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By Changmiao Liu, Dong Dong

"Magnesite is a major mineral resource in China, whose output and export are massive and quite important to the world. Flotation performances of eight anionic collectors on magnesite were studied to find the proper ones. Micro-flotation results indicated that collectors of HOl, SDBS and AEP had outstanding flotation performances on magnesite, with the recovery ratio all reaching above 90% in a wide range of alkaline pulp. Solution chemistry calculation, Zeta potential and FTIR measurements were employed to reveal the interaction mechanism between anionic collectors and magnesite surfaces. Solution chemistry analysis indicated that the main active components of HOl, SDBS and AEP were anions and association complex anions in alkaline pulp. Magnesite surface was negatively charged in the alkaline pulp. The active sites on magnesite surface were mainly the components of MgOH-, Mg (OH)2, and MgCO3 when the pulp pH was over 8. Anionic components of HOl, SDBS and AEP reacted with Mg in magnesite surface to make the insoluble anionic salts. And the chemical adsorption was confirmed by the FTIR measurement evidences.INTRODUCTIONAs an important industrial mineral, magnesite has been widely applied in metallurgy, building materials, chemical industry, agro-pasturage and other fields (Hu et al., 2006). It is a major mineral resource in China with abundant reserves. Its output and export are massive and quite important to the world. Liaoning province is rich in magnesite, whose reserves and production both come first in China. So far the proven reserves have reached 2.91 billion tons, accounting for more than 90% of total reserves in China, and more than 25% in the world (Li et al., 2012).Magnesite ores in Liaoning province mainly contain crystalline magnesite, and the gangue minerals of quartz, dolomite, talc, tremolite, chlorite and carbonaceous materials. Some ores also contain a little pyrite, chalcopyrite, hematite and apatite. Most of the ores must be preprocessed to separate the useful parts from the large amount of gangue minerals, so that their value and industrial application can be enlarged and promoted.Flotation is commonly used to process the magnesite ores, and the conventional flotation methods include anionic and cationic flotation. In the former, gangue minerals of silicates were separated by using amine type cationic collectors. After the impurity minerals were removed, high qualified magnesite concentration could be gained. For the cationic flotation method, it had some drawbacks of lower recovery ratio and poor performance in the lower temperature pulp (Li et al., 1995)."

Jan 1, 2016

By Christopher A. Jacobs

Project managers aim to maximise the NPV of their projects, but don't always appreciate the relationship between mine throughput, project value and the discount rate being used to evaluate their projects. Rate of production or throughput is perhaps one of the most crucial decisions a project manager must make, but if this choice is made arbitrarily, much effort may be spent on a feasibility study that does not optimise project value. The timing of the study in relation to the stage of exploration is examined and simple techniques are presented that project engineers and managers can use to home in on a production rate which will give their project the greatest chance of success.

May 1, 2006

By Q. Shi, Q. Feng

"The influence mechanism of chlorite on the flotation of pyrrhotite was investigated through flotation tests, Zeta potential measurements, optical microscope photos, solution ion measurements and absorption measurements. It is observed that, the addition of chlorite influences the flotation of pyrrhotite seriously. The IEP (isoelectric point) of pyrrhotite and chlorite is 7.6 and 4.3 respectively, in the condition of slight alkalinity, both pyrrhotite and chlorite are negatively charged, and the hetero-aggregation will not occur. With the existence of oxygen in solution, the iron ions are dissolved from pyrrhotite surface because of the oxidation of pyrrhotite during pulp conditioning. The dissolved iron ions adsorb onto the surface of chlorite in the forms of iron hydroxyl and iron hydroxide, and the adsorption results in the opposite charge of chlorite surface. As a result, the hetero-aggregation between pyrrhotite and chlorite occurs. The adsorption of chlorite changes the surface property of pyrrhotite and restricts the adsorption of amyl xanthate onto pyrrhotite surface, and then decreases the flotability of pyrrhotite.INTRODUCTIONIn sulfide ores processing, magnesium silicate bearing gangue minerals often report to the concentrate causing downstream processing problems as well as increased smelting costs. Talc,chlorite and serpentine are gangue minerals commonly encountered in complex sulfide ores (Engel, Middlebrook, & Jameson, 1997; Pietrobon et al., 1997; Witney & Yan, 1997; Chen, Grano, Sobieraj, & Ralston, 1999a, 1999b; Bremmell, Fornasiero & Ralston, 2005; Senior & Thomas, 2005; Wang, Somasundaran, & Nagaraj, 2005; WieseHarris & Bradshaw, 2007). All of them are characterized with uniform crystal structures consisting of silicon-oxygen tetrahedron and magnesium-oxygen octahedron. The magnesium-oxygen octahedron layers are broken during the liberation of serpentine to expose the magnesium-oxygen bonds with strong ionicity and hydration, which results in natural hydrophilicity of serpentine. In water, the hydroxyl on serpentine surface ruptures and dissolves into the aqueous phase while the Mg2+ remains, resulting in surface positive charge (Tao, 2012). As serpentine has a positive potential at alkaline condition, it is therefore likely that it will attach through electrostatic attraction to the negatively charged mineral surface and reduce both the flotation rate and recovery of target minerals (Lu et al., 2011). For talc, characterized as good natural hydrophobicity, the liberation comes from the interlaminar fracture to remain molecular bonds on surface with weak hydration. Being naturally hydrophobic, talc easily reports to flotation concentrates, thus reducing concentrate grade (Shortridge, Harris, Bradshaw, & Koopal, 2000; Beattie, Huynh, Kaggwa, & Ralston, 2006). Meanwhile, both molecular bonds and magnesium-oxygen bonds are exposed on chlorite surface when liberation occurs, resulting in moderate natural hydrophobicity between serpentine and talc (Tao, 2012). And thus the mechanisms of influence of chlorite on sulfide ores are more difficult to study."

Jan 1, 2016

By D. Chadwick, J. W. Matousek

Between 1860 and 1890 -- from the time of the American Civil War to the last decade of the 19th Century -- nickel production in North America was dominated (even monopolized) by the output of the industrial complex of the Gap Nickel Mine near Lancaster, Pennsylvania and the American Nickel Works in Camden, New Jersey. In some years, from one sixth to one third of the world's metallic nickel supply came from this enterprise. Mining and smelting were conducted at Lancaster; a matte of high iron content was shipped to Camden for pyrometallurgical and hydrometallurgical refining to produce nickel metal, copper sulfate, and cobalt oxide. The high purity nickel product was rolled into sheet for marketing, primarily for coinage, as nickel had few other uses at that time. The undertaking experienced all of the problems that face the mining and metallurgical industries of today: declining reserves, high labor and fuel costs, high transportation costs, fluctuating demand and prices, pollution concerns, and foreign competition. The technical features of the geology; the mining, smelting, and refining operations; and some of the economic aspects are assessed. The view is taken from that of the present time -- seeking those lessons from history that we are supposed to learn or face the prospect of repeating the mistakes of the past.

Jan 1, 2005

By O. A. Ojo, R. G. Ding, M. C. Chaturvedi

In this study, the fusion zone microstructure of tungsten inert gas weld of a directionally solidified NhAl-base alloy was examined by the standard metallographic techniques involving the use of optical, analytical scanning and transmission electron microscopes equipped with energy dispersive spectrometer. Fusion zone cracking was observed to be closely associated with interdendritic secondary solidification microconstituents identified as consisting of y, y' and NiMo (Y) phases. Depression of solidification temperature to the terminal ternary eutectic reaction temperature of the system during cooling is suggested as an important factor contributing to the fusion zone cracking.

Jan 1, 2006

By D. Y. Li, C. D. Ma, T. Zhou, T. J. Cheng

In this paper, a number of experimental tests are carried out to study the strength difference on rectangular prismatic marble specimens with different height-to-width (H/W) rations. The specimens have a nominal size of 45×15 mm in the compressive cross-section (W×T) and different heights (H = 22.5 mm, 45 mm, 60 mm and 90 mm). It is to say that the height-to-width ratios are equal to 0.5, 1.0, 1.33 and 2.0, respectively. The quasi-static uniaxial compressive tests are finished by a servo-controlled INSTRON machine (the strain rate at about 10-5/s), and the dynamic compressive tests are finished by a diameter of 50 mm cylindrical SHPB apparatus (the strain rate reaching about 101/s). The rock failure process of marble specimens is captured by a high speed camera in order to distinguish the fracture propagation behaviour. It is found that the compressive strengths increase when the H/W ratio of marble specimen changes from 2.0 to 1.0 due to the end clamping effect both for quasi-static and dynamic loads. However, when the H/W ratio changes from 1.0 to 0.5, the apparent compressive strengths decrease both for the two loading conditions. The strength decrease of short marble specimens may be attributed to the change of failure mode from shear to slabbing, which can be identified by the fracture patterns of the specimens. Based on the uniaxial compressive tests, the slabbing strength of the marble was found to be about 40% of its UCS for the specimens with a nominal height-to-width ratio of 2.0. In addition, it is found that the dynamic increase factors (DIF) are affected by the specimen’s aspect ratios. It implies that the same aspect ratios should be used to compare the dynamic and static compressive strength of rocks. Meanwhile, both the static and dynamic tensile strengths of the marble are obtained by the Brazilian disc tests. The ratio of the dynamic tensile strength to the static tensile strength of the marble is about 2.68.

Jan 1, 2015

By G. T. Lapidus, O. J. Solis-Marcial

Currently, ores with high-grades of copper oxides and secondary sulfides have become increasingly scarce, which has encouraged industry to look for alternative raw materials to obtain copper. The problem is that primary sulfides are difficult to dissolve at near ambient conditions. Proposed hydrometallurgical processes have not been implemented beyond a pilot or demonstration scale. One of the principal disadvantages is that the majority of these processes are not viable with ores that contain less than 4% copper. One of the more recently proposed techniques involves the use of organic solvents in the dissolution of copper concentrates with a chalcopyrite content of between 20 and 30%, which has shown high efficiency. The present research explores the ability of this process to leach copper from low grade chalcopyritic ores (<4% Cu) at different temperatures ranging from 20 to 50°C. It was found that depending on the temperature, high percentages of copper were extracted in 40 to 100 minutes, using different oxidants. Additionally, distinct leaching behavior was observed with each oxidizing agent. In some cases, the extraction kinetics adjusted to the diffusion controlled shrinking core model.

Jan 1, 2014

By R. Roufail

Mineral liberation is accomplished by comminution and is the first step towards achieving successful downstream processes such as flotation or leaching. In metal mining, one of the most effective comminution methods that is used to grind particles below 10 microns is stirred milling. In this paper the study of particle breakage mode vs. mill operating parameters is addressed. Stirred mills&apos; grinding action is mainly attrition, but operation can be manipulated to include breakage by compression or impact loading. Macro and micro analysis of particle breakage and grinding mechanisms are correlated. Macro analyses convey information that relates grinding mechanism to particle size and shape. It is speculated that the breakage mechanism in the horizontal stirred mills is massive fracture for the coarsest particles and attrition (abrasion) close to the grinding limit where the size reduction ratio approaches 1.0. For micro analysis, the particle breakage mode has a direct impact on fracture type either transgranular or intergranular. Intergranular particle breakage leads to higher mineral liberation compared to transgranular breakage. Similar minerals would have more homogeneous properties that convey a stronger bond compared to dissimilar, heterogeneous mineral bonds. Transgranular fracture requires higher energy than inter granular fracture; trans granular fracture toughness of pure single phase mineral is about 10-14 % higher than the intergranular fracture toughness. This communication presents the results of an investigation to assess how operating conditions can affect trans- vs. inter-granular breakage.

Jan 1, 2009

By Arnold R. Miller

Overview ? Vehicle Projects LLC (prime contractor) and the Fuelcell Propulsion Institute have developed the world?s first fuelcell locomotive. ? Principal applications are underground mining and tunneling. ? Because fuelcell vehicles solve the problem of underground emissions, mining is expected to be their first commercially viable market. ? The first year of a three-year project to develop a fuelcell mine loader is funded and underway.

May 1, 2002

By W. G. Jewitt

Introduction The use of the aeroplane in prospecting is already familiar to everyone connected with the mining industry. Apart from transportation companies, three organizations, the N. A. M. E., the Dominion Explorers, and the Exploration Department of the Consolidated Mining and Smelting Company, have made the aeroplane an everyday feature in every mining district in Canada. Its use has been demonstrated successfully in the mountains of British Columbia, but perhaps its greatest field lies in the Canadian Shield, where the numerous lakes and rivers afford an almost continuous series of landing places for aeroplanes, on floats in the summer and on skis in the winter. To the man who has travelled by canoe, toiling over fly-infested portages or held for days at a time, wind-bound, on the big lakes, the ease, speed, and cheapness of aeroplane travel have marked the beginning of a new era, in which ground previously covered with difficulty in a month or more is travelled with ease in a few hours. Development of an air service in the Consolidated Mining and Smelting Company has proceeded on different lines from those of other organizations, and this paper is concerned with that development.

Jan 1, 1931

By Kristie D. Tarr

Ideally, in situ monitoring would supply the input data for numerical modeling of backfill material property requirements. However, clue to production requirements and costs of conducting field tests, input data are often based on small-scale laboratory tests. The size of test samples is known to play an important role in the laboratory assessment of the behaviour of geotechnical materials, including backfill. There are observed differences between the mechanical properties of laboratory-scale samples and those of in situ materials, and these are generally attributed to the differences in scale. Various scaling factors have been proposed for converting laboratory observations to anticipated in situ conditions for soil and rock materials. With regard to mine backfill, very limited studies exist which have involved the effects of sample size on material properties. The literature indicates that reported backfill strength data are based on a variety of test sample sizes and in some cases, specimen geometries. Carefully determined laboratory scale effects could play an important role in estimating the potential backfill behaviour in the field, especially when developing new backfill systems. Laboratory studies were conducted with sample diameters ranging from 50 to 300 mm. Scale factors relating specimen size to strength were developed wherever possible, and are presented in this paper

May 1, 2008

By M. N. Pons, F. Ferrari, V. Houzelot, B. Laubie, A. Bani, Université de Lorraine-CNRS LRGP

"More than 400 plants in the world are able to accumulate nickel in their aerial parts at concentrations higher than 10 g per kg of dry biomass. Then, nickel (Ni) can be recovered from the biomass of these hyperaccumulator plants. Agromining is a chain consisting in growing such plants and recovering metal and has been developed thanks to the combined know-how of agronomy and hydrometallurgy. Plants can be grown on serpentine soils, containing rather high concentrations of Ni, on sterile heaps or on contaminated soils. This crop enables us to extract Ni from secondary resources, and to improve soil quality by lowering its metal content. For example, Alyssum murale can be grown at the field scale in the Balkans, at yields corresponding to 110 kg Ni per hectare.Hydrometallurgical processes have been designed from the lab scale to the pilot scale to produce nickel salts: ANSH (ammonium and nickel sulphate hexahydrate), nickel sulphate, acetate, etc. and so on. These salts are used for surface treatment and in the paint and chemical industry. Ni salts are prepared from ashes, after plant calcination. Processes are based on the conventional methods of hydrometallurgy: acid leaching followed by different precipitation steps. These processes will be presented, as well as the pilot scale design. A life cycle assessment has been performed and clearly shows the environmental interest of this approach as a potential part of an anti-erosion strategy. An economic assessment has proved process feasibility and the final step is the launching of a start-up. At the moment, the approach is widened to other metals (cadmium, cobalt) and rare earth elements (REEs)."

Jan 1, 2016

By G. L. Palmer

"In 1986, anomalous sampling results for heavy minerals were obtained at various sites in Namaqualand on the west coast of the Cape Province. Drilling in 1987 at Graauwduinen penetrated up to 35 meters of heavy mineral-bearing Tertiary sands which extend several kilometers inland from the coast. The heavy mineral suite includes ilmenite, rutile, leucoxene, zircon and monazite, along with gamet, pyroxene and amphibole. Three deposits are recognized, two of which comprise the resource to be mined by Namakwa Sands Limited, a recently formed Anglo American Corporation subsidiary company.Mineable reserves in excess of 500 million tonnes have been delineated, sufficient to sustain mining for over 35 years at projected production rates. During the feasibility study, on-site investigations included test mining at various sites to assess rnineability and to provide material for metallurgical testing in a pilot plant located at the site. llmenite produced at the mine will be smelted at a new facility to be built at Saldanha Bay. Saleable products comprise titania-rich slag, pig iron, zircon and rutile.During the exploration phase, company environmental guidelines were established and monitored. The feasibility study incorporated a Class 1 Environmental Impact Report, the contents of which were made public following the principles of the Integrated Environmental Management legislation."

Jan 1, 1994

By I. Protkova

Versa Power Systems solid oxide fuel cell (SOFC) stacks operate at intermediate temperatures 700 ? 800 °C allowing the use of metallic interconnects. Thermal expansion good matching with other stack components and cost restriction led to selecting ferritic stainless steels as interconnect material. Analytical tools and techniques were developed to understand the ferritic stainless steel behavior at high temperature while exposed to dual environment. Analytical tools such as X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) have provided valuable information towards describing interconnect degradation in a variety of testing conditions. Several examples are presented to demonstrate interconnect oxidation and its relation with SOFC testing results.

Jan 1, 2005

By K. M. Wild, C. D. Martin, F. Amann

Peak laboratory strength data obtained from low permeability clay shales/rocks often display a bilinear or non-linear failure envelope. In many of these tests pore pressures are not measured because of issues associated with back-saturation prior to confined compressive loading. In such tests the effective state of stress at failure remains unknown and provides room for speculation. The non-linear shape of the failure envelope may have several reasons including the influence of capillary forces or the tendency of a saturated clay shale to dilate as the confining stress is changed. The former stems from sample preservation, preparation or core unloading effects and represents a partly saturated state (i.e., not representative for the in-situ state); the latter represents the response of a saturated material. This contribution discusses these issues based on a data set obtained from Opalinus Clay specimens, and concludes that without a careful back-saturation processes knowledge of the underpinning reasons for the non-linear failure envelope cannot be obtained.

Jan 1, 2015

By H. Alzraiee

Traditional planning methods such as CPM and PERT have been useful tools to manage construction projects. However, the underlying model of these traditional methods often seems to fail to represent real projects as they tend to assume no interrelationship between project components. In reality, project components have complex dynamic feedback process that requires modeling of inherent uncertainty in the execution of these projects. Nevertheless, this dynamic nature and uncertainty have not been explicitly addressed by traditional planning methods. Project failure can be attributed to poor representation of the inner and outer aspects of operations that are responsible for project dynamics. Uncontrollable external forces are often cited but the real cause may be internal such as the feedback process among components of the project. An alternative perspective is offered in this paper through system dynamics (SD) that accounts for the feedback process and discrete event simulation (DES) for modeling the uncertainty. The proposed method utilizes SD method for modeling project dynamics and DES method coupled with CPM network for operational details and uncertainty, respectively. A case study that involves preparing engineering drawings in a design office is used to demonstrate the use of the developed method and to highlight its capabilities. Modeling the dynamic dimension is expected to enhance planning and scheduling of construction operations and to provide a better understanding of the impact of various internal and external factors on project schedule and productivity performance.

Aug 1, 2013

By George McIsaac

This paper discusses the formulation of a linear program with the objective of maximizing the cash flow of the long-term plan of an underground operation. A mine is split into eleven independent ore zones, each characterized by its reserves, required development and mining method. Based on practical considerations, maximum rates are set for each zone?s development and production capacity. As for the total mine plan, a minimum daily production rate is set along with a minimum feed grade to the mill. A maximum number of development metres per day is set based on the equipment and labour available. Proven and probable ore is mined preferentially over possible ore in the early years of the plan. Furthermore, the fixed cost of operating the mine is taken into consideration whenever mining activities take place. Once the linear program is solved, it can be critically reviewed, and unrealistic results can be identified. Some resource allocations constraints can then be changed in certain sectors, and new results can be analysed. What-if scenarios can also be examined, such as determining the impact of hiring a contractor to develop a given sector, or dropping an ore zone completely from the plan.

May 1, 2003

By Abani R. Samal

The Fe assay values from the diamond drill-holes within a magnetite deposit of magmatic origin are utilized in this study. Only assay data from the unoxidized magnetite mineralization was utilized. The data from the overlying hematite mineralization zone was not used. A threedimensional block model estimated using ordinary kriging (OK) is used for analysis purposes. To estimate the non-linear standard deviations (s) and the confidence intervals (CI) of block estimates a discrete Gaussian variogram model is used in this project. The change-of support coefficient (rv) and the block-support correction are used in the ?block-anamorphosis?. A new calculated value of rv is 0.7283, implies that its influence in the block-anamorphosis is not significant. The CIs are calculated from the block-gaussian variables; then back transformed to the raw values. At 95% probability, the CI for the kriged block estimates of Fe values are calculated using Gaussian kriged estimates of the Fe and the corresponding standard deviations (Gaussian). The results indicate that the block estimates with a high influence from relatively small amount of samples can be identified as high-risk estimates.

Oct 1, 2009

By D. Sediako

Excessive residual stress in Al engine blocks may result in cylinder distortion which reduces engine operating efficiency. As such, neutron diffraction was used to measure residual strain along the Fe liners and Al, in the hoop, radial and axial orientations with respect to the cylinder axis, at the cylinder interbore region. Residual stresses were subsequently calculated using generalized Hooke&apos;s law and related to the microstructure along the cylinder bridge. The results suggest that the residual stresses in the Al interbore region are tensile and increased with depth in the axial direction of the cylinder. The increase in residual stress at the bottom of the cylinder coincides with a finer and more uniform microstructure in this region of the cylinder. The refinement in microstructure at the bottom of the cylinder likely increased alloy strength, thereby decreasing this section&apos;s susceptibility to distortion. This study successfully quantified the residual stress profiles in a heat treated engine block and related the stress profiles to an as-cast engine block.

Jan 1, 2011

By Fathi Habashi

New technology first introduced by Nippon Steel Corporation at Kitakyushu in Japan in 1976 now used at a number of plants in other countries, known as dry quenching of coke, uses nitrogen in a closed circuit to avoid environmental emissions. In addition, heat is recovered in the form of steam, from the red-hot coke. In steel plants oxygen is used extensively and therefore by-product nitrogen from air liquefaction can be effectively utilized in this way.

Jan 1, 2014