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By N. S. Spence

INTRODUCTION WHILE TITANIUM, the element, has been known for over 150 years, titanium, the metal, is a relative newcomer to the metallurgical and industrial scene. The reasons for this chiefly lie in the refract1Hy nature of titanium compounds; the high melting point of the metal; the great activity of elemental titanium, particularly at temperatures close to .and above the melting point; and the pronounced deleterious influence of certain impurities on its mechanical proper-ties. Early efforts at production of the metal were, consequently, either unsuccessful or resulted in products having sub-metallic properties. With the considerable improvement in equipment, materials, and skills that have developed within the past twenty-five years, later investigators have had a better opportunity to overcome some of the inherent practical obstacles and to come to grips with the essential technical problems. NATURAL ABUNDANCE OF TITANIUM Titanium is one of the most abundant metallic elements. It has been estimated (1) that titanium comp-rises about 0.65 per cent of the earth's crust, and therefore ranks fourth among the structurally useful metals in the order: aluminum, iron, magnesium, titanium. It must be appreciated that the relative abundance of the element is only a crude indication of its potential availability, since a very substantial proportion is present as a minor constituent in practically all igneous rocks. By comparison, present-day ores of titanium are relatively few and are but a minor fraction of the estimated total titanium contained in the earth' s crust.

Jan 1, 1951

An optimized long-term mine planning determines the best order of material extraction, so that the Net Present Value (NPV) becomes maximum. In the case of oil sands surface mining, one of the key constraints in NPV maximization is the volume of tailings slurry that will be generated downstream. Specifications of tailings slurry are also important from environmental perspective. Moreover, most of the material that will be used for the reclamation of tailings ponds in later periods is generated in extraction and processing of oil sands. In this paper, an integrated optimization framework is proposed to maximize the NPV of the produced oil sands, with respect to tailings capacity constraints and reclamation material requirements. A mixed integer linear programming (MILP) model is developed to find the optimal solution for long-term mine planning problem. The proposed model is coded in Matlab and has been run using CPLEX for verification. The results for real-case oil sands dataset show that the optimal production schedule meets material requirements for reclamation, tailings volume is within tailings capacity range in all periods and the production schedule follows the predetermined horizontal direction.

Aug 1, 2013

By B. R. MacKay

Introduction Of all Canada's mineral resources, its coal deposits have probably received the most continued attention by the Geological Survey since its inception ninety years ago. A casual review of the many geological maps of coal areas by the Geological Survey will show how geological and topographical detail on the maps has gradually increased to meet the ever urgent demands of the mining industry. In the early stages of exploration, the mapping done, especially in the coalfields of the Rocky mountains, was largely of a reconnaissance nature. On these maps the topographical relief, where shown, is indicated by form lines or by hachures, the boundaries of the coal-bearing formations are only approximately defined, and the geological structure of the coal seams is illustrated by one or more generalized cross-sections. Once mining development on a coal area began, there arose a demand for more detailed maps. To meet this need, topographical and geological maps on a scale of one inch to a mile were made, in which the ?topographical relief is shown by contour lines having generally an interval of 100 or 200feet. On the geological maps, the boundaries of the formations are accurately delineated, and the geological structure of the area is illustrated by one or more structure sections drawn across the area, which show the position and attitude of fault lines, the crests and troughs of folds, and the attitude of the various formations (See maps of Costigan Coal Field, 1905, and Cascade Coal Basin, 1907, by D. B. Dowling).

Jan 1, 1932

By G. M. Swinkels

Sherritt Gordon and Cominco, with financial assistance from the Canadian Government through PAIT, have developed a hydrometallurgical process for refining copper from sulphide concentrates. The main objective of the project was to develop a process applicable to a wide range of concentrates with respect to copper content, other metals content and impurities, within the economic parameters set by present smelting and refining practice. Other important objectives were to recover sulphur in its elemental form and not as sulphur dioxide to assure improved hygienic conditions and a negligible impact on the environment. For the most abundant and relatively refractory chalcopyrite concentrates, the first step of the process is thermal activation with hydrogen to decompose chalcopyrite and pyrite, commonly associated with it, into more reactive sulphides more amenable to leaching. The iron is then selectively extracted by sulphuric acid leaching and subsequently rejected as jarosite. High-bornite concentrates do not require thermal activation and acid leaching; they are subjected to another hydrometallurgical iron removal step. The high-grade copper sulphide resulting from iron removal, and containing all of the initial precious metals, is then leached under oxygen pressure to produce elemental sulphur and copper sulphate solution . After suitable solution purification, the copper is recovered by high-current-density electrowinning as wire-grade product. Precious metals remain in the leach residue and are recovered after separation of the gangue materials and elemental sulphur. The laboratory and pre-piloting test work had indicated copper and precious metals recoveries comparable to those achieved in current practice. The process was shown to be suitable for handling relatively low-grade concentrates and, in addition, it was capable of high recoveries of associated zinc, molybdenum, nickel and cobalt in saleable form.

Jan 1, 1978

By C. H. Ash

"Abstract-The Red Chris Cu-Au deposit (522.7 Mt at 0.35% Cu and 0.27 g/t Au), northwestern British Columbia, is one of several pre-accretionary porphyry systems in the Cordillera of western Canada. It is hosted by an Early Jurassic hornblende monzonite to quartz monzodiorite porphyry which forms part of a suite of dikes and stocks that intrude Late Triassic volcanic strata. Major and trace element chemical data suggest that these Early Jurassic intrusions have compositions which fall on the boundary between alkalic and calc-alkalic compositions. Alteration and mineralization in the Red Chris deposit are more typical of calc-alkaline porphyry systems with abundant potassic, sericitic and argillic assemblages and quartz-rich stockworks. It lacks Na- and Ca-bearing silicate assemblages which characterize the alkalic porphyry deposits of British Columbia. One of the more unusual features of the deposit is the abundance of carbonate alteration and veins which occur throughout the hydrothermal history of the deposit. This type of alteration and veining is more typical of alkalic porphyry deposits. The composition of the carbonates vary both temporally and spatially with different alteration zones. Potassic zones, which are characterized by orthoclase±albite±quartz±chalcopyrite±bornite± magnetite±hematite and Au/Cu ratios of 1:1 (g/t Au:% Cu), contain minor siderite veins and alteration. Quartz-sericite-carbonate (QSC) zones overprint earlier potassic alteration and comprise quartz+ankerite+sericite+pyrite+chalcopyrite with Au/Cu ratios of 0.5:1 (g/t Au:% Cu). Ankerite is the main carbonate in this stage but has a variable composition with a more Fe-rich variety associated with mineralized veins. Localized chlorite-carbonate alteration zones, characterized by chlorite+ carbonate+quartz±kaolinite±pyrite±gypsum and high Au/Cu ratios [2 to 3.5:1; (g/t Au:% Cu)], contain predominantly calcite. Late stage carbonate-gypsum veins have an ankerite to dolomite composition which is very similar to the regional carbonate alteration and veins."

Jan 1, 1997

By R. K. Carnochan

MANY improvements have been made in recent years in the milling of industrial minerals and it is the purpose of this paper to review some of the more important innovations that are now being used in the preparation of these products. Some of the observations which will be made have been prompted by what was seen on a recent trip to industrial mineral milling plants in the north and central sections of the eastern United States. The flotation plants visited were those of the Valley Forge Cement Company at West Conshohocken, Pa., the International Agricultural Corporation at Mount Pleasant, Tenn., and the Aluminum Ore Company at Rosiclare, Ill. Besides these, sand plants in Pennsylvania, West Virginia, and Ohio, coal-cleaning plants in Pennsylvania, pyrophyllite, mica, feldspar, clay, and kyanite plants in North Carolina, and a zinc mill and the Tennessee Valley Authority ceramic laboratory in Tennessee were visited. The milling of industrial minerals can be considered under three broad headings, namely, crushing, grinding, and purification. Usually there is both a separation and grinding problem in treating an industrial mineral, but the problems are distinct, although sometimes a separation is made while grinding, as in the case of a Raymond throw-out mill, which grinds and at the same time throws out most of any hard material present in its feed.

Jan 1, 1939

By Matt Manson

?? Current Exploration and Assessment ?? Overview of Potential Development ?? Infrastructure ?? Opportunities and Challenges ?? Renard? 1-10 kimberlite pipes and ?Lynx-Hibou? kimberlite dyke system within ?Foxtrot? property ?? 50/50 Joint Venture between Ashton (a subsidiary of Stornoway) and SOQUEM ?? Discovered 2001-2003 ?? Québec is routinely assessed as one of the top mining jurisdictions in the world ?? Agnico-Eagle Mines Ltd. Is Stornoway?s largest shareholder and a leading mine developer in Québec

May 1, 2008

By A. D. Fisher

This paper describes the future position of metallurgical coal, particularly as applied to Canadian reserves. Quality coking coal is declining in availability, but preheating practices may alleviate this situation to some extent. Two new processes are discussed in the paper - formed coke and direct reduction - and their coal specifications are outlined.

Jan 1, 1972

By K. C. Grogan

"GeneralGIANT ORE is complex, with the gold values for the most part occurring in extremely close association with arsenopyrite, stibnite, jamesonite, and a wide group of antimonial minerals locally termed 'the grey minerals'. Pyrite is the most abundant of the sulphide minerals• and minor quantities of chalcopyrite, galena, and sphalerite also occur. Pyrrhotite has been found in some sections of the mine, but to date none of it has been nickeliferous. Native gold occurs in varying amounts throughout the ore bodies.In 1944, ore dressing investigations were commenced on diamond-drill core rejects and samples of surface outcrop ore. Results soon indicated that treatment to produce satisfactory recovery of the gold values would involve fine grinding to 80-85 per cent minus 200 mesh, recovery of free gold by jigs, followed by flotation, roasting of the flotation concentrate, and subsequent cyanidation of the calcine. Proceeding from this information, the flow-sheet was prepared, plant design worked out, equipment purchased, and construction of the treatment plant commenced in May, 1947.The crushing, grinding, and flotation units of the plant were rushed to completion and commenced operation on May 12th, l.948, at 225 tons of ore per day. This rate was maintained until January 27th, 1949, when the Allis-Chalmers roaster and cyanide plants were completed and commenced operation. During the period May 12th, 1948, to January 27th, 1949, gold recovered by amalgamation was the sole source of revenue. Flotation concentrate was stockpiled pending the completion of the Allis~Chalmers roaster and cyanide plants."

Jan 1, 1953

By Osamu Inoue, Takashi Yamashita, Takashi Ikemoto

The expansion project in Naoshima smelter and refinery to meet enhancing recycling business of E-scrap was successfully completed in 2016 to have a capacity of 110,000 tpa of E-scrap treatment. Increasing treatment of E-scrap has raised the Ni content of copper anode to 4000 ppm on average, which is double the level of 10 years ago, and to 6000 ppm or more occasionally. The tank house has refined such copper anode to copper cathode with starter sheets. Since most Ni in Copper anode dissolves in copper electrolyte, the Ni content of the electrolyte has increased to 27 g/L and more. Ni accumulated in the electrolyte has increased power consumption during the electrolytic refining of copper, although cathode quality has been controlled satisfactory so far. In order to ensure sustainable operation while growing E- scrap business, the NiSO4 process has been expanded recently so as to recover Ni in the electrolyte more and the pressurized-leaching technology will be introduced to the slime leaching process so as to enhance the capacity of slime treatment and to improve Ni recovery in the near future. INTRODUCTION In recent years, the treatment amount of E-scrap at Naoshima smelter and refinery has increased according to the growth of its recycling business as shown in Figure 1, while impurities from E-scrap have concentrated in copper anode as well. Especially, Ni content in anode has been increasing remarkably since 2012, causing to raise Ni content in the electrolyte as shown in Figure 2. The increment of Ni content in copper anode and electrolyte has adversely affected the electrorefining process, slime leaching process, and NiSO4 crystallization process at the tank house. Such severe conditions provided opportunities to redesign the tank house to establish a robust process to which more Ni is acceptable.

Jan 1, 2019

HIGH LAKE PROPERTY --HISTORYHISTORY -19501950??s ??Kennarctic Exploration discovers Exploration sulphides (A/B & (D Zones) at High Lake during helicopter reconnaissance exploration program.- -1991 93 Aber signs agreement to earn in to the High Lake Property from Kennecott. 63 holes drilled, primarily testing the known deposits. -2001 Wolfden purchases 100% interest in High Lake from Kennecott and Aber -2002 Wolfden performs helicopter borne TEM Survey over the High Lake Greenstone Belt. -2003 West Zone was discovered following UTEM & Gravity Surveys (performed by Teck Cominco ) over an airborne anomaly approx. 1km west of the known deposits. -2004 Wolfden awarded Bill Dennis Prospector of the Year

May 1, 2006

By B. K. Gorain

"As mining has evolved over a century, so are the challenges associated with mining. Mining of complex ore bodies at greater depths is a major challenge requiring high capital and operating costs due to remote locations, high energy costs, water quality and complex environmental issues. In addition, the stakeholder expectations are growing along with challenges associated with highly complex mine permitting processes and changing demographics of mining jurisdictions. The dynamic metals market adds to these challenges impacting the long term development and sustainability of mining projects.These challenges are compelling mining companies to look at various innovations with an integrated approach focusing on meeting the needs of various stakeholders. Mining companies are slowly tapping into some successful concepts that have transformed other industries such as manufacturing, chemical, pharmaceuticals along with oil and gas.This paper provides an overview of various innovations and technology developments in mineral processing that have shaped the current mining industry. A glimpse of the present and future challenges in mining is also presented. An integrated approach to problem solving involving various stakeholders is gaining momentum and this has been reflected in this paper. Various developments that are being pursed in mineral processing focusing on a change in the existing mining paradigm are also presented in this paper.INTRODUCTIONAs mining is evolving, so are the challenges associated with mining. Some of the key challenges are complex ore bodies at greater depths, high capital and operating costs, water scarcity and quality issues, high energy costs, complex environmental issues including tailings management, worldwide constraints on resource availability, more and more elaborated regulations in emerging economies impacting the permitting processes, increasing stakeholder expectations, changing demographics of mining operations with ever-changing cultural or community expectations and the urgent need for a better assessment of project viability, this in very dynamic metals markets impacting the dynamics of mining projects development and sustainability."

Jan 1, 2016

By L. H. Shang

The 319 Al-Si alloy is one of the most prominently used aluminium-based alloys in motor vehicle and engine applications, Microporosity present in 319 alloy castings reduces the load bearing capacity of the castings, The quantitative prediction of microporosity levels in Al-Si castings has been a subject of much interest for several years. In this research a new criteria function, tf 1,98 R13° (tf: local solidification time, R: cooling rate) was developed by multiple regression analyses, correlating thermal data from simulation studies to experimentally obtained microporosity values. This new criteria function gives a general prediction of microporosity in 319 Al-Si castings.

Jan 1, 2005

By J. Esson, R. A. D. Pattrick, M. K. Nimfopoulos, D. A. Polya, K. M. Michailidis

"Economic Mn-oxide ore deposits of commercial grade occur in the Rhodope massif near Kato Nevrokopi in the Drama region, Northern Greece. The Mn-oxide mineralization has developed by weathering of continental hypogene rhodochrosite-sulphide veins. The vein mineralization is con-?ned by tectonic shear zones between marble and metapelites, extending laterally into the marble astabular, pod or lenticular oreshoots (up to 50 m x 20 m x 5-10 m). Supergene oxidation of the hypogene mineralization led to the formation of in-situ residual Mn-oxide ore deposits, and secondary infills of Mn-oxide ore in embryonic and well developed karst cavities.Whole rock geochemical pro?les across mineralized zones con?rm the role of thrusts and faults as solution passageways and stress the importance of these structures in the development of hydrothermal and supergene mineralization at Kato Nevrokopi. Three zones are recognized in the in-situ supergene veins: (A) a stable zone of oxidation, where immobile elements form (or substitute in) stable oxide mineral phases, and mobile elements are leached; (B) a transitional (active) zone in which element behavior is strongly in?uenced by seasonal ?uctuations of the groundwater table and variations in pH-Eh conditions; and (C) a zone of permanent ?ooding, where variations in pH-Eh conditions are minimal. Zone (B) is considered as the source zone for the karst cavity mineralization. During weathering, meteoric waters, which were CO2-rich (PCO2~10-3.8 to 10-1.4) and oxygenated (fO2~10-17 for malachite), percolated downward within the veins, causing breakdown and dissolution of sul?des and marble, and oxidation of rhodochrosite to Mn-oxides. Karst cavity formation was favored by the high permeability along thrust zones. Dissolved Mn2+was transportedinto karst cavities in reduced meteoric waters at the beginning of weathering (pH~4-5), and as Mn(HCO3)2in slightly alkaline groundwaters during advanced weathering (pH~6-8). Mn4+-oxide precipitation took place by fO2increase in ground waters, or pH increase by continuous hydrolysis and carbonate dissolution. In the well developed karst setting, some mobility of elements occurred during and after karst ore formation in the order Na>K>Mg>Sr>Mn>As>Zn>Ba>Al>Fe>Cu>Cd>Pb."

Jan 1, 1997

By J. Esson, R. A. D. Pattrick, M. K. Nimfopoulos, D. A. Polya, K. M. Michailidis

"Abstract-Economic Mn-oxide ore deposits of commercial grade occur in the Rhodope massif near Kato Nevrokopi in the Drama region, Northern Greece. The Mn-oxide mineralization has developed by weathering of continental hypogene rhodochrosite-sulphide veins. The vein mineralization is confined by tectonic shear zones between marble and metapelites, extending laterally into the marble as tabular, pod or lenticular oreshoots (up to 50 m ?? 20 m ?? 5-10 m). Supergene oxidation of the hypogene mineralization led to the formation of in-situ residual Mn-oxide ore deposits, and secondary infills of Mn-oxide ore in embryonic and well developed karst cavities.Whole rock geochemical profiles across mineralized zones confirm the role of thrusts and faults as solution passageways and stress the importance of these structures in the development of hydrothermal and supergene mineralization at Kato Nevrokopi. Three zones are recognized in the insitu supergene veins: (A) a stable zone of oxidation, where immobile elements form (or substitute in) stable oxide mineral phases, and mobile elements are leached; (B) a transitional (active) zone in which element behavior is strongly influenced by seasonal fluctuations of the groundwater table and variations in pH-Eh conditions; and (C) a zone of permanent flooding, where variations in pH-Eh conditions are minimal. Zone (B) is considered as the source zone for the karst cavity mineralization. During weathering, meteoric waters, which were CO2-rich (PCO2 ~10-3.8 to 10-1.4) and oxygenated (fO2 ~10-17 for malachite), percolated downward within the veins, causing breakdown and dissolution of sulfides and marble, and oxidation of rhodochrosite to Mn-oxides. Karst cavity formation was favored by the high permeability along thrust zones. Dissolved Mn2+ was transported into karst cavities in reduced meteoric waters at the beginning of weathering (pH~4-5), and as Mn(HCO3)2 in slightly alkaline groundwaters during advanced weathering (pH~6-8). Mn4+-oxide precipitation took place by fO2 increase in ground waters, or pH increase by continuous hydrolysis and carbonate dissolution. In the well developed karst setting, some mobility of elements occurred during and after karst ore formation in the order Na>K>Mg>Sr>Mn>As>Zn>Ba>Al>Fe>Cu>Cd>Pb."

Jan 1, 1997

By Manjeet Chowdhry, Qingxia Liu, Phillip Choi, Zhenghe Xu

Computational chemistry methods, such as density functional theory (DFT), are powerful tools to quantify reagent-mineral interactions encountered in sulphide mineral flotation. A quantitative relationship between theoretically calculated parameters based on chemical structure of collectors and their reactivity with different metals/minerals can provide valuable insights for design and development of more powerful and tailor-made reagents offering enhanced metal/mineral selectivity. DFT calculations at B3LYP/6-311++G(3df,3pd) level were employed to elucidate the reactivity of neutral sulphide collector reagents, including thionocarbamates (TC), thioureas (TU), xanthogen-formates (XF), dialkyldithiocarbamates (DTC) and dialkyltrithiocarbonates (TTC) with different heavy metal ions (Cu2+, Zn2+ and Pb2+) in solution. The extent of delocalization of lone pair electrons of heteroatoms (attached directly to C in C=S) over C=S group was found to be the dominant factor in determining the collector’s reactivity. Order of reactivity was established as: TU > TC > XF > DTC > TTC. All the collectors showed superior affinity towards copper followed by lead. Unidentate binding was observed through sulphur atom except for xanthogen-formate for which bidentate binding mode was observed. Effect of nature of substituent groups at N and/or O atom on reactivity of thionocarbamate and thiourea was also investigated. The results obtained through DFT calculations are consistent with the experimental data reported in literature.

Jan 1, 2015

By John W. Bell

A FEW years ago the writer had the privilege of examining a piece of apparatus in the Forest Products Laboratory of McGill University which engaged his attention. The Forest Products Laboratory has an excellent installation of wood-grinding machinery, and the officials in charge were naturally interested in acquiring means for estimating the fineness of various wood grinds. The problem was referred to Dr. O. Maass ( l ). Dr. Maass designed a piece of equipment to measure the surface of a wood grind and derived an equation applicable in calculating its value, as follows : After inspecting this apparatus, the writer was disposed to believe that, with some modifications, Dr. Maass' ingenious idea might be utilized to measure the surface of mineral powders. Obviously, some difficulty would be found in maintaining an even suspension of mineral particles of high specific gravity compared to that of wood pulp. The writer will not bore the reader with a description of the various machines built and tried out. Some of these were satisfactory enough to obtain some valuable information, and to bring to light a difficulty which threatened to bring the investigation to an abrupt ending. For the mineral quartz, it was found that Kin the formula above stated was not a constant.

Jan 1, 1944

As a bubble travels through the pulp region of a flotation cell, it will collect the most hydrophobic particles of an intermediate particle size range, this being the primary source of true flotation selectivity. Despite its role on bubble-particle attachment, however, particle hydrophobicity is still missing a mathematical definition that can be used for plant simulation. In this paper, particle hydrophobicity is defined in terms of the induction time necessary for attachment and then linked to the mass of collector adsorbed per particle. This allows particle hydrophobicity to be written as a function of density of collector adsorption as well as particle size and mineralogy. The model is calibrated from the experimental measurement of the flotation rate constant. Liberation data from an industrial flotation rougher is used for model validation. It is demonstrated that the model can describe a broad experimental dataset by means of a minimal number of parameters. Main industrial application is in simulating the effect of the chemical environment upon plant metallurgical performance.

Jan 1, 2006

By James K. B. Booth

The natural crustal abundances of the principle metals of commerce are examined in relation to production and prices for each metal. Two factors, the abundance x price ratio (BP factor) and abundance/production (B/T factor) are listed for each metal. Ideally, for these desirable commercial metals, each factor should be a constant and the same for all metals; comparing the divergences for the full list of metals allows conclusions to be drawn on the relative degree of natural availability of each metal and the ease or difficulty of winning the metal from the earth's crust. Plotting the two factors for each metal over the past decade of steady industrial usage illustrates the anomalous position of copper and, to a lesser degree, molybdenum and it is concluded that over the long term the price of copper will continue to rise steeply. Possible future prices for copper are examined and a suggested preferred order of ranking of the metals as exploration targets would be copper, nickel, tin, zinc, silver, molybdenum and lead, for the near term, with molybdenum possibly increasing its ranking in the list within the next decade.

Jan 1, 1971

By C. M. Offenhauer

Abstract Zirconium markedly affects the formation of graphite in cast iron and may promote the formation of normal flake gaphite, fine flakes of eutectiform graphite, or spheroid nodular graphite, according to the composition of the Iron and the amount of the zirconium addition. Usually, it is employed in the form of a complex addition agent in order to facilitate its introduction and to guide its effect. The reported applications of zirconium as an inoculant for the production of pearlitic high-strength cast iron indicates that it is most effective as a silicon-manganese-zirconium alloy. Added in this form it reduces chill and minimizes zones of ferrite and eutectiform graphite. In low-sulphur cast iron, zirconium in amounts greater than 0.10 per cent tends to promote the development of eutectiform graphite. These irons are characterized by freedom from primary cementite or normal flake graphite and exhibit very little tendency to shrinkage on solidification. In hyper-eutectic low-sulphur cast iron, zirconium causes the formation of a partially nodular graphite structure. A combination of magnesium with silicon-zirconium alloy was found to produce completely nodular graphite structures without the hazards associated with the addition of elemental magnesium.

Jan 1, 1949