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In this paper, the use of electrochemical AC impedance spectroscopy (EIS) for in-situ diagnosis of high temperature PEM fuel cells is described. EIS was performed on single cell hardware, built in-house, using a fuel cell test station modified to operate up to 120°C and 30 psig. Electrode kinetics, membrane resistance, porous-layer and mass transport impedance of MEAs, assembled in-house, were measured at various current densities for the purpose of validating the test station and cell hardware, and for optimizing MEA and flow-field designs. The effect of temperature and humidity on the various impedances was investigated. Impedances obtained at lower and higher temperatures were compared to obtain insight into the issue of water management in operating fuel cells.

Jan 1, 2005

By Z. Wu, L. N. Y. Wong

The present study develops the numerical manifold method (NMM) as a tool to investigate the progressive failure in rock slopes. The entire processes of the progressive slide surface development related to crack initiation, propagation, coalescence and degradation to eventual catastrophic failure are successfully captured. To overcome the limitation of the original NMM associated with an improper removal of the interface cohesion of the discontinuities, the displacement-dependent cohesion removal method is adopted. Simple examples of failure of rock slopes containing different arrangements of discontinuities are modeled and their results are compared with those based on the popular limit equilibrium method proposed by famous pioneers Jennings and Jaeger. In cases of coplanar non-persistent discontinuities, close results are obtained despite the differences in the consideration of the stress concentrations at the crack/discontinuity tips. In cases of non-coplanar discontinuities, since the influence of the tensile strength is considered by both the Jaegers model and the NMM, the Factor of Safety (SF) values are similar despite the difference in the failure path trajectories predicted by these two models. The results also reveal that the original NMM without the displacement-dependent cohesion removal method is always more conservative due to the improper removal of the interface cohesion. The displacementdependent cohesion method can to some extent alleviate such a limitation.

Jan 1, 2015

By G. H. K. Pearse

Sulphur is derived from both 'voluntary' and 'involuntary' production. The former category includes sulphur obtained from elemental sulphur deposits and from pyrite and gypsumanhydrite deposits. Sulphur in the latter category is produced by pollution abatement at fossil Juel plants and from treatment of metallic sulphides. Canada is the world's largest sulphur exporter and third largest producer. Main resources of Canadian sulphur are sulphurous fossil fuels, metallic sulphides and native sulphur. Only the first two sources have produced sulphur in Canada 10 date; the first source accounts for over 85% of total Canadian production. Future sulphur sources will be derived increasingly through pollution abatement and decreasingly through voluntary production.

Jan 1, 1984

By G. J. Kipouros, N. Dadvand

"In recent years coatings of alloys have been produced for a wide range of applications including many for wire bonding application. The main characteristic of the baths of electroless plating is the presence of sodium hypophosphite as a reducing agent and also as the supplier of phosphorus. In the electroplating of alloys the Watts bath is predominantly used. This presentation compares the two techniques, electroless plating and electroplating, and discusses the possibilities of cross utilization of sodium hypophosphite in an attempt to formulate baths that eliminate the waste disposal issue related to some components.INTRODUCTIONThe importance of surface characteristics and the linkage of surface coating process to surface characterization has given rise to the evolution of surface engineering. Not only the surface preparation and morphology has become very important to the coating technology but also the knowledge of surface area exposed to the process of coating or corrosion is absolutely essential in ascertaining the behaviour of coatings and their adherence to the substrate. The above concepts are not unknown to researchers involved in the protection of surfaces, particularly metallic, from corrosion and/or erosion corrosion. However, the complexity of the surface defects, roughness, porosity, interconnected porosity and other related factors have contributed to the uncertainty of the true surface area versus the nominal surface area. Therefore critical parameters such as current density and chemical surface intensity although have been studied extensively at the atomistic level by carefully prepared surfaces are very difficult to be determined at the practical scale required during the coating processes.The most pronounced case calling for an understanding the relationship between the surface area and the effective protection is the coating of surfaces of items produced by compression or consolidation of powdery materials. With the advent of nanomaterials and the additive manufacturing through 3D metal printing this issue is becoming more important. Certain experience in this field come from the accumulated knowledge resulted from the attempts to characterize the electrochemical behaviour of powder metallurgy metals and alloys. Powder metallurgy has been a well-established process for half a century on basic metals such as iron, copper and their alloys. Recently the development of powder metallurgy process for aluminum, titanium and attempts to develop powder metallurgy processes for magnesium and its alloys has brought to light another important issue that of the development of coatings on difficult to plate reactive metals such as aluminum and magnesium. Despite of many successes in the development of powder metallurgy alloys the exact characterization of the corrosion behaviour of the coatings and the substrates is difficult to determine because of the unknown morphology of the exposed area i.e. the exact morphology and area of the exposed surface (Samal, 2007)."

Jan 1, 2016

By Malcolm Scoble

School Values ?? Each other; ?? Students, & helping them develop intellectually, personally & professionally; ?? Freedom to pursue educational & research opportunities; ?? Home-work-life balance; ?? The geographic-business community in which we operate ; ?? The pursuit of excellence; ?? Our contribution to society; ?? Creativity & innovation; ?? Teamwork & collaboration; ?? Career development, achievement & reward.

May 1, 2008

By H. Polkowska-Motrenko

Analytical methods for the determination of uranium and other precious elements in ores, industrial wastes and by-products have been developed. The analytical techniques employed are NAA and ICP-MS. Two procedures of digestion were applied: microwave acid digestion and alkali fusion. Accuracy was checked by using CRMs. Results of analysis of the same samples by the elaborated methods have been presented and compared. The methods will be used for estimating the capacity of uranium production for the Polish nuclear power programme.

Aug 1, 2010

By M. H. Ali

Codelco, a multi-process primary copper producer, is undertaking a full life cycle inventory (LCI) of all its commercial products based on copper and molybdenum. During this work, many questions have surfaced regarding the contribution of process unit design to specific aspects of a product's LCI and, more importantly, how such designs could be improved using a life cycle perspective. Management strategy efforts were undertaken to improve the LCI footprint, however it was found that the corrective actions were almost impossible to apply at the operation level in plant, given the ongoing timing pressures of extractive mining, and costs saving priorities. Additionally, it was found that most of the important comparative differences between operations had structural reasons. In this circumstance, the LCI practitioner group from 1M2, and the environmental managers from Codelco, decided to shift its efforts to place the critical LC1 aspects to the design process of future developments. Hatch Associates has developed unique tools in their Sustainable Plant Design (SPD) package that compliment and enhance LCA methods; these effectively drive sustainability into the heart of the design process. By using LCA and SPD in a project design phase, you cannot only address potential hotspots, but also decide on materials, location and size of certain facilities to optimize for energy efficiency. Moreover, you can avoid the shifting of environmental burdens upstream or downstream within the plant and finally it is extremely useful in identifying opportunities for greenhouse gas reduction.

Jan 1, 2007

By Mohammadreza Jalali

Alberta contains over 400 billion barrels of viscous crude oil in fractured carbonates but there is no viable extraction technology as yet. Petroleum geomechanics has become a vital part of the assessment of such hydrocarbon reserves, especially for naturally fractured cases, which are particularly challenging in terms of accurate recovery prediction because of joint fabric complexity and lithological heterogeneity. As a result of interconnected fractures, transport properties of fractures (mostly permeability issues rather than thermal effects) are affected by production and injection activities that change the pore pressures, temperatures, saturations, and effective stresses. Enhanced oil recovery methods involving massive amounts of fluid injection (hot or cold) at high pressure (pinj) may be used to mobilize and produce the oil; therefore, deeper understanding of the fractured systems is desirable. Pressure and temperature variations in a fractured reservoir change the in situ stresses in the reservoir and surrounding rocks; this affects fracture apertures, radically changing the bulk flow properties because flux rate is highly sensitive to aperture. Hence, coupled pressure, temperature and effective stress changes must be considered for fractured reservoirs under a thermo-hydro-mechanical (THM) coupling approach.A hybrid FDM/DDM coupled method is presented to couple pore pressure and stress around a fracture in an impermeable matrix block. Deformation and stresses are calculated in each time step and then fracture permeability, which is the most sensitive petrophysical parameter in fractured reservoirs, is updated based on the fracture aperture variation. This model is then verified with UDEC (Universal Distinct Element Code) which uses a discrete approach to cope with fractured rock mass behavior.

Jun 1, 2012

By Julie Q. Shang

The electrokinetic (EK) technology for dewatering of two tailings from the uranium mines in Northern Saskatchewan is studied in bench scale experiments. The study includes four phases: 1. Characterization of two uranium mine tailings; 2. Assessment of voltage loss on the coated Ti anode and water interface. 3. EK cell test series to measure electrokinetic permeability (ke) of two tailings; 4. EK dewatering test series to study electrokinetic enhanced gravity dewatering on two tailings samples. The results have demonstrated that both tailings responded positively to the EK process. For the tailings containing gypsum, the EK dewatering should be a short term process (within one hour) with anode conditioning (pH adjustment). The tailings containing clay minerals responded well to EK dewatering, in which pH adjustment is optional and will further enhance the EK flow. Both tailings as tested have low hydraulic conductivity and are particularly suitable for EK dewatering and consolidation.

Aug 1, 2010

By M. Hashemzadeh

The efficiency of water use is a top priority for the global minerals industry, especially in regions with limited freshwater supplies. In these areas, the freshwater shortage has prompted mining companies to search for alternatives to freshwater sources. Seawater has been proven to be a potential water source for mineral beneficiation and metal extraction processes. This study compares chalcocite leaching behavior with ferric chloride to that with cupric chloride. We carried out leaching tests with a highly pure chalcocite sample in jacketed reactors under fully controlled pH and solution potential. The effect of chloride concentration, oxidant concentration, and temperature on copper extraction was quantified in both cupric and ferric chloride systems. In the ferric chloride system, increasing ferric concentration showed a positive effect on the first stage of chalcocite leaching. In the second stage, increasing temperature markedly enhanced copper extraction. In the cupric chloride system, chloride concentration presented a considerable effect on both the first and second stages of leaching, while temperature had a remarkable effect only on the second stage. The findings of this study would be beneficial to mine operations aiming to replace fresh water with seawater for heap leaching of chalcocite. INTRODUCTION Mineral processing operations/plants are normally operated adjacent to mines which are often located in remote and arid area, such as northern Chile, southern Peru and Australia with limited access to fresh water (Liu, Moran, & Vink, 2011, 2013). Water scarcity in these areas has prompted mining companies to invest in sustainable technologies to reduce the water use and/or increase the water use efficiency. One of the current sustainable approaches in mineral processing operations is to replace fresh water with seawater. Seawater is now being increasingly used for mineral beneficiation and metal extraction processes (Hernández et al., 2015). Another application of seawater could be for heap leaching of copper secondary sulfides, mainly chalcocite. However, the high concentration of chloride ion in seawater may significantly affect leaching kinetics of copper sulfide concentrates and ores (Watling et al., 2014). Therefore, it is essential to develop a fundamental understanding of the leaching of chalcocite in chloride media.

Jan 1, 2019

By S. Knapp

Inconel 600 pipes welded to Carbon-Steel are used in CANDU nuclear reactors. Fracture of these welded tubes would have important consequences in term of safety, and therefore their mechanical properties need to be better understood. In this study, the weld region was analyzed at various length-scales using optical microscopy, micro hardness testing, small and large scale tensile testing and digital image correlation (DIC). Large grains were observed in the weld region and smaller grains in the Inconel and carbon steel base metals. Micro-hardness profiles showed variations across the weld and through thickness and were justified in terms of residual stresses in the sample. Large tensile samples were extracted from the welded pipe and were used to identify the material in which fracture initiates. In addition, the local strains in each material were obtained using digital image correlation. Local stress-strain curves were built from the DIC data and compared to stress-strain curves obtained from miniature tensile samples extracted from the carbon steel, Inconel and weld regions. The results demonstrate the advantage of using DIC for extracting local material properties in dissimilar weld systems. Variations in the materials stress-strain curves thought thickness are also presented and emphasize the need for obtaining a complete map of the mechanical properties in the weld region for predictive models to be accurate. Preliminary fracture studies will also be presented.

Jan 1, 2011

By M. E. Austin

Many numerical models for the tubular solid oxide fuel cell (SOFC) exist, with various degrees of sophistication. However, the question of what physics must be modelled, and what can be neglected has not been resolved. A parametric model is proposed and analyzed to quantify the influence of thermal phenomena such as reaction heat generation, cathode channel convective cooling, and thermal radiation with participating media. Currently, a three-dimensional model is used to simulate the conditions of an anode supported cell in the centre of a tube bundle. The interconnect and nickel foam spacers that bridge adjacent cells in series and parallel, respectively, are neglected thus enabling a domain consisting of a 45o azimuthal section of the tube. The conservation equations for mass, energy, and species transport are solved using commercial computational fluid dynamics software, and radiation heat transfer is also modelled using a Discrete Ordinates method. Finally, temperature-dependent material properties and reaction rates are used. The model predicts lower overall temperatures than models that do not include radiative heat exchange and more moderate temperature gradients than those that ignore participating media radiation. Further, different regimes are identified, from convection dominated heat transfer to radiation dominated heat transfer. The results can be used to aid in the selection of appropriate models for a given fuel cell operating regime.

Jan 1, 2005

By Michel Guillot

Gaz metal arc welding is commonly used for producing large frames and assemblies. Even for light aluminum and thin wall assemblies, the GMAW technique is increasingly preferred over the GTAW technique. This is particularly true where the welding gun motion is achieved accurately with automated or robotic systems and when using pulsed or regulated metal deposition. In this study, butt joints in floor welding position are tested at speed ranging from 1.5 to 16 m/min. Attempts are made of find parameters providing good and repeatable joint quality with minimal distortion and good appearance even at high travelling speeds. Taguchi experimental plans are proposed with different parameters tested with sheet metal samples. The parameters include typical GMAW machine settings, joint preparation geometries, wire gages, gun angles, wire feeds, and more. The robot motion speed and the proximity of the part are also considered. Direct monitoring of machine welding current and voltage is achieved. Once is found the best set of parameter settings, additional tests are carried out to verify the repeatability of weld quality. Secondly, these conditions are applied for joining and testing a floor panel made of several extrusions. Weld quality is established with Vickers micro-hardness measurements, cross section geometries of the weld pool including penetration, tensile tests and metallographic observations to establish the amount of porosity and weld microstructure in the HAZ.

Jan 1, 2011

By Kristine Haug

Although most in situ operations in Alberta do not encounter significant problems during resource extraction, there have been a few documented occurrences of oil or steam releases as a result of compromised caprock seals. The objective of the Oil Sands Caprock Integrity Project (OSCRIP) is to characterize the units above and below bitumen zones to determine which geological factors affect the quality of the caprock seal. In addition, geomechanical properties and stress measurements of the bitumen reservoir and overlying units will be examined to provide a better picture of the containment conditions in which in situ operations occur. The information from this study will aid regulatory staff and industry in determining the zone-specific geological and geomechanical factors that could affect the design, operation, and feasibility of in situ recovery projects. The OSCRIP study area (Townships 87 to 99 and Ranges 1 to 13, West 4th Meridian) encompasses the surface mineable area, the northeast extent of the Wabiskaw-McMurray bitumen deposit and the Clearwater Formation, as well as a wide band of the Devonian salt-dissolution zone. Regional geological mapping of the Cretaceous strata focuses on the spatial extent and thickness of the caprock seal. Mapping of the underlying Devonian strata is targeted at better understanding the potential effects of salt dissolution and collapse of overlying strata on the integrity of the caprock seal. Examination of LiDAR (Light Detection And Ranging) bare earth DEM in the study area has revealed localized depressions that may represent sinkholes rooted in subsurface collapse features in Devonian carbonate and evaporite strata. Mapping the location and understanding the timing of salt dissolution-related features and deformation in the Devonian strata will help address questions about the possible effect that geological structures, such as sinkholes, have on the integrity of the caprock, as well as the potential for localized variations in the stress regime of the bitumen zone and overlying units. The stress regime in units above 350 m is such that any induced fractures are believed to be horizontal, and therefore, there would appear to be no mechanisms that would allow these fractures to reach the surface. However, recent incidents have shown that vertical pathways can occur, linking the subsurface to the surface. The final phase of the project will evaluate the changes that may occur in the stress regime under thermal operating conditions in the study area.

Jun 1, 2012

By R. A. Triglavcanin

Delivering dilution water and mixing this water with incoming feed slurry, addition of flocculant, maximising flocculant-slurry interaction to build aggregate size, unabsorbed flocculant percentage, volume average of solids volume fraction, momentum dissipation ratio, dilution recycle ratio, volume average shear, maximum shear rate at exit, aggregate size on exit, uniform discharge profile and more ? all of these need to occur in the right order and in the right proportions within the thickener feedwell, the secret to thickener performance.

May 1, 2009

By James R. Yeager, Eric L. Hoffman, John R. Clark

"Abstract -This paper describes fire assaying and ‘high tech’ alternatives for gold analysis, including advantages and disadvantages of each method. These ‘high tech’ methods include INAA (instrumental neutron activation), aqua regia digestion/AA (atomic absorption), GFAA (graphite furnaceatomic absorption) or ICP/MS (inductively coupled plasma emission mass spectrometry) and a combination of cyanidation with AA, GFAA or ICP/MS methods.Fire assay remains the stalwart among analytical methods for gold but, even with its multiple analytical finishes, is not fool-proof for recovering 100% of the gold present. Consumers of assays should not blindly trust the assay results without consideration of quality control data. Laboratories can and do make mistakes. Some of these can be easily discovered if you do your own due diligence. All these measures should ensure that gold analysis values from successive campaigns and from different laboratories meet acceptable levels of accuracy and precision, and can be correlated together, particularly when they occur in neighboring holes. This is essential just as much for prospect evaluation as for project feasibility."

Jan 1, 1998

By K. Feindel

The distribution of water in operating fuel cells must be carefully managed to optimize the performance, durability, and functionality of the system. For example, the ionic conductivity of polymer electrolyte membranes decreases as membrane hydration is reduced. Flooding at the cathode inhibits mass transport, and it can lead to failure of materials. Build up of liquid water in the gas flow channels of a fuel cell stack will create a non-uniform distribution of pressure drops across the individual cells. We will discuss the application of 1H NMR microscopy to investigate in situ the production and distribution of water throughout an operating H2/O2 polymer electrolyte membrane fuel cell. Polymer electrolyte direct methanol fuel cells posses high theoretical storage capacities as power systems for portable electronic devices. There are, however, two long-standing hurdles to development of practical methanol fuel cell systems. First, the electro oxidation of methanol at the anode of the fuel cell is poisoned by absorbed carbon monoxide, an intermediate in methanol electro oxidation. Second, methanol readily crosses over from the anode to the cathode of the fuel cell. This methanol crossover wastes fuel, and it poisons the electro reduction of oxygen at the cathode. We are investigating use of 2-propanol as an alternative to methanol as a fuel. 2-Propanol is less toxic than methanol, and it is less prone to crossover from the anode to the cathode. More significant, however, is that the electro oxidation of 2-propanol to acetone is faster than the electro oxidation of methanol because it avoids formation of adsorbed carbon monoxide. We will present active catalyst systems for the electro oxidation of 2¬propanol to acetone in fuel cells. We will also present methods to convert the resulting acetone back into 2-propanol, possibly leading towards rechargeable portable fuel cell systems.

Jan 1, 2005

By D. Lemieux

A gold bearing pyrite concentrate was treated at the pilot scale for the extraction of gold. Mineralogical analysis of the concentrate identified gold to be mainly present in the form of a solid solution in pyrite. This gold distribution resulted in a poor extraction yield of 55% by direct cyanidation. A piloting campaign including an oxidative pre-treatment by roasting in a fluid bed was followed by treatment with halogens for gold extraction has led to a gold extraction yield of 96.5%. Sulphur removal during the oxidation was very efficient at >99.5% and gold extraction by the halogens was completed within a 1 hour contact time. The piloting was performed on a 300 kg sample and uses a diluted solution of hypohalites as the oxidizing agent for gold extraction. Sulphuric acid was injected in the reactor during the halogens treatment to lower pH to 2. The diluted solution of hypohalites (1-3%) was generated by electrolysis during the piloting campaign in a membrane-less electrolysis cell. The extracted gold was recovered over activated carbon in column and the gold depleted brine was treated for impurities removal and recycled for further gold extraction. With the recycling of water and brine, the regeneration of hypohalites and with a barren solid that is inert and stable, the Nichromet Extraction technology is a green process where the protection of the environment does not preclude profitability.

Aug 1, 2013

By Richard Hurteau

Design and validation of an integrated guidance system for articulated ground vehicles is investigated. The development of an autonomous industrial vehicle must take into the account the specific geometry of these vehicles; they can be composed of a tractor with 1 or 2 trailers or of articulated type like LHD. Moreover the tractor-trailers type vehicles can have on-axle hitch configuration or positive/negative off axle configuration. The path-tracking of a tractor-trailer vehicle in restricted space is presented and discussed in this paper. Recent results obtained in simulation and validated by experimentation are also presented. These studies can lead to better ways of maneuvering an articulated vehicle in a restricted space or automatically executing of docking and parking maneuvers

May 1, 2002

By John S. Stevenson

"Although we have no uranium- producing mines as yet in British Columbia, uranium, associated with gold and cobalt, has been found in two deposits in amounts such that the combined value of the metals not only warrants the further exploration of these deposits, but also encourages the search elsewhere in the Province for other similar deposits.Where uranium-bearing veins have been found in British Columbia, the uranium mineral is the crystalline variety of uranium oxide, uraninite, rather than the massive, non-crystalline variety, pitchblende, such as found in the Great Bear Lake deposit and in other similar deposits along the southwestern margin of the Precambrian shield.The principal occurrences of uranium known so far in British Columbia are associated with bodies of granodiorite and quartz diorite along the eastern side of the Coast Range belt of batholiths. In this part of the Province, interesting amounts of uranium occur on the Gem property in the Bridge River area and on the Victoria property south of Hazelton; and smaller amounts occur on the Red Rose, Rocher Debouze, Delta, and Ohio properties, also south of Hazelton. At the Gem and the Victoria, the uranium mineral, identified as uraninite, occurs in deposits that also contain abundant cobalt-nickel sulpharsenides, and molybdenite.At these properties, the uraninite occurs as clusters of small black crystals of sub-metallic lustre that may be seen upon careful -searching of a highly radioactive specimen with a hand lens. Under the microscope, the uraninite is seen to be in the form of cubes or modifications of cubes that may occur as individual grains widely scattered throughout the gangue or may be gathered into clusters of several grains. The grain size of the uraninite is in general small. Although a few clusters of grains are up to about 10 mesh in diameter, the individual grains, whether in clusters or widely disseminated, are rarely more than 400 mesh in diameter."

Jan 1, 1950