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By T. Hadley, Northern Minerals Ltd, C. S. Griffith, T. A. Safinski, K. H. Soldenhoff, M. Fainerman-Melnikova, A. Manis

"ANSTO Minerals and Northern Minerals have been working together since 2012 on the process flowsheet development for the Browns Range project for the recovery of the heavy rare earths (Dy – Lu, + Y). Initial efforts were directed toward defining the most efficient and direct flowsheet for the Preliminary Feasibility Study (PFS), issued in June 2014, then towards the Definitive Feasibility Study (DFS), issued in February 2015. These goals were achieved by undertaking comprehensive laboratory and continuous piloting programs. Further improvements to the flowsheet following the DFS have been made. This publication provides an overview of the evolution of the process flowsheet based on these laboratory and piloting programs from the PFS through the DFS and beyond.INTRODUCTIONNorthern Minerals Ltd (Northern) has been working on developing their flagship project at Browns Range for the recovery of the heavy rare earth elements (HRE, Dy – Lu, + Y). The project is located in the north of Western Australia as shown in Figure 1. The Total Mineral Resource at the project is currently estimated at 8.98 Mt @ 0.63% total rare earth oxides (TREO) comprising 56,663 t of contained TREO using a cut-off grade of 0.15% TREO. Of the Total Mineral Resource, 58% is classified as Indicated Resource, with the remainder in the Inferred Resource category.The deposit is characterised by breccia-hosted, hydrothermal, HRE-rich, xenotime mineralisation. The main gangue mineral associated with the xenotime is quartz. The distribution of rare earths (RE) observed for the xenotime mineralisation at Browns Range is presented in Figure 2. Extensive test work has shown that the xenotime can be readily beneficiated to between 20 – 40% rare earth oxide (REO) using a process consisting of crushing and grinding, followed by magnetic separation and flotation steps. Continuous piloting of this process was conducted on ~80 t of trench-sourced ore in late 2013 at SGS Perth, to produce ~2 t of ~20% REO mineral concentrate (MC) for hydrometallurgical testing. The composition of the MC produced during piloting is presented in Table 1."

Jan 1, 2016

The original JKMRC AG/SAG mill model was developed over 30 years ago and has been upgraded a number of times since then, with the current published version being the Variable Rates model that is now over 15 years old. Since this model was developed further enhancements have been derived, some of which are applied in-house and some which have yet to be incorporated. The published and the commercially available model in JKSimMet is currently undergoing a comprehensive overhaul with a vastly extended data base for model evolution and validation. Improvements developed within the AMIRA P9 project, in-house development and a number of collaborative projects, are being incorporated into the upgraded model structure. Enhanced capabilities will include: power-based breakage rates scaling; a far wider mill filling range (from 10% to 40%) that exhibits peak in throughput as mill filling increases; higher ball loads; improved pebble discharge function; improved slurry discharge function incorporating important mill design and operational influences; and the new size dependent breakage function. The model will also be able to accommodate some influence of liner design and multi-component ores (blends of hard and soft components). This upgrade is still a work in progress but substantial changes have been made to date. This paper presents some of the new improvements and their influence on the predictive capability of the model.

Jan 1, 2012

By C. D. Kaeding

IN the summer of 1937, the Algoma Steel Corporation, Limited, decided to embark on the full-scale development o their Helen mine and the erection of plants to produce commercial iron sinter from its ores at a rate ? of fifteen hundred tons per day. The Helen deposit has long been known as one of the largest bodies of non-commercial iron ore in Canada, consisting almost entirely of siderite with a band of pyrite along the north wall and some lenticular inclusions of pyrite throughout the mass. It originally contained a nominal amount of hematite (2,800,000 tons), localized at the western end of the ore-body, but this was mined out during the years 1900 to 1918. For details of the:-geology of the Helen range and of the surrounding district, the reader is referred to Memoir 147, Michipicoten Iron Ranges, Geological Survey of Canada, 1926 (1). The siderite mass was explored by diamond drilling in 1917 and the portion so drilled was estimated to contain 67 million tons of siderite averaging 36.0 per cent Fe, 3.2 per cent S, and 8.2 per cent SiO,, without establishing its ultimate depth or extent. The variation in the sulphur content shown by drilling was from 1.5 per cent in 72 per cent of the tonnage, to 7.2 percent in the remaining 28 percent. The pyritic ore aver-aged about 38 percent iron, but otherwise its composition was substantially the same as that of the siderite mass.

Jan 1, 1940

By J. Lee, K. B. Min, J. Rutqvist

Shear slip of fractures in fractured rock masses is a critical issue for many geological engineering applications, such as the design of underground nuclear waste repositories, enhanced geothermal systems (EGS), and geosequestration of CO2. This paper presents new development of the TOUGH-UDEC simulator for analysis of coupled thermal-hydraulic-mechanical (THM) processes in fractured porous media. As an alternative to developing a single coupled THM code in discontinuum, two existing wellestablished codes, namely TOUGH2 and UDEC, are coupled to cover coupled THM analysis of multiphase fluid flow, heat transfer, and deformation in fractured porous media. TOUGH2 is widely used for modeling heat transfer and multiphase, multicomponent fluid flow, and UDEC is a well-known discrete element code for rock mechanics, which have been verified and used by many groups all over the world. Although a sequential coupling of two codes is less efficient than having a single code in principal, a big advantage with coupling of TOUGH2 and UDEC is that both codes are well tested and widely applied in their respective fields. When linking two codes, the coupled equations cannot be solved simultaneously; they should be solved sequentially, with coupling parameters passed to each equation at specific intervals. After solving thermal-hydraulic equations through the TOUGH2 model, pressure (P) and temperature (T) information is delivered to UDEC model. Pressure information is directly stored at the center of each UDEC zone and domain, however, temperature information is interpolated from zone-centers to the corners nodes. After solving the mechanical equation through the UDEC model—considering new pressure and temperature—calculated fracture apertures are converted to equivalent permeability and porosity for TOUGH2 flow analysis. The solution was calculated by iteratively following an explicit sequence for numerical efficiency. Verification examples are presented to demonstrate the capabilities of the coupled TOUGH-UDEC simulator.

Jan 1, 2015

By Rufus L. Chaney

A new technology is available to the Ni mining and remediation community to “phytomine” Ni from mineralized or contaminated soils using rare plants which hyperaccumulate Ni to over 1% of shoot dry matter. Research has identified useful plant species, and even bred improved cultivars of Alyssum murale and Alyssum corsicum for commercial phytomining in temperate regions. All agronomic practices (fertilization, soil amendments, planting and harvest methods) needed for economic phytomining were identified to attain high yields and high Ni concentration in the biomass. In tropical regions, other species are available such as Phyllanthus which accumulate over 1% Ni in dry shoots. These species are perennial so they regrow after annual cutting to harvest biomass. Expiration of our patents on the technology opens the opportunity for other organizations which control Ni rich natural soils or contaminated soils requiring remediation to commercialize the technologies. Inexpensive methods to remediate/revitalize Ni contaminated phytotoxic soils using agronomic approaches have also been developed and demonstrated at Port Colborne, Ontario, but adoption is delayed until formal agreements with government are completed. These new simple remediation and profitable phytomining technologies can obtain Ni from soils which contain Ni well below levels considered economic for current mining technologies, and the plants biopurify the Ni so it is easy to recover Ni metal from plant ash by pyrometallurgical or hydrometallurgical technologies. Although increasing pH decreases the solubility of Ni in all soils, raising pH increases Ni accumulation by Alyssum species. Hence usual chemical extraction methods for phytoavailable soil metals such as the DTPA- or NH4-OAc-extraction cannot predict Ni accumulation by Alyssum species.

Jan 1, 2016

By F. H. Samuel, P. Burke, F. Mucciardi, J. Gruzleski, S. A. Musmar

A new thermal analysis technique has been developed and tested. It utilizes the enhancement in heat transfer characteristics associated with a recent advancement in heat pipe technology. Heat is extracted from a liquid sample of a melt taken in-situ within a vessel or furnace. The rate of heat extraction is such as to cause the sample to solidify. The technique was tested in both laboratory scale and industrial scale (Grenville Castings, Perth, Ontario). A 356 Al Alloy, subjected to various melt treatments was used to perform the tests. Classical thermal analysis was also performed simultaneously using a preheated graphite cup and at the same melt conditions. The comparison showed the potential of the new technique over classical thermal analysis. The major advantages of the new method are that it conducts the analysis inside the melt (i.e. a physical sample is not removed from the melt), it consumes less time and the cooling rate can be precisely controlled during the solidification process. Moreover, the resolution of the results is better than that of conventional techniques. Aluminium

Jan 1, 2006

By G. W. Poling, J. R. Hoffert

"A common practice in preventing gravity-fed tailing pipeline from plugging due to sanding is to add lime at relatively high dosage rates. The lime affects the rheology of the slurry ""vehicle"" which transports the coarser particles in a heterogeneous flow-regime. This paper describes a study of the effect of lime on the critical deposition velocities and friction head losses of Highmont Mining Company's mill tailing. Testwork using an extrusion viscometer was related to the surface chemistry changes brought about by the high lime additions. Lime additions which typically increased the tailing pH from 8.4 to 11.5 reduced the critical deposition velocities from approximately 3.2 to 1.7 m/sec.IntroductionCommon practice, at least in base metal concentrators in British Columbia, is to use high lime additions in tailing slurries when the pipeline becomes partially plugged with sands. Some concentrators, such as the Highmont Mining Co. Ltd. plant, add lime on a continuous basis during low tonnage periods and during startup/shutdown transition s. Although such high lime additions often solve temporary plugging problems, the effect of lime on slurry rheology has not been well understood.Slurry pipelines are designed to transport solids in suspension with a minimum of wear and without particle deposition. These two objectives are in opposition because the velocities required to maintain solid suspension can sometimes cause high head losses in the pipeline, as well as wear problems. Thus, the optimum velocity for a long distance slurry pipeline is in the range that provides just enough turbulence to keep coarse particles in suspension."

Jan 1, 1985

By C. Tan, A. Putz, P. Lacombe, R. Kemp, M. Kaya, B. J. Huls, A. R. Laplante

"This paper concentrates on the four recent plant trials/ applications of froth washing. Results showed that improved metallurgical performance can be achieved with wash water. Increased froth cleaning yielded better upgrading, and some cases slightly improved recovery. Froth sampling and salt tracer tests supported the findings of froth washing tests.At Falconbridge, Ni grade increased from l.47% to 2.15% and recovery from 85% to 87%. At Eastmaque, final Au grade increased from 2.3 to 2.7 oz/st at a slightly higher recovery. At Les Mines Selbaie, Cu grade increased from 24.5% to 25.S% and Zn grade from 54.5% to 56.l%. At Zinc Corp. of America, average Zn grade increased from 55% to 56. 8% at the same recovery for a 45-day period. A number of plants in Canada and the United States have evaluated and/or now practicing froth washing. Wash water has now proved itself in some plants over several months of operation.INTRODUCTIONFroth washing in mechanical flotation cells offers a number of metallurgical (i. e. increased grades and/or recoveries) and economical (i.e. decreased transportation and smelting & refining costs) benefits. Fundamental development work in laboratory and pilot scales performed at McGill yielded encouraging results. (Kaya and Laplante, 1988a and 1989a). Since laboratory and pilot flotation performance can differ from full-scale due to differences in hydrodynamics, kinetics, and froth characteristics (e.g. stability, loading etc.), plant trials were essential to prove the viability of this technology."

Jan 1, 1990

By P. L. Lehoux, R. F. Lopes

"Unanticipated low recovery or extraction of gold from heap leachable are can often be attributed 10 phenomena such as non-uniform percolation (channelling) of solution through heaps, excessively slow percolation rates due to densification of ore during stacking on the pads and parasitic or competing reactions of the cyanide solution with undesirable elements or geochemical ""impurities"" in the ore. The nature and causes of these phenomena are discussed in this paper, and it is suggested that geotechnical and geochemical expertise can contribute significantly to a better understanding of the relationship between laboratory results and actual field performance of the leaching process. Recommendations are made for bench-scale metallurgical testing to be complemented by geochemical and geotechnical laboratory evaluations, to ensure more successful heap leach projects. IntroductionHeap leaching is a simple, low-cost method of recovering metals from low grade ores which has now come into widespread application particularly for gold and silver metals in the United States.The heap leach process involves percolating a lixiviant (leaching agent) solution through broken or crushed ore (Chamberlain and Pojar, 1984). In the case of gold a dilute sodium cyanide solution is used and crushed ore is ""heaped"" on specially prepared impervious pads.The potential for use of heaping leaching methods for northwestern Ontario gold deposits was discussed by Beard (1983), who suggested that the use of this extraction technique in Canada should grow significantly for low grade ores as well as for small high grade deposits which cannot justify the installation of a new mill or the use of remote custom milling facilities. Two other potential situations for lise of a heap leaching extraction method are : as a low capital cost cash generator in the opening phase of a larger new project, and as a low cost output augmenter to complement a milling operation."

Jan 1, 1989

By H. J. Glass, J. G. L. Bekkers

"In order to determine the feasibility of a hydraulic ore hoisting installation, the optimal operating conditions were calculated for applying such a system at the Detour Lake Mine of Placer Dome Ltd. Next, a financial analysis was conducted in order to estimate the cost per tonne for hydraulic hoisting of the ore. Subsequently, the cost per tonne was compared with the hoisting costs associated with a new borehole hoist. Installing a hydraulic ore hoist at Detour Lake Mine was found to be feasible with considerably lower costs per tonne of ore. The applied research method appears to be very functional and can be used to do similar research for other mining operations. IntroductionThe principle of hydraulic ore hoisting is well known, yet hardly accepted in hard rock mining. Application of the system would result in a smaller diameter shaft requirement and a flexible, easily expandable system. However, underground ore size reduction might be necessary and practical experience with the system is limited. Following recent innovations in the field of pumping hardware, e.g. new GeHo and Siemag Transplan equipment, hydraulic ore hoisting should be seriously considered for certain mining operations. As a case study, a design was made for the development of the newly found QK-Zone at Placer Dome Ltd.’s Detour Lake Mine. Hydraulic ore hoisting has been compared with conventional skip hoisting by establishing the optimal operating conditions and pumping equipment requirements for similar capacities at a selected mining operation. Generally accepted equations for slurry transport were used to predict the variation of pressure and power requirements as a function of hourly production and pipeline diameter. These data are used to select suitable equipment and estimate cost figures in order to make a financial assessment."

Jan 1, 1998

By Walter Curlook

"With Inco recording record profits over the past year, most people have forgotten the painful years of the last recession/depression when Inco was losing up to a million dollars a day for a short period . While high nickel prices have contributed to the exceptional recent profits, the real achievements stem from the tremendous advances in productivity and cost improvements that make Inco one of the lowest cost nickel producers.Some of the major advances in productivity have occurred in the mines. The establishment of Mining Research Departments in both Thompson and Copper Cliff in 1979/80 provided the stimulus and the opportunity to dedicate personnel to specific research projects, on a full-time basis; and more particularly to concentrate on the efficiency of the total mine system. The Copper Cliff North Mine was brought back into production as a research mine dedicated to the development and testing of new mining methods and equipment. A shop facility known as the ""Murray Shop"" was set up as the centre of innovation for the development and construction of prototype equipment required for new bulk mining methods. While other expenditures were being curtailed , investment in mining research was being increased. An early success was an ""in the hole"" drill that could be broken down into small components to access even the remotest sectors of a mine to convert labour intensive undercut-and-fill mining to "" vertical crater retreat "" , VCR, bulk mining. A new mine manufacturing company-Continuous Mining Systems-was incorporated with the objective of building innovative mining equipment, with strong focus on automated continuous sytems. Continuous Mining Systems has now grown to a $25 million per year business. With these synergistic thrusts, the VCR bulk mining method was implemented in all of the Ontario Division mines, raising the percentage of ore mined by bulk mining techniques from 320/0 in 1981 to over 90% today. Coupled with re-designed job responsibilities, sup- ported by appropriate training, mine productivity more than doubled. It was discovered that VCR mining could be adapted to the narrower Thompson mine ores with identical improvements in productivity. Development of the Thompson Open Pit North had an additional favourable impact on production cost s in Thompson. The timing of the open pit development could not have been better. It permitted Inco to rapidly increase production at high productivity and low cost, in years of record demand and prices."

Jan 1, 1990

By G. Kachaniwsky, M. Bédard

"The Noranda Continuous Smelting Process at the Home smelter was commissioned in March 1973. The ability of the process to handle a wide variety of feed materials and a steady stream of technical innovations in recent decades has served to maintain the Home as an efficient and versatile custom smelter. This paper reviews recent technological development and capabilities in areas such as sampling and preparation of secondary and complex materials, as well as the smelting and related environmental control issues. Future trends and improvements are also addressed.IntroductionThe Noranda Home smelter commenced operations in 1927. It was originally designed to treat 910 tonnes per day of copper concentrates and ores coming from the new Home mine site. In the 19305, the company opened its doors to other mines in northwestern Quebec. Treatment of feed materials on a custom basis has, therefore, always been an important factor in the operation of the Home smelter. Throughout the years, the Home gradually increased its custom smelting capacity, while maintaining its production from the Home mine. By the early 1950s, 65% of the materials processed was from outside customers, and by 1974, this figure had increased to more than 85% . With the closure of the Home mine in 1976, the company extended its smelting operations beyond ore and concentrate, and began to treat more scrap metals and residues rich in copper and precious metal content.Corresponding with the ever-changing pattern of feed sources, the Home smelter has adopted technological improvements to meet new and challenging business conditions. The technology of the original smelter of 1927has been completely replaced over the years in the quest for improvement. One of these major changes occurred in 1973 with the start-up of the Noranda Process Reactor. This extremely efficient smelting system has been exploited to treat a wide variety of copper and precious metal (PM) containing custom materials. This paper reviews recent developments and improvements achieved at the Home smelter, in the receiving, sampling and treatments of copper and PM scrap and secondaries, with particular emphasis on the development of new technology and equipment in complex feed materials treatment."

Jan 1, 1991

By M. Carvalho

The primary motivation underlying the proposal of polygeneration systems for mine sites is to increase the efficient use of natural resources by combining different technologies and energy resources while satisfying energy service demands. For many mineral producers, particularly in Canada?s mining extremes of climate and depth, energy in support of mineral production can be the second largest cost centre after labour. A generic methodology is proposed for the design of energy supply systems in mine sites, based on a search for the minimum discounted cost of energy supplied for all feasible different plant configurations. These configurations can be represented within a connectivity matrix which corresponds to a network representation. A Mixed Integer Programming formulation is set out for the multiperiod synthesis and operational planning problem. This is characterized by i) binary variables for the selection of technologies, ii) integer variables for the determination of the number of units installed, and iii) by continuous variables for the representation of energy and economic flows. Through the integration of particular energy supply strategies matching specific mine circumstances (on-grid, remote, degree days, etc) and consideration of technologies that improve energy efficiency, hitherto not considered new technologies and demand management systems or new perspectives on optimal mine site energy supply can be investigated. Some of these investigations identify the economic conditions through which biomass energy feedstocks should be used, for direct heat production, for gasification and providing for Fischer-Tropsch syndiesel manufacture. As well as integrating demand from mobile diesel-fuelled plant into an optimization procedure that hitherto has only been considered for static energy production and consumption plant, this analysis shows how the techniques can be used to explore economic conditions of threshold prices for biomass (purpose-grown biomass and peat are considered herein) and trucked-in diesel. The methodology also allows for electricity and syngas storage and diesel and biomass bunkering. Within the paper the energy demands for a remote, open pit mining operation located in Northern Ontario are considered as a case study to illustrate the technique and investigations. As expected, for mines close to electricity, natural gas, and diesel distribution infrastructures, the optimal choice is to connect. When a constraint is applied specifying that connection is not possible, as would be for the case exemplified, the optimal choice includes some of the more exotic options for mine site energy supply.

Aug 1, 2013

By Fidelis T. Suorineni

HydraboltTM is a Swellex-type dowel support element developed and manufactured by New Concept Mining in South Africa. Like Swellex, the HydraboltTM is a folded tube which can be inserted into a larger diameter hole without pushing. It is then activated by injection of high pressure water which inflates the folded tube to intimate contact with the walls of the borehole at a set pressure, normally 25 MPa. Unlike Swellex however, the set water pressure at the end of the inflation is maintained throughout the life of the dowel. An integral non-return valve makes this possible. The HydraboltTM is being investigated as a possible stress change measuring cell. This paper presents the results of closed form solutions, numerical modeling and laboratory test to date. Preliminary results indicate that the HydraboltTM can be used as a stress change monitoring cell in addition to its conventional role as a rock mass reinforcing element. If successful, the HydraboltTM will supplement microseismic monitoring systems in rockburst-prone ground conditions where they will give quantitative stress change data for both mine design model calibrations and means for proactive safety measures.

Oct 1, 2010

By Shantanu Patel, C. Derek Martin

"The objective of this work is to develop a practical numerical approach for applying the confining pressure to discrete element cylindrical triaxial tests. A layer of membrane particles with very low stiffness and extremely high contact bond strength was created around the lateral boundary of the cylindrical numerical specimen. To prevent the membrane particles from penetrating into the rock specimen on application of confining forces and to provide a smooth boundary surface, the space between the membrane and rock particles was filled using small-diameter packing particles. The results of this method were compared with those of rigid boundary method with confining pressure of 20MPa. The results obtained show that new approach gives both peak strength and post peak response that are in closer agreement with laboratory findings. BACKGROUNDThe discrete element method (DEM) has become the cornerstone for simulating both intact material and discrete fractures for low porosity strong rocks (ISRM Classes R3 to R6). Despite the advances in its application, simulating realistic behaviour of intact rock using the DEM remains a challenge. The bonded particle model was introduced as a potential solution for simulating the complex mineral grains in strong rock and other granular materials (Potyondy and Cundall, 2004; Utili and Nova, 2008; Salot et al., 2009). While some issues were resolved, a remaining challenge is the lack of the bonded particle model to simulate the brittle response commonly observed in strong rocks during the triaxial compressive test. Such behaviour is shown in Fig. 1 for Lac du Bonnet Granite at a confining pressure of 20MPa."

Jan 1, 2015

By Technische Universität Braunschweig, K. Saksl, J. Furste, P. Eschenbacher, F. Brunke, D. Wolter, M. Kohnke, C. Siemers, J. Kiese, M. Schlemminger

"In general, titanium alloys combine outstanding mechanical properties with corrosion resistance and biocompatibility and are, therefore, used in many challenging applications. Nevertheless, for special products, well-tailored properties are required which might not be achievable by a specific design so that new or modified alloys are needed. In this overview paper, alloy development strategies performed at the Institute for Materials of the Technische Universitat Braunschweig are discussed at different examples, namely, (1) oxidation-resistant, microstructural-stabilized and cold-workable alloys for exhaust applications, (2) aluminum- and vanadium-free, medium-strength and cold-workable alloys for implants and osteosynthesis applications and (3) free-machining alloys by the addition of particles with low melting points for non-safety critical light-weight constructions to replace heavier steels, e.g. in automotive applications. A special focus is set on the alloy development techniques and the analyses carried out to achieve well-balanced properties by the optimization of the alloy compositions. INTRODUCTIONTitanium belongs to the allotropic metals and can therefore exist in two different equilibrium lattice modifications. Pure titanium crystallizes at 1668°C in a body centered cubic (bcc) structure called ?- titanium which at 882°C transforms to a hexagonal close packed structure (hcp), the a-titanium. A martensitic ?-to-a-transformation is possible at large cooling rates. This thermally induced hexagonal martensite is called the a'-phase. The transformation temperature named ?-transus-temperature (T ?) can be influenced by alloying elements (Peters & Leyens, 2002).For titanium alloy production typical alloying elements are aluminum (Al) and oxygen (O), both a-stabilizers shifting the ?-transus temperature to higher temperatures, whereas tin (Sn) and zirconium (Zr) only show a limited influence on the ?-transus temperature. The ?-stabilizing elements are subdivided into two groups: Niobium (Nb), molybdenum (Mo) and vanadium (V) stabilize the ?-phase between the melting point and room temperature and are therefore called isomorphous -stabilizers. Elements like copper (Cu), iron (Fe) or silicon (Si) also stabilize the ?-phase to lower temperatures but undergo a eutectoid reaction during cooling. ?-titanium then dissociates to a-titanium and an intermetallic compound. Consequently, these elements are called eutectoid ?-stabilizers (Boyer, Welsh & Collings, 1994)."

Jan 1, 2016

By Pingchao Ke, Zhihong Liu

Fe(III)-As(V) precipitates were synthesized from the Fe(II)-As(V)-SO42--H2O system at 90°C in initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The synthesis were carried out by introducing oxygen gas into the system to oxidize Fe(II) ions into Fe (III) ions, and at the same time, adding aqueous sodium carbonate solution into the system to neutralize the acid released by the hydrolysis reactions, with the purpose of keeping the pH constant at 1.5±0.05. The precipitates obtained were characterized by XRD, chemical composition analysis, SEM, XPS, and Raman spectrum. The results indicated that the particles in the precipitates were in the morphology of irregular aggregation with their sizes in the range of about 1–4 µm. The precipitates consisted of scorodite, ferric arsenate and amorphous hydrated ferric oxide, of which amorphous hydrated ferric oxide formulated as Fe(OH)x(SO42-)y. The characteristic XPS peaks of Fe-AsO43- and Fe-O in the precipitates located at 711.8 and 713.3 eV, separately, and the existence of amorphous hydrated ferric oxide led to two series of shake off lines developed over the end of high binding energy of Fe2p XPS. The precipitates were stable in TCLP tests at pH 4.93 for 60 hours with the arsenic concentrations in the leaching solutions being 0.27 mg/L and 0.59 mg/L for the precipitates prepared in the initial Fe(II)/As(V) molar ratios of 4.0 and 5.0, respectively. The tests for the long-term stability of the precipitates were carried out by leaching them for 40 days at 25°C under various media in the pH range from 9.50 to 10.57, and the results showed that the precipitates synthesized in this study were much more stable than those by previous researchers.

Jan 1, 2017

By P. Keller, T. E. Lister, G. G. Clark, L. A. Diaz

As electronic technology continues to evolve there is a growing need to develop processes which recover valuable material from antiquated technology. This need follows from the environmental challenges associated with the recovery of raw materials and fast growing generation of electronic waste. Although present in small quantities in electronic devices, the availability of raw materials such as rare earths and precious metals becomes critical for the production of high tech electronic devices and the development of green technologies (i.e. wind turbines, electric motors, and solar panels). Therefore, the proper recycling and processing of electronic waste presents an opportunity to stabilize the market of critical materials, providing a proper disposal and treatment of a hazardous waste stream. This paper describes the development and techno-economic assessment of a comprehensive process for the recovery of value and critical materials from electronic waste. This hydrometallurgical scheme aims to selectively recover several value streams (base metals, precious metals, and rare earths) present in electronic waste. The economic feasibility for the recovery of rare earths from electronic waste is mostly driven by the efficient recovery of precious metals, such as Au and Pd (ca. 80 % of the total recoverable value). Rare earth elements contained in magnets (speakers, vibrators, and hard disk storage) can be recovered as a mixture of rare earth oxides which can later be reduced to the production of new magnets.

Jan 1, 2016

By M. Ye. Shulgina, M. L. Bolotin, S. A. Prokopev, Ye. S. Prokopev

Iron ores concentration at Russia’s operations is carried out using conventional flow sheets. They comprise the two-four stage grinding followed by one-two stage magnetic separation. This results in the maximum recovery of magnetite to concentrate and the tailings generation. The final concentrate is generated only during the last stage of magnetic separation. Technologically, this flow sheet layout is not effective at recovering the liberated magnetite grains during grinding to the resulting concentrate. Advanced models of magnetic separators do not allow for the selective separation of the tailings and the portion of the resulting iron ore concentrate. Magnetic product which is the ore mixture of the liberated magnetite grains, high grade and low grade intergrowths is directed to the next grinding stage. In this case, regrinding of the liberated magnetite occurs. In addition, the performance of hydrocyclones during classification in closed grinding circuits is poor. Their classification efficiency does not provide the material separation in accordance with the size. In this case, simultaneous separation in accordance with the density occurs. The quartz particles with the size of 300 mm have similar velocity and trajectory like the particles of magnetite with the size of 60 mm. As a result, light and coarser intergrowths report to the overflow and free heavy magnetite grains report to underflow and return to regrinding (“the density effect”). This resulted in a significant increase of a mill circulating load, the decrease in the feed throughput and higher power consumption. In this connection, the development of iron ore concentrate stage recovery with the focus on gradual liberation of the intergrowths is getting much attention. Gravity concentration technique, particularly, spiral separation is effective at solving the problem of stage recovery not only the dump waste product but also high grade magnetite concentrates at the early concentration stages. This can be attributed to a significant difference in magnetite (4.9-5.2 g/cm3) and host minerals (quartz 2.7 g/cm3) densities, which is the principal during gravity concentration. The test work on concentration of various products samples from current operations (the mills discharges, concentrates from various stages of wet magnetic separation and cyclones underflows) was carried out. Spiral separators SV-500 and ShV-500 manufactured by Spirit LLC were used for the test work. High grade iron ore concentrate (69.05% Fe) was generated during primary wet magnetic separation concentrate concentration using a spiral separator. During the concentration of mills discharges the content of iron in the resulting concentrates and middlings of wet magnetic separation II stage was 64.5% and 64.6%, respectively. The recovery of iron to the concentrates of spiral separation was 33.6-42.0%. The studies presented demonstrate that by using spiral separation for iron-bearing ores concentration, you can separate magnetite liberated grains at the early concentration stages, decrease their regrinding and circulating loads in grinding circuits. This process is able to improve the overall recovery and economics of iron ores concentration process.

Jan 1, 2016

By Rashid Bashir

Shaft sinking through solid rock, which contains little or no water, poses little difficulty. However, when loose, water-bearing strata have to be contended with, water control measures, and pumping facilities are needed. Shaft sinking in Athabasca Basin requires sinking through water bearing sandstone which can be highly fractured. Intersection of local zones of extensive fracturing results in the potential for high water inflows with pressures up to 5 Mpa. Grouting is carried out ahead of each shaft sinking interval as water control strategy. In the grouting method, liquid cement is forced into the water-bearing earth under very high pressure. Shaft sinking performance which can be quantified in terms of rate of advance is highly dependent on the days spent at each interval grouting before sinking can advance to the next interval. This paper presents the shaft sinking experience in Athabasca basin and how some of this is translated into Geoscientific Investigations for Future Shafts. A comparison of Geoscientific data collected from future shafts at McArthur River and Millennium Mines is compared to historical data collected from pilot holes, where shafts have already been sunk. The paper concludes with the strategies for better integration of hydrogeological, geotechnical and geophysical data.

Aug 1, 2010