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By R. I. Jeffery, J. W. Summers

An account is given of the verification and calibration of a numerical modelling technique that has been developed for the prediction of subsurface strata deformation following the extraction of coal by longwall mining methods.

Jan 4, 1992

By S. G. Tsimas, A. K. Moutsatsou, S. G. Tsivilis, G. K. Parissakis

(NH4)2SO4 can be used with success as a leachant to remove gypsum contained in celestite ores. The process, which is applied before flotation, provides an upgraded feed and problems related to the simultaneous flotation of CaCO3 and SrSO4 are reduced. The process is independent of the gypsum content of the feed so that each leaching stage decreases the gypsum content by almost 50%. The use of (NH4)2SO4 has an insignificant effect on the co-leaching of SrSO4 (0.45 wt.%) at each stage

Jun 13, 1905

Thermodynamical data of importance in connection with copper smelting have been reviewed and a collection of the most reliable information is presented in Tables XXV-XXVIII and Figs. 67 and 6 8 (folding plate). The data given in these figures and tables consists of (i) graphs and equations showing the variations in the temperature range 0-2000°C. of the standard free energies of formation of most of the oxides and sulphides met with in copper smelting (Table XXV and Fig. 67); (ii) equations showing the temperature variation of the free energy of formation of iron silicates (Table XXVI); (iii) graphs showing the variation with temperature in the range 1000°-1600°C. of the standard free energies of the principal reactions occurring in the smelter (Fig. 6 8 ); (iv) the standard heats of formation at 1200°C. of the main iron and copper compounds and gases reacting in the smelter (Table XXVII); (v) the standard heats of reaction at 1200°C. of a few of the reactions for which the free energy relationships were given in Fig. 6 8 (Table XXVIII). The data presented are discussed in more detail.

Jan 1, 1953

By Zhengya Lu, F. Lawson

The surface tensions of lead and lead alloys with very low concentrations of silver, tin and copper were measured by the sessile-drop method. The enrichment of silver and tin in the surface of liquid lead alloys at temperatures close to the freezing-point of lead was confirmed, which may explain the unusual behaviour of small amounts of silver and tin in lead bulllion during the sulphur-drossing step of the refining process. From the limited data available copper also appears to concentrate at the surface of the liquid alloy

Dec 1, 1991

By J. H. E. Jeffes, K. T. Jacob

Solid oxide galvanic cells, of the type: Pt,Ni-NiO | Solid electrolyte | O(metal),Cermet,Pt, were used to measure the activity coefficient of oxygen in liquid Cu at 1 100 and 1 300°C and in Pb at 1 100°C. Similar cells were used to study the activity coefficient of oxygen in the whole range of Cu + Pb alloys at 1 100°C and in Pb-rich alloys at 900 and 750°C. The results obtained are discussed in terms of proposed solution models. An equation based on the formation of 'species' of the form M(2)O in solutions of oxygen in binary alloys is shown to fit the experimental data

Dec 1, 1971

By R. Winand, P. Harlet

he cathodes produced are of electrorefined grade; metallographic structure and surface roughness are controlled to a depth of 1.3 cm (single-side deposits); silver levels in the cathode are regulated by the presence in solution of Cl- and Br- ions; organics must be used at very low concentrations (around 0.1 mg/l with a consumption of about 0.01 mg/l/hr). The required concentrations of additives were established according to a well-defined strategy based on the consumption of organics at the cathode by a mass transfer limited-process.

Jan 4, 1992

By S. K. Chaulya, R. S. Singh, B. B. Dhar

Two prominent local species, Dendrocalmus strictus (bamboo) and Saccharum spontaneum (kashi), and two exotic species, Cymbopogon citratus (lemon grass) and Vetiveria zizanoides (vetiver), were selected for growth trials on dumps at Mandaman, Chora, Mudidih, South Balanda and Ghugus. The climate at these sites is dry tropical and the surface soil layer a slightly acid to neutral sandy to clayey loam 10-11 cm thick, impoverished in major plant nutrients. After two years bamboo had grown the most, up to 325 cm in height, and contributed the greatest biomass, 638 g/m2 of plant. The local kashi species had a very good regenerative capacity, which was lacking in the lemon grass and vetiver. The grasses had very good soil-binding capacity and could also provide income if used as cash crops

Jun 21, 1905

The following procedure was used to determine cut-off grades: define the orebody profile; plan the stope layout and quantify the work involved; formulate equipment-performance norms; calculate unit costs; input process recoveries and metal prices; and calculate the cut-off grade. Use of the method is illustrated using data from a copper mining complex in India. Results from the study led to the following conclusions for underground mines in general. Cut-off dependent costs vary significantly with the stoping method employed, orebody thickness, the degree of mechanisation and the working efficiencies of the workforce and equipment. This applies even within the same deposit. Sub-level stoping and its variants can be operated at a lower cut-off grade than cut-and-fill and its variants. Thinner orebodies affect cut-off grades adversely, but with thinner orebodies very little further reduction in cut-off grade can be achieved once a certain minimum width has been exceeded. For the same stoping method and in the same mine the cut-off grade varies with the degree of mechanisation. Labour-intensive methods require higher cut-off grades. An allowance for working efficiency should be made when calculating cut-off grades. Higher process recoveries allow a significant lowering of cut-off grades

Jul 1, 1996

By M. Dobias, N. Mayor, J. Lillo, A. Gonzalez, R. Lunar, R. Oyarzun

The central domain of the Spanish Central System contains a series of Ba-(F)-(base metal sulphide) hydrothermal vein deposits that are hosted by adamellitic granitoids. Fluid inclusion and sulphur isotope data suggest that the mineralisation was formed by low-salinity hydrothermal solutions that incorporated fluids, metals and sulphur from a magmatic source. Mineralisation occurred in two main stages; a first stage of open-space filling with quartz-Ba-(F)-(base metals) ; and a second stage of brecciation and deposition of quartz-barite. The two mineralising events can be clearly related to two tectonic episodes of late Variscan age that involved extension along east-west trends followed by ductile transcurrent movements along northeast-southwest trends.

Jan 4, 1992

Discussion following the presentation at the North of England Institute of Mining and Mechanical Engineers' general meeting held in Newcastle-upon-Tyne, 8th April 1916, included the author's introduction, written contributions by Bedson P.P., Gregory T.W.D. and Morgan J.D., oral contributions by Louis H., Greener T.Y. and Severs W., and the author's reply

Dec 1, 1916

By J. Cech

Discussion is presented of a decision-making support method for the spacing of ore passes along a long vein orebody and the division of the orebody into convenient stopes for future mining operations. The method was tested on a Slovak siderite deposit and also on some hypothetical cases with the objective of obtaining more general results

Jun 18, 1905

By Tawsaporn Nuchanong, Ian Nichol

Investigations of the dispersion of gold in soils and stream sediments associated with three gold deposits in Thailand indicate the existence of different geochemical dispersion patterns in the three areas, demonstrating the need for the adoption of a variety of exploration techniques. The three gold deposits which were investigated were the Phu Tham Phra-Phu Thong Daeng copper-gold prospect, the Doi Tung and the Huai Hin Lab gold prospects. Overall the investigations at the three localities demonstrate clearly that the chances of exploration success can be significantly enhanced if composite soil samples are analysed to ensure a more reliable estimation of the gold content in soils and if both the 63 micrometre fraction and the field-panned concentrates of stream sediments are analysed because of the variable grain size of the gold characterising different gold deposits and surface environments.

Jan 4, 1992

By L Casari

A study of samples from three sectors of the mine, which was worked from Roman times to 1991, revealed different textures, mineral associations and distributions of trace elements in the sulphides. In the last decade before closure, grades of sphalerite concentrate were in the range 51.67-53.30% Zn and 2.21-2.86% Pb and of galena concentrate 69.43-71.62% Pb and 4.70-8.36% Zn, while the estimated by-product germanium content of sphalerite concentrates sold was 300-400 g/t. Passing the different run-of-mine materials through the same concentrator flowsheet produced middlings and tailings during the preconcentration processing. Separate and alternative treatment of run-of-mine products would have yielded improved recoveries of sphalerite and galena and better values of by-product germanium and cadmium

Jun 18, 1905

By D. J. Reddish, B. N. Whittaker, G. X. Sun

An image analysis technique has been used in the assessment of subsurface fracture levels in the context of water inflow into longwall mine workings. The technique was used to analyse results from physical modelling which are represented by black and white photographs taken directly from the model tests. Binary images of fracture patterns are obtained by scanning the photographs with an image analyser coupled to a video camera. The images are manipulated by a C program which allows them to be processed in vertical and horizontal directions and filtered to differentiate quantitatively between vertical and horizontal fracture intensities. The fracture density distributions provide a valuable database for further numerical and statistical analysis. This allows assessment in terms of water inflow into the excavation. A comprehensive image analysis was undertaken on several extraction models. Results indicate that extraction thickness has a significant effect on the fracture pattern and the fracture density distributions. The results can be used to adapt model findings to situations with a range of extraction thicknesses. The technique has allowed improvement in image enhancement and in the interpretation of model results. In particular, a qualitative comparison between different models is possible.

Jan 12, 1992

By P. W. Edwards

"This paper summarises many experiments conducted, and how in North American industry the use of aluminium in treatment and prevention has been adopted widely. The Pottery Insurance Co., Ltd., made it possible for me to investigate conditions in Canada and the U.S.A., and I thank them for permitting me to submit this short paper- an abstract of my report to them."

Jan 1, 1947

By D. J. Fray, F. Tailoka

Microporous ceramic tubes (15 micrometre pore diameter) and PVC membranes (10 micrometre diameter) have been used as spargers in the electrowinning of copper from concentrated and dilute chloride electrolytes. At a current density of 600 A/m2 and a nitrogen gas sparging flow rate (at NTP) of 1.53 cm3/s per unit electrode length, it was possible to electrowin planar rather than powdery deposits with copper concentrations as low as 0.157 M. To obtain a planar deposit at higher concentrations of cupric chloride the most realistic optimum current density appears to be between 1 000 and 1 500 A/m2.

Jan 4, 1993

By Fearnsides W. G.

Discussion at the The Midland Institute of Mining, Civil and Mechanical Engineers' general meeting held in Doncaster on 27th May 1916, on the paper published in Trans. I.Min.E., vol.LI, 1916, p.409-448, included oral contributions by Lupton A. on the mechanisms of subsidence and water egress and by Kendall P.F. on the validity and accuracy of the contour extrapolation technique and the effect of major faults, together with the author's response

Dec 1, 1916

By R. E. T. Hill

"A laboratory study was undertaken to determine the condensed equilibrium phase relations at 600°C in that portion of the quaternary Fe-Ni-Cu-S system which lies in the neighbourhood of the monosulphide solid solution (MSS). The study sought to determine to w hat extent copper affects the temperatures of stability and compositions of iron-nickel sulphides in bulk compositions similar to those of massive Fe-Ni-Cu ores. Experimental data, including stable phase assemblages and phase compositions, are presented.In the quaternary system at 600°C MSS forms stable phase assemblages with pentlandite, chalcopyrite solid solution, pyrite and vaesite. Over the range of bulk compositions displayed by natural ores copper as well as metal/sulphur ratio have a significant effect on the thermal stability of pyrite and pentlandite. Errors therefore accompany the widespread practice of ignoring copper or chalcopyrite when the mineralogical and compositional changes that have accompanied the initial cooling of primary magmatic sulphides or their subsequent homogenization during isochemical metamorphism are being deciphered. These errors are most significant for ores the bulk compositions of which lie tow ard the sulphur-deficient side of the cupriferous MSS. Temperatures as much as 300°C above the copper-absent value are possible for the interpreted upper stability limits of pentlandite in these ores.The experimental data show that up to 2.0 at% copper can occur in pentlandite stable at 600°C in a bulk composition equivalent to natural magmatic ores. This is equivalent to nearly 10 vol% chalcopyrite. Pentlandite contains more copper than coexisting MSS and the copper content of both phases increases with increasing iron."

Jan 1, 1984

By J. R. Budden, P. A. Spencer, J. Barrett

The initially produced arsenic (III) is very toxic to the unconditioned culture but the mixed culture has the capacity to oxidise it to arsenic (V) in the presence of iron (III). It was possible to build up the resistance of the culture through progressive sub-culturing on arseno-pyrite until it could tolerate steady-state concentrations of 30 mM arsenic (III) and 200 mM arsenic (V). With some samples tested in the continuous systems the final arsenic concentrations reached 330 mM. It proved possible to use the laboratory batch data to establish the optimum operating conditions for continuous test systems with capacities of up to 32 m3. Data on the residence time, oxygen uptake rates and gold extraction from the bio-oxidised residues could then be confirmed by continuous testing without the need first to use empirical means to determine optimum conditions for continuous bio-oxidation. The data on residence time, oxygen uptake rate, solids density and neutralisation could be used to estimate the capital and operating costs of treating any given tonnage of the concentrate of interest. It was established that the arsenopyrite concentrates can be suitably bio-oxidised to cause the liberation of at least 90% of the gold content. The method is simple to operate and is flexible over a wide range of external conditions

Apr 1, 1991

By B. Sonmez, B. Aksanl, S. Ersaym, I. F. Erkal, S. L. Ergun

The comminution circuit at the plant has experienced severe problems arising from a feed containing much larger amounts of clay and having a higher moisture content than expected. Three solutions were proposed: replacement of the crushing circuit by tooth roll-type crushers; using washing drums; and introducing primary autogenous/semi-autogenous millling instead of crushing. Computer simulations studied the effects of the first two solutions on the circuit capacity. Laboratory and industrial scale ball mill batch grinding tests were carried out. The parameters of a kinetic model were determined. The ball mill circuit was sampled and operating model parameters were calculated. The ability of batch grinding parameters to represent the operating conditions was studied. Tests failed to find acceptable model parameters, but parameters from an industrial size batch mill were found to be suitable for simulation studies. The simulations indicated that a continuous feed of -12 mm provided by tooth roll crushers would maintain the desired capacity. Increasing the feed size to -25 mm would reduce the capacity by 8-15%. The use of washing drums could also solve the capacity problem, but small fluctuations in water flow rates might result in problems of excess water in the grinding circuit.

Jan 4, 1993