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By F. Karakas

Organo-bentonite production enjoys important applications including solvent based paints and, more importantly, the production of polymer/bentonite nanocomposites. Quarternary ammonium salts in this regard are still considered as the most versatile reagents in the process of hydrophobization. In this study, a purified form of Resadiye region bentonites, which is one of the most significant sodium bentonite deposits in the world, was used. The raw Na-Bentonite was typically characterized by chemical analysis, XRD and DTA analysis and more importantly for its cation exchange capacity (CEC). Other technological properties such as swelling index, pH, apparent viscosity, water absorption, oil absorption were also conducted on the raw bentonite. The mineralogical analysis of the raw bentonite reveals that it contains about 80 % montmorillonite together with other associated gangue minerals including feldspar, quartz, calcite, dolomite, coloured impurities and other clay minerals. The raw bentonite was subjected to two stage processing involving a series of hydrocylones. Different apex and vortex diameters and different pressures were employed in order to produce a bentonite concentrate with 95 meq/100g CEC from a CEC of 71 meq/100 g. This high quality concentrate was used in the production of organo-bentontonite. The modification was performed with two different quaternary amines, i.e. Trimethyl Phenyl Ammonium Chloride (TPAC) and Hexadecyl Trimethyl Ammonium Bromide (HDTMA-Br). In the modification procedure, three parameters, i.e., adsorption density, zeta potential, swelling index and apparent viscosity were studied simultaneous-ly from the same suspension to identify both the mechanism of the process and also the degree of hydrophobicity. Adsorption measurements were made as a function of conditioning period, pH, and reagent concentration. Simultaneous examination of the adsorption density, zeta potential and apparent viscosity enabled us to pinpoint the optimum region of hydrophobicity which was subsequently tested by settling and critical coagulation concentration in both water as polar and toluene as nonpolar solvents. The results are analyzed in the light of experimental data.

Jan 1, 2014

By W. M. Zeng

A mixed culture of moderately thermophilic microorganisms was enriched from Acid Mine Drainage (AMD) samples collected from several chalcopyrite mines in China,which can leach copper from chalcopyrite effectively. Its tolerance to chalcopyrite was brought up to 80 g/L after being adapted to gradually increased concentrations of chalcopyrite. The effects of several leaching variables on copper recovery in Stirred Tank Reactor had been investigated. The ore contained chalcopyrite (62.2%) and galena (25.6%) as the main sulfide minerals. The results of the tests show that it is possible, operating at 8% of pulp density to attain copper extraction of 75% in 44 days. The leaching rate of chalcopyrite tends to increase with the dissolution of total iron. Microscopic counts of microorganisms in the solution tend to be higher at low pH range. Furthermore, the analyses of leached residues indicate that the passivation of this chalcopyrite is mainly due to the formation of a mass of jarosite and anglesite (about 48.3% and 21.7% in residue respectively), other than elemental sulphur layer. The bacterial community composition was analyzed by using amplified ribosomal DNA restriction analysis (ARDRA). Two moderately thermophilic bacteria species were identified as Leptospi-rillum ferriphilum and Acidithiobacillus caldus, with different proportion in the bio-pulp, 67% and 33%, respectively.

Jan 1, 2014

By M. Saghaeian, R. Hejazi, L. Hosseini, M. Zare

Difference between plant feed specifications in practice and design feed is a problem that most of processing plants face during operating and commissioning. This topic has led to inappropriate operating and necessitates repeating the basic tests on new feed. Gol-E-Gohar fourth concentrate line with a capacity of 2 MTPY, located in Kerman province, is the first iron concentrate plant in Iran in which High Pressure Grinding Roll (HPGR) technology has been applied. Plant&apos;s feed consists of 30% AG mills pebbles of lines 1-3 and 70% run of mine crushed ore whose Fe=51%, Fe/FeO=2.5, S=1.7% and work index=15 kWh/t. Desired concentrate has Fe>68% and S<0.7%. After the plant construction and operation commencement, providing design feed was not possible due to the crushing unit`s not being complete, therefore the plant was fed by AG mills pebbles. For predicting optimal conditions of the plant and investigating the possibility of improving the current concentrate specifications, sampling from the new feed and laboratory and pilot tests was performed again. Studies showed that new feed has Fe=41%, Fe/FeO=3.5, work index=17 kWh/t. Results of laboratory tests with Davis tube device and pilot tests run using magnetic separators with simulating the plant`s circuit showed that with current feed, achievable recovery in industrial scale would be 75.52% which compared to plant&apos;s recovery in studied period (75.94%) shows that plant operated in optimal conditions. To improve the current concentrate specifications (Fe=66%, S=1.03%, Ferec=75.94%) and for achieving desired concentrate, samples were reground to four fractions with k100= 300, 212, 100, 45 and Davis tube tests were performed on each of the samples separately. Results showed that the fraction whose k100=212 µm or k80=200 µm has respective Fe and S grades of 68.27% and 0.681% which are consistent with the desired concentrate.

Jan 1, 2014

By M. S. Prithvi

Over the decades, mine and mineral processing plant operations for the most part, have been found to have had adverse impacts on the environment. At the same time, mineral processing and mining operations produce mineral products that are indispensable to modern society. Thus, the sector has desirable and undesirable attributes simultaneously. The situation presents itself as a contradiction (i.e.) the mineral processing and mining operations are wanted by society, and at the same time unwanted by society. The existing methods of addressing the issues raised above have evidently not been very successful in reducing the opposition to new projects and to the related activities such as land acquisition. This paper attempts to show the relevance and applicability of TRIZ for addressing the issue. TRIZ, or Teoriya Rezheniya Isobretatelski Zadach, is a Russian acronym meaning Theory of Inventive Problem Solving. TRIZ is a powerful tool that can be usefully applied to resolve such contradictions, using resources usually available within the system of interest. Accordingly, this paper introduces the issue background, followed by an introduction to some key concepts of TRIZ such as the 40 principles, separation principles and directed evolution. The paper goes on to apply the 40 principles to two case studies. The results show that TRIZ could be a useful tool to generate potentially innovative and sustainable approaches. Its most appropriate position would be as a supplement to current decision-making procedures, and as a validation tool to review existing solutions for possible improvements. Keywords: minerals, environment, TRIZ, contradiction, resources

Sep 1, 2012

By Z. Q. He

This paper introduces the structure and working principle of SLon magnetic separator that has excellent performance in iron removal, and summarizes a part of the examples of applications, which applies this machine to remove iron from non-metallic ores, and shows widespread prospect of application of this machine in the purification of non-metallic ores.

Jan 1, 2014

By X. Q. Cui

The surficial collapse pits of the mining areas are continuously spreading in Beiminghe iron mine of Hebei Province as a result of the exploitation, which has done a lot of damage to the circumjacent ecological environment of the mine. It is a new path to handle the mine tailings at the present time that the thickened tailings are used to backfill the collapse pits, in which way the problems of the surficial collapse and the nowhere discharge of the tailings are both solved, and the rational utilization of the mine tailings and the clean production of the mine enterprise are realized. The?200 mesh content of the tailings of Beiminghe iron mine is 76.87%, and?325 mesh content is 63.50%. Semi-industrial dehydration experiments to the tailings have been done using the hydro-cyclone classified thickening process. The results show that when FX125 hydrocyclone is adopted, the concentration of underflow can achieve 73.31%, and the yield ratio is 61.78%; when FX150 hydrocyclone is adopted, the concentration of underflow is 70.57%, and the yield ratio is 54.31%, which indicate that the minor diameter hydrocyclone is propitious to improve the yield ratio of the underflow. The semi-industrial dehydration system of hydrocyclone classified thickening process is com-posed of FX125 hydrocyclone, D3600 high-efficient thickener and D2000 thickening bucket. The capacity to tailings disposal can achieve 3.07t/h and the tailings can be thickened from 28.86% to 62.45%. Compared with the traditional thickening-filtrating process and the total tailings directly filtrating process, the hydrocyclone classified thickening process has the merits of simple flow and high thickening efficiency, so it is easy to be realized in the mine.

Jan 1, 2014

By S. N. Shahcheraghi

Bioleaching method makes use of bacteria in solving metallic sulphides, so that these bacteria tend to convert insoluble metal sulphides into soluble sulphates. Since the kinetics description of this process is inevitable for better interpretation of relation between metabolism and growth of live organisms, as well as optimization of metals extraction processes, in this paper, this description is represented and designed in mathematic (kinetics) model for copper sulphide minerals based on Monod kinetics model. According to this model, special growth rate of bacteria (?) is a hyperbola function of restrictive substrate concentration (S). By Solving and developing of Monod kinetics model, a comprehensive kinetics model for bioleaching of copper sulphide minerals results. The designed is also applicable for other metal sulphides.

Sep 1, 2012

By Sanchita Chakravarty, Sumantra Bhattacharya, Divya Jyoti, A. K. Mukherjee, Soni Jaiswal

"Release analysis is independent of collector and frother dosage and type, but it is primarily influenced by the degree of liberation or “state of release of the sample”. The shape of release curve is an indication of the degree of liberation. This paper briefs about the effect of reagent combination, particle size and surface characteristics on the release analysis of difficult-to-clean LVC coal.Release analysis of three LVC coal fines obtained from two different coalfields of India was carried out at three different size levels such as -0.5mm, (-0.5+0.1) mm, and -0.1mm. The collectors used were n-dodecane and commercial diesel oil. Incomplete liberation of coal fines even at a size of -100µm, corroborated by photomicrographs of ROM and clean coal macerals, in a great measure reduced the flotation-based cleaning potential of the fines. FESEM images of fines reveals that the adherence of ultrafine onto the surface of relatively coarser particles reduced the clean coal recovery. The results obtained also appear to be coal, reagent combination and, particle size and particle surface specific. Only one coal indicated the liberation as is usually expected for -0.1mm particles with a reasonable yield of 65% at 18% ash. INTRODUCTION Froth flotation has a long history of being used to treat coal fines. Coal flotation is considered to be difficult, if the percentage of Near Gravity Material (NGM), i.e. essentially locked particles, in flotation feed is >10% [Aplan, 1993], which is usually the case with all the coking coal fines in India. The fines are rich in vitrinite, so valuable for coking coal. Unfortunately, there appears to be no standard procedures to determine the separation efficiency of froth floatation. Release analysis proposed by C.C. Dell in 1953 [Dell, 1953], aimed to determine the ultimate floatability of coal. Several other techniques had been proposed but release analysis technique has been considered to be a vast improvement over the batch flotation process [Forrest et al. 1994]."

Jan 1, 2018

By N. P. Haran

A detailed study was undertaken to beneficiate sub-grade iron ore sample from Kenojhar District, Orissa, India containing 57% Fe (T), 7.7% SiO2, 4.8% Al2O3, 4 % L.O.I. 0.4% TiO2,1.3 % Mn and traces of S(T) to make it suitable for the user industry. The mineralogical study indicated that it predominantly consists of haematite with subordinate amounts of goethite and clay. Quartz, Cryptomelane / Psilomelane, Pyrolusite, Gibbsite, Feldspar and Muscovite mica were present in very minor to trace amounts. The Denver grind ability tests indicated, that the sample could be categorized as ?medium soft to medium.? The Bond ball mill work index was determined to be 14.19 kwh per short ton. The beneficiation process involved classification followed by tabling of the classified sand, ground to minus 48 mesh size. The table slimes were subjected to Wet High Intensity Magnetic Separator (WHIMS). The developed process yielded a composite concentrate from tabling and WHIMS operations assaying 65% Fe(T), 2% SiO2, 1.8% Al2O3, 2% Mn and 0.9% LOI with a recovery of 60.1% Fe (T), amounting to 52.5 wt.% yield. To meet the size specifications for pellet making, it was further ground. Dewatering studies were also carried out on the ground combined concentrate and rejects. The thickener area of ground combined concentrate using 0.02 kg/t of Sufloc A 1115 flocculant was 0.02 m2/tonne of dry solids per 24 h. And for the combined rejects using 0.12 kg/t of flocculant, it was 0.035 m2/tonne of dry solids per 24 h. The moisture content, in the pressure filtration cake, in the ground combined concentrate product was 10.0%, and productivity was 506.7 kg/m2h. Thus, by thickening and filtration of process products, 90% of water used in the process could be recovered. The study highlights the development of a simple and cost effective flowsheet with almost complete water recovery for a subgrade iron ore sample. Keywords: tabling, WHIMS, thickener, filtration

Sep 1, 2012

By Z. L. Huang

A new porous apatite product was prepared using phosphorite from Yichang China by a tem-plate-directed method in self-made reaction equipment under constant temperature and pressure. The product was characterized by XRD, FT-IR and SEM. The results showed that the product was a kind of micrometer porous sphere three-dimensionally structured by apatite nanoflakes, that the average thickness of nanoflakes was about 50 nm, that the average pore size was about 1.2 µm and that the particle average size was about 20 µm. Great amounts of Ca2+channel, high special surface area and regular spherical shape show the potential promising applications of this special porous apatite product in the fields of catalyst, medication, chemical engineering and environment engineering

Jan 1, 2014

In many base metal sulphide concentrators reagents such as collector and cyanide are often added to the grinding mill as well as to the flotation circuit. Whilst good reasons can be cited for splitting the reagent addition in this way, the benefits of such are rarely quantified and the complex reagent-mineral-media interactions occurring during milling are often poorly understood in terms of pulp chemistry. A new laboratory batch grinding mill designed by Magotteaux allows the user to measure, monitor, and control the pulp chemical conditions during grinding when testing different ores and media. Some of these parameters include pulp pH, pulp Eh, temperature, gaseous atmosphere, and dissolved oxygen concentration. In a recent development, the mill has been coupled with a simple on-line reagent monitoring system, designed by CSIRO, which allows the levels of species such as xanthate and cyanide in the grinding pulp to also be measured continuously during milling using a robust UV detection system. In this way the uptake of collector during grinding and the rate and ex-tent of cyanide interaction with the minerals and media can be determined as a function of grinding time. A series of grinding tests using an Australian nickel sulphide ore was conducted with the coupled system in which the cyanide dose, xanthate dose, and media type were systematically varied. The xanthate and cyanide levels were monitored as a function of grinding time and the data collected are discussed in terms of the pulp chemistry of the system and implications for plant reagent dosing strategies.

Jan 1, 2014

By Y. S. Song

Flotation separation of galena, sphalerite with pyrrhotite in ethanoic acid + sodium acetate sys-tem was studied in this paper. The flotation tests show that galena and sphalerite can float but pyr-rhotite can hardly float in the pH range of 3.6 to 5.6 in ethanoic acid + sodium acetate system. The flotation tests also show that galena can be separated efficiently from pyrrhotite and sphalerite can be separated on the whole from pyrrhotite, but the separation efficiency of the former is much better than the latter. The flotation results have been investigated by ultraviolet spectrum and XPS analysis, and explained by theory of hard and soft acid and base (HSAB), hydrogen bond and galvanic coupling.

Jan 1, 2014

By T. Tumidajski

The purpose of the separation processes in coal processing is obtaining products of certain ash contents. In the most of cases it is assumed that the separation process is described by one, selected parameter, which usually is grain size or material density. The separation may be described by means of statistical distributions of random variables, what allows forecasting the separation results of certain enrichment method. There are very well known the applications of approximations of Tromp separation curves or distribution functions of Erasmus, Meloy or Weibull. It is necessary to say that if the fitness of the approximation more suitable, then the characteristics of the process itself is also better. In purpose of obtaining more appropriate results, these methods were modified by application the mathematical functions, as i.e. hyperbolic tangens function. Furthermore, on the basis of empirical data, so-called interpolations may be performed in purpose of getting more appropriate results of approximation. One of the most known techniques of interpolation is Hughes method. This method for interpolating standard data involves breaking down each interval into a number of smaller sub-intervals. The results of such one-dimensional approach not always contain the full in-formation of the searched distribution. It happens because such interpretation of the problem is not completely correct. In practice, the separation process depends not only on the one parameter (i.e. grain size), but also on many other features characterizing certain material (i.e. its density). It seems then that in some cases the application of multidimensional grain characteristics distributions will be more appropriate. In this paper, the technique of joining the distributions of grain size and density by means of so-called Morgenstern distributions is shown. The general form of these distributions is as following:

Jan 1, 2014

By Z. He

Based on full investigation of the characteristic of sphalerite in the residue obtained from cyanidation leaching process and the study of the mechanism of the interaction between flotation reagents and sphalerite with the aid of electrochemical analysis, the reagent named YO was developed for eliminating the depression effect of CN- on sphalerite and reducing the dosage of CuSO4. The achievements have been used in commercial production for the treatment of the cyanidation residue to recover the zinc minerals, obtaining a zinc concentrate with grade of 56.49% Zn and recovery of 86.63% Zn.

Jan 1, 2014

By M. Illikainen

Limestone is used for neutralization of acid leachates in a number of hydrometallurgical processes. The aim of this study was to clarify how limestone ground to different particle sizes can neutralize sulfuric acid. The laboratory scale ball mill was used in grinding experiments carried out using ball sizes of 20, 30 and 40 mm and volumetric slurry densities of 30, 40 and 50 percents. Varied grinding times were used in order to produce limestone samples with different particle size classes on which the neutralization potential and rate were determined. The results of the study showed that the neutralization potential of limestone is not dependent on its particle size between 5 and 120 µm. However, the particle size strongly affected the neutralization rate of sulfuric acid: The smaller the particle size, the higher the rate of neutralization. Thus, when optimizing the cost efficiency of the process, the optimal degree of grinding should be considered taking in account the required residence time in neutralization phase.

Sep 1, 2012

By A. G. Bulaev

Biohydrometallurgical technologies based on activity of acidophilic microorganisms oxidizing ferrous iron, sulfur, and sulfide minerals are widely used to extract base and noble metals from sulfide ores and concentrates. As sulfide minerals oxidation is exothermic, industrial processes are usually preformed at 40–50°C. Moderate thermophiles predominate under these conditions. Most of moderately thermophilic acidophilic microorganisms that oxidize metal sulfide are mixotrophic, i.e., they use both organic nutrients and CO2 as carbon sources. Carbon availability is crucial for microbial activity and affects efficiency of biohydrometallurgical processes. Aeration with CO2-enriched air is often used to increase microbial activity in biooxidation reactors. Organic nutrients can be used as alternative carbon source for moderately thermophiles performing biooxidation of sulfide concentrates. We performed several experiments with different sulfide concentrates to study effects of organic carbon sources on biooxidation efficiency and demonstrated that application of such organic nutrients as yeast extract (YE) and molasses made it possible to increase biooxidation efficiency. For example, addition of 0.02% YE in the nutrient medium increased biooxidation rate of pyrite–arsenopyrite gold bearing and chalcopyrite concentrates in batch mode at 45°C. YE addition increased oxidation rate of sulfide sulfur and gold recovery level from 65 to 87% and from 73 to 81%, respectively. Similarly, YE addition increased copper extraction from 47 to 54%. At the same time, YE addition increased efficiency of biooxidation of pyrite–arsenopyrite gold bearing concentrate in continuous mode. Without YE addition, oxidation rates of pyrite and arsenopyrite were 65.7% and 94%, while gold extraction was 71%. YE addition (0.02%) made it possible to oxidize 74% and 95 % of pyrite and arsenopyrite and extract 78% of gold. Addition of molasses (0.02%) similarly affected biooxidation efficiency. Thus, addition of organic nutrients in nutrient media is a promising strategy for improvement of biohydrometallurgical processes.

Jan 1, 2018

By Dongyun Liang

Process mineralogy focuses on the chemical components and mineral composition of ore, dissemination size of valuable minerals, the occurrence of valuable and detrimental elements as well as the behavior of each mineral in the process. Through determining process mineralogy parameters and analyzing the characteristics of minerals, the results of process mineralogy study can provide mineralogy data for making a reasonable mineral processing technology program and optimizing the process. A detailed process mineralogy study is carried out for a complex rare metal ore in this paper and the results show that niobium mainly exists in the form of ferrocolumbite as well as nioboaeschynite and zirconium primarily occurs as zircon. The valuable minerals including Th-nioboaeschynite, ferrocolumbite, zircon, etc. have the characteristics of fine dissemination size, wide size range, complex chemical composition and variable physical properties, which mean it is a refractory ore. According to the results of mineral composition of ore, chemical composition of minerals, dissemination size of minerals, magnetism ranges of minerals and the distribution of niobium and zirconium, the process of ?desliming-Nb-Zr bulk flotation? is designed for this ore and the niobium-zirconium bulk rough concentrate with the grade of Nb2O5 9.43%, ZrO2 24.95%, Ta2O5 0.36% and the recovery of Nb2O5 77.66%, ZrO2 76.70%, Ta2O5 75.13% to crude ore can be obtained in the whole process closed-circuit test.

Sep 1, 2012

By Ying Gu

Automated mineralogy methods and tools, such as the Mineral Liberation Analyzer (MLA) and the QEMSCAN, are now widely used for ore characterization, process design and optimization. Several case studies published recently demonstrate that large gains can be obtained through grinding and flotation optimization guided by automated mineralogy data. However, since automated mineralogy can only provide the information pointing to where the process gains can be made, it does not directly impact the production gain. Thus, a question is often asked: how to value the contribution of automated mineralogy to process improvement of a particular plant. This appears to be a difficult question. On close examination however, it is found that this is essentially a question of the value of information and it is reasonably well documented in various other industries. Hubbard (2010), in chapter 7 ?Measuring the Value of Information?, dealt with exactly this type of problem. The value of information is the reduced risk of an investment and opportunity loss. The methods Hubbard developed can be applied to estimate the value of automated mineralogy, as well as metallurgical test work, which also produces information that reduces the risk of investment. This paper first introduces Hubbard?s theory on the value of information and how to measure it. It then applies his methods to estimate the value of automated mineralogy, using Anglo Platinum?s fine grinding project as an example. In this case, the value of automated mineralogy includes the reduction in investment risk worth US$ 62.5million, in project rejection worth US$197 million and in opportunity loss worth US$320 million. In the end, a general model is developed to allow the simulation of the value of automated mineralogy in different mining operations constrained by different parameters.

Sep 1, 2012

By L. S. Zhou

Germany-made AFX-100 multi-grade fluidized classifier, with exquisite built-in structure and unique novel design, materializes not only advanced and efficient classification, but also precise particle distribution and safe operation, in addition to lower energy consumption and operational cost. It, simultaneously in place of screw grader, water cyclone, and fine mesh sieve, is equipped with multi-function, and indicates superior advantage in comparison with other else grading facilities. As the third-generation equipment, which is efficient and modern, it, in China and therefore all over the world, will find wide application in processing both fine and ultra-fine iron ore resources. Industrial test, carried out in Benxi Steel?s Waitoushan Iron Mine, shows efficient classification, i.e., ?74µm particle contents in coarse, medium and fine products come to 6.09%,11.82% and 82.73%, respectively, while qualitative and quantitative efficiencies end up by 74.38% and 87.66%, respectively. Its separation efficiencies amount to 2.2 times as many as spiral classifiers, 1.8 times as hydrocyclones, and 1.3 times as vibration high-frequency fine screens. Another industrial test, which was practiced in Anshan Steel?s Donganshan Sinter Plant, indicates that classification qualitative efficiency comes to 65.06%, equal to 1.51 times as many as hydrocyclones; yield, 55.79%; -71µm particle contents in medium and coarse products, 42.02%; -71µm content in fine product, 95.42%; and concentration, 12.33%. Estimated separation indexes are as follows: Yield for concentrate at 31.22%, up 0.22% than that from general processing line; concentrate grade at 66.42%, up 1.13%; recovery ratio comes to 65.84%, up 1.28%, which, based on pilot study, results in 20 million yuan of economic return for Donganshan Floatation Plant.

Jan 1, 2014

By J. Wiese, K. Corin, Z. Song

"Relating flotation performance to the electrochemical characteristics of a pulp is complex both in fundamental research and in practice. In the case of thiol collectors, different Eh values in the flotation system can result in the formation of the dimer or the metal thiolate which may or may not enhance the hydrophobicity of the mineral. Reducing or oxidizing conditions in a flotation system, viz. changing the Eh value, are usually manipulated to achieve an optimum flotation response by control of pH and dissolved oxygen levels in the system. A variation in pulp potential may also be achieved by the addition of potential modifiers such as sodium hydrosulphide (NaHS), sodium hypochlorite (NaClO) or hydrogen peroxide (H2O2). There exists anecdotal evidence which suggests that the addition of small amounts of H2O2 to the flotation process can improve sulphide mineral recovery. The objective of the present study was to investigate the effect of the addition of the potential modifier, H2O2, on sulphide mineral recoveries and grades in the flotation of sulphide minerals from two copper bearing ores from China and compare the results to those obtained for a PGM bearing ore South Africa. Batch flotation tests were conducted using the three different ores at the natural pH of the different systems, in the presence of a xanthate collector and the absence and presence of H2O2 as a potential modifier. The results indicate that the addition of carefully controlled low concentrations of H2O2 resulted in improvements in flotation performance. INTRODUCTIONElectrochemical potential as a control parameter in the flotation of sulphide minerals has been widely studied (Allison et al., 1972; Gardner and Woods, 1979; Ross and Van Deventer, 1985; Chander, 2003; Woods, 2003; Javadi, 2013). There is concensus that in order to be recovered during flotation, sulphide minerals require a suitable redox environment. During the flotation process thiol collectors and sulphide minerals are involved in electrochemical reactions which result in the formation of hydrophobic species at the mineral surface (Finkelstein and Goold, 1972; Rand and Woods, 1984). Sulphide minerals act as semiconductors and electrons are transferred during the interaction of the mineral with collector. The resultant potential difference and its magnitude are responsible for the transfer of electrons and the rate of the reaction (Bard and Faulkner, 2001; Fuerstenau et al., 2007). Reducing or oxidizing conditions in a flotation system, viz. changing the Eh value, may be manipulated to achieve an optimum flotation response by control of pH and dissolved oxygen levels in the system (Heyes and Trahar, 1979). The use of potential modifiers viz. reducing or oxidizing agents which include H2O2, NaClO, and NaHS, is an alternative method by which to control the potential of the pulp in a flotation system which may or may not promote the flotation of desired minerals (Rao, 2004). The oxidizing agent, H2O2, undergoes a cathodic reaction which can result in the enhanced flotation of valuable minerals. The potential of the system is increased which results in a shift in the mixed potential of a mineral. The magnitude of the over-potential influences the rate of the oxidation process and thus the flotation response of sulphide minerals (Kocabag and Guler, 2008). Equation 1 shows the proposed oxidation of xanthate by H2O2 (Lipkina and Streltysn, 1970)."

Jan 1, 2018