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By K. Baris

Methane (CH4) present in coal seams, generally known as Coalbed Methane (CBM), Coal Mine Methane (CMM) or Coal Seam Gas (CSG), is a major energy source, as it is the primary constituent of natural gas. At the same time, released methane is a potent greenhouse gas (GHG) and a major safety hazard in underground mining operations. Therefore, a considerable effort has been undertaken to develop coal bed methane extraction and utilization technologies that can achieve both environmental and safety benefits. Countries with significant coal reserves and gassy seams, i.e., USA, Australia, Canada, China, India, Poland and Germany have developed mature methodologies and practices to extract, before and during mining, and utilize significant amounts of methane from coal seams. Nevertheless, on a global scale, methane recovery remains untested and many technical and economic challenges require urgent attention. The research presented in this paper, sponsored by the United States Environmental Protection Agency (EPA), is focused on the Zonguldak Basin, the only hard coal region in Turkey. The basin is known to contain very gassy coal seams and consists of three major regions: Armutcuk, Zonguldak and Amasra. Among the three, the Amasra coalfield is considered as the most favorable for CBM recovery, as it comprises of deeper coal seams and where a private company, Hema Enerji A.S. (Hema) is already developing coalbed methane production facilities. This study aims at developing a reservoir model to predict the potential CBM recovery from the CBM-2 well, the only producing CBM well drilled by HEMA Enerji A.S in the Amasra coalfield. History matching was utilized to model the 15-day production data and uncertainty analysis was performed to estimate the optimum values for the reservoir parameters. The produced model yielded an average production rate of 143 m3/day for 10 years. The total amount of CH4 to be produced during this period was 0.53 million m3. Furthermore, the total amount of GHG to be avoided was estimated at 6585 tCO2e.

Aug 1, 2013

By Jack F. McQuat, Ross D. Lawrence

"Most geologists and mining engineers, in the course of their professional careers, frequently become involved with the appraisal of metalliferous mineral deposits and develop a familiarity with and standard approach to the evaluation of these deposits. When the same individuals approach the industrial mineral field, however, their usual approach pattern can be rudely disturbed.This paper highlights the difference in appraisal approach and outlines the factors common to both but which have entirely different emphasis. These comprise geological appraisal, analytical requirements, the importance of transportation, marketing requirements and standards, including appropriate allowances for product development, and marketing penetration.Out of these ""different"" considerations, however, a pat-tern or standard approach emerges which is as common to the industrial mineral field as that used either consciously or subconsciously in the metallic field.The paper reviews the different factors and points of emphasis and offers an outline of the common pattern of appraisal for industrial minerals."

Jan 1, 1971

By E. Engelbrecht

"A pressure non-oxidative leach is employed at Anglo American Platinum Base Metal Refiners to extract nickel from a slow cooled matte. The design base requires two 80 m3 autoclaves in parallel to achieve a nickel extraction of 60% at the nameplate capacity of 32.4 ktpa nickel plated. Isothermal modelling of mineralogical and chemical concentration profiles, through a reactive mass balance, permitted rate constant parameter estimation and selection of the most probable reaction pathway. The model was validated with plant data up to a capacity of 26 ktpa Ni plated and suggested by extrapolation that nameplate capacity may be viable through one 80 m3 autoclave.INTRODUCTION Anglo American Platinum Base Metal Refiners is situated on the outskirts of Rustenburg in the North-West province of South-Africa. The refinery produces nickel cathode, copper cathode, cobalt sulphate powder, covellite rich copper pressure leach residue and bulk sodium sulphate through an integrated circuit that refines slow cooled converter matte. The converter matte is milled, non-magnetics are separated as solid nickel copper matte (NCM), and the magnetics are leached yielding a pressure vessel liquor (PVL). The remaining solid platinum group metals (PGM) concentrate after leaching is sent for downstream processing in the Precious Metals Refinery (Hofirek & Kerfoot, 1992). The work presented here is applicable to the base metals refinery which receives the two base metals feed stocks NCM and PVL. In 2009 the capacity of the refinery was upgraded from 21 ktpa nickel cathode plated to 32.4 ktpa. This paper deals with evaluating the capacity of the pressurised non-oxidative nickel leach (NOX) process which accounts for at least 28% of the nickel leached from NCM by design. The NOX design base requires two 80 m3 autoclaves divided into four compartments operated in parallel at 155°C and 600kPa(g). Elevated temperature is required to speed up the leach kinetics of particularly nickel and iron which are trapped in slow leaching mineralogical phases namely millerite and bornite, (Dinham, 2006). The stated equivalent capacity for the NOX configuration was 32.9 ktpa nickel plated at first pass nickel and iron leach efficiencies of 60% and above 80% respectively and is a key step for the selective removal of iron (Bryson, Hofirek, Collins, Stiksma, & Bereaowsky, 2008)."

Jan 1, 2017

By T. Güyagüler, U. Y. Önder

"This study investigated the psychrometric properties of ventilating air in GAL coal mines. Related measurements were done in underground openings and have been arranged as input data for computer programs prepared for ventilation network and psychrometric analysis.Results obtained from network analysis have been used for psychrometric analysis of ventilating air. Changes in heat and moisture content of air in two major path s between entry and discharge of ventilating air have been investigated. Psychrometric processes occurring in the mine were determined and are shown graphically in Figures 1 and 2. Special attention has been given to determine the changes in psychrometric properties and processes involved in the faces. Results are outlined in this paper.IntroductionThe psychrometric properties of mine air are important factors to mine productivity and efficiency. Therefore, psychrometric analysis should be made for all underground mines; any undesired situation observe d could be corrected by taking the necessary precautions.The analyses were done as a case study for GAL mines, the only mechanized lignite coal mine in Turkey. In this mine, workable reserve is about 300 million tons of coal and yearly planned production is 2.2 million tons. Production is continuing from a coal measure-bed having two coal seams with average thicknesses of 1.52 m and 1.72 m respectively. A 0.85 m shale band exists between these two seams.Two full y-mechanized faces, approximately 220 m long, usually work simultaneously. All measurements, including mine gases and air velocity, are done by sensors connected to a control room by a monitoring system.In the analysis, a line diagram is utilized to described the mine on which every junction and branch is numbered."

Jan 1, 1992

By C. Cutts, K. Wheatley

The Dragon Lake Zone (uranium prospect) comprises a N160º trending vein that is approximately 110 m long, up to 5 m wide and from 1 to 40 m high. The zone is mostly within altered sandstone of the Fair Point Formation, the basal unit of the Paleoproterozoic Athabasca Group, but it also extends downward (up to 3.5 m) into basement rocks that occupy the northerly trending Maybelle River Shear Zone (MRSZ). This subvertical shear zone separates graphitic paragneiss and weakly deformed granitoid rocks to the east from non-graphitic paragneiss and foliated granitoid rocks to the west. The Dragon Lake Zone cuts across both the MRSZ and N060º-N070º-trending cross-faults that offset the shear zone but not the mineralized vein, which contains values up to 54.5% U over 50 cm core length. Strong chloritization occurs in graphitic paragneiss and sandstone adjacent to mineralization. Silica was depleted from the basement rocks and redeposited at the borders of the 5-15-m-wide alteration zone, as well as within overlying sandstone of the Manitou Falls Formation. There are minimal alteration effects in the overlying Lazenby Lake Formation. Geochemistry shows that the alteration zone in the Fair Point Formation is highly anomalous in metals, most notably in Ni, As, U, Pb, Co, and B. Clay within this zone is illitic and Fe-rich chlorite is also present. Brittle deformation is not as widespread or as well developed in the Fair Point Formation as it is in the overlying Manitou Falls Formation, which is extensively brecciated and contains some anomalous metal values.

Jan 1, 2013

By D. H. Rousell

"Rocks of the Whitewater Group (Aphebian age) oc ithin the Sudbury Basin and consist of three formations rre, from oldest to youngest: Onaping, heterolithic breccias lus an igneous-textured component; Onwatin, argillite and siltstone; and Chelmsford, greywacke with minor argillite with siltstone. Mineralization in these rocks is as follows:1) Sulphides are disseminated throughout the Onaping Formation. Pyrrhotite, the major sulphide mineral, occurs mainly as fragments; other sulphides are chalcopyrite, sphalerite, galena, pyrite and marcasite.2) Zn, Pb, Cu, Ag and A u mineralization in the Vermilion member, a carbonate-chert unit near the base of the Onwatin Formation (Vermilion and Errington mines).3) Pyrite and minor base metals in the Onwatin Formation .4) Mineralized quartz veins, located at or near the base of the Onaping Formation, include such deposits as Moore Lake (Pb, Zn and Ag), Foisey (Zn, Pb), Papineau (Cu, Au and Co) and Proulx (Pb, Zn, and Cu). Quartz-carbonate veins in a meta-gabbro sill contain Cu, Zn, As and Au. Material from quartz veins from two former ""gold mines"" (Gordon Lake and Creighton) yielded no Au values.5) Anthraxolite veins in the Onwatin Formation .The mineral occurrences can be explained in term of either the volcanic theory or meteorite-impact theory of basin formation. According to the latter theory, the sulphide fragments in the Onaping Formation may have been formed by the brecciation of sulphide-rich pods located in the upper mantle and at the base of the transient crater; some of the sulphides may have been derived from target rocks of the Huronian Supergroup. The Vermillion-Errington deposits may represent sedimentary exhalative deposits of the Remac type; mineral-rich brines, trapped at the base of the transient crater, rose upward and precipitated the mineralized carbonate-chert under reducing conditions. These conditions continued throughout the deposition of the upper Onwatin Formation but pyrite was the only sulphide that formed.The quartz veins were emplaced during the time of basin deformation. Metamorphism remobilized and concentrated carbonaceous material in the Onwatin Formation 10 form the anthraxolite veins."

Jan 1, 1984

By L. M. Amaratunga, G. G. Hein, D. N. Yaschyshyn

Fine tailings produced in the milling process have traditionally been disposed of in tailings ponds. Attempts have been made to use these fine tailings in backfill, however, to date the majority of backfill operations have utilized only a small percentage of fines. The remaining fines are, therefore, being sent to tailings ponds creating a waste disposal and environmental problem. This disposal practice is even more acute in the gold milling industry where fine grinding, required for value liberation, results in the production of large quantities of fine tailings, of which a large percentage cannot be used in backfill. Through Cold-Bond Tailings Agglomeration (CBTA), these fine tailings can be agglomerated into pellets which can then be used as a coarse aggregate in back-fill. This paper presents the results of using these pellets to create an Agglomerated Tailings Paste Fill (ATPF) made entirely of fine gold mill tailings and cementing binders. Through this process, supplementary imported aggregates such as sand, gravel, rock-chips are not required while still maintaining adequate back fill strength. By using this CBTA technology, fine tailings are diverted from tailings ponds and becomes utilized as a value added resource in the form of aggregates for use in paste fill.

Jan 1, 1997

By R. H. Duthie

As at any other mine in Canada, grade control procedures are used at Steep Rock Iron Mines (1) in order to ensure that concentrator and pellet-plant operator s have a uniform feed so that they can manufacture a pellet to suit buyers' specifications and (2) to maximize ore recovery so that as little as possible finds its way to the waste dump or is downgraded by contamination. At Steep Rock, material grading 40% to 66 % Fe is considered ore. The ore may contain up to 10% sulphur. These ranges create six different stock pile types, with the possibility of more if large concentrations of arsenic are encountered. Although grading and mining techniques used to accomplish these ends are fairly standard, there is an appreciation and willingness by hourly and staff pit personnel to make grade control effective. This produces vertical and horizontal communication, which is necessary for success in this field. At Steep Rock, the waste-to-ore ratio is greater than at any other iron ore mine in Canada. Also, a high percentage of the ore mined is direct pellet feed. For these reasons, .grade control is very important.

Jan 1, 1977

By M. F. Goudge

ROCK wool, one of the most recent additions to the list of Canadian-made, insulating materials, is a soft, light, fibrous material consisting of interlaced, flexible, glassy fibres so exceedingly fine that, individually, they are almost invisible to the naked eye and will float in air. In the process of manufacture, a suitable rock, generally a self-fluxing argillaceous dolomite consisting of nearly equal proportions of acidic and basic constituents, is melted to a completely fluid state and then converted into fibres either by a blast of steam or air, or by a mechanical device. The increase within the past five years in the number of plants in the United States making rock wool and slag wool has been remarkable, especially in view of the depressed conditions prevailing 'with most industries during this period. In 1930, there were only 8 plants reporting production of .these materials, whereas at the present time there are 44 plants in the United States listed as making these products, and there are 3 plants in Canada. In 1929, the total sales of rock-wool products in the United States amounted to-$2,377,324. In 1934, according to the National Rock and Slag Wool Association, 26 member companies reported sales of $3,695,405, and in 1935 the sale's of 30 member companies had a value of $5,571,469. The establishment of the rock-wool industry in Canada followed the publication in 1931 of a report (1) by the Mines Branch, Department of Mines, Ottawa, in which was set forth the results of field work and laboratory studies which indicated that large deposits of rock in the Niagara peninsula, hitherto regarded as valueless, were suitable for the making of rock wool. This report was supplemented in 1934 by another report (2), giving the results of further laboratory and commercial-scale tests on the rock from these particular deposits, which proved conclusively that rock wool of good quality could be made from the rock in question.

Jan 1, 1936

By Zolfan F. Oszter

As exploration for new mineral deposits advances farther into the Canadian North, the more the design engineer is faced with the problems of cold weather conditions. This is especially true when designing belt conveyor systems for open-pit operations where the temperature in the winter may go to -40°F or below. Problems with the mechanical components and also with the belting will arise, which in turn may reduce the availability of the system. This paper outlines the problems encountered during cold weather operation and what precautionary measures must be taken into consideration in the design of equipment, as well as in the selection of materials, in order to ensure a system which will maintain production. THE conveying of ore and waste in the pit or to the processing plant poses problems during cold weather, when temperatures may drop to -4o?F or be-low. Troubles with the mechanical components, the belting or the supporting structure may arise, and this, in turn, will reduce the availability of the conveying system.

Jan 1, 1965

By G. M. Ritcey, V. M. McNamara

"In the processing of gold ores by the cyanidation route, effluents which are discharged to the tailings areas can contain up to several hundred parts per million of cyanide in complex combination with similar quantities of heavy metals. Complicating this obvious problem of waste control are concentrations of thiosalts and thiocyanates which are roughly equivalent to the amounts of cyanide species. Although most gold mills are located in thinly populated areas, such contaminants can represent a potential environmental problem due to the various limitations exhibited by on-property ponding.The former Extraction Metallurgy Division of CANMET recognized the problem and, in early 1974, invited representatives of the gold mills to Ottawa to discuss the situation. At that meeting members of the Division presented a ""state of the art"" literature survey of cyanide abatement technology for waste solutions, together with preliminary cost estimate data(1). Shortly thereafter, Environment Canada, together with Environment Ontario, decided upon a guideline of 0.1 ppm (0.1 mg/l) total cyanide content as tolerable for an effluent stream which is discharged, in any manner, to the watershed."

Jan 1, 1978

By Chenming Liu, Xiao Lin, Bo Wang, Hongbin Cao, Xingang Li

Over 2 million tons of NH3-N were discharged in China per year recently, rare earth industry contributed 7.03% of NH3-N pollutant from industrial wastewater in 2007. Wastewater containing NH3-N and heavy metals mainly produced in RE extraction saponificated with ammonia and precipitated by ammonia bicarbonate. Generally, 1 ton REO cost 0.6-1.2 ton ammonia for extraction and 1.6 ton ammonia bicarbonate for precipitation, and produce 35-100 ton wastewater. Processes, like Na-saponificated, Ca-saponificated and Non-saponificated technique, are widely studied to reduce the adverse environmental effect of RE industry, while traditional processes still have advantage in production cost, process stability and product quality. In this study, a novel process that combines distillation and air-stripping is developed. NH3-N is removed and recovered based on relative volatility difference of NH3 and H2O. Phase equilibrium, heat equilibrium are calculated to determine process parameters. Hydrodynamic performance like flow field distribution is also simulated. Then, design parameters for distillation trays or structured packing are determined based on calculations and simulations. Besides, the phase diagram of (NH4)2SO4-NH4Cl-H2O in 30°C - 100°C, the typical salts composition of nonferrous wastewater, is studied to ensure commercial plants’ continuous operation. Ammonia removal tower (ART) with different high efficient column internals is designed to fit RE wastewater treatment requirement. The novel process has been commercialized in RE industry in Jiangxi, China. The commercial project operation results show the novel process reached a nearly zero-emission with >99.5% NH3-N was removed and then recovered as ammonia. Combined the novel process, the traditional REO separation process using ammonia and ammonia bicarbonate could achieve NH3-N reuse and the effluent quality meets the discharge standards.

Jan 1, 2016

By L. Mohammadi

Outline ?Background on the accident at the Sullivan Mine No.1 Waste Dump ?Holistic approach to understand the reason for accidents (Atmospheric) ?Specific hazards at reclamation sites ?Regular atmospheric risk assessment at reclamation sites ?Fuzzy risk assessment ?Managing risk at legacy sites

May 1, 2010

By J. S. De Lury

The metalliferous areas of Manitoba have been described in more or less detail. Since the descriptions were written some new prospects have come to light and considerable mining development has taken place in two or three localities. No attempt will be made in this paper to give an account of recent activities or to describe the several areas in detail. In a general way, geological conditions are similar in all metalliferous areas of the province, a similarity that invites a discussion of the prospects as a whole, the features that are common to all deposits and the reasons for their uniformity. Modern theories of metallogenesis have a direct bearing on such a discussion and an effort will be made to show their application.

Jan 1, 1925

By D. E. Salman, R. R. Maclachlan, R. J. Barclay

"There is a considerable resource of data for spherical charge cratering, both as single charges and in row-of-charge geometr(1). The data are. however, based on cratering performance to a single free planar surface.In practice. the more common circumstance involves an angular surf ace geometry. such as occurs at the toe of a bench or the wall of a stope. It is for the purpose of investigating this circumstance that the described test work was conducted.The test objectives were: (1) to observe the change in single-charge cratering performance between planesurface and angle geometry; (2) to identify the optimum performance of single charges cratering to a plane surface. cratering from a bench sub-grade position and cratering from a condition of zero sub-grade or stope wall geometry; and (3) to observe the performance of row-of-charges cratering to an angular surface at various row burials and spacing. The row charge burial and spacing dimensions were to be expressed in simple numerical multiples of single-charge depth-of-burial data."

Jan 1, 1981

By Lynne Bowen

"On the da y shift in Number One Mine at Nanaimo on Vancouver Island, on May 3, 1887, William Griffiths, a coal miner with many years experience, fired a shot to advance the face of the crosscut. A flame ran out for a distance of fifteen feet along the roof and then extended up the slope for ten to twelve feet, and although many would have called this a blowing out shot, Griffiths said it was just a feeder. ""A blower"", he said, ""would have caused an explosion."" 1There was no explosion. Griffiths reported gas and the area was cleared for three hours and then work resumed. When the shift changed at 3:00 p.m., the fireman reported all places clear of gas and the ventilation good.2The ventilation in Number One Mine was the best anyone had ever seen. The air in the mine was almost too cold. The current was so strong that it sometimes blew out the flame on the miners' fish oil lamps. It delivered five to six hundred cubic feet of air for every man and animal working in the mine. The law required only one hundred cubic feet 3The miners considered Number One to be relatively safe. The manager was proud of the mine and its up-to-date equipment"". Recently, there had been reports from France and America about the explosiveness of coal dust, but the manager did not think his mine was sufficiently dusty to be dangerous.5 The dust lay thick on the floor of the mine. Sometimes when a shot was fired the dust rose in great clouds. When a miner was shovelling it, the dust would billow up and be carried off by the current of air. The dust was also in the roof and in the stopings, put there intentionally to fill up the spaces and prevent the accumulation of methane gas."

Jan 1, 1992

By C. V. Sibbald

"This paper provides a description of the Highmont copper-molybdenum concentrator from primary crushing through grinding, flotation, tailings disposal and water reclamation. The unique features of the operation will be emphasized.IntroductionThe Highmont property is located in the southern portion of the Highland Valley adjacent to and east of Lornex and about 4 miles south of Bethlehem Copper. The plantsite is at an elevation of 5100 ft.Highmont acquired the property in 1966 and in 1969 Teck Corporation entered into an exploration agreement which contained the option to finance the property to production . A detailed feasibility study of the project was completed in 1971. A positive production decision was deferred at that time because of the prevailing soft copper market and relatively low molybdenum price. The development of a strong molybdenum market in late 1978 and early 1979 led to a re-examination of project economics, and a decision to proceed to production was made in April 1979.The Highmont ore zones occur adjacent to and on either side of an east-west-trending quartz porphyry dyke. The two major zones , the east and west pits, contain 122 million tons of ore assaying 0.27070 Cu and 0.029% Mo. Chalcopyrite, bornite and molybdenite are the minerals of economic interest. Chalcopyrite is the predominant copper mineral. Mineralization occurs primarily along fractures and is zoned according to fracture density. Some pyrite is present, but for the most part it is outside the ore zone. Surface oxidation is shallow throughout the orebody.Wright Engineers Limited were responsible for the major part of the engineering design. Site construction, which began in the spring of 1979, is under the direction of Commonwealth Construction. The first concentrator line is scheduled for completion late in 1980, the other for early in 1981."

Jan 1, 1981

By E. G. Joe

The continuing increase in costs for power and fuel are affecting significantly the cost of milling Canadian ores. In order to ascertain the scope and source of energy consumption in Canadian mills for further energy conservation opportunities, CANMET, in cooperation with the Canadian Mineral Processors, carried out a detailed survey on the metallic mineral processing plants. Sixty-seven mills representing almost 300 million tons of annual capacity participated in the survey. The results indicated that, in general, copper and iron ore mills, representing the bulk of the tonnage, consumed relatively low levels of energy per ton. Nickel-copper, zinc-copper and lead-zinc .ore mills were moderate in energy consumption, and uranium and some copper-lead-zinc mills reported much higher energy consumptions due primarily to the increased heat requirements of the ore pulp. Although plant heating costs varied somewhat with location, it was apparent that the lowest heating costs were achieved by those plants built with proper insulation and energy conservation design. If the cost per million British thermal units is taken as $2.00, the mill energy costs generally ranged from 40ft to $1.20 per ton.

Jan 1, 1979

By Fridrik J. Kristjansson, Stephen R. Hicock

"Three varieties of till are recognized in the Beardmore-Geraldton area: local lodgement till, nonlocal carbonate till, and local supraglacial till. The local lodgement till unit is examined in detail for the first time in this paper. It is the best potential overburden exploration medium for gold and other metals because its particles were locally-derived and deposited subglacially, probably within a few kilometres downglacier (southwestward) from their sources, and have not been diluted by distantly-derived glacialdebris. Both local tills are richer in gold and other metals, relative to nonlocal carbonate till. Local lodgement till rests on bedrock and was encountered frequently at or near the surface in thin drift/bedrock terrain (a widespread terrain type within the west half of the study area), and commonly at the base of boreholes in thick till terrain.INTRODUCTIONDrift prospecting in areas of glaciated terrain has been well documented (in a variety of journal publications and symposium volumes; e.g . Strobel and Faure 1987; MacDonald and Mills 1988) and has proven valuable especially where overburden thicknesses hinder traditional exploration techniques. Drift prospecting techniques may well prove valuable in the Beardmore Geraldton area. This applies especially to the Wildgoose Lake Turkey Lake area where a thick and laterally extensive sheet of nonlocal carbonate till has impeded conventional mineral exploration programs (Fig. I; note the lack of gold occurrences around Wildgoose Lake).Till in .particular has been cited as the best prospecting medium among the various types of glacial sediment (e.g. Shilts 1984). Three end member till varieties are recognized in the study area: (I) local lodgement till which rests directly on bedrock; (2) non local carbonate till; and (3) local supraglacial till which occurs predominatly within, or just downglacier of, upland areas where it commonly mantles the other till varieties. Previous authors have documented how the non local carbonate till hinders gold exploration (Geddes and Kristjansson 1986; Karrow and Geddes 1987; Kristjansson 1986; Hicock 1986, 1987a, b, 1988; Kristjansson and Thorieifson 1987; Thorleifson and Kristjansson 1987, 1988a, b) and why the local supraglacial till may be a good unit for prospecting (Hicock 1986). One detailed surficial geology map sheet of the area has been published (Kristjansson et al., 1988) and others are in preparation. Closs and Sado (1981) reported on the geochemistry of soils and glacial sediments in the west half of the study area. This paper documents the local lodgement till unit and demonstrates why it is the best overburden unit to use for drift prospecting."

Jan 1, 1989

By Ali M. Ghazi, Ronald J. Goble, Lowell S. Whiteside

"Geerite (Cu1.6S) is a rhombohedral copper sulphide which occurs naturally in epitactic replacement of sphalerite; cell dimensions closely approximate those of the host sphalerite.Geerite-type structures can be produced by leaching digenite (Cu1.8S) in ferric sulphate solutions. X -ray diffract ion and electron microprobe studies indicate that eight metastable geeritetype structures can be produced, depending upon the concentration of f erric sulphate solution used and the duration of the each. Although compositions cluster on or near values observed for natural phases, optical properties indicate that we are dealing with polymorphs of these phases. Leaching of chalcocite (CU2Sj in dilute f erric sulphate solutions produces similar results. In contrast, leaching of chalcocite in more concentrated solutions seems to produce true analogues of natural minerals.During froth flotation, sphalerite is activated with a monolayer of floatable copper sulphide with the composition, CuS, of the mineral covellite. However, covellite is not significantly more floatable than sphalerite, and has an incompatible structure because of the presence of covalently-bonded atoms of sulphur. Leaching ofdigenite was used to produce a polymorph of covellite with a geerite-type structure, compatible with that of sphalerite. This polymorph has a flotational behaviour similar to copper-activated sphalerite, suggesting that the monolayer has a geerite-type CuS structure. IntroductionIn an ideal close-packed sulphide structure the distance between sulphur layers, D, is equal to 2R 2/3, where R is the radius of the sulphur atoms. In sulphides with covalently-bonded sulphur layers, such as covellite (Fig. I), D will be an average of the number of covalentl y-bonded and close-packed sulphur layers, weighted as to the relative number of each type of layer. Both D and R are spacings which are readily identifiable structurally and on X-ray diffraction patterns. Goblel has shown that for copper-iron sulphides with metal-to-sulphur ratios between 0 and 2 and copper-to-total metal ratio s between 113 and I there are strong correlations between composition and measured D and R distances (Fig. 2). D can be represented by a single empirical equation relating interlayer spacing to composition; R must be represented by three equations relating the radius of sulphur atoms to composition. One of these equations (R, in Fig. 2) represents ideal close-packed behaviour, the other two represent sulphur radii greater than (R1) or less than (Rh) the ideal."

Jan 1, 1988