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By T. H. Jeffers

The U.S. Bureau of Mines has developed porous beads containing immobilized biological materials for removing metal contaminants from waste waters. The beads, designated as BID-FIX beads, are prepared by blending biomass, such as sphagnum peat moss or algae, into a polymer solution and spraying the mixture into water. Laboratory studies were conducted to determine bead sorption and elution characteristics. Batch and continuous tests demonstrated that BIO-FIX beads sorbed arsenic, cadmium, lead, and other toxic metals from acid mine drainage waters collected from several sites. Selectivity for heavy and toxic metal ions over calcium and magnesium was demonstrated. The beads exhibited excellent metal sorption and handling characteristics in stirred tanks, column contactors, and a low-maintenance passive system. The sorption process was reversible, and metal ions were eluted from the beads using dilute mineral acids. Cyclic tests indicated that the beads continued to extract metal ions after repeated loading-elution cycles.

Jan 1, 1991

By K. L. Paciorek

The aim of the present study is to determine on a gram per gram basis the toxic products of the thermal oxidative degradations of selected compositions. Four families of materials were investigated under the subject contract namely polyvinyl chloride and neoprene compositions, rigid urethane foams I and woods. Three methods were employed to conduct the thermal oxidative degradations: a sealed system (quiescent environment) I a stagnation burner arrangement (dynamic environment) I and a flow-through apparatus (dynamic I but less severe than stagnation burner conditions). The majority of tests were conducted using the first two systems; only limited experiments were carried out employing the third decomposition procedure. All decomposition was done at temperatures of 370 -4000C I the higher temperature being used in the stagnation burner. It has to be stressed that the nature of the products and the relative product concentration are temperature dependent. Thermogravimetric and differential thermal analyses were performed to supplement and extend the above delineated studies and to explore the feasibility of using these analyses as a method for material differentiation.

Jan 1, 1973

By R. L. Marek

The number of persons fatally injured in the California petroleum industry, in 1932 was 24, a decrease of 6, or 20 percent from the number killed in 1931. The decrease in the number of fatalities occurring in 1932 caused the fatality curve of the California petroleum industry to reach its lowest point in 10 years. Changing conditions in the oil industry--reduced personnel, decreased active field development, and curtailed production--have undoubtedly caused a part of this decrease, but continued accident-prevention efforts by the industry have also contributed to the reduction in the number of fatalities for 1932. The Bureau of Mines has analyzed and reported annually the fatalities in the California petroleum industry for a period of 10 years. Figure 1 shows the trend of fatal accidents during that period.

Jan 1, 1933

By W. L. Dare

Tri-axial strains in pillars, created by pillar robbing, were measured in an experiment at the Dysart No. 1 uranium mine near Grants) New Mexico. At this mine, room-and-pillar stoping is used on the advance, and pillars are recovered on the retreat. The are deposit is, for all practical purposes, horizontal. Measuring devices were installed in pillars approximately 90 to 200 feet from the break line, and strains were recorded over a 4-to 6-week period. The measurements indicate that, in general, the algebraic magnitude of vertical strains increased, and the horizontal strains decreased, in turn, indicating that vertical (or near vertical) loads on the instrumented pillars lessened as pillars were recovered.

Jan 1, 1962

By R. H. Hiltz

The Coal Mine Health and Safety Act of 1969 legislated maximum dust levels for the working place. As the law was implemented, extensive efforts were undertaken to provide the technology necessary to control dust generation. One approach to dust control was the use of high expansion foam in place of the usual water sprays on coal cutting equipment. At the time of the act, high expansion foam had already seen considerable testing for the suppression of dust in underground coal mines. Work by MSA, several coal companies and the Bureau of Mines itself had provided data which showed foam to have some merit as a dust control mechanism. It suffered in a few areas, however, which limited its practical application. Its principal difficulty was persistence which hampered operations due to foam buildup, but problems were also encountered due to equipment size and form.

Jan 1, 1975

By F. G. Scott

This document is a proposed program plan for mining environmental research to be conducted by the U.S. Bureau of Mines in support of industrial oil shale mining and processing. This program plan is one of three research alternatives being considered by the Bureau, each based on a different level of anticipated funding. This report documents the low funding level program plan.

Jan 1, 1980

By Fred V. Carrillo

Of the total quantity of secondary copper and zinc that became obsolete in the United States from 19b1 through 1970, more than 11 million tons of copper and 10 million tons of zinc were not recovered. These estimates are based on a study of the flow and recovery of old copper and zinc scrap by consumption end-use. This report describes (1) where copper and zinc are being used; (2) when they become obsolete and available as secondary metal; (3) how they are being collected for recycling; and (4) how much might be recovered from scrap that presently is not being recycled.

Jan 1, 1974

By W. E. Robinson

Differences in the composition or chemical structure of the organic material in samples of Uinta Basin (Utah) oil shale were studied relative to stratigraphic position within the Green River Formation. This involved a systematic study of the soluble organic material and the insoluble organic material (kerogen) present in the samples. Emphasis was placed upon the distribution of the alkanes (normal and isoprenoid compounds) in the soluble extracts and upon the aromaticity of the kerogen. Significant differences exist in the chemical composition of the organic material from various strata within the Uinta Basin, some of which were related to burial depth but most were related to source material variations, environmental differences, or other factors. The Uinta Basin samples differed significantly from Piceance Creek Basin and Green River Basin samples in the large amount of soluble extract they contained.

Jan 1, 1975

By C. T. Baroch

CESIUM-137 ISOTOPE began to displace cobalt-60 III the treatment of cancer during 1956. Production and Consumption.-Consumption of cesium and rubidium was approximately the same as in 1955. Production, however, decreased, as several companies shipped from stocks produced in previous years. South Africa was the source of most cesium and rubidium minerals used in the United States in 1956. Cesium and rubidium metals and compounds were produced from ore by: DeRewal International Rare Metals Co., Philadelphia, Pa.; Fairmont Chemical Co., Inc., Newark, N. J.; Foote Mineral Co., Philadelphia, Pa.; and Rocky Mountain Research, Inc., Denver, Colo. Most sales were to domestic consumers, but small quantities were exported to Australia, England, Germany, and Sweden. New production facilities were under construction in. 1956 by San Antonio Chemicals to produce mixed potassium, rubidium, and cesium carbonates. A plant capable of separating and packaging 200,000 curies of cesium-137 annually was under construction at Oak Ridge National Laboratory.6

Jan 1, 1958

By Don Conrad, Tom Friend, Bill Wiehagen, Lynn Rethi

On-the-job training (OJT) is a very common method of teaching job skills. Much of the training is done by experienced workers. This paper discusses small investments that can help improve the effectiveness of OJT. Effective OJT involves some structure and planning in the transfer of responsibility for task performance from the trainer to the novice. Assisting the OJT trainer could involve helping develop up-to-date job analyses and offering strategies for teaching and evaluating job skills. The scope of this paper addresses (1) organizational considerations supporting structured OJT, (2) general strategies for structuring OJT, (3) a typical approach for conducting OJT, (4) characteristics and duties of OJT trainers, and (5) limitations of OJT as a teaching method. Health, safety, and operational skills can be connected through training. Haul truck operator training is used to illustrate some of the concepts discussed in this paper.

Jan 1, 2002

By G. Andrews

This case study details the process that was used for project planning and permitting for the Greens Creek Mine, located near Juneau Alaska, as seen through the eyes of one of the primary environmental consultants. This case shows how a Company could involve the public and the agencies in the early 1980's and develop a project sensitive to concerns expressed with a high level of environmental protection. Comparisons are made to the current environmental permitting situation. Initial baseline studies performed during the exploration phase provided helpful information for more detailed environmental work in 1980-1981 as planning and permitting formally got underway. Since the mine was in a National Monument and abuts up to a designated wilderness, the Monument Manager administered the project for the lead agency, the USDA Forest Service. Planning and permitting progressed smoothly to a Final Environmental Impact Statement (FEIS) in 1983. Metal prices were depressed when the FEIS was completed and the project permitting proceeded slowly. Ownership changed several times in the mid-1980's. New owners re-evaluated the project and suggested five changes that required a supplemental EA prior to development. The project was fully permitted and started construction in 1988. Operation began in 1989. Today the environmental process in southeast Alaska is now much more complex, detailed, expensive, and time consuming than in the early 1980's. Significant issues discussed that may impede development and operation include overlapping agency jurisdictions, personal agendas of agency staff, conflicts between agencies that impede project progress, changing regulations, and a well organized environmental opposition.

Jan 1, 1993

By J. R. Nettle

The purpose of these studies by the Federal Bureau of Mines was to determine the feasibility of refining low-grade hafnium by an inert-gas-shielded molten-salt electrorefining technique to produce a hafnium metal meeting reactor specifications. The techniques were adapted from those used success-fully for titanium electrorefining. Three electrolytes containing hafnium chlorides were developed from which deposits having a Brinell hardness of 170 or below were recovered. A KC1 + NaC1 + HfC14 electrolyte produced deposits in the hardness range of 140 to 165 Brinell. Deposits with a hardness range of from 132 to 152 Brinell were pro-duced from an electrolyte composed of KC1 + LiC1 + HfC14. A third electrolyte composed of NaC1 + K3HfC17 produced deposits with a hardness as low as 139 Brinell. In a fourth electrolyte, composed of NaC1 + K2HfF6, a measure of refining was accomplished, but under the test conditions no metal meeting specifications was recovered; none was softer than 174 Brinell. A number of metallic impurities were reduced in quantity by the electro-refining process, notably iron, which normally was reduced from 250 p.p.m. to less than 50 p.p.m. Magnesium generally was reduced from 680 p.p.m. to less than 80 p.p.m. Manganese content was also reduced by the electrorefining process. Sponge containing 90 p.p.m. Mn yielded deposits containing a maximum of 50 p.p.m.; some deposits contained only 10 p.p.m.

Jan 1, 1961

By Thomas M. Sweeney

This open-file map is a quick reference containing location, ownership, and general lithology information on 124 active or significant Nevada gold mines. The map includes all counties, significant towns, and major highways in Nevada to aid in mine location. Several geologic trends with which the mines are associated are also depicted. General ore genesis for each deposit, including sedimentary, volcanic, plutonic, and placer-hosted deposits, are also identified. Gold mines are also listed alphabetically, by mine name, on the map. Each entry includes the appropriate county, percent of company ownership, operating company, and the property status as of May 1992. For additional information, contact Thomas M. Sweeney, U.S. Bureau of Mines, Western Field Operations Center, 360 East Third Avenue, Spokane, WA 99202; telephone (509) 353-2700.

Jan 1, 1993

By Noel N. Moebs

Valley Camp No. 3 mine was the scene of an experimental shortwall introduced in 1973 in an attempt to improve the recovery from the Pittsburgh coalbed in the Ohio Valley area where adverse ground conditions have imposed partial extraction methods with only 40 to 55 percent recovery of the valuable resource. The Bureau of Mines, under a cooperative agreement with Valley Camp Coal Co., monitored ground pressures and caving in the shortwall section in an effort to determine whether the roof strata, notably the limestone main roof, will cave to the extent that roof pressures at the face are relieved and whether the powered roof supports can sustain the roof load. The Bureau's efforts included mapping of clay veins, instrumentation of chain pillars and shortwall panels with encapsulated pressure cells, recording hydraulic pressures in the legs of the shortwall chocks, and core drilling underground and from the :surface. The experimental shortwall was a qualified success. Recovery increased 5.4 percent compared with partial extraction. Pressures in chain pillars and the abutment zone were not excessive. Hydraulic pressures in the chock legs did not approach the yielding pressure. Apparently, the limestone strata caved and the roof pressure at the face was relieved.

Jan 1, 1976

The principal activities of the Bureau of Mines Explosives Research Center during fiscal year 1969 (July 1: 1968, to June 30, 1969) are reviewed in part 1. Part 2 presents short abstracts of the publications issued during this period in the Bureau series and in the outside press. These publications are referenced in part 1 by underlined numbers in parentheses. Other publications, which are not abstracted, are cited in footnotes throughout the paper. ACKNOWLEDGEMENTS The Bureau acknowledges the support received through cooperative agreement in fiscal year 1969 from the Manufacturing Chemists Association. It also acknowledges the sponsorship by the following Government agencies of research conducted during that period: Department of the Air Force, Department of the Army, Department of Health, Education, and Welfare, Department of the Navy, Federal Aviation Administration, National Aeronautics and Space Administration, Space Nuclear Propulsion Office, and United States Coast Guard.

Jan 1, 1970

By N. A. C. Smith, A. C. Fieldner, R. R. Sayers

Gases and vapors given off by petroleum and its products have long been recognized as somewhat injurious, when inhaled in high enough concentrations. The petroleum industry has recognized these effects and has tried to minimize the possibility of employees encountering dangerous concentrations of the vapors. Petroleum gases and vapors have not, however, been considered as actively poisonous, in the sense that hydrocyanic (prussic) acid and phosgene are poisonous; men have been exposed to them repeatedly, and for long periods, without any marked ill effects. Light Mexican crude oil when first introduced into the United States for refining was handled in much the same way as was customary with other apparently similar crudes; but experience soon showed that some toxic substance escaped from the crude during production and transportation and in most of the refinery operations. After a preliminary investigation several of the larger companies decided that the gases from the petroleum were the source of trouble, and therefore took precautions, wherever possible, to protect the men from exposure to these gases. With the increasing use of Mexican crude, this problem has become important. The present report covers the work done on the subject by the Bureau of Mines and the Public Health Service under a cooperative agreement with the American Petroleum Institute.

Jan 1, 1925

By Frank M. Vodoklys

This is the final report on Contract H0220049 covering the period from 27 April 1972 to 30 April 1974. The objective of the contract was to develop and evaluate materials and methods to achieve post explosion identification of explosives reliably and economically through the use of phosphor coded grains incorporated into the explosive during its manufacture. A coding system of two spotting phosphors and seven coding phosphors was successfully developed during the execution of the contract. The ability of the coded grains to survive detonation in many different types of explosives was demonstrated and the complete code was extracted from a single 100 micron post-explosion fragment. A method was established for testing grain strength to correlate with field test results and an optical system was designed for extracting the code from the grains. Also in fulfillment of the contract requirements a laboratory method for manufacturing the coded grains was established and ten one-pound samples, each with a different code, were fabricated. Finally, a method was developed for applying a coating of polyethylene to the grains to prevent sensitization of the tagged explosives and the ten one-pound samples were coated and delivered to the Bureau of Mines.

Jan 1, 1974

By Sam S. Taylor

Disposal of brines produced with crude petroleum and natural gas is a continually increasing problem. The necessity for studying this problem has been realized more generally in recent years, and in August 1934 an agreement was made between the Kansas State Board of Health and the United States Bureau of Mines to conduct a cooperative technical study of methods of brine disposal. To date one paper in the technical press4/ and three reports5/6/ have been published in which are given results of studies carried on under this cooperative agreement. In the Mid-Continent fields, the methods used most generally for handling oil-field brines are: (1) Impounding in evaporation ponds; (2) controlled diversion into surface streams; and (3) injection into subsurface formations through wells assigned for this purpose. Various States recognize one or more of the methods as legally authorized procedure. Impounding brine in ponds and solar evaporation have proved inadequate as a general rule, owing, usually, to the porous nature of the soil, the low rate of evaporation, or both. Diversion, of

Jan 1, 1937

By Sam S. Taylor

Disposal of brines produced with crude petroleum and natural gas is a continually increasing problem. The necessity for studying this problem has been realized more generally in recent years, and in August 1934 an agreement was made between the Kansas State Board of Health and the United States Bureau of Mines to conduct a cooperative technical study of methods of brine disposal. To date one paper in the technical press4/ and three reports5/6/ 7/ have been published in which are given results of studies carried on under this cooperative agreement. In the Mid-Continent fields, the methods used most generally for handling oil-field brines are: (1) Impounding in evaporation ponds; (2) controlled diversion into surface streams; and (3) injection into subsurface formations through wells assigned for this purpose. Various States recognize one or more of the methods as legally authorized procedure. Impounding brine in ponds and solar evaporation have proved inadequate as a general rule, owing, usually, to the porous nature of the soil, the low rate of evaporation, or both. Diversion of

Jan 1, 1937

By D. R. Flinn

A newly developed chemical conditioning technique, which greatly simplifies the preparation of plating baths for the electrodeposition of titanium diboride (TiB2) coatings, is described in this report. The new plating technique was used to prepare samples of titanium diboride (TiB2) coatings on three types of substrate materials. These samples were then evaluated in both low- and high-speed wear-test programs to determine the wear resistance, microhardness, and adhesion of the coatings. In general, it was found that the wear resistance of the coatings is independent of substrate. Scanning electron micrographs have shown that the coating wear surfaces are very smooth, suggesting slow and continuous removal of the coating during the wear test (that is, adhesive wear). Adhesion between the coating and all substrates was excellent. Microhardness results show that the TiB2 coating is harder than alumina, with a hardness value exceeding 5,000 kg/mm2 measured in one test. The results of the wear tests show that TiB2 coatings have relatively poor wear resistance compared with alumina in low-speed unlubricated sliding environments, but exhibit wear properties comparable with alumina in high-speed unlubricated sliding environments.

Jan 1, 1981