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By P. J. Mackey

"The metal producing industries in Canada and in the U.S. in many ways owe their technical beginnings to Welsh technology. The first copper smelter in Canada started in 1849-50 with a Welsh reverberatory furnace and skilled furnacemen brought across from Swansea to operate the equipment1- The Rocky Mountain smelting industry began with the installation of furnaces resembling the Swansea smelters(2). It was only later that the North American industry developed newer and improved methods. This article briefly describes the metallurgical history of the Lower Swansea Valley, being that section of land stretching northward from Swansea along the banks of the River Tawe, and bordered by hillsides east and west of the river. The Valley has had a classic cycle of development and decline common to industrial areas of Britain which grew in the Industrial Revolution. Perhaps more than any other area today, the Swansea Valley represents a complete cycle of use from agricultural to the peak of industrial development through to decline and dereliction. The conditions which made the Tawe Valley attractive to certain industries were laid down nearly 300 million years ago with the Carboniferous swamps and forests which covered the area, later forming the south Wales coalfield. As a result of glacial action and the deposit of glacial outwater and alluvial gravels, the valley adopted the traditional configuration, with its rocky sides occasionally remaining exposed. Up to probably about the 16th century, the Lower Swansea Valley was similar in use and appearance to many other valleys in the region. From the 14th century, the natural oak woodland had provided a continuous source of timber to produce charcoal for iron making as well as for structural purposes. Agriculture was the main activity in the valley in this period, but it was likely that the farmers also mined small amounts of coal by way of ""bell pits"", and adits into the coal seams."

Jan 1, 1999

By Lauri Gregg

The implementation of Energy Management within the global mining industry has advanced significantly during the past 20 years. Consequently, the industry?s knowledge of energy efficiency improvement opportunities, more energy efficient technologies, renewable energy technologies, energy procurement practices, and most importantly, practical approaches for integrating the energy management best practices into business processes and operational procedures has improved greatly. Based on 25 years of experience leading the management of energy in mining operations and the Canadian mining community, the author discusses the key building blocks in the evolution toward becoming an energy efficient mining facility. Sustainable energy management depends on the internalization of the behaviors related to the effective energy use by a mining organization. The paper outlines the typical business drivers that stimulate top management commitment to allocate the resources necessary for this to happen. It also explores the barriers that mining companies must overcome to maintain the commitment. Additionally, it will advocate the need for the application of the principles of organizational change management as part of the energy management implementation process. The question regarding how energy management can be made to happen in a way that is practical for an established organization is answered by providing the details of the framework for energy management, the methodology for controlling energy use, and the roadmap for integrating energy as a key business parameter and production process input variable. An Energy Management System standard developed within the Mining Association of Canada?s ( MAC ) Towards Sustainable Mining ( TSM ) initiative has played an important role in increasing the capacity of the Canadian mining industry to manage energy. The impact of the application the MAC TSM Energy/GHG Management Protocol by Canadian mining companies will be discussed. In June of 2011, the international ISO 50001 Energy Management Systems standard was finalized and published for use. The structure of ISO 50001 will be outlined along with its applicability to the mining industry. Opportunities for practically improving mining energy performance along with the most appropriate current new technologies will be identified. A brief discussion of case studies will be included that demonstrates the successful implementation of Energy Conservation Measures ( EAC?s ) and economic benefits. In conclusion, thoughts on important areas of research and development related to increasing mining energy efficiency will be provided.

Aug 1, 2013

By Z. Zhang

Aluminum boron carbide particulate reinforced composites have found new applications in nuclear industry due to their special capability to capture neutrons, Recently, Alcan successfully developed a liquid metal mixing process to fabricate Al¬B4C metal matrix composite instead of powder metallurgical technology. In the process, titanium is added into the composites to control interactions between boron carbide particulates and aluminum matrix, To understand the effects of titanium on the composites, the solidification microstructure of Al-16%B4C without or with titanium was examined by optical and electron microscopes. The results show that titanium can improve the uniformity of the particulate distribution within aluminum matrix if the titanium content in the composites is more than 0,5%, Furthermore, it is found that the layer with rich titanium on the surface of the particulates can limit the formation of AlB2 type compounds, which may greatly deteriorate the fluidity of the composites, In addition, it is also found that the amount of the reaction products in the composites increases with the increase of holding time. However, the rate of the increase is mitigated by the increase of the content of titanium in the composites. Besides, a procedure was proposed and implemented for the evaluation of uniformity of particulate distribution within aluminum matrix.

Jan 1, 2005

By P. Chu, J. A. Finch

The formation of small bubbles in flotation is usually accomplished by the use of frothers, or sometimes is due to the presence of inorganic salts in the process water. The effective mechanism associated with the presence of these solutes is generally considered to be coalescence inhibition. However, recent work has demonstrated that the presence of frothers and salts also reduces the size of bubble at the initial formation stage. In this paper we adapt the same experimental setup to investigate the time that it takes for a bubble to form; for a known system power input, the energy to form a bubble can then be estimated from the time. The hypothesis is that the presence of frother and salt will reduce the time for a bubble to form, which can be interpreted as an added energy component being derived from the solute. Testing different types and concentrations of frothers and salts, the hypothesis is supported: the mechanical energy required to form a bubble decreases by about 10% in the presence of these solutes.

Jan 1, 2015

By H. Lachmund, R. Bruckhaus

At Dillinger Hüttenwerke/Germany steel production of grades for linepipe applications especially for sour service has a long tradition. The BOF process after replacement of the vessels is optimized by a newly developed lime addition model and variations in lance tip geometry. Equipped with three state-of-the-art VOD tank degassers metallurgical requirements of lowest contents of e. g. sulphur, nitrogen and hydrogen can be achieved. Three continuous casting machines of vertical bending type with solid core even improve already high levels of cleanliness. The vertical part corresponds to the metallurgical length of 12 to 15 m and therefore assures a maximum of cleanliness after solidification before bending. Slab thickness up to 400 mm can be produced with model controlled dynamic soft reduction. The accurate alignments of the casters assure minimized segregation and microporosity. Surface and internal cracks can be avoided by special cooling, bending and straightening strategies.

Jan 1, 2005

By R. V. Fox, L. K. Sinclair, D. L. Baek

"In this study, rare earth elements were recovered from bastnasite concentrate and waste fluorescent lamp phosphors using supercritical carbon dioxide extraction with a nitric acid/tributyl phosphate adduct. Several pretreatment methods were used to alter the crystal structure of the source materials, and thus improve rare earth element recovery. Pretreatment methods included 1) dry roasting of the source material at 730oC, 2) decomposition with 50% sodium hydroxide solution at 150oC for 4 hours, and 3) decomposition with 12 M sulfuric acid at 300oC for 4 hours. Treated and untreated samples underwent supercritical extraction at 24 MPa and 65oC for 1 hour. Untreated bastnasite and phosphor samples showed <10% rare earth element recovery, but sodium hydroxide digestion resulted in >60% recovery for most rare earth elements. Dry roasting of the bastnasite concentrate was also effective, resulting in >60% recovery for cerium.INTRODUCTIONRare earth elements (REEs) consist of the 15 lanthanides, scandium, and yttrium. Scandium and yttrium are included because they are in the same group as lanthanum, appear in many of the same ore deposits as the rest of the lanthanides, and exhibit many similar chemical properties. REEs are used in a wide array of applications including electronics, magnets, catalysts, glass, and solid-state lighting (Xie, Zhang, Dreisinger, & Doyle, 2014). Because of China’s continued dominance of worldwide REE production, the United States Department of Energy has sought to diversify domestic supplies of REEs (United States Department of Energy, 2011). A key part of this strategy is the development of improved extraction methods for both ores and recycled sources.Supercritical fluid extraction (SFE) is a promising technology for extraction and separation of rare earth elements. Contact with an acid adduct dissolved in supercritical carbon dioxide allows for the rapid extraction of REEs from solid matrices. Supercritical CO2 has several potentially useful properties as a solvent, including high diffusivity and the ability to tune solvation properties by adjusting pressure. Such tunability may have applications in separating the REEs once they have been extracted from the solid phase. Tributyl phosphate/nitric acid adducts (TBP:HNO3) are a particularly promising class of adducts for SFE extraction of rare earth elements. Using TBP:HNO3 adducts in supercritical CO2, several researchers have successfully extracted REEs from their oxides (Wuhua, Pijia, & Yongjun, 2010; Zhu, Duan, Xu, & Zhu, 2009). However, there is a complication in applying this technique to many types of ores and recycled sources: REEs are often locked in refractory minerals which are resistant to acid attack, resulting in limited recovery in supercritical extraction."

Jan 1, 2016

By M. V. Rowley, D. D. Warkentin

With high commodity prices, tightening operating budgets and increasing disposal costs, there is an increasing interest in processing municipal waste streams, such as the ash derived from combustion processes. This paper describes laboratory development work for a process to recover metal values from the finer fractions of these wastes. The work was initially aimed at recovery of copper and the removal of lead and other heavy metals from the ash residue, but results showed gold and silver recovery to be an important objective as well. The process uses gravity and flotation as the principal separation steps, with gold recovery occurring mainly in the flotation stage. The particle size range and chemistry of the ash presented numerous challenges to developing a suitable flotation method, but an effective flowsheet was developed by separating the ash into a fine fraction and a separate slime fraction, each with a unique flotation strategy. Specialized conditioning stages and careful reagent selection have resulted in effective gold and silver recovery from a range of ash types and sources. The work has resulted in a patent being issued for a process based on this novel approach to the treatment of combustion wastes.

Jan 1, 2017

By Mike Broczkowski, Laura Dewhirst, Kieran Large, Angelo R. Fernando, Heather Daigneault, Jim Johnson, Randy Wiens

The radioactive isotope radium 226 is a contaminant of potential concern in effluent waters from metal mining operations in Canada. Acceptable release levels of radium 226 are governed by Metal and Diamond Mining Effluent Regulations. Since radium is invariably present as a companion element in uranium ore, monitoring and controlling of radium 226 is a must for uranium mining operations. Measurement of radium 226 is traditionally carried out through a radiochemical technique involving selective co-precipitation of radium with barium sulphate followed by alpha spectroscopy for quantification. As of 2010, Cameco has also been using an ICP-MS based radium analysis method developed in collaboration with a research team at Trent University, Peterborough, Ontario. This method, which is highly automated and requires significantly less sample handling, with improved turn-around-times, is being used by Cameco site laboratories at the McArthur River and Cigar Lake mines as well as the Port Hope Conversion Facility. This paper compares the benefits and drawbacks of this new method, compared to the traditional alpha counting procedure drawing from almost ten years of field experience.

Jan 1, 2020

By G. Ozbayoglu, Z. Ozdemir

Turkey is the main boron minerals producing country in the world. The most important boron minerals are tincal, colemanite and ulexite. All mining, beneficiation and handling operations generate fines which cause ecological and economical problems. Utilization of this accumulated material requires both upgrading and agglomeration. The aim of this research was to exploit the ulexite fines by improving their grade and size. Attrition-scrubbing followed by washing and screening was employed for upgrading the fines. It was found that the grade can be increased from 23-25% B2O3 to 29% B2O3 with 73% recovery. Briquetting was applied as the size enlargement process. During the briquetting, the effect of moisture content, pressure, amount and type of binder, and drying on the quality of briquettes were investigated. The tests showed the possibility of production of strong briquettes by adding water alone, but the briquettes had no resistance to abrasion and water. Binders, namely boric acid and borax have been added to improve the properties of briquettes. The results showed that the compressive strengths and abrasive resistances of briquettes obtained with both binders were acceptable. However, the briquettes have no water resistance properties.

Jan 1, 2004

By C. Cristonffanini, S. Nazari

"In the past, simulation was considered to be an offline tool disconnected from plant operation. Advancements in the computation power combined with utilizing physics and chemistry sciences have allowed us to significantly improve the modeling and simulation technology for mining and mineral processing. This paper investigates the benefits of first principle models and simulation by connecting them to real time operation. Process data are connected to high fidelity models executed in parallel to the operation. In recent literature, this concept is known as Digital Twins. The Digital Twin is used for various purposes such as optimization, virtual instrumentation and condition monitoring. Using IDEAS™ simulation software we are able to construct a digital twin for different equipment inside a mineral processing plant. Two case studies for building a digital twin for the primary hydrocyclone feed pump and thickener underflow are presented. Using the pump’s model, a digital twin is developed and is installed in a gold extraction plant that is able to infer the slurry density in real time. Additionally, it is used for detecting sanding in the pipes and impeller condition monitoring.INTRODUCTION Since the eighties, thanks to advances in computation technologies, computer based simulation of processes using first principle models has become a well-known engineering tool for various industries. As our understanding of processes has increased, their representative models have become more realistic and more sophisticated. Due to this increase of accuracy, use of simulation is becoming more fundamental in process industries. The main goals to use accurate simulation is to decrease the engineering and construction cost, optimize the process design and improve the operation performance by decreasing operation cost and increasing efficiency. The term Digital Twin was first introduced in 2010 by NASA (Shafto et al., 2012) in aerospace industry. Subsequently, the concept quickly spread through other industries. As of today, no standard organization has provided an official and unique definition of Digital Twin for process industries. However, there are three important aspects that are common throughout various descriptions. When simulation is core functionality of the process (1) along the entire life cycle of the plant (2) with direct linkage to operation (3), it is called that process has a Digital Twin. According to Gartner, the concept of Digital Twin has elected as fourth most important disruptive technology for the year 2018 (https://www.gartner.com/, 2017)."

Jan 1, 2019

By O. Lashkari

Manipulation of pouring temperature is an efficient way to produce different microstructural features. In order to characterize the microstructure of rheocast billets due to different superheats of 615-695 °C, the parallel plate compression method was employed. Foundry 356 Al-Si alloy with different morphologies of primary a-Al particles were tested at different initial pressures of 4,8, 11,2 KPa, The resulted strain-time graphs were further treated mathematically to calculate viscosity of SSM billets. The interrelationships of viscosity, the microstructure and primary phase flow during compression are discussed, It is shown that the dendritic primary a-Al structure has the highest viscosity number which is almost three orders of magnitude greater than those for globular morphology, The current research have, for the first time, shown the validity and reliability of "parallel plate compression viscometry" method in characterizing microstructural evolution of Rheocast SSM billets.

Jan 1, 2005

By H. Pempel, J. Markowski, P. Ay

"Metal-coated thermoplastic parts find more and more functional and aesthetic applications in the interior and exterior of cars. The vapor-deposited or electroplated coatings are usually composed of a plurality of nickel- and chromium-containing layers, which are applied to copper-containing carrier layers on the polymers. Previously, recycling processes are mainly focussed at the recovery or thermal utilization of the plastics. Targeted and selective recycling of the metallic coatings is usually not carried out. Together with several SME, BTU developed a process, in which a complete and separate recovery of all components in high purity is possible with biotechnological methods. The bioleaching is carried out with iron and sulfur-oxidizing bacteria, especially Acidithiobacillus ferrooxidans. The copper-containing layers are dissolved in the solution; chromium- and nickel-containing particles are precipitated as solids. After the bioleaching, a mechanical separation of the individual metal-containing components and their separate workup are carried out. End-products are metallic copper, a nickel- and chromium-containing solid and the cleaned plastics. The bioleaching ensures a high purity of the end products. Through the use of bacteria, which are also found in nature, the process is environmentally friendly. Compared to chemical leaching using inorganic acids, considerably shorter leaching times can be achieved. In addition to the optimization of the leaching process, the R/D-project also includes the development and testing of the apparatus technology.INTRODUCTION The material complexity of many end-user products has increased in recent years, especially in the fields of electrical appliances, vehicle technology and medical technology. However, the demands on functionality, safety, comfort and energy efficiency still play a greater role in product design as factors such as sustainability and usability. For example, if a car still holds more than 70% of steel in the 1980s, a vehicle nowadays includes a larger proportion of a variety of difficultly separable plastics and composite materials, as well as complex metal composites. This relates in particular to composites made from such different materials as metals and plastics. The processing and recovery of the components of those complex material mixtures is difficult for recycling companies."

Jan 1, 2017

By Unknown

With the present-day trend of rising labour costs and a lowering of production efficiency of workmen, it has become imperative that every effort be made to use manpower to the greatest advantage and to mechanize mining as much as possible. During the past few years this trend has gained much prominence in the Porcupine camp. In view of this, the executive of the Porcupine Branch considered that the Mechanical Movement of Muck would be a very timely subject for a Symposium. Accordingly a Committee was formed, with A. K. Douglass, Mine Superintendent for Delnite Mines, Ltd., as Chairman, and the Symposium was held in the Auditorium of the McIntyre Community Building, Schumacher, on March 25th last. Papers dealing with shovel loader and mechanical scraper operation at six of the larger mines of the camp were presented and discussed, and a tabulation was prepared giving data on the machines in operation at a total of eleven mines. The papers and tabulation, reproduced below, will doubtless be of considerable interest to operators of mines in all parts of Canada.

Jan 1, 1948

By R. C. Gegg

The property of MacLeod-Cockshutt Gold Mines, Limited, is in the Little Long Lac area of the Thunder Bay Mining Division, Ontario, about four miles south of the Canadian National railway station of Geraldton. The town of Geraldton is about 170 miles east of Port Arthur and 22 miles west of Long Lac, which is on the main line of the Canadian National railway. The Trans-Canada highway passes through the property and during the winter season the road is maintained between Port Arthur and Long Lac. Electric power is supplied by the Hydro-Electric Commission of Ontario from their Cameron Falls plant and is distributed at 44,000 volts by a local transformer station. Early History The South orebody was discovered by diamond drilling in the spring of 1936. This is a porphyry contact orebody with major pyrite and minor arsenopyrite mineralization. Some gold is present in the &apos;free&apos; state, but for the most part it is locked in the pyrite, with little or none in the arsenopyrite. Preliminary test work was based on comparing straight cyanidation with bulk flotation and cyanidation of the concentrates. The overall results by the two methods were found similar, but for economic reasons the flotation-cyanidation process was adopted. Before the mill came into operation, a new and entirely different type of orebody, consisting of massive sulphide lenses in banded iron formation, was discovered to the north of the existing workings. These bodies are an intricate mixture of pyrite and arsenopyrite, both carying gold.

Jan 1, 1949

By L. K. Mireku

"Abstract - The Halfmile Lake South Deep zone, Bathurst Mining Camp, New Brunswick, was discovered by Noranda Inc. (Exploration) as a result of a 3-D seismic survey in 1998 and the subsequent drilling of ten diamond-drill cores. The deposit consists of massive, breccia, and stockwork Pb-Zn-Cu sulfide minerals, and is hosted by a volcano-sedimentary sequence belonging to the overturned Ordovician Tetagouche Group. Epiclastic rocks and interbedded fine-grained felsic pyroclastic rocks dominate the stratigraphic footwall. Locally, crystal-rich felsic tuffs and subordinate epiclastic rocks comprise the immediate stratigraphic hanging wall. The entire stratigraphic sequence was intruded by quartz-feldspar porphyritic intrusions, and cut by intermediate and basic dikes. The volcanic and sedimentary rocks can be discriminated geochemically using trace element ratios such as Zr/TiO2 and Nb/TiO2, despite intensive alteration and cleavage development. These ratios indicate that four protolith volcanic compositions exist: rhyolite, dacite, andesite, and basalt. The aphyric and feldspar- and quartz-phyric volcanic rocks are dacitic and rhyolitic in composition; epiclastic rocks have trace element ratios consistent with dacitic compositions. Pearce element ratio diagrams, general element ratio diagrams, and petrographic observations demonstrate that the rhyolitic volcanic rocks exhibit evidence of albite, potassium feldspar, and quartz fractionation, dacitic volcanic rocks exhibit little evidence of any fractionation, and epiclastic sedimentary rocks exhibit evidence of quartz sorting only. Hydrothermal alteration is best represented by the presence of phengitic muscovite and daphnitic chlorite. Minor calcite occurs in the stratigraphic hanging wall, deep in the stratigraphic footwall, and in post-mineralization dikes, and thus is not interpreted to be part of the causative hydrothermal event. Element additions and losses during alteration have been used to determine net alteration reactions, and these have been used to identify alteration parameters that are independent of other forms of alteration and fractionation/sorting, and which can be used to guide exploration. These parameters include: a bulk hydrolysis measure, (2Ca+Na+K-2CO2)/Al; a muscovite alteration measure, K/Al; an albite destruction measure, Na/Al; a chlorite alteration measure, (Fe+Mg-S/2)/Al; a chlorite composition measure, (Fe-S/2)/Mg; a sulfidization measure, S/Ti; and a carbonatization measure, CO2/Ti. With the exception of the carbonatization measure, these alteration parameters define a distinct lateral and vertical zone of intense hydrothermal alteration in the stratigraphic footwall of the deposit, and demonstrate that the epiclastic rocks are predominantly chlorite altered, and the volcanic rocks are predominantly muscovite altered. Within the alteration halo, element additions of Fe and H, and element losses of Na are characteristic. Potassium was added to muscovite-altered rocks, but subsequently removed from chlorite-altered rocks. The results from this study demonstrate that metamorphism and deformation have not significantly obscured hydrothermal alteration signatures."

Jan 1, 2006

By Liang Zhen, Jian-Tang Jiang, Guo-Ai Li, Xiao-Ya Wang

"Deformation behavior of 2A97 aluminum alloy containing coarse secondary phases was studied using uniaxial hot compression (HC, 340–490°C, 0.4001–1 s-1). The flow stress could be described by a Zener-Hollomon parameter in hyperbolic sine function with the hot deformation activation energy of 237 kJ/mol. Based on the experimental data and dynamic materials model, processing maps were generated to demonstrate the hot workability of the alloy. The coarse secondary phases experienced dissolution by varying degree under different deformation temperature, which producing different effects on the microstructure evolution. When deformed at relatively low temperatures, a mass of fine grains shaped up in the original grains and grain boundaries, and the dominating deformation mechanism was believed to be dynamic recrystallization. As the deformation temperature rising to 490°C, most secondary phases disappeared and few recrystallized grains were observed, indicating that the secondary phases dissolved sufficiently along with dynamic recovery occurred during the hot deformation. Particle stimulated nucleation related to the coarse secondary phases was believed to promote the recrystallization and the recrystallization behavior was sensitive to deformation temperature.INTRODUCTION Al-Li alloys has received much attention as new promising structural materials in the aircraft and aerospace industries, due to their lower density, higher elastic modulus and improved fatigue crack growth resistance in comparison with the conventional commercial aluminum alloys (Ou Ling, 2015). 2A97 alloy is one of the 3rd generation Al-Li alloys targeting at comprehensive improvement of aviation aluminum alloy and applications for wing spars and ribs to other internal structures for transport aircraft. Al-Li alloys are usually formed by hot deformation, either by rolling or extruding. The deformation behavior and resulted microstructure evolution during the forming process mainly dominates the formability of the alloy and the serving performances as well. Therefore, the deformation behavior and microstructure evolution at elevated temperature need be made clear for optimizing the hot processing parameters and controlling microstructure evolution."

Jan 1, 2018

By L. A. Jameson, J. Awmack, P. J. Lind

"Peñasquito is a polymetallic deposit containing gold, silver, lead, and zinc. The operation is currently the largest producer of gold in Mexico. Over the next few years, the process flowsheet will be expanded beyond the flotation of lead and zinc to include flotation of pyrite from zinc tails and subsequent leaching of the pyrite concentrate. This paper outlines mineralogical leach characterization that has been carried out to improve the understanding of the complex hosting of gold and silver minerals in the ore. Organic carbon that is present in the ore can have an impact on flotation and leaching. Mineralogical techniques used to characterize this deleterious component of the ore are introduced.INTRODUCTION Goldcorp’s Peñasquito operation is located in the Mexican state of Zacatecas, approximately 200 km from the city of Zacatecas as shown in Figure 1. Peñasquito has been in operation since 2009 and is currently Mexico’s largest gold mine. Mining is carried out by open-pit methods, with oxide ore proceeding to a heap leach facility and sulfide ore treated in the sulfide processing plant.The processing capacity of the sulfide plant is 130,000 tonnes of ore per day and in 2016 production amounted to 450,000 ounces of gold, 17.6 million ounces of silver, 109 million lb of contained lead, and 263 million lb of contained zinc in lead and zinc concentrates. GEOLOGY The Peñasquito deposit is hosted in and adjacent to two breccia pipes; Peñasco and Breccia Azul. The two breccia pipes are branches of a larger intrusive-related complex, which is hosted in the sedimentary Caracol formation as illustrated in Figure 2. The regional geology is dominated by Mesozoic sedimentary rocks which comprise a thick series of marine sediments deposited during the Jurassic and Cretaceous periods. A 2 km thick sequence of carbonaceous and calcareous siltstones and interbedded sandstones is underlain by a 1.5 to 2 km thick limestone sequence (Goldcorp Inc., 2015)."

Jan 1, 2017

By R. D. Merer

The production of low- and medium-Btu gas from coal provides a more economic source of energy for most industrial users than pipeline-quality coal gas (SNG), although the latter has received more publicity. The paper reviews existing and advanced methods of coal gasification, with particular emphasis on the production of low- and medium Btu gas for industrial and utility use. Some of the ways in which coal gasification can be integrated into power cycles and industrial plant energy balances are discussed.

Jan 1, 1978

By Joseph Licavoli, Paul Sanders, Yang Yang

"Al-Sc-Zr alloys form thermally stable L12 precipitates which provide high temperature strength. Although the overall fraction of L12 Al3Sc and Al3Zr may be increased by increasing scandium (Sc) and zirconium (Zr) content, such additions may increase primary phase fractions and do not produce desirable secondary phase morphologies. Rapid solidification techniques, such as melt spinning, increase solute atom concentration within the matrix. When the supersaturated matrix is aged, higher precipitate volume fractions at low Sc and Zr levels can be achieved improving high temperature strength. Melt spinning was used to rapidly solidify (107 k/s) a thin ribbon of Al-0.5Sc-0.4Zr at. %. The ribbon was compacted and extruded into 99.8% dense rods, and then aged using multi-step isochronal heat treatment up to 600°C. Precipitation strengthening was evaluated by ambient hardness measurement. The ambient hardness of melt-spun ribbon after precipitation hardening increased by 450 MPa (~67% increment) during isochronal heat treatment.INTRODUCTION Small Sc and Zr additions to aluminum improve strength and creep resistance above 300°C due to tri-aluminide precipitation of Al3(Sc,Zr) in L12 structures similar to ??, Ni3(Al,Ti) in nickel superalloy, but the Al3(Sc,Zr) particles have a Sc-rich core surrounded by Zr-rich shell (Figure 1). The Al3Zr shell limits atomic transport between the Al3Sc core and the matrix and reduces coherency strain. These factors reduce precipitate coarsening rate at elevated temperature (Bergner & Van Chi, 1977; Fujikawa, 1997; Knipling et al., 2011; Clouet et al., 2006).Figure 1. Simplified schematic model of precipitate Al(Sc,Zr) in Al-Sc-Zr alloy. Shell is rich of Al(Zr) intermetallic phase, particle core is rich of Al(Sc) intermetallic phase (after Voorhees, 2006). Numerous Al3(Sc,Zr) particles increase alloy strength and creep resistance as the precipitates impede dislocation glide and to a lesser extent climb. Previous work on ternary Al-Sc-Zr alloys show large strength increases versus binary Al-Sc, and Al-Zr alloys in Table 1."

Jan 1, 2018

By J. K. Shaw

The science of low temperature engineering is well entrenched in mining. Uses for common cryogens, including liquid oxygen (LOX), liquid nitrogen (LN2), and liquefied natural gas (LNG) in the gas and minerals industries are reviewed. Potential future applications are discussed within the scope of mining, particularly in refrigeration and ventilation. The second part of this paper focuses on the Linde cycle, which is at the heart of most liquefaction plants. Steady state equations describing the mass and energy flows are presented. The paper concludes by explaining the concept of a wind powered Linde- Hampson cryogenic cycle and assessing, with scoping calculations, the technological feasibility of producing cryogens with an intermittent source of (renewable) energy.

Aug 1, 2013