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By Esau Arinaitwe

The most extensively used methods and approaches for characterizing and selecting frothers for plant application are based on measurements in clean water in the absence of solids and without consideration of physicochemical factors that are known to influence the properties and behavior of practical flotation froths, and hence metallurgical performance. These factors include aquatic chemistry, collectors, modifiers, particle shape and size, and pH. Understanding interactions between these factors and the role and relevance that they play in characterizing frothers and froth zone properties will greatly aid in the frother selection and evaluation process. Such an understanding will also greatly enhance the ability to create frother solutions that are sufficiently robust to plant variability (such as mineralogical, comminution, operational, physical and chemical). This paper reports results of a “systems approach” study designed to probe ways in which physicochemical factors a) influence frothing and bubble size in 2- and 3-phase systems, and b) confound correlation of fundamental measurements with flotation outcome. The concepts and insights gleaned from fundamental frother studies, together with empirical laboratory flotation tests and a thorough understanding of plant needs and challenges were used to develop and implement customized frother formulation at a Cu-Mo flotation plant. Plant metallurgical data and qualitative assessment of froth zone properties showed that a frother formulation developed using the approach described here provided marked improvements in froth characteristics (mineralization, mobility, stability, persistence). These improvements resulted in better circuit control and significant performance advantages, such as improved coarse particle recovery, without detrimental downstream effects. INTRODUCTION Successful recovery of value minerals of sufficient grade via the flotation process requires selective manipulation of the value minerals to render them hydrophobic using collectors and modifiers. The hydrophobized minerals then attach to air bubbles and the mineral-bubble aggregates are selectively transported through the froth zone into the launder. Frothers play a critical role in froth formation and more importantly in achieving and maintaining desirable froth characteristics (for example, stability, mobility, persistence) that are essential in facilitating the selective transport and recovery of value minerals. Fundamentally, frothers contribute to the transient stability of thin liquid films and so aid in reducing bubble coalescence rates in the pulp and froth zones, thus maintaining the small bubbles required for efficient bubble-particle attachment. Invariably, the action of frothers at the liquid/gas interface in the pulp and froth zones impacts bubble stability, water and solids transport to the froth, which in turn impacts froth mobility, froth carrying capacity, and the concentrate grade. Consequently, selection and evaluation of frothers for flotation plants requires careful consideration of the frother type, though the choice is limited to only two main classes of compounds in terms of fundamental chemistry (short chain alcohols and polyglycols). Even with the selection of what is thought to be the best frother for a given application, practical knowledge of the froth zone and experience in controlling its properties is essential for maximizing metallurgical performance.

Jan 1, 2019

By Janne Karonen, Stephen Hughes, Mikael Jåfs, Jan Stål, Hannu Johto

End-of-life electrical and electronic scrap material attracts attention as a good opportunity for new value creation through efficient metal and energy recovery of such materials. On the other hand, the treatment of such wastes becomes important to avoid problems for society and environment. Treatment of such secondary raw materials faces multiple challenges due to their increasing complexity and evolving nature. Processing of these complex scrap materials together with recovery of a wide range of valuable metals with a combination of pyrometallurgy and hydrometallurgy using Outotec technology is discussed in this paper. One key consideration is environmental performance which needs attention when processing such complex secondary E-waste materials. Outotec has successful experience with commercial projects in the countries at the forefront of environmental and operational standards. INTRODUCTION Increasing attention has been drawn to the responsible processing of end of life Waste Electrical and Electronic Equipment (WEEE) as part of metals recycling, especially copper. It has been estimated that the amount of WEEE globally in 2016 was around the level of 46 Mtpa (Balde et al., 2017), representing a major disposal challenge but at the same time huge opportunity for resource recovery. The potential for increasing the recovery is high, because the official recycling rate of WEEE is in 2016 only 20% (Balde et al., 2017) and at the same time the estimated increase of the WEEE amount is between 3 and 5% per annum in the EU (Eurostat, 2019).

Jan 1, 2019

By H. W. Fleming

In 1955, the results of a regional, geological interpretation of the northern portion of New Brunswick were used as a basis for selecting, for intensive exploration, three areas in which structural and stratigraphic conditions were believed to be favourable. Airborne electromagnetic work, in one of these areas, provided the justification for acquiring the Murray group. Even though the initial results were discouraging, this geological interpretation, combined with the fortuitous discovery of cop• per-bearing float, was sufficient reason for carrying out further work using geochemical methods. This work finally resulted in the discovery of the Murray massive-sulphide deposit, after about eighteen months of coordinated exploration on the property. While this deposit is a typical New Brunswick-type base-metal occurrence, extensive leaching has produced a fossil gossan that rendered it an elusive target for exploration techniques of limited penetration Full credit for localizing the target area is given to the geochemical techniques, but geophysical surveys were needed to provide the necessary

Jan 1, 1961

By P. Maltais

Over the last 10 years, Computer Aided Design, Finite Elements Analysis and field testing of prototypes have enabled the cycling industry to grow and to significantly improve its products. However, today's cyclists have become more and more demanding, making these classical design approaches almost obsolete. Devinci understood that problem four years ago and fully revisited its design approach; to offer bicycle frames better suited to real life riding, one must fully know those real life conditions. In partnership with the University de Sherbrooke, Quebec, Canada, Devinci then developed a bicycle enabling them to measure the actual load applied on a bicycle frame in real-time for real riding conditions: the instrumented bike. Today, Devinci uses its instrumented road and mountain bikes, combined with virtual prototyping and laboratory testing capabilities to develop better bicycles, faster.

Jan 1, 2006

By Oakley B. Gwillam

The study of leached outcrops as an aid in determining the character of mineralization beneath the surface is in its infancy. Practically all the work on this subject up to the present has been applied to the 'porphyry' copper deposits of the southwestern United States. Some work has been done also on the zinc-lead solid sulphide deposits of the western United States. The question has been asked, "Can this study be applied, and would it have any practical application, in northern Manitoba?" When one realizes the size of the unprospected territory in this Province and the consequent need for a cheap and rapid method of interpreting the countless outcrops which occur in order to discriminate between valueless iron sulphides and valuable sulphides of the base metals, it is readily seen that the study is of great value if it can be applied with a reasonable degree of surety. Augustus Locke, well known economic geologist of the southwestern United States and a pioneer in the study of leached outcrops of disseminated copper ore, has written much on the subject. Messrs. Blanchard and Boswell in a series of articles have dealt with the leached outcrops derived from lead and zinc sulphides in the western United States. Since this paper is essentially a comparison between the leached outcrops of the southwestern United States and those of northern Manitoba with the purpose of testing the adaptability of the study in this Province, an outline of the criteria used in the southwest will be of value to the reader.

Jan 1, 1930

By Simon Houlding

"The objective of Part J of this paper is to identify the limitations of the traditional modelling methods and to illustrate, by example, the potential for error created by their application to complex deposits and mining situations. Part 2 describes the evolution of new, proven technology which eliminates these deficiencies and provides precise and practical alternatives. These promote the use of realistic geological and mining shapes and eliminate altogether the rectangular approximations of traditional methods.The Case for Precision ModellingIt is not the intent of this paper to promote the benefits of computer modelling per se. It is assumed that these are recognized by the mining industry in general. The concern of Part 1 is to identify, qualify and quantify (where possible) the limitations of the tractitional modelling methods. In many instances these methods continue to be applied to complex geological and mining situations for which they were never intended nor designed. The source and magnitude of the resulting errors, conflicts and inefficiencies are not always obvious, however, they can have far-reaching effects on the efficiency and profitability of mining operations.The conclusions support a rapidly growing demand by industry for practical, precise modelling technology which eliminates the deficiencies and can be applied with confidence to evaluation, design, planning and control of mine production in all situations. Part 2 describes new technology which has evolved in response to these industry pressures and has already been successfully applied to complex mining situations. This new technology can aptly be described as appropriate technology for the 1990s."

Jan 1, 1991

By R. Liu

As Building Information Modeling (BIM) becomes widely adopted by the construction industry, it holds undeveloped possibilities for supporting Facility Management (FM). Some FM information systems on the market claim to address the needs for FM requirement. However, the question of whether the functionalities provided by the current BIM-based FM software companies are those actually required by the FM Professionals still need to be answered. The data is required by FM professionals in the operation and maintenance phases of facilities and type of maintainability problems that frequently occur, which can be solved early in design phase, have not yet been addressed. The aim of this paper is to clarify the frequently occurring maintainability problems and to investigate the potential areas that can use BIM technology to solve the maintenance problems in early the design phase. A survey was conducted to collect perspectives from the industry practitioners for the maintenance problems and their frequency. The survey results indicated that maintainability considerations should be taken into consideration during the facility design phase. The results also address the perceived areas by practitioners that need maintainability consideration in design phase.

Aug 1, 2013

By D H. Sharp

The Quebec Cartier Mining Company produces iron concentrate for twelve months of the year from Port Cartier. This J>Ort is designed to handle ship varying in size from 3,000 to 100,000 d.w.t., requiring 50 feet of water at low tide. The harbour was built on shore for reasons of economy and layout, after considering many more conventional offshore designs. It provides for heavy oil bunkering, tanker off-loading, a heavy lift derrick and freight handling, besides ship loading and mooring. The weather for the previous fifty years was studied to enable wind and wave conditions to be accurately assessed for design purposes, and to determine probable lost time due to adverse weather conditions through-out the year. The first ship to be loaded was 60,000 d.w.t.; the second, 20,000 d.w.t. The latter entered the harbour after dark, under its own power, following a tug through the partly dredged narrow entrance. Large ships use tug assistance. Ships may leave the loading berth with the other berths occupied.

Jan 1, 1963

By H. G. Harper, R. C. Hart

"The Mississagi quartzite is the basal formation of the Quirke Lake trough. As it is traced around the rim, a gradual change in dip is observed, as follows:Northwest corner 50 degrees south.Algom Quirke mine 34 degrees south.Quirke Lake 25 degrees south.Whiskey Lake 22 degrees west.Pecors Lake 25 degrees north.Algom Nordic mine 18 degrees north.Elliot Lake 11 degrees north.Pistol Lake 5-7 degrees west.Thus the apparent synclinal axis is a curving east-west line lying closer to the north limb than to the south. The axis appears to plunge west at about 5 degrees.The Huronian sediments lie on a basement of granites, gabbros, and volcanics. Diamond drill evidence indicates that this basement has a surface of peneplanation, and that the areas of soft basic rock have a smoother topography than the granite. For the most part the orebodies at the Quirke and Nordic mines overlie a basement of soft basic rock.The Mississagi formation is the host rock of the deposits, and its primary structures are suggestive of the conditions under which the conglomerate beds were deposited. Cross-bedding is common, although normal bedding varies from thick to thin to essentially lacking. Grain gradation is not common. Where coarse and fine grains occur together, the coarse tend to be more rounded than the fine. These features are characteristic of shallow-water deposits, laid down above the lower limit of wave action. Therefore, the quartz-pebble conglomerates probably represent ancient water courses, bays, beaches, and bars.The causes governing the creation of the trough can only be conjectured, but there is evidence that both subsidence and compressive stresses played active roles. Drag-folds in argillite beds near Whiskey Lake indicate compressive stress. On the other hand, gentle crumpling in thin-bedded limestones on Quirke Lake is probably due to pre-induration slumping and folding. If strong compression had been widespread within the trough, one would expect drag-folding and shearing of the incompetent beds to be more general. Two large-scale, fold-like structures were mapped by Collins, but their axes do not parallel the trough axis, and they are therefore not related to the major structure."

Jan 1, 1949

By F. L. Thompson

MAN has been using lubricants of one type or another for at least four thousand years, and probably for a much longer period. We have learned from the inner wall of the tomb of Tehuti-Hetep, on which is a decoration illustrating the method of moving a great stone statue, that as early as 1650 B.C. lubricants were used to facilitate the movement of heavy loads. The Egyptians had available nearly every animal oil and fat, as well as at least thirteen vegetable oils, of our time, all used for food products and in the arts. Examination of the deposit on the axle of a chariot from an Egyptian tomb of 1400 B.C. showed it to consist of animal fat, quartz, sand, iron, and compounds of aluminium and lime-indicating a manufactured lime-soap grease made with lime-soap and possibly tallow. This would not be a bad lubricant for the axles of chariots which had to travel over sandy soil in hot weather. As to the method of grease application, it is remarkable that, from the time wheels were first used in the far distant past up to the present day, no one has ever thought it necessary to design a seal to keep the lubricant in and the dirt out. While time certainly marches on, we have today, in waggons throughout the world, exactly the same form of lubrication as was used in the earliest chariots. From the early days of the chariot until shortly before 1800 A.D. (when the steam engine was introduced), the main heavy equipment required for mining purposes, for machines of war, etc., was made of wood. The bearings were rough, but usually they had metal in the lower half. Light machinery was made of bronze, brass, or iron. Large clearances and poor alignment, plus the fact that speeds were much below present-day demands, combined to provide conditions that were quite satisfactorily met by the lubricants available. These were often produced locally by the machine operator. In northern countries, lard oil, prepared from the fat of hogs, was the universal lubricant employed in machine shop, as a belt and leather dressing, and for cutting operations. Sperm oils were used for light machinery, whereas beef and mutton tallow were more generally employed for the largest bearings. For the early steam cylinders, a slug of heated beef tallow was injected wherever the cylinders gruntingly complained of a lack of lubricant. Southern countries, however, resorted to the use of vegetable oils-olive, cocoanut, etc.

Jan 1, 1940

By Jas. E. Thomson

"The Kirkland Lake-Larder Lake gold area is in northeastern Ontario and is a continuation of the ore-bearing belt that extends across northwestern Quebec through the Rouyn, Cadillac, Malartic, and Bourlamaque areas. It is the oldest mining camp along this famous mineral belt. Gold discoveries were first made at Larder Lake and Swastika in 1906, but it was not until 1913 that important developments at Kirkland Lake created a real interest in the country. Total gold production of the camp passed the million dollar a year mark in 1920 and increased in amount yearly until the advent of the second World War when there was a falling off due to labour shortage. The Kirkland-Larder camp ranks as the second largest gold producing area ' in Ontario. To the end of 1944, twenty-two mines in the area had produced bullion valued at $515,631,428 and ten mines had distributed dividends amounting to $205,981,116. The average grade of the ore milled in this period has been $15.17 a ton for the mines in the Kirkland Lake area and $6.49 a ton for the mines at Larder Lake.ROCK FORMATIONS OF THE AREAIn a general way the rocks of the country may be divided into the lithological groups indicated on the accompanying geological sketch map. This map has been compiled largely from recently issued geological sheets of the Geological Branch of the Ontario Department of Minest. Owing to the present difficulty of separating the formations of the Larder Lake country into the twofold age divisions of Keewatin and Timiskaming, the usual custom in the past, a lithological grouping of formations has been adopted. The age terms 'Keewatin and 'Timiskaming' are loosely used in this article to express the often used but not necessarily accurate distinction between the main groups of older strata."

Jan 1, 1954

By V. Songmene, R. Khettabi, J. Masounave, R. D. Njoya

L'augmentation régulière des règlements environnementaux et de la sécurité au travail deviennent de plus en plus strictes. L'usinage fait partie des opérations industrielles qui peuvent causer des problèmes de santé au travail et sur l'environnement. La plupart des particules de poussières produites pendant toutes les opérations d'usinage à sec ou lubrifie causent des nuisances environnementales graves. Le travail propose étudie l’influence des paramètres de coupe, des alliages et des états des matériaux sur la formation des copeaux et sur la génération de poussière lors de l'usinage à sec. Deux modes d'usinage (le fraisage et le perçage) sont abordés. Une loi reliant la ténacité des matériaux aux émissions de poussières est proposée. Les effets des matériaux et de leurs conditions, ainsi que des procédés d'usinage sur la génération des poussières ont été mis en évidence. Des mécanismes de formation de poussières sont identifiés et reliés à la formation des copeaux.

Jan 1, 2006

By L. Gawlik

Since the beginning of the 20th century, coal has been the world?s main source of primary energy. In the last few decades, consumption of coal has gradually decreased in some European countries and elsewhere due to the introduction of other energy sources. Regardless, industry continues to use solid fuels for energy production despite of their association with carbon dioxide emissions (about 7 billion Mg). For global development going forward, it is important to estimate what level of energy consumption can be expected as far into the future as the next few decades. To answer this question, specialized global institutions such as the International Energy Agency, the World Energy Council, the World Coal Institute, the U.S. Energy Information Administration, the International Institute for Applied Systems Analysis, as well as oil companies (BP, Shell), conduct periodic forecasts of world energy consumption. The development of such forecasts is very complex because their reliability is influenced by many factors that are difficult to estimate, such as economic development, population growth, climate change, and public awareness. We are all aware that the global demand for electricity will rise significantly in the coming years as a result of anticipated population growth, industrial development, rising living standards, and the general development of civilization. The world?s mineable resources in 2010 were as follows: coal 665.6 million Mg, brown coal 195.4 billion Mg, oil 163 million Mg, and natural gas 185.5 billion m3. The annual global primary energy demand in 2008 was more than 12 billion toe (12,267 Mtoe). In 2006, electricity production in the world amounted to 18,921 TW?h. The structure of the primary energy mix in TW?h (2006) was as follows: coal 41.0%; natural gas 20.1%; nuclear fuel 14.8%; hydro energy 16.0%; liquid fuels 5.8%; and other renewable energy sources 2.3%. The European Union (EU) is one of the largest coal consumers in the world. In 2010, the EU-27 produced 396.1 million Mg of brown coal, and 132.9 million Mg of hard coal; 188 million Mg of coal was imported from outside the EU. The largest hard coal producers in the EU-27 are Poland, Great Britain, Germany, the Czech Republic, and Spain; major brown coal producers are Germany, Greece, Poland, the Czech Republic, and Hungary. For many years, the Polish energy sector has been based on domestic fuel sources ? hard coal and brown coal. The characteristic feature of the Polish balance of primary energy resources is a very high share of coal ? much higher than the world average. Pursuing the decarbonisation of the Polish economy may jeopardize Poland?s energy security, leading to a significant increase in electricity prices, which would hamper the country?s economic development. Price volatility and supply uncertainty are now the dominant features of the international markets for oil and natural gas. The high share of these fuels in meeting energy needs is the reason for unrest in many countries, including those in the EU. Under these circumstances, coal may become the stabilizing element of EU energy security.

Aug 1, 2013

By C. A. Morais, L. V. Resende

"The technological development observed in recent years has stimulated the application of rare earth (RE) elements. Amongst their various applications it is well worth mentioning their use in electronics, superconductors, nuclear medicine, as well as in special inks - as those used in radar invisible airplanes. TV and computer monitor screens present as coating a powder containing some rare earth elements, mainly Europium and Yttrium. The recovery of the RE elements from electronic scrap is extremely important as the economic and environmental issues are concerned. This paper describes the study of the Eu and Y recovery from e-scraps. The first step of the process was the leaching of the powder obtained by manually scraping the inside surface of the screen. After the optimization of the leaching, the dissolution of Eu and Y was higher than 98 w/t% and a pregnant sulfuric liquor containing 11.9 g L-1 Y and 0.72 g L-1 Eu was obtained. The second step was the separation of the metals found in the liquor by the solvent extraction technique. The separation of Eu and Y was carried out in a counter current circuit compound of 3 extraction stages, 7 scrubbing stages and 15 stripping stages. DEHPA was used as the extractant, whereas a diluted sulfuric acid solution was applied as scrubbing agent and a hydrochloric acid solution at high concentration was used as the stripping agent.INTRODUCTIONThe rare earths (RE) are a moderately abundant group of 17 elements composed of lanthanides, scandium and yttrium. Amongst the RE, promethium (Pm) is extremely rare, however several of the RE elements are not very rare and occur dispersed in a variety of forms (Greenwood & Earnshaw, 1984; Tyler, 2004).The innumerable applications of the RE elements are based on their particular properties, mainly their spectroscopic and magnetic properties (Martins & Isolani, 2005). The technological development observed in recent years has stimulated the application of rare earth (RE) elements. They have been used in agriculture, electronics, superconductors, nuclear medicine, automobile industry, special inks – as those used in radar invisible airplanes, X-ray screens, high intensity mercury vapour light bulbs, neutron scintilators, charged-particle detectors and optical memory reading systems (Maestro & Huguenin, 1995; Nagaosa & Binghua, 1997; Sánchez et al., 1999)."

Jan 1, 2012

By R. H. Andrews, F. J. West

"Jones & Laughlin Mining Company, Ltd. operate the Adams mine at Kirkland Lake, Ontario, where they mine approximately 4,000,000 tons of extremely hard iron-formation and 3,500,000 tons of volcanic waste rock annually in order to produce 1,100,000 tons of iron pellets. This paper will discuss the maintenance of the four Model 1600 P & H shovels and the two 50-R drills used to obtain this production. The chief maintenance problems at the mine are due to the hard, abrasive ore and the cold winter weather."

Jan 1, 1970

By G. E. Rowan

"DURING the dark ages, the cherished dream of chemists was to find a process for converting base metal into gold. Many a wealthy-but-gullible patron lost a fortune in the search. Men who work with metals today are a bit more realistic. I haven't heard of a metallurgist who expects to develop any one alloy that will resist all corrosive media. In the field of stain-less steels, there are about forty different types of alloys that are used where corrosion is a •problem.A stainless product is ordinarily selected because it offers one or more of the following qualities:(1) Resistance to corrosion (2) Resistance to oxidation at high temperatures (3) Good mechanical properties at room temperature (4) Good mechanical properties at high or low temperature (5) Attractive appearance (6) Ease of maintenanceToday we are interested in discussing the stainless steel family of alloys because of their .ability to resist corrosion. We• will not try to explain the Theory of Corrosion. Let us assume that, when surface potential and oxide formations are properly controlled, iron will resist attack in various chemi.cal solutions. The addition of alloying elements to iron does this for stainless steels. The principal stainless alloys used by various Canadian industries are listed in the accompanying Table."

Jan 1, 1959

By W. N. B. Armstrong

CORROSION of metals, for the purpose of this talk, may be divided into two general classes, namely, atmospheric and chemical. Atmospheric corrosion is caused by the natural agents -water, air, salt, and temperature -as well as by the agents arising from industrial operations which pollute the atmosphere. Chemical corrosion affects metals in refineries and chemical plants where severe conditions exist due to .acids, alkalies, salts, solvents, gases, ?steam, etc. A special condition is encountered on road equipment and motor vehicles due to the large amounts of corrosive salts which are used on our roads in the winter. Exposure to corrosive conditions such as those referred to above causes metal to be destroyed and, therefore, it has to be protected. The non-metallic or organic coatings used to protect the metal are themselves destroyed ultimately by these same conditions. Since all types of organic coatings do not have the same kind and degree of resistance to degradation, a particular kind of -coating must be used for a particular set of conditions in order to obtain the maximum benefit. In ?addition to the above mentioned agents, organic coatings are degraded ?by sun-light, which is probably the severest single factor in the breakdown of organic coatings exposed outdoors. We can divide organic coatings, in a general way, into the following classes: (1) Conventional coatings, and (2) Special coatings.

Jan 1, 1958

By M. Hajian Heidary

In this investigation, effect of pressure depth on the globulizations of AZ91 magnesium alloy was studied. Cylindrical samples of AZ91 alloy with 1 cm and 2cm in height and 2.5cm in diameter (H/D = 0.4 and 0.8) were prepared, then the samples were hot pressed at 10 and 30% strain at a constant temperature of 200°C; subsequently reheated at 555°C in different times. Results obtained from optical microscopy (OM) showed that the thickness of the samples and consequently, depth of strain affected regions have remarkable effect on the degree of globulization. In addition, it was found that at a constant strain and holding time, structure of thinner samples is more globular than thicker ones.

Jan 1, 2007

By G. V. Sirianni, G. E. Viens, R. A. Campbell, G. N. Banks

A combination shaft-electric furnace for the smelting of ores and the melting of metallized feed is being developed at the Mines Branch. When iron oxide pellets are smelted in this unit, they are preheated and partially reduced in the shaft before being transferred to the electric furnace where smelting is completed. Also, limestone flux added with the pellets is-preheated and calcined in the shaft. It has been demonstrated that, in smelting iron oxide in this unit, the throughput of the 250-kva electric furnace can be approximately doubled and the amount of electrical energy required can be very significantly reduced when the shaft furnace is operated in conjunction with the electric furnace. These benefits are achieved mainly by utilizing the sensible heat and latent energy contained in the arc furnace off-gases.

Jan 1, 1971

By A. A. Sizikov, V. A. Sizikova

Key parameters to consider for any producer: bring down production cost and lead time; Lean production as a tool to achieve maximum efficiency; How to implement lean principles: discontinuous vs. continuous production (aluminum industry); About RUSAL: global top-three aluminum producer; Lean tools at use at RUSAL's production facilities; Pull system, Standardization of work, Just in time, Continuous improvement, Customer-Supplier relations, etc.

Jan 1, 2006