, the experiments do provide evidence that the actions of certain unique properties of silica surface on the cell membrane are the starting point of the silicotic process (Allison et al., 1966; Allison and Harrow, 1971; Bateman et al., 1982; Marks, 1957; Parazzi et al., 1968; Reiser and Last, 1979; Summerton et al., 1977). This article summarizes literature on chemical properties of silica dusts and how silica dusts are thought to interact with the cell membrane, with emphasis on hydrogen bonding and free-radical interactions."

Jan 1, 1989

By M. B. Cooke

An analytical method for the determination of the gum-forming material in gasoline has been developed by the Bureau of Mines, during a study nor in progress to determine the best rays for elimination of such constituents from gasoline. This method is similar in principle to that previously described by Smith end Cooke,2 which involved evaporation of e sample of gasoline in a small glass dish. The evaporation was started on an actively boiling steam bath and completed in an air oven at 105°C. In the improved method described below, the stem bath has been replaced by a steam heated oven in which an inert atmosphere is maintained. Air is excluded from the oven, consequently the precision of the determination is increased. Furthermore, evaporating dishes different from those previously described may be used.

Jan 1, 1925

By G. R. Palmer

Preliminary studies by the Bureau of Mines were conducted to determine the feasibility of a multiple-compartment, ion-exchange (MCIX) column simulator for examining the effect of multiple-orifice plates in the column. A rectangular, five-orifice, three-compartment, MCIX simulator with a cross-sectional plate area of 0.66 ft2 was used for the investigation. Orifices with open areas of 1, 3, and 5 percent were used with various operating conditions. The study was separated into three separate sections: (1) solution flow effect, (2) fluidization effect, and (3) resin transfer effect. The solution flow and fluidization studies showed that for solution flow rates of about 3 gpm/ft2, a I-percent open area plate functioned best, while at solution flow rates of 9 and 15 gpm/ft2, the best open areas were 3 and 5 percent, respectively.

Jan 1, 1981

By J. H. Holden

The Federal Bureau of Mines is doing research and development work on a pressure-gasification pilot plant for producing synthesis gas directly from pulverized coal, oxygen, and steam. A pressure-gasification pilot plant has been constructed, and an investigation was made with the following basic objectives: 1. Determining the effect of varying pressure (75, 100, 150, and 300 p.s.i.g.), coal rate (400, 700, and 1,000 pounds per hour), and oxygen-to-coal ratio (8 to 11 std, c,f. per pound), on percentage of carbon gasified, oxygen and coal requirements per unit of CO + H2 produced, exit-gas temperature, and heat loss. The steam-to-coal ratio was maintained at approximately 0.3 pound per pound. 2. Development of a stabilized gasification zone or reaction space. 3. Improvement in operability of the pilot plant.

Jan 1, 1960

By B. W. Gandrud

In July 1948, the Bureau of Mines, United States Department of the Interior, in cooperation with the University of Alabama and mine operators, published Report of Investigations 4306, "A Combination Cleaning and Dewatering Process for Treating Fine 'Sizes of Coal, Preliminary Report In this report a new process, referred to as kerosene flotation; was described, and results of experimental work with the process Previous to the fall of 1947 were given, The contents of the report. were summarized on pages 19 and 20' as follows: In coal-preparation plants using wet methods of cleaning, the most difficult problem is the cleaning and dewatering of the "fines" from about 10-Mesh to 0. A combination proceed is now under investigation that shows promise of practically and feasibly solving this problem. The process is similar to froth flotation, but a generous quantity of kerosene is used as one of the reagents, and the feed is from approximately 10-mesh to 0 considerably coarser than the usual froth flotation feed. The kerosene and the coarseness of the reed result in a floated product that, under certain circumstances, can be dewatered satisfactorily by a simple process of mechanical squeezing, Squeezing is accomplished by means of an ordinary conveying' Auger-and trough assembly with a section of pipe easing at the outer end of the trough. The bottom of the trough and. casing is fitted with wedge-wire sections to permit escape of the water freed by the squeezing action of the auger. On account of the important role of the kerosene, the process has been referred to in this report as kerosene flotation. Up to now, the investigative work has been divided about evenly between the laboratory and commercial plants. Nearly all of the work has been done on sludges containing the solids from the underflow of dewatering screens. A few runs have been made on 10-mesh to 0: fines from raw coal, but in some of those runs the dewatering mechanism, failed to function.

Jan 1, 1950

By P. Nicholls

[This paper sets forth the burning characteristics of coke used as a domestic fuel as shown by work of the U. S. Bureau of Mines and others. Coke is a truly smokeless solid fuel and is held in high regard for this quality. Ways are being found for making commercial coke from a wider range of cools than heretofore, and tale use of coke for domestic heating is increasing. ACKNOWLEDGMENTS The experimental work reported in this paper was conducted at the Pittsburgh Experiment Station of the U. S. Bureau of Mines cinder the authority of O. P. Hood, chief mechanical engineer; M. L. Orr, assistant feels engineer, and W. M. Brewer, junior fuels engineer, assisted by Charles Schramm cooperated in making the tests.]

Jan 1, 1929

By P. G. Barnard

The Bureau of Mines investigated the effects of various additions of rare-earth metals or rare-earth oxides on the mechanical properties of cast and wrought plain-carbon steels. Rare-earth metals, as misch metal, were added to medium-carbon steel in amounts to 0.70 weight-percent; rare-earth oxides, as a commercial mixture, were added in amounts to 1.50 weight-percent. The melting and casting of conditioned steels were done in a vacuum-induction furnace, to avoid formation of oxides from the melting atmosphere and to pro-vide better control over chemical composition. At room temperature, data for tensile strength, yield strength, elongation, and hardness of cast and wrought steels were obtained by standard testing equipment and procedures. Impact tests were conducted on as-cast steel specimens. The greatest amount of tensile ductility and impact strength was obtained in as-cast steel with 0.50 to 0.70 weight-percent misch metal additions. No significant improvement on mechanical properties was indicated in wrought steels containing rare-earth metal additions in the range from 0.10 to 0.70 weight-percent. In general, the rare-earth oxide additions up to 1.50 weight-percent had little effect on the tensile properties of steel in the cast, wrought and annealed, or wrought and normalized condition.

Jan 1, 1967

By Lucien Eaton

This paper describing the mining practices at Mine No. 1, Menominee Range, Mich., is one of a. series being prepared by the Bureau of Mines on mining practices, methods, and costs in the various mining districts of the United States. It is felt that the publication of this information will be of interest and value to the mining industry at large and especially to operators whose mining conditions are similar to those described. ACKNOWLEDGMENTS The author is indebted to the superintendent, engineer, and mining captain of Mine No. 1 for much of the information presented.

Jan 1, 1929

By Margaret R. Egan

The Bureau of Mines subjected three commercially available brands of transformer fluid to a series of combustion studies. The experiments were conducted in the intermediate-scale fire tunnel, which was designed to simulate environmental conditions in underground mines. The work was divided into three phases. In phase one, the brands were compared for gas production, smoke characteristics, and combustion yields. In phase two, the production constants of transformer fluids and other fuels were compared for the rate of formation of gas and smoke as a function of fire size. In phase three, several diameters of liquid-pool fires were compared in terms of fire size and burning rate. These transformer fluid measurements will be added to the existing coal and wood data that can be used as a basis of comparison for future studies of other mine combustibles. Further research into the combustion product emissions from combustible materials found in underground mines will lead to improved and realistic fire detection and suppression systems,

Jan 1, 1986

From the National institute for Occupational Safety and Health Disasters take many forms and demand quick response from emergency workers. They may include natural disasters such as earthquakes or hurricanes, or they may involve manmade disasters such as technological failures or terrorist attacks. As a member of an emergency response team, you and your team members are at risk of experiencing what psychologists refer to as a traumatic incident—an incident that may Involve exposure to catastrophic events, severely injured children or adults, dead bodies or body parts, or the loss of colleagues, for instance. Traumatic incidents can produce unusually strong emotional reactions that may interfere with your ability to function at the scene or later: You may experience any of the physical, cognitive, emotional, or behavioral symptoms listed below in Table 1. Some people experience emotional aftershocks weeks or months after they have passed through a traumatic event. Others may experience these reactions while still at the scene, where they must stay clearly focused on constantly changing hazards to maintain their own safety and to rescue injured victims.

By W. D. Mcmillan

Although the Shafter district of Presidio County, Tex., is principally renowned for silver production from the Presidio mine, the occurrence of lead-zinc ores in the western part of the district has been known for at least 50 years, and there has been some production. An area of about 3 square miles in the vicinity of an extending westward from the Presidio mine was investigated in detail by C. P. Ross of the Federal Geological Survey in 1934. In the fall of 1943, A. B. Needham, an engineer of the Bureau of Mines, called the attention of the Geological Survey to the area west of that included in Ross's map, and requested a detailed investigation of that area by the Survey in advance of development by the Bureau of Mines. After a brief reconnaissance by the Survey in the spring of 1944, detailed studies were made by Federal geologists in the summer of 1944, during which about 450 acres were surveyed, on a scale of 1 inch to 100 feet. Recommendations for the exploration of certain parts of the area were made in the accompanying report.

Jan 1, 1949

To pinpoint dust sources and to improve dust control on longwalls. Approach Use short-term gravimetric sampling to determine the severity of various dust sources, and to evaluate dust control techniques used in longwall mining. Short-term gravimetric sampling can be used to isolate dust levels produced by various dust sources. How It Works Traditionally, gravimetric samples have been collected over an 8-hour shift, yielding time-weighted, average dust concentrations. This method gives a good indication of the full-shift respirable dust exposure of underground workers, but is less than satisfactory for identifying dust sources, determining their severity, or for evaluating the effectiveness of dust control techniques. Short-term gravimetric sampling uses equipment available to all mine operators. Two individuals composing the survey team each collect multiple (three to four) gravimetric samples during selected segments of the mining cycle. Multiple samples are necessary to insure accuracy, and to obtain a valid average measurement of the respirable dust concentration when sampling for short periods of time (typically 20 to 30 minutes). The gravimetric instruments may be carried in a sampling package or in a "sampling vest." A fishing vest with four large pockets can be used for this purpose. The sampling pumps are carried in pockets and the sampling head assemblies arc hung across the front of the vest.

Jan 1, 1982

Lower noise exposure levels for operators and cleanup personnel working in portable nonmetallic mineral crushing and screening plants.

Jan 1, 1983

By R. V. Ramani

In this the available information friction factors and leakage report, on characteristics are reviewed and summarized. The use of Penn State Mine Ventilation Simulator (Volumes II and III of the Final Report) to analyze the sensitivity of the ventilation system to the changes in leakage and friction factors is discussed with examples. In simple ventilation systems, the results of changes in leakage and friction factors can be easily solved and explained by the laws of air-flow. In complex systems, with fixed quantity branches and multiple sections, the effect of changes in leakage and friction factors cannot be generalized. This study points out the importance of good input data for obtaining reliable information from computer analyses and demonstrates the application of simulators to analyze the effectiveness of ventilation systems. An extensive bibliography on friction factors, leakage characteristics and ventilation economics is included.

Jan 1, 1977

By C. H. Riggs

This report presents pertinent data on all active water-flooding projects in Washington County, Okla., and describes in detail the operation and production history of five representative floods. The flooding of partly depleted oil-bearing sands to produce petroleum that would not be recovered by other methods is becoming increasingly important to the oil industry. In 1942, two water-flooding projects in Washington County produced 35 barrels of oil daily from 90 developed acres. In March 1951, 4,000 barrels of oil was being produced daily by the injection of 58,000 barrels of water on 19 active projects covering 1,645 acres. Several projects are being extended, and new operations are being initiated. Figure 1 shows the location of the active water-flooding projects in Washington County. The yearly oil production from Washington County increased from 1,076,000 barrels in 1948 to 1,720,000 barrels in 1950, owing principally to the effects of water flooding. To March 1951, permits to flood more than 8,000 acres in Washington County had been granted by the Oklahoma Corporation Commission.

Jan 1, 1951

By Robert G. Bottge

Hard rock mining has grown in importance in the Yukon Territory during the last 10 years while Alaskan hard rock mining has declined. One asbestos deposit in Alaska is dormant, but an asbestos deposit 55 miles to the east in the Yukon Territory is being mined by the Clinton Mine Div., Cassiar Asbestos Corp., Ltd. In this Bureau of Mines report, the economics of mining in the two locations were derived using the Clinton mine as a model. Both deposits were assumed to be of equal size and mined by similar methods. Conventional open pit mining and processing methods were assumed, and capital and operating costs were derived using flowsheets and standard costing methods. The estimated cost for the mine, mill, and support facilities in Alaska was about 30 percent more expensive than that in the Yukon Territory. The higher labor rates in Alaska were the primary contributor to the higher construction costs; freight rates added only slightly to the total costs. Approximately two-thirds of the additional annual costs of operating in Alaska were for wages and fringe benefits. The price required for the Alaskan asbestos fiber was $356.65 per ton compared with $287.44 for Yukon fiber, plus or minus 20 percent. A 12 percent discounted cash flow rate of return, 100 percent equity financing, and a rapid writeoff of assets were assumed.

Jan 1, 1975

By K. J. Liles

This Bureau of Mines paper describes the composition and properties of drilling fluids for use in high-temperature geothermal wells, and summarizes the problems encountered with fluid use at the known major geothermal sites throughout the world. These include the western continental United States, Hawaii, Italy, Iceland, Japan, New Zealand, and Turkey. Water-base drilling fluids of 9- to 10-lb/gal weights are relied on primarily for geothermal well use, although air drilling is sometimes used. Bentonite-lignite-water systems have been used most often, and additives such as polyacrylates, lignosulfonates, and chromates are employed to improve the properties of the basic system.

Jan 1, 1976

By T. J. Ballard

The Rickard mine in York County, S. C., named for the original owner, Alexander Rickard, was operated about 50 years as. No records are available of the quantity of corundum shipped. Pratt states, "Many tons were picked up from the surface and shipped." The mine was visited on August 6, 1943, by the author, accompanied by Gilbert W. Withers of Atlanta, Ga. Investigation of the property was begun by the Bureau of Mines after some initial work by the Mi-Cor Corp., a company organized by Gilbert P. Withers of Atlanta to explore the property. In conducting the Bureau program, 754 linear feet of trenches were dug, 110 feet of old drifts cleaned out and examined, and 38 feet of shaft retimbered.

Jan 1, 1948

By R. E. Cerullo

Many computer programs have been written which are capable of performing a least squares fit, both linear and nonlinear, to data gathered by the petroleum researcher. However, when the petroleum engineer tries to program methods of analysis he has used manually in the past, such as forecasting production by decline-curve analysis, more than a knowledge of the use of existing least squares programs becomes necessary. It is the intent of the authors to report the techniques used in the development of such a decline-curve program.

Jan 1, 1970

By Joseph E. Matta

The Bureau of Mines conducted a field study to investigate thin suppression of respirable dust by water sprays on a continuous-mining machine. Determining the importance of the top and bottom sprays for two types of spray nozzles was emphasized. Results showed, at a 90-pct confidence level, that (1) at least 70 pct of the dust was generated during the sump cut, even though nearly half of the coal was mined during the downshear operation, (2) the water sprays on the top of the boom had little effect in suppressing respirable dust, and (3) B.D. 5 spray nozzles mounted beneath the boom reduced dust at least 33 pet more than B.D. 5 sprays mounted on top of the boom. A single-cut technique was developed that gave good reproducibility for replicate cuts (coefficient of variation of 20 pct).

Jan 1, 1976