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By Helmer Kraemer

One of the CIM 2003 conference themes is ?Globalization and the impact on mine operations?. In this context, the first official version of the new ?International Rock Excavation Data Exchange Standard? (IREDES) is being released. This new standard is a highly flexible data interface for exchange of information between production equipment and central computer systems. The standard was defined by global players in the mining industry and will soon be used to enhance local operations of global mining companies. Beside the standard definition now other aspects are coming into focus: The question how to design and how to implement IREDES compliant data exchange in practice. Implementation of IREDES covers the following aspects: !" Implementation on in-field production systems !" Communication and networking !" Implementation on databases and commercial IT systems In-field production systems are characterized by a big variety of different automation systems. Therefor, different IREDES implementation philosophies have to apply to those systems. One philosophy uses an integrated IREDES compliant automation system on every machine. The alternative method uses one shared IREDES compliant ?Proxy server? for a number of machines connected to this server using proprietary interfaces. Communication and networking can be integrated openly and independently from hardware infrastructures. The only precondition is that communication and networking has to be Ethernet - TCP/IP protocol compatible. IREDES Implementation on the commercial IT level means to exchange IREDES data sets with databases, simulation software, office packages and special applications. Interfacing is easy as long as the software or the database system provides an interface to the Extensible Markup Language (XML).

May 1, 2003

By Stewart W. Daniel

"Increasing labour costs, the trend to larger mills, the processing of lower grade ores and a diminishing sup-ply of well-trained and experienced mill operators contribute to the necessity of automating a grinding circuit. With sophisticated process control techniques, supervision of the mill line is reduced to an occasional inspection by the shift supervisor. Process operating decisions and/or adjustments are quickly and accurately performed by the electronic devices to be described. When the variables in the grinding circuit are stabilized using the sensors and controllers as discussed, the over-all grinding circuit is maintained at its optimum grinding load level, with ample protection against under-and overloading."

Jan 1, 1967

By Adriana Ramirez, Bradford C. Wesstrom, Blanca Olave

The Freeport McMoRan El Paso Copper Refinery optimizes electrolyte quality using a number of systems. The facility controls copper, arsenic, antimony and bismuth using electro-winning cells within the Tank House and Nickel Carbonate Plant Liberator Circuit (NCP). The NCP manages sulfuric acid content utilizing recycled electrolyte in the slimes autoclave as well as operation of the Acid Purification Unit, APU. The El Paso Refinery removes common sulfates using metal hydrolysis with sodium carbonate. Finally, a Mechanical Vapor Recompression, (MVR), at the water recovery plant removes sodium sulfate generated by the NCP. This paper will provide a summary of these operations. INTRODUCTION In the mid 1920’s Nichols Copper Company, in Laurel Hill, New York, recognized the need for a modern copper refining facility in the southwest. Because of the many railroad heads, affordable power and abundant labor supply, and the close proximity to regional copper smelters in Mexico, Arizona, and New Mexico, El Paso became the ideal location. In December 1928, ground was broken for the joint venture refinery between the Nichols Copper Company, Phelps Dodge, and the Calumet and Arizona Mining Company. In September 1930, Nichols Copper Company became a part of Phelps Dodge Corporation after a stock exchange. In July 1938, Nichols Division officially became Phelps Dodge Refining Corporation. In March 2007, Freeport McMoRan Copper & Gold acquired Phelps Dodge. Water is a precious commodity in the desert southwest, making conservation of this natural resource an important goal for the El Paso Operations. In the 1980’s, work on the treatment of slimes was improved through the use of pressure leaching of the refinery slimes using an autoclave. Due to the high tellurium content in the leached slimes solution, it was crucial to implement a method for its removal before the solution returns to the tank house electrolyte. A copper telluride cementation operation was installed for tellurium recovery and the ability for the recycle of the leachate and wash water to the refinery electrolyte. In October of 1997, ground was broken for the construction of the water recovery plant using an MVR to reuse process water, reducing water consumption by 25%. In 2002, electrolyte purification was further improved with the installation of an Acid Purification Unit, (APU) (Sheedy, Pajunen, & Wesstrom, 2007). The APU recycles 90% of the acids (both sulfuric and arsenic acids) back to the tank house electrolyte. The solution that passes through the APU is treated with soda ash to precipitate metals out of solution as carbonates and generates a sodium sulfate solution. This sodium sulfate solution is easily processed in the new water recovery plant, where the majority of the water recycles back into the plant as pure condensate. In 2012, the power plant at the refinery upgraded its Reverse Osmosis System to provide RO water to the tankhouse. This insured that the refinery would not have to bleed electrolyte for metals contained in well water such as: calcium, magnesium, iron and sodium chloride.

Jan 1, 2019

By Esteban M. Domic

"T.L. Leaching ProcessCommercial PerformanceSociedad Minera Pudahuel Ltda. (SMP) has been innovating in the copper producing field with the commercial application of the Thin Layer (T .L.) leaching process in its two operating division s: Lo Aguirre and La Cascada. Since November 1980, SMP' s Lo Aguirre Division has been producing high-purity copper cathodes at a nominal rate of about 16,500 metric tonnes / year, by mean s of the new route of T.L. leaching, followed by solvent extraction and electrowinning (TLlSX/EW). This has been the first commercial application on T .L. technology in the world, and the only commercial application in Chile for solvent extraction and electrowinning.By mid -1980, SMP acquired Sagasca Mining Co., renaming it as La Cascad a Division. The existing vat leaching facilities were modified to apply T.L. in the same old vats. The existing scrap iron cementation recovery circuit was kept running for the continuing production of copper precipitates. The modifications in the leaching circuit allowed shorter treatment cycles with a lower acid consumption and consequently, copper product ion increased from a previous historical high of 12,000-13,000 metric tonnes /year to a new level of about 22,000 metric tonnes/ year . These changes have been in operation since March 1981.T.L. Leaching commercial performance, both at Lo Aguirre (TL / SX /EW) and at La Cascada (TL/cementation), has been presented in several recent publications. Real operating parameters and process requirement s were reviewed in detail. A breakdown for TL / SX/ EW economics was also published based on Lo Aguirre' s performance during 1982(41."

Jan 1, 1986

By R. Scheepers

"Mineral deposits and prospects of the Pan African Saldanian orogenic belt in the southwestern Cape Province South Africa, are reviewed. Despite the entire absence of operating base or precious metal mines in the area, this study has established at least four metal associations that offer enticing exploration potential.The poly-phase deformed, low-grade metamorphosed volcano-sedimentary Malmesbury Group constitutes a complex, poorly understood supracrustal sequence that has been loosely subdivided into the Tygerberg, Swartland and Boland tectono-stratigraphic terranes by northwesterly trending fault zones. Syn- and post-tectonic granitoids of the Cape Granite Suite selectively intruded these terranes. Early S-types preferred the Tygerberg terrane whereas the later I-types dominate the remaining areas. Anorogenic A-type granites, however, occur in all three domains. Known metallization is directly or indirectly related to the intrusives, yet syngenetic deposits are conspicuously absent from the supracrustals. Four metal associations have been identified.• Cassiterite-wolframite (± Au, Cu, Mo, Fe-sulfides) in quartz and quartz/aplite veins hosted by tourmalinized and locally greissenized S-type granite. Similar exo-granitic veins occur in proximal metamorphites.• Juxtaposed disseminated, stockwork, breccia and vein style Cu-Mo-Fe-(Au)-sulfide mineralization hosted by mafic to intermediate intrusives of high K calc-alkaline, I-type affinity. • Cu-Mo-Au-sulfides hosted by hydraulic breccia pipes, stocks and veins occurring in anorogenic A-type alkali feldspar granites and amphibole quartz syenites.• Scheelite with minor Cu-Mo-sulfides and Au-associated with endo- and exo-skarns spatially related to I-type monzogranite, granite and alkali feldspar granite.The first three associations occur along the Yzerfontein-Helderberg-Zone, a 180 km lineament in the Tygerberg terrane, a zone exploited by syn-, late- and post-tectonic intrusives and their related mineralization. The fourth association is typical of the Boland terrane. The spatial and temporal relationships between the various metal associations is interpreted as the result of sequential intrusion of relative early high level S-type, followed by intermediate level I-type and finally anorogenic A-type granitoids during the evolution of a contracting continental margin arc and its irmer arc. This plate tectonic setting suggests subduction in an easterly direction underneath the Kalahari craton. The spatial configuration of the various terranes at the present erosional levels is the result of rifting and significant differential vertical displacement following cessation of subduction, a terminal tectonic event possibly synchronous with intrusion of the A-type granitoids.Near surface preserved roof zones and cupolas of both S- and I-type granitoids in the Tygerberg and Boland terranes, respectively, render these areas extremely prospective for Sn, W, Mo and Au mineralization. The presence of intermediate to mafic volcanics, a diversity of calcareous lithotypes and favorable plate tectonic setting of the Malmesbury Group suggest potential for the thus far elusive VMS, MVT and Sedex base metal and minor precious metal deposits."

Jan 1, 1994

By Hans D. Gougar

To meet an increasing demand for minerals, mining operations are moving to ever more remote regions. The lack of a local energy supply and infrastructure, coupled with social and regulatory demands for lowered environmental impact of mining operations, presents an opportunity for a seemingly unlikely competitor ? a nuclear power plant. The Modular Pebble Bed Reactor concept, currently in various stages of research and development around the world, offers a high degree of reliability and safety with minimal consequences for the local or global environment. The passive safety features of this design eliminate the need for the extensive active safety systems that add significantly to the cost of current water-cooled reactors. With the MPBR, as with all nuclear plants, there are no appreciable quantities of waste products released to the environment during normal operations. In contrast with conventional reactor designs, the MPBR would also remain radiologically safe even under the most severe abnormal circumstances. The key to the design is the fuel element. Enriched uranium microspheres are coated with various layers of pyrolytic carbons and silicon carbide to form a highly-temperature resistant particle that effectively retains all fission products. These particles are mixed with graphite and formed into 6 cm pebbles. A randomly packed vessel of such pebbles forms the reactor core through which helium is circulated as a coolant. Computer models and tests performed on actual pebble bed reactors confirm that fuel failure temperatures are not reached even during the most severe conceivable loss of coolant accident. The reactor drives a gas turbine cycle with resulting efficiencies as high as 48%, comparable to natural gas-fired units. The low price of uranium fuel and low maintenance requirements translates into competitive operating costs. However, high capital costs prevent the MPBR from competing with natural gas in most markets. In remote applications where no fossil supplies are readily available, the playing field is more level. This paper summarizes the features of two of the more promising candidates for remote applications and discusses the strengths of the MPBR from the perspectives of fuel supply and environmental impact.

May 1, 2002

By Chris Yellowega

The construction and startup of a new mine is a daunting task. To successfully locate, design, build and startup an immense human endeavour like a new mine, takes perseverance, planning, dedication and significant capital. The application of capital requires a thorough evaluation of risk and where that risk is most properly limited to create the risk/return profile. One area of significant capital and thus, significant risk is the selection and maintenance of the very machinery needed to deliver the creation of investor wealth. Albian Sands Energy is the operator of the new Muskeg River Mine located north of Fort McMurray in Alberta?s oilsands. The Muskeg River Mine is owned by a joint venture of three companies: Shell Canada, Chevron Canada Ltd.and Western Oil Sands. The mine is designed to run 400,000 tons per day, 365 days per year. The mine conditions vary from material as hard and of similar consistency to pavement to underfoot conditions as soft as saturated sands. Water cannot be drained below surface conditions, shovel teeth can disappear in less than 24 hours and the primary business is often constructing large civil structures that have little to do with the delivery of ore. The mine starts with the deposit (if it doesn?t exist, nothing else matters), moves into the design, the feasibility study and the approval. The evaluation of risk and the strategies surrounding the control of that risk truly lie after these stages are complete. The strategy and execution stage is where risk is eliminated or accommodated. The point at which the investors money is being spent is the point at which the decisions made cannot be reversed. It is of absolute importance that the execution of the decisions are consistent with the strategy agreed to, lest the investors need to be asked for more money. The key sources of risk identified for the Muskeg River Mine were recruitment of trained and experienced personnel and the delivery of ore to maximize early (<2yr) cash flow. The Muskeg River Mine personnel determined that to minimize risk, personnel would be recruited to operate the mine equipment yet, the requirements for maintaining the equipment would best be held by the manufacturer. The strategy was to obtain the correct equipment for the operation of the mine and leverage the supplier?s expertise to ensure the mine wasn?t training a maintenance organization at the same time as a mining organization. In essence the key strategy for the mine start up and early operation was to leverage the equipment suppliers to maintain and repair the equipment. Albian Sands would maximize the utilization of Maintain And Repair Contract?s.

May 1, 2003

By Mark Sherman

One of the main functions of a process technology and engineering services provider is to select grinding equipment that will meet the client?s throughput rate target. Prudent risk mitigation strategies would suggest that throughput rate estimates be cross-checked using a variety of techniques. Whilst some comminution circuit designers have estimated specific energy requirements via the manipulation of the Bond specific power equation e.g. Barratt?s Grindpower and OMC?s FSAG approach, other designers have opined that the Bond Indices have no role to play in the calculation of SAG mill specific power. As a result, they have developed their own specific energy estimating methodologies, e.g. SMCC?s Drop Weight based power methodology, SPI, SAGDesign, etc. Each method has its supporters and its critics. The challenge facing the engineering provider is how to nominate an SAG mill based circuit throughput rate estimate when faced with significantly disparate specific energies calculated by the different methodologies. This challenge is exacerbated via the continuing evolution of contemporary circuit configurations such as two stage pebble crushing some of which incorporate HPGR technology as the second stage of pebble crushing. The methodology presented in this paper shows that the Bond Indices are an excellent tool for estimating the specific energy requirements for SAG mills in SAB, SABC and SSS circuits. The method accommodates primary crushed feeds, partial and or fully secondary crushed SAG mill feeds, and emulates the impact of pebble crushing on SAG specific energy. As a result, the new Bond Index based method has provided an additional tool for increasing Fluor?s confidence when predicting SAG mill based circuit throughput rates. Based on this outcome, the author proposes that the decades old conundrum of using Bond Indices to calculate SAG specific energies for SAG mill based circuits has been solved.

Jan 1, 2012

By Douglas Brand

"The data that many mineral processing plants make use of, is provided by samples taken from sampling systems which are inadequately designed or improperly maintained, and therefore cause detrimental effects to plant operations, production planning and metallurgical accounting! Poorly designed or maintained sampling systems will likely produce low probability samples which give the operator a false sense of security of the product and the process. If data is the basis for action (Flintoff, 1992, p.2), then using the resulting suspect or bad assays by operators, control systems, or metallurgist and administration personnel will act and make decisions which may adversely affect the profitability of a processing plant. Here we will discuss some of the fundamental sampling problems, propagation of errors and a method to estimate what impact this has on an operations Net Smelter Return.INTRODUCTIONIn order to control a mineral processing plant at its best potential, it is necessary to obtain the best possible measurement results of the metal or mineral in question. The sample which is delivered to a measuring instrument, or lab, needs to be of the highest probability to be able to achieve this. This paper will discuss the effects of sampling errors on grade / recovery and grade / Net Smelter Return (NSR) and provide a method to estimate the monetary advantages of using probabilistic sampling in a processing plant.REVIEW OF SAMPLINGSampling, by definition, is the removal of a small representative portion from a total consignment, or flow, for the purpose of accounting or process control.• A sample can only be considered representative, if each and every increment collected, in each of the sampling stages, is representative.• Each particle of the sampling lot must have the same probability of being included in the final sample.• If both of the above conditions are met, then the final sample will be representative of the complete sampling lot.It is commonly known that in order to take truly representative and probabilistic sample, best practices indicate that:• The total stream should be sampled.• The sample cutter should intersect the sample at right angles to the flow.• The sample cutter should travel through the stream at a linear and constant speed and the speed deviations should be less than 5%."

Jan 1, 2016

By K. Thuro, H. Käsling, C. Wieser, G. Nuijten

"The time-dependent behavior of brittle rocks during stress relaxation is of great interest for mining industry, nuclear waste disposal as well as tunneling and underground construction. Several studies have shown that both elastic as well as inelastic deformation occur during stress relaxation (Emery, 1964; Zang & Berckhemer, 1989). While elastic strain occurs already during the drilling process, inelastic deformation is time-dependent and can endure for hours, days or weeks. To investigate the evolution of microcracks during core relaxation, two crystalline core samples were recovered from high in situ stress conditions in Europe’s deepest mine in Pyhäsalmi (Finland). Samples were prepared for testing within one hour after coring such that a large portion of the time-dependent component of relaxation could be recorded over several days using ultrasonic velocity as well as acoustic emission (AE) measurements.Results from AE analysis show an exponential decrease in the number of events over a period of several hours. Repeated sudden increases of acoustic events can be related to the propagation or the interaction of cracks. In the first hours of recording also the signal energies reached the highest values and the increases in signal energy correlate well with increased event rates. On additional drill cores, P-wave velocities were measured parallel and in 45° distances perpendicular to the core axis. After core recovery, stress-induced microcracking caused an exponential decrease in wave velocities similar to AE rates. Lowest compressional wave velocities were measured parallel to the core axis and thus normal to the foliation and in the direction of the maximum in situ stress component. The highest measured velocities occurred parallel to the foliation plane. Within the samples, the anisotropy ratios were up to 1.37 at the beginning of the measurements and increased to values of up to 1.8 after 45 days. The wave velocity anisotropy is in agreement with the in situ stress orientations."

Jan 1, 2015

By J. A. Brusset

Introduction The West Canadian Collieries, Limited, operate three bituminous coal mines in the Crowsnest Pass district of Alberta. Two seams are worked; their thickness varies from 10 to 20 feet and their pitch from 10 to 45 degrees. The Bellevue mine was opened in 1903, the Greenhill in 1914; both are gassy and dusty, and at both the haulage is a problem, as the workings are spread over distances of several miles. Compressed-air locomotives are used at Bellevue, rope-haulage at Greenhill, both of which solutions of the haulage problem are costly in installation an operation, and lack flexibility. In 1943, the Adanac mine was opened; and the question soon arose as to which system of haulage should be selected. Compressed-air locomotives and ropes were rejected on the ground of high cost. Since, under the Alberta Mines Act, the use of trolley locomotives underground in coal-seams is not permitted, the choice lay between storage battery locomotives and Diesel locomotives. The preference of the author, who had had experience with both in French gassy coal mines prior to 1930, was for Diesel locomotives, due to lower cost of installation and greater flexibility and reliability. However, Regulation No. 13 of the Mines Act of Alberta reads: &apos;No gasoline-driven engines shall be used underground in any mine, and no internal combustion engine shall be used underground in any coal mine, except only when authorized by the Chief Inspector in writing, and on such terms as he may prescribe"

Jan 1, 1948

By K. D. A. Whaley

Abstract -The Captain North Extension deposit consists of five sulfide lenses hosted in cherty and chloritic metasediment that is bounded by quartz-eye rhyolite and laminated rhyolite . Lens 2 consists of sphalerite and galena with silver-rich tetrahedrite in chert. Lens 3 contains massive pyrite, with chalcopyrite and minor gold, gradational to minor pyrite in a chloritic metasediment . The other lenses are unexplored. The sulfides occur as beds, fracture infills, and disseminated grains. Reserves are estimated at 207 555 tonnes grading 7.38% Zn, 2.76% Pb, and 91.81 g/t Ag. The deposit is isoclinally folded, dips steeply west, plunges 50 degrees south, and is faulted out to the north, where drag folding has reversed the plunge. Minor cross-faults contain talc and sericite. High sphalerite but low pyrite abundances result in poor responses to standard electromagnetic techniques. Lens 3, which contains more pyrite than Lens 2, responds better to induced polarization and allows detection. Geochemical anomalies are found in a nearby swamp and stream, but an impervious till cover inhibits the development of soil anomalies.

Jan 1, 1992

By Victor F. Hollister

Although none of the deposits discovered to date are of commercial interest, significant Frasch or sedimentary sulphur deposits occur in Nova Scotia in Upper Mississippian Windsor Group evaporites. The evaporite sequence contains anyhdrite and is overlain by impervious shales. It also is •mderlain by locally petrolijerous formations that are potential hydrocarbon sources for reaction with anhydrite to produce sulphur. As well, stratigraphic and structural traps are known to exist in the Mississippian beds. Thus, all requisites for sedimentary sulphur genesis are present. Available hydrocarbon sources are numerous but small; resultant sulphur deposits therefore are probably also small. Evidence suggests, however, that sulphur deposition is not yet complete.

Jan 1, 1984

By Kenneth L. Graham

Horizontal directional drilling from existing underground workings will greatly reduce, if not replace, surface exploration drilling. Diminishing ore reserves along with increasing difficulty in acquiring access and permitting of drilling surface holes requires a change in procedure. The length and direction of the required long holes is site specific, but once determined could be quickly mobilized. Data would be available for a much more timely evaluation without any surface disturbance and required reclamation issues. Preplanned directional drilling from underground will also provide an evaluation of already inconsistent uranium deposits located under surface terrain that is inaccessible to surface drilling.

Aug 1, 2010

By J. Drozdiak

In this paper we present the results of preliminary investigations into the applicability of new laboratory scale tests for the prediction of operating gap and specific throughput in high pressure grinding rolls (HPGR). The work is a part of the CAMIRO HPGR research program being conducted at the University of British Columbia, which aims to develop a suite of small-scale tests and procedures for the selection and sizing of HPGRs. A focus of the presented study is to test sample types in terms of their terra-mechanics based characteristics and relate them to specific throughput and gap results from pilot HPGR testing on the same samples.

Jan 1, 2012

By M. Feinendegen, Ph. Siebert, C. Clauser, K. Willbrand, M. Ziegler

"Three institutes of RWTH Aachen University collaborate on laboratory tests and numerical simulations of hydraulically driven fractures in igneous rocks. The project´s target is to enhance the understanding of hydraulic induced fractures for deep geothermal energy exploration. Based on the idea of creating new discrete fractures in hot dry rock (HDR) reservoirs, the current project stage deals with this process on a laboratory scale. Especially for this purpose, a new testing facility has been developed and laboratory tests are performed to verify a hydraulic fracture propagation code based on the extended finite element method (XFEM). The testing facility enables us to initiate and propagate fractures in large samples of dense rock under triaxial confining pressures and to monitor the fracture propagation by extensive measurements. This contribution gives a short introduction to the project‘s background and mainly focusses on the test facility, the experimental procedure and exemplary results.INTRODUCTIONThe most efficient technique to increase the permeability of subsurface rock is to initiate and open fractures by applying hydraulic pressure from a packed borehole-section and to inject fluid into these fractures to propagate them. Since its first use in petro industries to enhance the production of wells in natural gas and oil reservoirs, the interest in targeted creation of hydraulic fractures has increased exponentially. As the key technology to the extraction of unconventional gas from shale, hydraulic fracturing (HF) became a major topic in a heated public debate. Based on the fact that a fracture tends to propagate in a direction perpendicular to the minimal principal stress, hydraulic fracturing has become an established tool for estimating geological stress states in almost any depth. Enhanced geothermal systems (EGS) in HDR reservoirs use engineered fractures as a heat exchanging system for a cycling fluid driving a power plant."

Jan 1, 2015

By R. Tipman

"In 25 years, processing of tar sand progressed from two small pilot plants to two major commercial operations owned by Syncrude and Suncor. These plants mine tar sand and extract the bitumen which is then converted into a synthetic crude oil. Considerable research on extraction of bitumen from tar sand has been undertaken by these two companies as well as other major oil producing companies, private individuals, universities and the federal and provincial governments. These studies have produced a number of alternate processing schemes which have yet to be commercialized. The producing companies are focusing their efforts on achieving increased processing efficiency, which includes improved bitumen recovery, reduced unit cost, energy conservation, and equipment reliability. In this review, the Syncrude process and examples of new process developments will be briefly described. IntroductionTwenty-five years ago, tar sand processing was limited to two pilot plants owned by Cities Service Athabasca Ltd., and Great Canadian Oil Sands. Earnest Manning was Premier of Alberta and was inviting proposals for the construction of a commercial tar sands plant. The invitations called for a much larger operation than those which had been undertaken in the past. All of the previous attempts at commercial operations up to 1960's had failed, largely because of a poor technical understanding of the process requirements, lack of suitable equipment, and lack of adequate capital. The previous record was not good. The pending new large scale plant was based on improved but not proven technology and equipment, which were developed from the pilot plant studies. In addition, the surplus of conventional oil in Alberta and low world oil prices were factors reducing the need for such a plant."

Jan 1, 1987

By M. E. Coleman, G. Money

Pneumatic Conveying and Process Injection Technologies have been implemented in the metals markets for the last 40 years and have considerably improved the productivity and the performance of many processes. There have been many steps forward in handling technology and this paper seeks to consider those now offered by Clyde Materials Handling who as an established customer-driven solutions provider has turned its attention to supporting the Metals Market. Clyde seeks to utilise its knowledge, expertise and technologies to transform the production processes of its customers, who operate in the ferrous and non-ferrous metals industries.

Jan 1, 2008

By C. Ayora

The Iberian Pyrite Belt (SW Spain and Portugal) contains one of the largest reserves of pyrite in the world with mining activities dating back to prehistoric times. About one hundred abandoned mine wastes and galleries release a huge acidity and metal load to the Tinto and Odiel rivers. Once the mining activity is over, polluting discharges can persists for decades or even centuries with no specific responsible entity. In-situ passive remediation technologies are especially suitable for these orphan sites. The concept is to insert a reactive porous material in the natural flow path of contaminated surface and ground waters, and it is implemented through infiltration ponds and reactive barriers, respectively. Calcium carbonate pea-size gravel is the common alkalinity supplier to neutralize acidity and precipitate metals. These remediation systems have been traditionally implemented in coal mines. However, the acid drainages from the Iberian Pyrite Belt contain metal concentrations one to two orders of magnitude higher than those from coal mines and require special designs to avoid quick clogging or passivation (coating) of the grains of reactive material. To overcome these problems, a Dispersed Alkaline Substrate (DAS) mixed from fine-grained limestone sand and a coarse inert matrix (e.g. wood chips) was developed. The small grains provide a large reactive surface and dissolve almost completely before the growing layer of precipitates passivates the substrate. The high porosity and the dispersion of nuclei for precipitation on the inert surfaces retard clogging. However, limestone dissolution only raises pH to values around 6.5, which is sufficient to precipitate the hydroxides of trivalent metals (Al, Fe), but it is not alkaline enough to remove divalent metals. Magnesium oxide, which hydrates to Mg hydroxide upon contact with water, buffers the solution pH between 8.5 and 10. A DAS system replacing limestone with caustic magnesium oxide has been tested to be very efficient to remove divalent metals (Zn, Cd, Mn, Cu, Co, Ni, Pb) from drainage previously treated with limestone.

Aug 1, 2013

By B. Farabi Khoshmehr

In the present study the effect of Silicate Sodium oxidation agent concentration and Plasma Electrolytic Oxidation (PEO) treatment time were investigated on properties of oxide layer on Aluminum alloy. The phase composition and surface morphology of PEO films were evaluated through x-ray diffraction (XRD) and scanning electron microscopy (SEM). Pin on Plate abrasive machine were used to investigate of were resistance of coating. The results showed that oxide layer which formed on Aluminum surface consist of high temperature a- Al?O? and ?- Al?O? phases. The diffraction peak intensity and percentage of these phases were increased by increasing silicate sodium concentration. Microscopic studies revealed a porous surface for PEO coating. This was affected by silicate sodium concentration and oxidation time. The wear test results showed that the weight loss of PEO coating was reduced due to improvement of their wear resistance.

Oct 1, 2011