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By J. U. MacEwan

Introduction The equilibrium between copper, zinc, and chlorine may be considered as the simultaneous equilibrium of the two separate chemical reactions of formation of the stable chlorides of copper and zinc at the temperature of the reaction i.e., l440°K. (1,167°C., 2,133°?F.)§ [Zn(g) +Ciz(g) ZnCl2z(g). ... (1) ] [2Cu(l)+Cbi'g) Cu2Cl2(l 1 ....... (21 ] Subtracting, [Zn(g) +Cu2(Clz(l i ZnClz(g) +2Cu!l) ... . (3) ] If this reaction is carried out with a copper-zinc alloy at some constant temperature above the melting point of brass, and at a total pressure of one atmosphere, the equilibrium concentrations obtained will depend on the free energy decrease .of the reaction as written in (3) and on the activities of the various components in. the reaction mixture. If the equilibrium is examined from the point of view of the phase rule, it is a three-component system, and if it exists in two phases (liquid and gas) it will have three degrees of freedom. If the restrictions of constant temperature and pressure are imposed, the degrees of freedom are reduced to one. This means that, in a two-phase system under these conditions, each different alloy phase will be associated with a gas phase of constant composition.

Jan 1, 1951

By T. G. Joseph, A. Sharma

ABSTRACT: Ultra-class haul trucks operating in oil sand face operational and maintenance issues as a result of soft underfoot conditions (Joseph, 2002). With exposure to frequent high g loading events, tire life is reduced due to sidewall belt fexure and frequent ground contact. Therefore, an improved under-standing of the interaction between tires and oil sand is needed. This paper examines the outcomes of a series of static and cyclic loading tests, performed using a scale tire on rigid, sand, and oil sand surfaces. Geometric predictions are made regarding the footprint area and vertical deformation of an ultra-classtire on similar surfaces.

Jan 1, 2011

By R. H. Nafziger

A novel process has been developed for preparing directly workable steel ingots from prereduced iron ore pellets by a two-stage process. The pellets are continuously charged into an electric arc furnace, where molten metal is separated from the gangue. The molten metal flows out of this furnace through a hollow nonconsumable graphite electrode immersed in a molten flux in an electroslag furnace. The molten metal solidifies on a continuously withdrawing base plate to form the ingot. A variety of standard carbon and alloy steel ingots . free of porosity , were produced using suitable decarburizers and ferroalloy additions. Some advantages of the two-stage process include: (a) consumable electrode fabrication is eliminated; (b ) no expensive deoxidizers are required; (c ) the uncontaminated electros lap flux can be reused; (d) energy consumption averages 25% less than in a conventional electric arc - electroslag operation ; and (e) the operation is continuous.

Jan 1, 1977

By T. J. Fee

Introduction The International Nickel Company have been pioneers in mine rescue work in Ontario. Following the fire in the Hollinger mine in the spring of 1928, the Company purchased ten self-contained oxygen breathing outfits, ten all-service gas masks, an oxygen high-pressure pump, life line, inhalator, ten cap-lamps with batteries, and a complete stock of spare and accessory parts. An instructor from the U.S. Bureau of Mines, Pittsburgh, came to the Creighton mine for one week and trained twenty men in the use and limitations of all equipment. Monthly training courses were commenced in the fall, and have continued to the present time. Of the original twenty men trained, ten are still on the Creighton mine rescue teams. In the meantime, and as an aftermath of the Hollinger fire, the Work-men's Compensation Board of Ontario and the Ontario Department of Mines established a central mine rescue station at Timmins. This was completed in the spring of 1930. It was then decided, in view of the great expansion in mine development in the Sudbury district, to build and equip a similar station to serve all the mines there, namely, Creighton, Frood, Garson, Falconbridge, Sudbury Basin, and Errington. An extensive survey was made and a central location selected opposite the Frood mine. The International Nickel Company donated a site, and the station was completed in the fall of 1930. The station is a two-storey brick building, 27 ft. by 47 ft., with a large garage adjoining it. The ground floor is used for equipment and for training the crews. On the second floor are living quarters for the superintendent and his family. The garage houses a closed truck, in which all necessary equipment can be taken to any desired point for training purposes or for actual mine rescue work, if and when necessary. The garage is also used as a gas room, where the men are trained in an irrespirable atmosphere. A gas-tight observation window between it and the training room enables the superintendent to see and direct the men undergoing training, weight exercisers and other devices being used.

Jan 1, 1935

By H. K. Olsen, B. Thomassen, H. K. Schønwandt, L. Grahl-Madsen, H. Stendal

Abstract-The central part of the early Proterozoic Ketilidian orogen in South Greenland consists of an I-type granitoid batholith transected by four regional NE-SW-trending shear zones. The batholith was probably emplaced during subduction, from the south toward the Archaean craton in the north, in a sinistral transpressional system. A regional sediment sampling program covering 5000 km2 shows a close connection between a gold-mineralized trend and one of the major shear zones within the epizonal facies of the batholith. The gold mineralization is not directly related to the major shear zones, but occurs in quartz-veined and silicified second-order structures. High-grade (up to 114 ppm Au over 6 m) low-tonnage mineralization is found within these second-order structures cutting both amphibolites and granitoids. The mineralization is characterized by negligible or small alteration halos. Gold is associated with various element combinations of enhanced As-Bi-W- Cu, which indicate that the mineralization is mesothermal in origin.

Jan 1, 1995

By H. K. Olsen, B. Thomassen, H. K. Schønwandt, L. Grahl-Madsen, H. Stendal

The central part of the early Proterozoic Ketilidian orogen in South Greenland consists of an I-type granitoid batholith transected by four regional NE-SW-trending shear zones. Thebatholith was probably emplaced during subduction, from the south toward the Archaean craton in the north, in a sinistral transpressional system. A regional sediment sampling program covering5000km2shows a close connection between a gold-mineralized trend and one of the major shearzones within the epizonal facies of the batholith. The gold mineralization is not directly related to the major shear zones, but occurs in quartz-veined and silicified second-order structures. High-grade(up to 114 ppm Au over 6 m) low-tonnage mineralization is found within these second-order structures cutting both amphibolites and granitoids. The mineralization is characterized by negligible or small alteration halos. Gold is associated with various element combinations of enhanced As-Bi-W-Cu, which indicate that the mineralization is mesothermal in origin.

Jan 1, 1995

By E. Norton

"Even though the subject of this panel discussion is dust control, rather than dwell on the design aspects of dust collection systems which are well documented in numerous publications, :it was considered more pertinent to the present economics of mining to examine the energy costs involved.At the present time, the facts of shrinking fossil fuel reserves and spiralling fuel costs are being constantly brought to our attention. Industry is being motivated to consider the possibilities of incorporating heat recovery systems in areas where they prove to be economical. Unfortunately, it is not a simple exercise to determine if the installation and operation of heat recovery equipment is feasible and economical. Each process involving heat recovery potential must be thoroughly studied in all aspects.In a paper presented at the 1975 Annual General Meeting of the Canadian Institute of Mining and Metallurgy in Toronto, Ontario, entitled ""The Influence of Energy Conservation on Concentrator Design"", it was stated that the largest single energy consumer in winter is space heating with the largest portion of this supplied to crushing and screening plants. (1) Within the scope of this panel discussion we will study, as one example, a crushing and screening plant using natural gas heat in the province of British Columbia and we will explore the feasibility and economics of installing air-to-air heat recovery equipment."

Jan 1, 1976

By A. M. Martinez, L. Melis, R. C. Peláez, L. G. Garcia

Orovalle Minerals S. L. operates a copper/gold mine in the Asturias region of northern Spain, with the operation dating back to December 1997. The feed to the El Valle mill, consisting of oxide/sulphide (skarn) mineralization, is highly variable, even on a shift by shift basis and presents challenges to the mill operating staff on a daily basis. The mineralogical characteristics of the ore are quite complex with copper present as native copper and sulphides as well as copper minerals with deleterious elements. Gold is present as native gold and electrum. The mill circuit includes SAG/ball mill grinding, gravity recovery of native copper and gold, flotation of copper concentrate, carbon-in-leach gold recovery and SO2/air cyanide destruction. The paper will provide a description of the different unit operations and present operating data of the mill operation.

Jan 1, 2019

By V. T. Panayotov, M. I. Panayotova

Wastewater from mining and mineral processing activities is often polluted by anion forming metals, such as molybdenum and chromium. Low cost materials, including zeolites, are studied for removing heavy metals from wastewater. It is widely accepted that natural zeolites are not effective in removing metals in anionic form. The paper presents study on use of metal modified natural clinoptilolite to remove Mo (VI) and Cr (VI) ions from model soft wastewater. Modification with Pb, Fe(III), Zn and Ba increases clinoptilolite uptake capacity with respect to Mo(VI) at low pH values of the water subjected to treatment, the efficiency decreasing in the order Pb > Fe(III) > Zn > Ba. Only lead-modified clinoptilolite shows high uptake of Mo(VI) in acidic, neutral and slightly alkaline conditions. Modification with Pb, Ba and Fe(III) increases zeolite uptake capacity with respect to Cr(VI) from neutral water. The effectiveness of Ba-modified zeolite decreases in slightly acidic water. Over 90 % uptake of initially available Cr(VI) is achieved by lead-modified clinoptilolite both under neutral and slightly acidic conditions. Increasing the initial pollutant concentrations increases the removed amount both of Cr(VI) and Mo(VI) for Pb-modified clinoptilolite. The findings could be a basis for using the natural clinoptilolite to remove in consecutive steps: firstly Pb(II) and/or Fe(III) ions and then loaded zeolite to be used for Mo (VI) and/or Cr(VI) removal. The kinetics of Mo(VI) uptake by CL-Ba, CL-Fe(III), CL-Pb, and CL-Zn is best described by the pseudo-first order kinetic equation. The kinetics of Cr(VI) removal by CL-Ba, CL-Fe (II), CL-Fe (III) and CL-Zn is best described by the pseudo-first order kinetic equation. Kinetics of Cr(VI) removal by CL-Pb obeys the equation for the first order irreversible reactions. Finding way to remove anions-pollutants from the mineral processing wastewater will render this industry more environmentally friendly and socially acceptable.

Jan 1, 2016

By M. C. Walton, W. Roelofs

ABSTRACT: In most cases, a refractory repair involves dealing with used refractory linings above shoulder height, defining these as overhead refractories. This paper details a method of personnel protection involving a low-pressure inflatable balloon system, installed to prevent the dislodgement and freefall of in-situ refractories. This system has been successfully applied to numerous types of vessels in the process industries in the last three to four years. This paper, prepared for the CIM Conference of Metallurgists held in Vancouver, British Columbia in October 2010, outlines details of the system and gives examples of successful applications.

Jan 1, 2012

By A. G. Scobie

THE research laboratory of this Company was recently faced with the problem of determining trace amounts of tungsten in a series of classifier sands. A spectrographie survey revealed the feasibility of using this instrument in the final evaluation, but a check of the common methods in use for the isolation of tungsten (3, 4) showed these methods to give incomplete separation for trace amounts. An investigation into the possibility of modifying these procedures, or developing others, was thus indicated. ASSAY PROCEDURE Weigh 10 grams of 200-mesh ore or concentrate into a 400-ml. beaker, wet the sample well with about 20 ml. of water, and add 100 ml. of hydrochloric acid. Cover, digest at 60° to 70° C. for about 1 hour, and then boil down to approximately 25 ml. Cool, add 25 ml. of hydrochloric acid and 10 ml. of nitric acid, and again boil to former volume. Add 20-ml. portions of nitric acid with successive boiling clown until chemical action is complete. Then add 20-ml. portions of hydrochloric acid until all nitric acid is removed. Take nearly to dryness on a law-temperature hot plate, but do not bake. Take up in 10 ml. of hydrochloric acid and 20 ml. of water and heat on a law-temperature hot plate until all iron goes into solution. Dilute to 200 ml. and heat to just below boiling. Stir in pulp of about half of a No. 41 Whatman filter paper (12.5-cm.) and continue digestion on plate with occasional stirring for 15 to 20 minutes.

Jan 1, 1943

By Patrick Fantin

Mining ? The Past Safety Not a priority; Health Not a priority; Energy Manual Labour; Horsepower? Literally. Financially Robust For the Owner?s; Mining ? The Future Safety Zero Harm Health Understanding and elimination of Industrial Disease Energy Efficient use of energy through technology. Full value of renewable energy. Financially Robust Continually build shareholder value through optimum CAPEX/OPEX.

May 1, 2013

By B. K. Gorain

Barrick' s Buzwagi copper-gold deposit in Tanzania comprises oxide, saprock and sulphide mineralized zones averaging approximately 0.058oz/t gold, 0.13% total copper and 0.03% cyanide-soluble copper. A comparative evaluation of the project based on two potential flowsheet alternatives is presented. The first flowsheet included a gravityconcentration and carbon-in-leach (CIL) plant. The second flowsheet was based on a Gravity-Flotation-CIL plant, which proved to be more economically robust. Selective flotation of copper minerals to produce a saleable copper concentrate proved to be challenging. Detailed characterization of the Buzwagi deposit was carried out through understanding of ore mineralogy, mineral liberation, floatability and selectivity, reagent chemistry and regrinding issues. With this insight, a flotation concentrate of greater than 25% Cu was achieved, recovering a significant amount of copper minerals and tellurides. The overall economics of the project improved significantly with the addition of flotation. Leach tests on gravity and flotation tailings showed an overall increase in gold recovery of approximately 6% for a Gravity-Flotation-CIL plant compared to that for a Gravity-CIL plant.

Jan 1, 2007

By E. Kordzadeh, M. Reza Bateni, M. Karaminezhaad, A. Moeini

A series of austenitic heat resistant Fe-Ni-Cr-Al alloys with different nickel contents have been investigated at 1100 ° C and 25, 50, 50,100 hours in S/0 bearing atmospheres. Before sulphidation test, the specimens were annealed in argon at 1250 °C for 8 hrs. Weight changes were measured using an automatic thermo gravimetric analyzer and corrosion products were analyzed by scanning electro microscope (SEM), energy dispersive X-ray spectrometry (EDAX), X-ray diffraction and optical microscope. The results showed that sulphidation resistance decreased with increasing nickel content. Internal sulphidation controlled by gaseous transport through cracks and pores and the formation of internal sulphide increased when liquid sulphides formed on the surface.

Jan 1, 2004

By Michael Sudbury

Introduction The essence of a good presentation is said to be: Outline what you are going to say Say it Summarize what you said This is perhaps especially good advice at 8.30 a.m. So here goes: This is an attempt to put numbers on three inextricably linked subjects: People and the Future Irrigation and Agriculture Mine Water and Mine Waste

May 1, 2013

By C. L. Lewis

"The development of computer process control at the Lake Dufault concentrator is reviewed and the on-stream X-ray analysis -computer system is described briefly. Some applications of the computer in metallurgical process control are described.The computer sequences slurry sample streams to the analyzer and translates the analytical results from voltage signals to elemental percentages. The required flotation reagent flow rates are calculated from analyses and mill-feed tonnage rates and the reagent feeders are set automatically to provide such flow rates. X-ray calibration time has been reduced from about 45 minutes to 15 minutes by the use of a computer program. Metallurgical and operating personnel have acquired the ability to program the computer and have extended the system capability to allow the calculation of recoveries, averaging of mill data, application of ore specific gravity in grinding control, control of oxidized ore flotation and the development of an economic recovery program."

Jan 1, 1971

By C. A. Anderson, C. A. Young, H-H. Huang, L. G. Twidwell

An equilibrium calculational computer program (STABCAL) can be used for titration simulation. The program can handle various forms of titrants: solid, aqueous, gaseous or another solution, and various type of reactions: reductive, oxidative and adsorption. Background chemistry, mathematical considerations, and program development will be illustrated. Also, simple titration applications such as how to determine the acidity of aqueous solutions and alkaline sulfide leaching of gold are presented. Processing of an acid mine water from the Berkeley Pit in Butte, Montana has been used for illustration purposes. The treatment studies included: cementation, sulfidization, and neutralization. The calculational results for the neutralization treatment using various alkaline reagents are compared to actual experimental data and potentially appropriate processes are discussed. Computational

Jan 1, 2005

By L Gill

The four basic types of electric motors -squirrel-cage, wound rotor, synchronous and D.C. -are de-scribed, with particular reference to speed-torque characteristics. The three classifications of squirrel-cage motors, C.E.M.A. B, C and D, are compared, and methods of selection for specific drives are outlined. Wound rotor and synchronous motors are covered from the viewpoint of construction details, methods of operation and control required. The application of these motors to crushers, conveyors and ball mills is described and reasons for their selection are given. The application of D.C. motors to haulage equipment and mine hoist drives is included, and the basic principles of a variable voltage drive are illustrated. Efforts have been made through-out to provide specific examples of motor selection, with particular reference to the mining industry. THIS paper will attempt to answer the question -"which motor should be used for a specific drive?" Although it is impossible to cover the complete subject of electric motor application here, we hope to give some idea of the types of motors available and why certain types are used on specific applications.

Jan 1, 1963

By J. P. Messervey

THE story of the efforts made by the Department of Mines of Nova Scotia in the search for and investigation of mineral resources for the Canadian war effort began in the spring of 1937. During the past five years, however, heavy enlistments in the Active Service Forces by employees of the mining industry of the Province caused a recession in the production of coal, salt, and other essential minerals required to keep industry rolling on a wartime basis. A marked increase was shown during the period in prospecting for 'strategic' minerals, not only by individuals but also by some of the foremost mining companies. The Provincial Government offered encouragement in this field of endeavour by the enactment of legislation whereby the prospector was enabled to secure the maximum area of ground in a prospecting license at a minimum of cost. The labour requirements on the ground staked, however, remained unchanged. The Nova Scotia Department of Mines continued active investigation of minerals vital to the war effort. These included fluorspar, barytes, diatomite, limestone, and coal. Fundamental knowledge concerning the geology and mode of occurrence of these minerals was accumulated and extensive diamond drilling was carried out on the promising occurrences. Work in these fields is being continued.

Jan 1, 1945

By L. Kong, V. G. Papangelakis, L. Li

"The Eh-pH diagram of lithium-titanium-water system at 25°C, 100 °C and 200 °C was constructed. It shows that there exist thermodynamic stability areas of Li2TiO3. This indicates a thermodynamic possibility for the formation of Li2TiO3 in aqueous solution. A hydrothermal process has been applied for the preparation of Li2TiO3 using TiCl4 and LiOH•H2O as raw materials. The prepared samples were examined with X-ray diffraction, scanning electron microscopy and thermo-gravimetric analysis and differential scanning calorimetry. The results show that temperature and washing condition have significant effects on the phase composition of the product. Phase-pure Li2TiO3 powders were obtained at 200°C with Li:Ti molar ratio of 2.0.INTRODUCTIONLithium-containing ceramics enriched in 6Li, such as Li2O, LiAlO2, Li4SiO4, Li2ZrO3 and Li2TiO3, are considered as tritium breeding materials (Saito et al., 1998; Roux et al., 1998; Johnson et al., 1998; Hoshino et al., 2002). In view of its admirable properties: low-activation, good thermal stability and thermal conductivity, excellent tritium release performance and reasonable lithium atom density (Kopasz et al., 1994; Roux et al., 1996; Saito et al., 1998; Wu et al., 2008), Li2TiO3 is recognized as one of the most promising candidates of tritium breeding materials. Meanwhile, Li2TiO3, as the precursor of H2TiO3-type lithium absorbent, receives more attention as the development of extracting lithium from salt lakes (Zhong, 2004; Zhang, 2010).Several synthetic techniques have been applied to prepare Li2TiO3 powders, such as solid-state methods (Lulewicz and Roux, 2002; Ramaraghavulu et al., 2011; Mandal et al., 2012), sol-gel processes (Deptula et al., 2002; Lee, 2008) and solution combustion routes (Cruz et al., 2006; Jung et al., 2006; Sinha et al., 2010). A solid-state method may produce a series of problems, including impurity contamination and difficulty in morphology control of the obtained powders, although the process involved is simple. The solgel process is prolonged and usually demands for multi-step reactions, while solution combustion route requires plenty of energy and easily causes product contamination by the fuel used. Owing to its environmentally benign and highly suitable characteristics in fabricating materials, hydrothermal technology has been widely used and became a powerful tool in the field of material synthesis (Yoshimura and Byrappa, 2008). For example, ZnO in the form of bulk single crystals, fine particles and thin films, which is an attractive photoelectric material, was successfully synthesized by hydrothermal process (Sekiguchi et al., 2000; Ohshima et al., 2004). A hydrothermal technique was also used to the preparation of carbon nanotube, which possesses outstanding mechanical, structural and electric properties (Bernholc et al., 1997), and is superior to the commonly used method (Gogotsi and Libera, 2000). There, it provides an option for preparing Li2TiO3. Laumann et al. (Laumann et al., 2010) synthesized cubic a-Li2TiO3 by hydrothermal reaction at 180 °C for 18 h, using TiO2 powder, comprising of anatase and rutile, and lithium hydroxide in de-ionized water. However, the prepared a-Li2TiO3 is extremely unstable with a maximum lithium loss of 75% when treated in bathing experiment."

Jan 1, 2012