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By J. F. Shirley

"Very seldom, if ever, is a molybdenite by-product plant operated exactly the way the process design engineer visualizes it. The best thing the design engineer can do is provide a sound, basic circuit with enough room and flexibility in order that the operating staff can make the necessary modi fi cations to optimize the process. The plant, with minor modifications, should be capable of handling more than one process. This is especially true when the client is having the plant designed for a new process.The writer would like to propose the following ten ""rules-of thumb"" for designing by-product molybdenite plants where the molybdenite is floated out of a copper concentrate. The term rules-of-thumb is used, because there are probably valid reasons for not using one or more of them in a particular plant design. In fact it was 1980 before the writer was all owed to start up a plant where all of these rules were honored in the plant design. This was after 19 years of experience in the design of molybdenite by-product processes and plants. The main reasons for not following the rules are available capital, available space, and the client's experiences based on pilot plant and laboratory test results."

Jan 1, 1981

By J. F. Wang, Y. Jin, Z. L. Wang

Smelting reduction as an ironmaking technology for the 21st century has been challenging the traditional blast furnace. The process has many attractive advantages over the blast furnace, however, the massive by-produced coal gas mainly containing CO, H2 and CO2 requires further treatment. From a chemical engineering view, coal gas is a valuable chemical stock and can be transformed into hydrogen-rich synthesis gas. Hydrogen can be directly used as clean fuel and synthesis gas can be used for the production of some important chemicals such as methanol, ammonia and dimethyl ether. Among those chemicals, dimethyl ether as an alternative clean fuel for diesel engine and liquefied petroleum gas has been drawing more attention. It has excellent environmentally-benign behaviours not only in compression ignition combustion, but also in the much lower emission of SOx and NOx. In this work, a combined technology of smelt reduction ironmaking and direct synthesis of dimethyl ether, which will strongly promote the energy efficiency, environmental protection and resource recovery, is proposed and described in detail.

Jan 1, 2004

Experimental determination of the response of an AG/SAG mill treating two components of significantly different impact resistance is challenging for two main reasons: firstly, small scale laboratory tests have yet to be confirmed as valid representations of the full scale milling environment, and secondly pilot plant testing requires 10-20 tonnes of ore per scenario which precludes the use of drill core, rendering the process very expensive. In order to mitigate these difficulties, modelling was considered as a potential way forward. However, as the JKSimMet AG/SAG model currently has no capacity to simulate the interaction of two ore types with differing impact resistance, density and/or feed size distributions, an alternative modelling approach was developed. This approach aims to essentially calibrate the AG/SAG process under a set of given conditions, for which survey data and the ore properties of the main components in the feed blend already exist. This paper describes a new conceptual model, which provides a simplified approach for investigating the multi-component behaviour of two ores of differing hardness/SG in a given AG/SAG milling environment, and which can potentially be used for scale-up from laboratory/pilot testwork and geometallurgical estimation of throughput.

Jan 1, 2012

By Claude Gosselin

En 1995, la Compagnie minière Québec Cartier a mis de l'avant un projet de recherche sur la modélisation de l'écoulement des gaz pour ses fours de frittage à l'usine de bouletage de Port-Cartier. Cette démarche s'inscrivait dans un large processus de collaboration avec l'Université Laval et le Consortium de Recherche Minérale (COREM). L'usine de bouletage possède deux fours de frittage d'une capacité moyenne de 600 tonnes/heure pour chacun des fours. Les fours de frittage sont des systèmes complexes d'échange de chaleur qui fonctionnent à contre-courant (le débit de boulettes versus les débits de gaz). Pour rencontrer les spécifications reliées aux propriétés mécaniques des boulettes, le processus de fabrication requiert des mesures et un contrôle des systèmes très précis. L'information fournie par plus de 70 capteurs (pression, température, puissance, vitesse, hauteur de lit, position de volet....) est utilisée pour manipuler une vitesse de grille, cinq ventilateurs et neuf zones de brûleurs. Malheureusement, les variables qui influencent fortement les mécanismes de frittage, c'est-à-dire les débits de gaz dans les différentes zones du four ainsi que la masse de boulettes qui circulent ne sont pas mesurées. Une méthode est donc proposée pour une estimation en ligne de ces variables. La méthode est basée sur un arrangement de 65 équations reliant pressions, températures et débits de gaz dans les conduites, les ventilateurs, les sections du lit et les fuites (Gosselin, 1998). Pour des raisons de simplification de cet article, seul un sous-système du four sera présenté. Les techniques de réconciliation des données reliées à la conservation de la matière et de l'énergie montrent que la mesure en ligne du débit de boulettes mène à l'estimation des débits de gaz et apporte des avantages intéressants pour le contrôle des variables stratégiques des fours.

May 1, 2001

By P. J. Oakley, W. M. Thomas, S. W. Kallee, D. G. Staines

A Friction stir welding (FSW) is now extensively used in aluminium industries for joining and material processing applications. The (FSW) technology has gained increasing interest and importance since its invention at TWI almost 15 years ago. The basic principle, recent applications and the continuing development of the FSW technology are described. The paper will introduce some of the variants of FSW, such as Dual-rotation, Twin-stir(TM), and the Stir-lock(TM) technique.

Jan 1, 2006

By H. J. B. Couto, J. G. S. Puelles, M. L. Torem, R. H. Rojas, A. G. Merma

Understanding the limits of fine particle flotation is fundamental to achieving a significant and selective separation. Conventional flotation processes are not suitable to treat these particles because of their low collision efficiency. This problem can be overcome by decreasing the bubble size or by increasing the apparent particle size. However it is worth noting that the use of small bubbles or micro bubbles also involves some disadvantages such as their low momentum resulting in a slower process comparing with conventional flotation. Electroflotation is an attractive alternative for treating fine particles with small bubbles less than 100 µm, generated by the electrolysis of water. In this sense, this study assesses the effect of current density and pH on bubble size in a binary electroflotation cell. An increase in the bubble generation rate was reported with an increase in current density. In addition, at acid pH values, the size of oxygen bubbles increased and conversely decreased at basic pH values; this may be due to the electrostatic attraction between the oxygen bubbles and the anode resulting in a greater nucleation time. An opposite trend was observed with the hydrogen bubbles. These results are in agreement with their electrokinetic studies, which reported that at acid conditions the bubble surface may be positively charged for both the hydrogen and the oxygen bubbles. Finally the bubble size was slightly affected by the electrolyte concentration, resulting in smaller diameter bubbles at higher concentrations.

Jan 1, 2016

By M. Leroux, C. J. Martin, S. R. Rao, J. A. Finch

"The effect of nitrogen on the flotation separation of sulphides from complex ores from Brunswick Mining and Smelting (New Brunswick) and Mattabi Mines (Ontario) was investigated. The most significant finding was enhanced pyrite floatability after as little as 3 minutes nitrogen conditioning. This was used in a novel sphalerite/pyrite separation process developed on the Brunswick ore. After aeration and Cu/Pb bulk flotation in air using xanthate the slurry was nitrogen conditioned, xanthate added and the pyrite floated in nitrogen. As an example up to 70% pyrite recovery with about 20% sphalerite recovery was achieved. Sphalerite was recovered from the pyrite tailings and the pyrite concentrate by copper-activation, raising the pH to 10 and floating in air. About 65-70% recovery at 35-40% Zn grade was achieved compared to 25% Zn grade by the conventional route. The process offers a promising alternative to current practice which seeks to depress pyrite at all stages. A possible mechanism of the effect of nitrogen is presented. INTRODUCTIONUse of gases other than air in froth flotation has been reported from time to time. [Podobnik and Shirley, 1982; Lin and Metzer, 1975]. Of all the gases, nitrogen would appear to hold the greatest practical promise because of its easy availability and chemical inertness. It is used in froth flotation in chalcopyrite-molybdenite separation [Redfearn, 1983]. The use of nitrogen in polysulphide chalcopyrite. this case is mainly to reduce the oxidation of a compound (Nokes reagent) used as a depressant for There is no reported use of nitrogen in the flotation of other sulphide minerals."

Jan 1, 1988

By L. A. M. Castro

As Canadian mines progress to greater depths, magnitudes of induced stresses increase, becoming high enough to cause rock mass damage and failure during excavation. In addition, depending on the orientation of key geological structures in relation to the in-situ stresses, induced shear loading can be developed on these structures, creating the potential for: a) remobilization of existing geological structures, b) formation of new seismically active structural zones, created through rock mass damage and coalescence along such structural zones, and/or c) interaction between existing and newly created structures. Numerical analyses were carried out to investigate four possible factors that might cause fault slip on controlling structures, namely: (a) unclamping, (b) day-lighting, (c) stress rotation and (d) pillar shear. Application to an underground mine in the Sudbury Basin allowed verification of these factors and the proposal of two alternative mine planning methods to limit fault slip on key structures: (1) pillar clamping and (2) stope sequencing.

May 1, 2009

By G. W. Diehl, G. A. Griffiths

"Gentlemen, one week ago, I attended the University of Minnesota's Annual Symposium on Mining, in Duluth. A good part of this symposium was dedicated to mill linings of rubber.At this symposium, three mining companies published results from long time full scale tests with rubber linings in mills at four different mines. These were the Republic and Empire Mines of Cleveland Cliffs Iron Company, the Groveland Mine of Hanna Mining Company and the Eagle Mountain Mine of Kaiser Steel Corporation. These papers will be printed in due time and I will not endeavour to relate their full contents, let me only say that in three of the plants, the linings were found to be very economical compared wi.th steel, and that these three are converting over completely to rubber linings, while the fourth, Empire Mine, reported no economical results as far as the shell lining goes, whereas the grates showed promise of becoming economical. The authors of the Cleveland Cliff's paper, however, stated that design improvements in the rubber lining possibly could result in an economical lining also for Empire Mine.That rubber linings in mills, in most cases, show better wear life than steel linings, is known by most of the audience. But, one thing that has not before been disclosed by the endusers is the effect of rubber linings on the grinding economy. All three papers mentioned above reported no change in capacity or grind and two of them reported a decrease in power consumption per ton ground. Hanna Mining reported an average decrease over a three year period for one mill of over 10%. This, of course, puts the economy of a rubber lining in a completely new light. Finally, a point of interest at this meeting was that all three papers emphasized the design aspect, Thus the industry has acknowledged what I believe to be a very important fact - the design of a lining is often more important than the material it is made of."

Jan 1, 1970

By P. Radziszewski

Industrial practice in mineral processing shows that an important problem in understanding and monitoring in-mill parameters is due to the lack of fundamental knowledge and appropriate sensors. With the development and growing use of DEM charge motion simulators for mill optimisation and design, it is possible to describe the fundamentals of grinding mill behaviour, in improving the understanding of internal grinding mill dynamics and in developing solutions to industrial practice. The main challenge to bringing this DEM technology to the mill operator however was the need for substantial computing power and time. However, what about a simplified DEM charge motion model running in real-time? What about the use of sensor technologies to correct any possible drift in simulator prediction? Could such a technological system be used to predict mill performance and eventually be used for mill control and optimisation? Some of these questions are answered with the development of an "on-line" DEM charge motion simulator package (SAGTools?) along with that of a number of sensor technologies (liner wear, acoustic, instrumented ball) that can contribute to simulator precision. With the objective of bringing this modelling and sensor technology into the concentrator control room to assist operators, this paper aims to describe the main elements of this emerging and developing technology and discuss how it can lead to online mill performance prediction and eventual control.

Jan 1, 2007

By David W. Mogk, Tamara Darsow, Macgregor L. Fogelsong, Robert M. Hunter, Frank M. Stewart, Edwin H. Abbott, Courtney A. Young

Abstract: Development of cost-effective techniques for recovering precious metals from their ores has been the goal of metallurgists for hundreds of years. Today, metallurgists are increasingly called upon to design processes for ores that are refractory to conventional recovery techniques. These challenges and the addition of environmental costs (including site remediation) to the total cost of mining have stimulated a search for alternatives to conventional processes, such as cyanidation. This paper describes the progress made to date in development of an innovative alternative to cyanidation, termed bisulfide leaching, for extracting gold, silver and platinum-group elements from refractory ores and concentrates. While bisulfide leaching can be implemented abiotically, significant benefits accrue from its practice as a bioprocess that integrates the steps of precious-metals liberation and extraction. In many applications, bisulfide leaching appears to offer significant advantages over the traditional cyanidation process. Dissolved bisulfide and hydrogen sulfide are much less toxic than dissolved cyanide and hydrogen cyanide. Recommended workspace exposure limits and harmful concentrations for hydrogen sulfide gas are higher than those for hydrogen cyanide gas. While the facilities required to practice the bioprocess on an industrial scale would be similar to that of cyanidation plants, chemical reagent costs could be 80 percent less. The bioprocess may also offer advantages in the leaching of ores and concentrates that are not amenable to cyanidation. For example, bisulfide leaching of ores containing carbonaceous material may produce higher gold recoveries if the "preg-robbing" characteristic of the material can be controlled biologically or with dissolved sulfide binding. Moreover, in that precious metals are much more soluble than base metals in bisulfide solutions, bisulfide leaching offers distinct advantages over cyanidation for selective dissolution of precious metals from base-metal concentrates. Thus, the bioprocess uses the natural sulfur cycle to mitigate pollutant production and to enhance precious-metals recovery.

Jan 1, 1998

By M. Pötsch, W. Schubert

"The kinematic analysis of rock blocks is one part of a block stability assessment. It provides information about a block’s movability, i.e. if a block can detach from the adjacent rock mass and move towards the free space. This paper introduces an analytical method for the analysis of pure rotations of arbitrary finite polyhedral blocks. It enables the engineer to judge a block’s rotatability about a corner or an edge. The method is presented using a graphical and computational method. The application of the method is illustrated with an example. INTRODUCTIONThe kinematic analysis of rock blocks deals with the determination of the movability of blocks. Established methods typically cover: (a) translational motion (John 1968, Markland 1972, Londe et al. 1969, 1970, Goodman & Shi 1985, Warburton 1981) and (b) the specific rotational cases Toppling (Goodman & Bray 1977) and Slumping (Kieffer 1998). Mauldon & Goodman (1990, 1996) and Tonon (1998) introduced rotational kinematic analyses for three-joint pyramids and tetrahedral blocks extending Goodman & Shi’s block theory.All mentioned methods are subject to assumptions that limit the applicability to engineering problems. For example, the kinematic test of daylighting joints or intersections inherently assumes a finite block, which only can be proved by the finiteness theorem (Goodman & Shi 1985). Daylighting of an intersection or plane is not a sufficient condition for removability. Goodman & Shi’s and Warburton’s methods are limited to translational block motion. The methods for block rotations so far address tetrahedral blocks only. They also address only pure rotational modes and neglect the general motion of a rigid body. This paper introduces an analytical method for the analysis of the kinematic rotatability of finite rock blocks. It extends Mauldon's and Tonon's theory of rotatability of tetrahedra to arbitrary polyhedral blocks. A graphical method using the stereographic projection and a computational method are presented."

Jan 1, 2015

By A. Singh

"Flotation of fine (< 10 µm) minerals is a challenge exacerbated by the emerging practice of fine grinding flotation feed to better liberate targeted minerals; however, the ability of conventional flotation cells to float liberated fines remains questionable. The Gold Ore solution using Mach reactors was tested at Mintek, South Africa, and showed an ~180% increase in the Kelsall kfast factor, a projected recovery improvement of 4% for the Mach-reactor case, and final concentrate grade twice that of conventional flotation. Theory, pilot plant results, and key aspects of plant design, supplemented by operational plant observations after commissioning, are discussed.RÉSUMÉ Le procédé de flottation de minerais fins (< 10 µm) pose de grandes difficultés, lesquelles sont aggravées par la pratique émergente de l’alimentation du circuit de flottation avec des mailles de broyage très fines pour mieux libérer les minéraux ciblés ; la capacité des cellules de flottation classiques à flotter les fines de minerais libérées reste cependant discutable. La solution proposée par la société Gold Ore, qui utilise des réacteurs Mach, a été testée à Mintek, en Afrique du Sud ; elle affichait une augmentation d’environ 180 % du facteur kfast développé par M. Kelsall dans son modèle de flottation, une amélioration prévue de la récupération de 4 % dans le cas du réacteur Mach, et une teneur finale des concentrés deux fois plus importante que celle obtenue avec la flottation classique. Sont débattus dans cet article la théorie, les résultats générés par l’usine pilote ainsi que les principaux aspects de la conception de l’usine complétés par des observations relatives à l’usine en activité après sa mise en service."

Jan 1, 2018

By F. Rosenblum, P. Spira

"A correlation has been established between the oxygen demand of Brunswick Mining and Smelting ore and flotation results at the bench, pilot plant and operating plant scale. A method of dete""1llining the aeration requirement of sulphide ores on the basis of this correlation is presented. It is shown that abraded iron from grinding media plays an important role in aeration and flotation. Laboratory grinding must therefore be conducted under controlled conditions with suitable grinding media in order to obtain the true aeration requirement of the ore.A method of evaluating aerator efficiency, also based on oxygen demand measurements, has been used successfully at Brunswick Mining to design pilot plant and full-scale aeration systems.1. IntroductionPre-flotation aeration of sulphide pulps has been practiced in the Noranda Group for many years to help in the depression of pyrite and pyrrhotite and to promote chalcopyrite and/or galena. Recently, two out of three parallel circuits at the Brunswick Mining and Smelting Corp. Ltd. concentrator have been converted on a test basis to a new flowsheet incorporating aeration as a basic step. Among other benefits, a substantial decrease in the middlings load has been achieved as a result of improved pyrite rejection. There has been increasing interest in other organizations in the potential advantages to be derived from' aeration in terms of improved metallurgy and/or decreased reagent consumption."

Jan 1, 1978

By T. Macpherson

Drawing on past research experience with sprayable polymer mine support agents (TSLs), Spray On Plastics Ltd. has developed a TSL ground support system called RockWeb. Using a relatively new polyurea polymer technology, RockWeb has been engineered to solve problems encountered underground with polyurethane liners by incorporating rapid curing, moisture insensitivity and superior physical performance. RockWeb possesses a unique, patented ability to be sprayed in a ?cobweb? like consistency allowing the applicator to span fissures in the rock, ensuring no initial defects in the liner, and maintaining design thickness over highly irregular surfaces. This ability, coupled with the high strength and elasticity of polyurea, allows RockWeb to mitigate rock movement through yielding, while maintaining intimate surface confinement. RockWeb provides reduction in logistics through the transport of 1/25 of the material quantities required for shotcrete, rapid deployment rates of as little as 30 minutes per round, and immediate return to the work area. This paper will discuss the technology and advantages of RockWeb as well as opportunities for overall mining cycle cost reduction. The safety benefits, as well as health and environmental considerations regarding application of isocyanate-based liners will also be discussed.

May 1, 2009

By Z. Zhao, B. Li

"Fractures are the key channels for fluid flow and mass transport in fractured rocks of low/negligible matrix permeability. In single rock fractures, surface roughness causes fluid flow in tortuous paths, and reduces the overall fracture conductance. A number of empirical models have been proposed to relate the reduced hydraulic aperture to the mechanical aperture due to surface roughness, which were revisited and compared. Using two of those relationships between hydraulic apertures and mechanical apertures, we studied the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks. The results show that fracture roughness can affect the flow rates and residence time to varying extent, mainly depending on the empirical models between hydraulic apertures and mechanical apertures. However, fracture roughness has negligible influences on the general patterns of fluid flow (channeling) and solute migration (e.g., travel paths and shape of breakthrough curves). This is because the connectivity of a fracture network is mainly determined by other geometrical parameters (fracture positions, orientations, and lengths), rather than roughness or apertures. INTRODUCTIONIn fractured crystalline rocks of low or negligible matrix permeability, fluid flow and contaminant migration mainly occur within the connected fractures. An understanding of fluid flow and contaminant migration in fractured rocks is a crucial issue in many deep underground projects, e.g. underground repositories for radioactive waste, CO2 sequestration, enhanced geothermal systems, oil and gas production, etc. Rock fractures are typically rough-walled, and surface roughness appears to have first order control on the mechanical and hydraulic behavior of single rock fractures (Boutt et al., 2006).It is well known that the mechanical aperture of a rock fracture is usually larger than its hydraulic aperture, due to fracture surface roughness (Tsang and Witherspoon, 1983). However, for naturally fractured rocks including numerous discontinuities, the effects of this reduced hydraulic aperture in local fractures on macroscopic fluid flow and solute transport in complex fracture systems still remain unclear. Many previous studies assumed identical hydraulic and mechanical apertures in discrete fracture network models for simplicity (Min et al., 2004; Zhao et al., 2011). Therefore, the main objective of this study is to evaluate the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks, by employing the empirical models that relate the hydraulic aperture to the mechanical aperture."

Jan 1, 2015

By J. E. Dutrizac, R. J. C. MacDonald, J. B. O'Reilly

"Sometime around 3000 B.C., primitive metallurgists working in the mountainous regions of Asia Minor bordering on the Black Sea (Pontus) produced a soft, easily fused metal today known as lead. It appears certain that the first metal was made by reductive smelting of galena, but whether this recovery arose by the accidental inclusion of galena in the stones of a fire hearth or whether it occurred as a consequence of simple pyrometallurgical experiments on a series of interesting ""stones"" will likely never be known with certainty. The properties of galena, high metallic lustre, great density and facile cleavage, must have excited the ancients, and such ""stones"" would have been the object of primitive testing111 - Shortly after the discovery of lead, the ancients found that the controlled oxidation of this metal at elevated temperatures yielded smaller amounts of a more interesting material, silver. Again, it is uncertain if the production of silver by primitive cupellation techniques was the result of a fireside accident or the consequence of a deliberate experiment, but the important fact is that silver was produced shortly after the discovery of lead. The techniques for making lead and silver spread gradually throughout the entire civilized world, likely as a result of both technology diffusion and independent rediscovery. The physical properties of lead could not have been overly attractive to the ancients, but silver was a different matter altogether. The gleaming white lustre and relative immunity to oxidation quickly assigned silver to the precious materials category, a status it still enjoys. In early times, argentiferous galena was inevitably processed only for its silver values; lead was generally an unwanted byproduct and was frequently discarded as litharge (PbO) during the cupellation process. The silver was eagerly sought, however, and resulted in considerable mining activity culminating in the famous Athenian silver mines at Laurium at the southern end of the Athenian peninsula."

Jan 1, 1999

By T. Macpherson

ABSTRACT: Drawing on past research experience with sprayable polymer mine support agents (TSLs), Spray On Plastics Ltd. has developed a TSL ground support system called RockWeb. Using a relatively new polyurea polymer technology, RockWeb has been engineered to solve problems encountered underground with polyurethane liners by incorporating rapid curing, moisture insensitivity and superior physical performance. RockWeb possesses a unique, patented ability to be sprayed in a ?cobweb? like consistency allowing the applicator to span fissures in the rock, ensuring no initial defects in the liner, and maintaining design thickness over highly irregular surfaces. This ability, coupled with the high strength and elasticity of polyurea, allows RockWeb to mitigate rock movement through yielding, while maintaining intimate surface confinement. RockWeb provides reduction in logistics through the transport of 1/25 of the material quantities required for shotcrete, rapid deployment rates of as little as 30 minutes per round, and immediate return to the work area. This paper will discuss the technology and advantages of RockWeb as well as opportunities for overall mining cycle cost reduction. The safety benefits, as well as health and environmental considerations regarding application of isocyanate-based liners will also be discussed.

May 1, 2009

By D. R. Schmitt, N. Ong, R. S. Kofman

Shales and mudstones comprise about 75% of all the sedimentary rocks. In, particular, organic rich shales are considered as a petroleum source rock and more recently with the advent of hydraulic fracturing technology to be a reservoir in their own right. In this sense, the aforesaid motivates our work with laboratory measurements of elastic properties of these geologic materials, which are known to be anisotropic. As such, assuming Vertical Transverse Isotropy (VTI) symmetry, the dynamic and static moduli of a series of cores from various geological formations in Alberta, Canada are simultaneously investigated as a function of confining pressure using the ultrasonic pulse transmission method and strain gages. Dynamic moduli were obtained from ultrasonic P- and S-wave velocities measured on a prism cut with faces perpendicular, parallel and oblique to the assumed vertical axis of symmetry. Static moduli were calculated from strain-stress curves obtained along the directions perpendicular and parallel to the assumed axis of symmetry as well. Velocity measurements show that samples are highly anisotropic, but that the pressure-dependent behaviour of the wave speeds differs. VP(90°) and VSH(90°) both with layer parallel propagation and polarizations change little with pressure while VP(0°) and VS(0°) (both with layer perpendicular propagation) display significant nonlinear responses particularly at pressures < 25 MPa. These characters transfer to the derived full set of elastic constants. In order to effect a proper comparison of the dynamic and static moduli, we convert the dynamic elastic constanst to linear compressibilities pependicular (Kdyn1) and parallel (Kdyn3) which are directly comparable to the static tangent compressibiities obtained by differentiation of the observed strains. Both sets highlight the anisotorpic nature of the material but most interestingly Kdyn1 _ Ksta1 but Kdyn3 > Ksta3 by nearly 40% for one of the samples. The other samples measured respond similarly suggesting that conceptually the structure of such materials could be considered to be constructed of alternating stiff or compliant layers. This finding has implications in the response of the formation to stress particularly during hydraulic fracturing and the interpreation of acoustic logs in providing appropriate measures of elastic properties for engineering purposes.

Jan 1, 2015

The dissolution of chalcopyrite has received a significant amount of attention. The predominant paradigm of investigation is that its rate of dissolution is limited or passivated by a surface coating or film of material. The common candidates for such a passivating coating are numerous: polysulfide coating, metal deficient layers, copper sulfide coating, bornite layers, jarosite precipitates, and elemental sulfur films. While this line of explanation, that is, the explanation based on passivation, seems to have won some form of consensus with researchers, there is another explanation for the results that can account for all the results observed. Crundwell (1988) proposed that the solid state properties of chalcopyrite, in particular, the semiconducting properties, are responsible for the observed behaviour of chalcopyrite. The purpose of this paper is to outline the semiconductor mechanism of dissolution, and to show how this mechanism accounts for all the observed phenomena recently reported in the literature. The paper outlines the semiconductor mechanism of dissolution, shows how this mechanism accounts for the dissolution

Jan 1, 2014