Search Documents

By P. W. Waggitt

ABSTRACT From approximately 1986 until 2000, uranium production was at a historic low. In 2003, uranium mineral exploration surged, despite the global financial crisis; however, the shortage and aging of qualified and experienced operators and regulators might soon become a constraint to this upsurge. This is true for all types of engineers, geologists, other scientists, tradespeople, and technicians. The situation raises questions about how the global mining industry in general and the uranium sector in particular will cope with future staffing needs. In this paper, the author examines the current situation and describes how some organizations are seeking possible solutions.

Jan 1, 2014

By N. A. P. Kiran Kumar

The Zr-Nb alloys are reported to be showing superior resistance to corrosion and substantially lower hydrogen pickup when compared with zircaloys. In the present study zircaloy-4 and Zr-1Nb (E110) alloys were hydride using high pressure hydrogen gas furnace at a pressure of 20 MPa. Thermal cycling was done on the samples at a temperature of 3500C for 10 cycles with 5h soaking time at 3500C per each cycle. The Microstructural observations on zircaloy-4 samples show long and interlinked hydride like chain, oriented along the circumferential direction. Whereas in Zr-1Nb, short hydrides were observed with hydride platelets not showing interlinked chain like structure. The hydrides in Zr-1Nb were observed to be not showing particularly orientation along the circumferential directions. Electron backscatter diffraction was use to understand the hydride precipitation and their orientation in Zircaloy-4 and E110 alloy.

Aug 1, 2010

By T. A. Apelt, B. J. Elliot

"In September 1993, the flash furnace at Kalgoorlie Nickel Smelter, KNS, was brought off line after almost 12 years of operation. This is a record campaign life for a flash furnace. The furnace was' totally rebuilt and the capacity of the plant increased from 540 000 tpo to 750 000 tpa of concentrate throughput. The throughput increase was' achieved through the construction of a 525 t/day oxygen plant and upgrading of various plant ancillaries. A number of significant design modifications were also built into the flash furnace and oxygen enrichment was implemented in the operation of the Peirce-Smith converters.This paper discusses the rebuilding of the flash furnace and design modifications made to furnace equipment and ancillary plant. Some preliminary post-startup operating data are presented.IntroductionIn September 1993, Campaign 6 of the flash furnace was concluded and the furnace brought off line for rebuilding. The campaign length was almost 12 years and set a new record for campaign length. Planning for the rebuild took place over the last five years of the campaign. A number of modifications to the design of the furnace and the ancillary plant were planned to coincide with the furnace rebuild. The furnace was rebuilt and recommissioned in 70 days. The increased plant capacity of 750000 tpa has been achieved by the construction of a 525 t/day oxygen plant and modifications made to ancillary plant which centred around increased p~ control, efficiency and hygiene. This paper examines the development and implementation of the modifications made to the furnace and ancillary plant. Preliminary post-shutdown performance data are presented."

Jan 1, 1995

By MKS Vel, S. Mukhopadhyay, R. Mishra

Off late, the criteria of selecting the refractory have acquired a trend line aiming to a cleaner environment and the utmost importance is given to the eco-friendly approach. The stainless steel making furnaces normally use mag-chrome refractories for the obvious reasons of changing slag basicity from acidic to basic. Such refractories generate toxic fumes and compounds with hexavalent chrome, which is unhygienic if inhaled. The present paper describes the development of a chrome free alumina magnesia carbon refractory, it's different test properties, simulative testing and microstructures. The optimum quantity and distribution of carbon in the brick restricts the carbon pick-up by the steel. Bricks with the same composition were manufactured in the commercial scale and used in a stainless steel making furnaces in USA. The performance of same refractory in this furnace was quite encouraging and at present the same quality brick has become a normal practice in this furnace. Since no chromite is used in making this brick, so no toxic compounds are generated environment remains pollution free.

Jan 1, 2004

By Dwayne D. Tannant

This paper presents a new mining concept for oil sands called ?hydraulic underground mining of oil sands? or HUMOS. While this mining method is still at the conceptual stage it has great promise to allow extraction of bitumen from areas that are currently uneconomical or technically infeasible using surface mining or steam assisted gravity drainage. HUMOS is founded on a combination of recently proven technologies such as directional drilling, water jet cutting of oil sands, slurry transportation, cold water extraction of bitumen, and thickened tailings. One key component in the mining concept is the caving of oil sands and the creation of an underground cavern. Scaled-down physical models will be designed and built to demonstrate water jet cutting, cave development, and insitu primary bitumen separation. These will be used as a 'proof of concept'. On-going research will establish and prioritize issues that need to be resolved, outline key areas where further research is needed, foster establishment of research teams to divide and conquer the important questions, and create framework for future coordinated research efforts.

May 1, 2001

By G. K. Quainoo

Investigation by researchers on the application of various thermo-mechanical process histories on 6000 series aluminum alloys have found improvements in mechanical properties of these alloys. However, natural aging, which is unavoidable in the automotive processing line, has been found to have deleterious effect on subsequent artificial aging properties in these alloys. In this study, the evolution of yield strength during natural aging modeled by Lloyd and Gupta has been adapted to investigate the effect of cold deformation on the natural aging kinetics in AA61 11 by means of tensile testing, differential scanning calorimeter (DSC) and scanning electron microscopy (SEM). Also, intermetallic particles in the alloy were extracted from the matrix and XRD performed on them to ascertain their composition and their role on the kinetics in the alloy. The results show that cold work effect on the natural aging kinetics of AA6111 is in very good agreement with the model proposed by Lloyd and Gupta. The kinetics of natural aging in AA6111 aluminum also decreases with increasing level of cold work. This is attributed to dislocations serving as sinks which consume quenched-in vacancies formed during the early stages of clustering. The phases of the intermetallic particles identified in AA6111 are those of a-A15Mn12Si7 and a-A15MnSi.

Jan 1, 2007

By M. B. M. Monte, M. L. Torem, E. R. Pecanha, A. G. Merma

The recent literature has unveiled the potential use of microbial strains in mineral bioprocessing. This study presents the use of a Gram-positive bacterium (Bacillus subtilis) as bioreagent for hematite flotation. The bacterium presents the ability to modify the properties of mineral surface (electrophoretic mobility and hydrophobicity). It was studied the electrokinetic behavior of hematite particles, before and after the interaction with the bacterial cells. The results revealed a shift of the isoelectric point (IEP) of the hematite after interaction with bacterial cells, suggesting a chemical adsorption mechanism. Moreover, after bacterial conditioning, the zeta potential curve of hematite presented high values in the alkaline pH range. The hematite and the bacterial surfaces presented contact angle values around 27.4° and 41.0°, respectively. According to the results, the B. subtilis strain was capable of modifying the hematite surface, and after interaction the hematite surface presented a contact angle value around 46.0°. The flotation tests were carried out in a modified Hallimond tube. The experiments revealed a significant increase in hematite flotability using the Gram-positive strain as bioreagent. The tests pointed out a maximum recovery of hematite in the presence of 600 mg/L and pH 5. Therefore, the results from this study showed the potential use of the B. subtilis strain as a biocollector for hematite flotation, and its possible application in the mineral flotation industry.

Jan 1, 2016

By Jean-Guy L. Gauthier

"With the Ontario Ministry of the Environment stipulating that the cumulative concentration of copper, lead, zinc and nickel in mine mill effluent must be no greater than 1.0 milligram per litre, it has become necessary for the mining industry of find some form of treatment for the removal of heavy metals from effluent waters.To comply with these guidelines, it became necessary for Mattabi Mines Ltd., which is situated 50 miles Northeast of Ignace in Northwestern Ontario, to develop a compact, cost effective and technically sound treatment process to remove heavy metals from their tailings overflow. A design committee consisting of mine metallurgists, environmental engineers, a Dutch research and development team and the equipment supplier engineering staff was set up to accomplish this.Using some new and innovative wastewater treatment equipment, the guidelines established by the Ontario Ministry of the Environment can now be met. The sludge produced from the precipitated heavy metals is sent directly to the concentrator, thus eliminating the danger of re-dissolution of the metals in a landfill site, while recovering some of the valuable metals that would otherwise be wasted in a sludge landfill."

Jan 1, 1980

By Etienne Roy Grégoire

Since the early 1990s, the Canadian mining industry has been increasingly defined by the signing of Impact and Benefit Agreements (IBAs) between mining companies and Aboriginal peoples. While these agreements are intended to complement the legal system, they also serve to establish the legitimacy of mining projects and to encourage the harmonious integration of these projects into their social and environmental contexts. Beyond their practical implications, what are the effects of such agreements on the ability of Aboriginal communities to access the institutional space where the authorization of mining projects and the conditions of their implementation are decided? Can we view IBAs as a preliminary step towards the operationalization of the principle of Free, Prior and Informed Consent? This paper aims to explore the potential of IBAs as a sustainable solution to the legitimacy issues that result from the implementation of the formal regulatory framework governing mining activities in this jurisdiction. We highlight what constraints and opportunities the James Bay and Northern Quebec Agreement (JBNQA) engenders for local communities and draw attention to the ways in which the negotiation of the Raglan IBA and the environmental evaluation processes act upon each other. We find that certain structural problems - and problems of legitimacy ? related to mining in Northern Quebec cannot be solved by the sole signature of an IBA, which suggests the need for caution when considering such agreements as a panacea. The Raglan case demonstrates that IBAs, like other modes of regulation relying on the direct interface between companies and communities, would benefit from a stricter framework and more explicit ties with official regulation channels.

Aug 1, 2013

By N. Kolev, M. Poibrenski, I. Nishkov

"The following paper examines the flotation of copper porphyry ores in Assarel concentrator with focus on the reasons for low molybdenum recovery in the final copper concentrate. The copper-porphyry ore of the Assarel deposit is characterized by its variable mineral composition and high clay content, which influence the process efficiency of their concentration. Particle size distribution, chemical and mineralogical analyses have been made on various flotation products showing the distribution of the main elements of interest - copper and molybdenum. It was found that molybdenum is not concentrated into the final copper concentrate as usual in the flotation of copper-molybdenum ores but into the tailings of the copper selective flotation (cleaner tailings). An attempt to explain these results has been made with proposals to improve molybdenum flotation. Low floatability of molybdenite is caused by the ultrafine clay minerals content in both the run-of-mine ore and copper flotation streams. In order to achieve selectivity of copper minerals against pyrite a significant amount of lime is used in the plant leading to higher pH conditions, which could be another possible explanation for the molybdenite depression. The results obtained after the laboratory experiments, showed that it is possible to restore molybdenite floatability using traditional reagents such as diesel, kerosene, etc., and introducing a new polymeric reagent as froth modifier.INTRODUCTIONOne of the main technical difficulties in the area of copper-molybdenum flotation is the selective recovery of both metals, especially the fine (<40 micron) mineral particles. The problem is even more serious when Cu-Mo ore treated contains a lot of natural fine particles, predominantly clays, micas and other gangue minerals. Peng and Zhao (2011) conclude that the mineral processing industry is well aware of the difficulty in treating ores in the presence of clay minerals. Tremolada et al (2010) found that clay minerals have been named as the main problem in ore beneficiation processes due to their small size, which cause a higher viscosity in grinding. In flotation, these clay minerals have natural hydrophobicity or float by entrainment.The impact of clay mineralogy on flotation performance has been reviewed in the literature and the various deleterious roles of clay minerals have been investigated (Bulatovic, Wyslouzil & Kant 1999; Jorjani et al, 2011; Farrokhpay, Bradshaw & Dunn, 2013). It is widely accepted that the actual flotation recovery problem appears to be caused by the properties of these fine particles: small mass (and/or momentum) – high interfacial free energy (Rubio et al., 2007; Farrokhpay, 2011). In most cases, the loss in recovery is found to be insignificant, but the detrimental effect on the concentrate grade is found to be more prominent. The main reasons for the flotation inefficiency are the low probability of bubble-particle collision and adhesion, formation of dense froths and as a result - low process kinetics. A great deal of fine valuable minerals is discarded as slime in flotation due to lack of effective recovery methods."

Jan 1, 2016

By A. E. Wraith, J. Protheroe Jones, P. J. Mackey

INTRODUCTION When Victoria became queen in 1837, that technical wonder of the 19th century—electricity— had progressed from being an exciting physical curiosity and was now a field of intense scientific investigation, invention and application. Its role in electrochemistry had been brilliantly quantified by Faraday in 1833–1834, and his earlier discoveries in electro-magnetism were to lay the foundations of electricity generation and the electric motor. In this age of electrical experiment, silver electro-plating emerged as a popular decorative art, at first using batteries to provide the deposition current, superseded by dynamos in the early 1840s. The decorative chemical and electroplating of precious metals was largely pioneered in England by the firm of G.R. Elkington and Co., founded in Birmingham by George Richards Elkington (1801–1865) in 1832, and protected by a series of patents which helped the company establish a leading position in the new field of ‘electrometallurgy’. In the same decade, the technique of electrotyping emerged, the first application of electro- forming by electrolytic deposition. Simultaneously invented by Spenser in England and Jakobi in Russia, but generally claimed for Jakobi, electrotyping involved plating a thick copper layer on to an electrically conducting mould wall embossed or incised with a pattern or profile which would consequently be replicated on the copper deposit—essentially a method of casting by electro-deposition with the mould wall as cathode. Woolrich’s invention of the low voltage magneto-dynamo in 1842 eliminated the need for batteries as a continuous source of deposition power, opening up the possibility of making more massive electroplated deposits, and by the mid-point of Victoria’s reign in 1869, the work of Wilde, Wheatstone and Siemens had produced the self-excited electro-dynamo, capable of higher voltages and yet greater deposition power. In this early Victorian period copper was extracted and refined by methods which had developed step-by-step over many decades. Only relatively rich copper ores containing more than, say, 6% Cu were economically useful, and the final copper product was far from pure. Copper production in Britain was located principally in the Swansea area of South Wales, based upon the ‘Welsh process’ of reverberatory batch smelting and refining, using locally mined coal and ore imported from Cornwall and elsewhere. Silver was an important by-product. Much of the output was exported and South Wales remained a principal supplier to the world copper market until the 1890s. It was here at Pembrey, a few miles west of Llanelli, that a new primary copper smelter was stablished in 1849 under the name Mason and Elkington, arguably to supply the Elkington company’s market for electrotype products.

Jan 1, 2019

By A. Scheltema Beduin, M. Kalisch, E. Floch, R. J. Dijkhuis, H. J. Oterdoom

In metallurgical copper production, the traditional aim is to increase recovery of copper to the maximum. SMS Siemag (SMS) has supplied numerous furnaces for this application. New targets are to make sure end of line products are as safe as possible with respect to health and environment, and to maximize raw material utilization. This means a for example a minimization of leachable metals in slag, so it can be safely used as a construction material, and either a targeted concentration or fixation of volatile compounds, such as arsenic. Currently, 2 process routes are generally applied for slag cleaning. The first is grinding followed by flotation, and the second is slag cleaning in an (electrical) furnace. Popularity of both options has fluctuated over the years, and currently the milling-flotation seems to be the more popular option. In this article some of the advantages and disadvantages of both methods are described, and especially how long term environmental policies could have an impact on the decision which process route to choose. Finally, this article will describe some of the developments SMS is working on in pyrometallurgical slag cleaning that could influence the direction for the design of the copper plant of the future.

Jan 1, 2014

By R. S. Forgan

The synthesis and study of a systematic series of phenolic oximes have shown that substitution in the 3-position can greatly affect extractive efficacy. Solid state, solution and gas phase analytical techniques, including X-ray crystallography, EPR and IR spectroscopy and collision induced dissociation mass spectrometry have been assessed for their applicability in interpreting the origins of differences in extractant strength. The dominant substituent effect on pH0.5 is the change in ligand pKa, with the more acidic ligands being stronger extractants. The influence of the 3-substituent on the stabilising intracomplex H-bonding of their copper(II) complexes also affects extractant strength. The 3-NO2 substituted ligand shows the lowest pH0.5 value, due to a combination of its low pKa and a stabilising bifurcated H-bond assembly around the copper(II) centre. Appending an aminomethyl group to the 3-position gives a ligand capable of binding a metal and its attendant anion. These metal salt reagents show potential to open up new flowsheets for the processing of high tenor copper feeds.

Jan 1, 2007

By Mary Jean Buchanan

The last twenty years have seen the advent of environmental concerns and sustainable development, and the industry has witnessed the rise of Environmental Management Systems and their registration through several international standardization systems such as EMAS and ISO 14001. Beyond EMS and ISO 14001, which new goal the mining industry should aim at. Life-cycle assessment (LCA), another tool from the Environmental Management System series, is also on the rise and currently the object of an international standard (ISO 14040:1997). Through LCA, it is possible to assess the environmental aspects and potential impacts associated with products and services, taking into account all the activities required for its fabrication, its use, its transportation and its disposal. How could LCA be applied to the mining industry ? Is the international market pressurizing on mining companies to supply an ?environmental ore?? What about the automobile industry and its use of LCA ? Will it influence the ferrous and non-ferrous metal industry, suppliers of raw materials ? This paper presents a review of possible applications of LCA for the mining industry as well as world trends.

May 1, 2001

By S. J. van Rensburg

Competition for resources, including water and arable land, refocused attention on water and gold tailings management with respect to quantity and quality. MINTEK established and validated an "Advanced Leach Facility" to record kinetic leach information aimed at gold refractory sulphide ores. This facility was developed because of the need for additional leach process information to enable proactive decision making. Instead of focussing on optimised gold recovery only, the impacts of pre-oxidation methodologies were evaluated by considering key parameters, including cyanide speciation, reagent consumption, thiocyanate, arsenic, heavy metals, salt loads, water quality and residue stability. Results from oxidative leaching of a refractory gold ore employing oxygen, ozone, ultra-fine grinding, high shear and pressure oxidation are discussed. The relative cyanide and lime costs and environmental and sustainability effects associated with these technologies are briefly outlined.

Jan 1, 2011

By Michele L. Kimble

A fast-flow reactor mass spectrometer has been utilized to investigate the reactions of gas-phase gold cluster anions with CO and oxygen. Addition of CO to Aun - produces species of the form Au(CO)m -, where m = 2-5. However, CO does not bind to Au2 - or Au3 -. With oxygen addition in the cluster source, gold oxide species with both molecular and atomized oxygen are produced. The addition of carbon monoxide to these preoxidized gold cluster anions reveals that select species with 1, 2, and 3 gold atoms participate in the oxidation reaction to produce CO2. Bimolecular rate constants for the reactions between these species and CO are also discussed.

Oct 1, 2003

By S. J. Buckler

Many metallurgical processes use submerged gas injection to increase the contact area between gas and liquid phases in order to promote faster overall reaction rates. The work presented in this paper is part of an experimental investigation to measure the gas-liquid interfacial area available in bubble plumes within molten metal baths. Measurements of the nitrogen absorption rate during submerged injection into molten iron baths have been used to estimate the interfacial areas of the bubble plumes. A theoretical model was used to predict the superficial nitrogen transfer rate under mixed liquid phase mass transfer -interfacial reaction control. The interfacial area was calculated by dividing the overall nitrogen absorption rate by the superficial rate. Reasonable agreement was obtained between the interfacial areas measured in our laboratory with data from a comparable system reported in the literature. The experimental results were compared with the predictions of three theoretical models and one empirical correlation. The models of Turkdogan (3) and Zhao and Themelis (5) gave the best agreement with our data.

Jan 1, 2004

By Lastram Rolando, Larry J. Hulbert, Louis J. Cabri, J. H. Gille Laflamme, John L. Campbell, Soey H. Sib, Chris G. Ryan

"The mineralogy of samples from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon Territory, is complex and the metals of interest are contained within fine-grained minerals which vary in size and mineral associations from sample to sample.The major Ni carriers are pentlandite and violarite; the major Cu carrier is chalcopyrite. About 700/0 of the major Ni carriers and 78% of the major Cu qurier will be liberated at a grind of 80% -U,.7 ,an (-500 mesh) for typical low-grade gabbro (West zone, sample No.1). For typical ""clinopyroxenite"" (West zone, sample No.2) and typical ""clinopyroxene-rich peridotite"" (East zone, sample No.3) the liberation would be 71% and 65% for Ni, 74% and 60% for Cu, respectively. Fine grinding, however, cannot liberate the Ni contained in silicates and pyrrhotite, estimated to total 24.5% for typical low-grade gabbro (West zone, sample No. I), 15% for typical ""clinopyroxenite"" (West zone, sample No.2), and 12% for typical ""clinopyroxene-rich peridotite"" (East zone, sample No.3).The principal Pt carrier (sperrylite) varies considerably in grain-size between samples and fine grinding, required to liberate the major Ni and Cu carriers, may be counterproductive in samples where sperrylite is relatively coarse-grained, as some would then be unrecovered (e.g. sample No. 1). In addition, sperrylite in samples No.2 and No.3 is closely associated with magnetite. Palladium occurs in diverse ways. It occurs in the form of several Pd minerals (e.g. sudburyite, testibiopalladite, merenskyite), as a replacement for Ni in several tellurides, antimonides and tellurantimonides (e.g. melonite), or as very low concentrations in pentlandite (up to 34 ppm), chalcopyrite (up to 9 ppm), and pyrrhotite (up to 5.6 ppm). Palladium minerals and Pd-bearing minerals are strongly associated with chalcopyrite in sample No. 1 and will thus report to a Cu concentrate.However, 22% of the total Pd is in solid solution in pentlandite in this sample and will thus report to the Ni concentrate. In samples No.2 and No.3, less Pd occurs in solid solution in pentlandite, and the PGM are distributed mainly among pentlandite, chalcopyrite, and magnetite in sample No. 2, and among pentlandite, pyrrhotite, chalcopyrite, and magnetite in sample No.3. Therefore, the feasibility of magnetic concentration should be investigated for samples like No. 2 and No.3, in order to improve Pt and Pd recoveries. Rhodium was found to occur as rare hollingworthite, in sparse cobaltite (up to 2.7%) and, as low concentrations in chalcopyrite (to 10 ppm) and pentlandite (to 12 ppm) by proton microprobe. Iridium occurs in hollingworthite (up to 7.8%) and very rarely as the native metal or in an undefined Re-Ir-Qs..Ru alloy. Ruthenium was determined by proton microprobe analyses to occur in pentlandite (up to 13 ppm) and chalcopyrite (up to 10 ppm), in addition to rare laurite and Re alloy."

Jan 1, 1993

By Bish Chanda

In the minerals business, like any other commodity-based business, management faces the daily challenge of holding down costs while the real prices of products are continually falling on an inflation-adjusted basis. Since the marketplace sets the prices, often without any premium attached for product quality, being one of the lowest-cost producers is the most viable competitive strategy. Continuous improvement is the mantra that can make the difference in terms of long-term survival of a mining company. Yet, this message has not always been followed, especially during periods of prosperity ushered by high commodity prices. More often than not, the need for improvement is only triggered by a crisis. This may be caused by events such as the onset of a severe economic recession, a prolonged oversupply situation due to an optimistic expansion of capacity during the period of prosperity, or simply falling profits alerting management to bring costs under control. At that time, there would be a need to implement a new cost-saving program, bring in a consultant to find ways to reduce costs, or re-activate an old program that had been shelved for some time.

May 1, 2003

By J. Kouam

Al-Si-Cu and Al-Si-Mg alloys are widely used in several applications. Although they can be produced near-net-shapes, products made of these alloys very often require some machining. The purpose of this study is to evaluate the machinability of A319 and A356 under TO and T6 conditions. The machinability was assessed using during dry drilling machining process and the machinability indexes used are the chip form, the chip breakability and the cutting forces. It is found that 319 and 356 exhibit different machinability behaviors, especially in the T6-condition in terms of forces requirements, chip breakability and chip segmentation. It is also found that both the microstructure of the workpiece materials and the machining conditions significantly affect the chip formation mechanism, and therefore, the machining parameters could be selected to promote a chip form that is easily manageable in production.

Jan 1, 2011