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By M Hino, D R. Swinbourne

The thermodynamic properties of arsenic in metal, speiss, matte, slag and gas phases are first summarised in this paper. Arsenic associates with sulphide minerals and generally has compounds of high volatility, but it has a weak affinity for sulphur and a strong affinity for metals, especially copper and iron. In the initial stage of the oxidation of sulphide concentrates arsenic is volatilised easily prior to the oxidation of FeS, although it tends to be fixed in the condensed phase as FeAsO4 if the concentrate is over-oxidised. Thermodynamic simulation of oxidative copper smelting reveals the distribution of arsenic between matte, slag and gas, and the possibility of condensation of arsenic from the resulting waste gas is discussed. In reductive smelting more arsenic remains in the metal or matte, and is sometimes concentrated as a separate speiss phase. The phase relations and thermodynamic properties of speiss are also summarised briefly. Arsenic refining from smelted copper metal is shown, from an examination of the basic principles of arsenic removal into slags, to be difficult. Owing to its weak affinity for lead however, arsenic refining from lead bullion is seen to be much easier.

Jan 1, 2000

By Haigh C. J

A process has been developed to recover at least 75% of the 2-naphthol contained in cobalt precipitate produced during the removal of cobalt from electrolytic zinc plant solution. The recovered material is in a form suitable for recycling to precipitate further cobalt from solution. The process consists essentially of two steps. The first involves leaching of cobalt precipitate in 400 g/l sodium hydroxide solution at 95¦C in the presence of an additive. The second step involves treating the filtrate from the leaching stage with sodium sulphide to precipitate cobalt as the sulphide thereby re- generating the sodium hydroxide for recycling. The process is only marginally profitable at present 2-naphthol prices, giving a net return of 20% on a capital investment of $1 200 000. A reaction mechanism is proposed which accounts for the 25% loss of the 2-naphthol in the recovery process.

Jan 1, 1977

The treatment of beach sands in'' the Bunbury/Capel' area for the extraction of ilmenite is a very recent development in the mining industry in'J7estern Australia. Nevertheless since the commencement of production in 1956, ilmenite has become the sixth most important mineral produced. The increasing world recognition of W.A. as a major' Iiroducer of ilmenite is due primarily ' to its low chromic oxide. ; (Cr203 content,, 0,03% to 0.04%, combined with a medium to high grade TiO2 content, 54% - 6 , supported by large reserves, a'. stable government with close access to good shipping facilities.. Ilmenite is produced from-these deposits at low-costs, enabling the industry to compete on world markets despite high rates for sea freights because of the distance from.major markets.

Jan 1, 1964

By R Sharpe, M D. Hannington, K Perrin, K Simpson, S Petersen, H Gibson, N Augustin, K Lackschewitz, T Monecke

Semi-massive to massive sulfides were drilled in a shallow-water (630 m) hydrothermal system in an island arc volcanic setting at the Palinuro volcanic complex in the Tyrrhenian Sea,Italy. Overall 12.7 m of sulfide minerlisation were drilled in a sediment-filled depression in a water depth of 630 - 650 m using the lander-type Rockdrill 1 drill rig of the British Geological Survey. The longest drill core recovered consists of 4.9 m of continues semi-massive to massive sulfides + sulfates with abundant late native sulfur overprint. Metal enrichment at the top of the deposit is evident in some cores with polymetallic (Zn, Pb, Sb, As, Ag) sulfides overlying more massive and dense pyritic ore. The massive sulfide mineralisation at the Palinuro volcanic complex contains a number of unusual minerals, including enargitefamatinite, tennantite-tetrahedrite, stibnite, bismuthinite and Ag-sulfosalts, that are not commonly encountered in mid-ocean ridge massive sulfides. In analogy to epithermal deposits forming on land, the occurrence of these minerals and the abundance of native sulfur suggest an intermediate to high sulfidation state for the hydrothermal fluids during deposition, implying that the mineralising fluids were acidic and oxidised rather than near-neutral and reduced as those forming typical base metal-rich massive sulfides along mid-ocean ridges. Oxidised conditions during sulfide deposition are likely related to the presence of magmatic volatiles in the mineralising fluids that were derived from a degassing magma chamber below Palinuro volcanic complex. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Chappell BW

A zone of northwest trending dykes extends for over 600 km in the hinterland from Cairns to Mackay. In sate regions the zone is up to 120 km wide. Figure 1 shows their approximate extent, compiled from published regional maps and from specific studies in more limited areas : Palm Islands, Cardwell Ranges, Jourama Falls, Townsville area and Burdekin Delta. The context of the dyke swarm is the Tasman Orogenic Zone, the region of Eastern Australia conprised of Palaeozoic metamorphic, sedimentary, volcanic and plutonic rocks which has experienced a complex history and evolution. In the Whitsunday region, the Tam-an Zone also involves Cretaceous volcanism and plutonism. Geological relationships indicated a wide span of ages for the intrusions in the dyke, swarm zone. They intrude a range of volcanic and sedimentary rocks, and in some areas plutonic rocks. Older dykes, apparently part of the same regional swarm are intruded by sate of the granites.

Jan 1, 1987

THE alkaline method for the estimation of zinc cannot, in the writer's opinion, be relied. upon to within very narrow limits between two assayers on unknown quantities of zinc. The end point is not decisive enough, and allows the personal factor toenter largely into the assay. The following investigation was undertaken to see how accurate the acid method is on Broken Hill concentrates and ores, and what should be the limit between the results of two assayers. The method adopted is as follows:Weigh sufficient amount of ore to give titration (between 20 and 50 cc.), place in tall 400 cc. beaker, cover, add 7 cc. nitric acid and heat till brown fumes cease to be evolved. Wash dock glass into assay, add potassium chlorate, evaporate to dryness on a slow fire with the beaker uncovered. When no smell of chlorine or nitric acid is observed, remove and cool. Add 100 cc. boiling water, then 7 grm. ammonium chloride, W cc. ammonia (.880 sp. gr.), boil for five minutes, filter, wash...

Jan 1, 1911

One of primary causes of poor blast performance is the improper relief of explosive energy. Under or over-confined blasts modify the explosiveÆs path of least resistance, which changes where and when the explosive energy is applied resulting in less than optimum blast performance. During the research for this paper the overbreak characteristics of five full-scale blasts were quantified using high speed cinematography and borehole cameras. The effectiveness of various overbreak control methods was also evaluated to guide design refinement. The results of this research along with general recommendations for reducing excessive damage are included with this paper.

Jan 1, 1999

By Graham JW, Cullen GV

edicted increase in, Aluminium production and the possibility of a diminishing supply of petroleum coke for anode electrodes in alumina reduction cells makes it desirable to find alternative electrode materials. Brown coal char, with a lower ash content and with an elemental purity similar to petroleum coke, has been produced by leaching in hydrochloric acid, washing with water and charring at 115000. The cost of processing is estimated to be competitive with petroleum coke. Without further processing the bulk density and real density were undesirably low, but. by briquetting the coal before charring and crushing, the bulk density was improved to 92 per cent of the petroleum coke value and the Particle density was improved to 92 per cent of the density of petroleum coke by water-displacement or 75 per cent by mercury displacement. Pre-baked electrodes were prepared from the char alone, mixtures of petroleum coke and char and from petroleum coke alone, all bonded with coal tar pitch. The electrodes were tested for the usual physical properties and were, evaluated for performance in a laboratory size alumina reduction cell. Electrodes based on brown coal char alone were found to be inferior in physical properties, and performance, but mixtures of the char and petroleum coke, despite poorer density, electrical resistivity and carbon consumption on a theoretical basis, in performance tests gave up to 17 per cent better carbon consumption per weight of aluminium produced and 21 percent better electrical current efficiency than the electrodes based on petroleum coke alone. It is suggested that larger scale tests are warranted.

Jan 1, 1970

A considerable debate has arisen regarding the best route for the beneficiation of iron ore. Supporters of jigging technology claim that although the technology is old, due to recent advances in jig control and a better understanding of the separation processes within jigs, it offers significant advantages over dense medium separation, especially in terms of reduced capital and operating costs and simplicity of design. Supporters of dense medium separation claim that this technology is proven to provide the best possible separation and that the gain in efficiency over the life of the plant, compared to that of a jig, will more than offset any differences in capital or operating costs. The truth is that both viewpoints are valid and that the choice is ultimately determined by specific characteristics of the ore being treated. Factors that need to be taken into account in deciding upon the correct option include the size/density distribution of the ore to be treated, the different size fractions which must be treated (lumpy or fines), differences in yield at grade, plant layout and capital and operating costs. Each of these factors will be discussed in detail and a case study for both lumpy and fines will be presented.

Jan 1, 2007

By Abraham B. K, Jensen B, Gillies A. D S

The aim of the research was to investigate the feasibility of using an impedance cell and ratio-transformer bridge to measure solids content in coal slurry pipelines. It appeared that this technique could be developed to measure variations in conductance which correlate with solids content. Successful implementation of the measurement technique would have a variety of applications in existing coal wash plants and the potential for automatic process control. A small pilot plant was designed for a feasibility study. This was a closed loop system in which the coal was uniformly dispersed in a tank with a variable speed agitator and then circulated through an external pipe returning to the top of the tank. The impedance cell was located near the end of the external pipe. Slurry concentrations were varied from clean tap water to 50 per cent solids by weight with the addition of weighed quantities of dry coal dust. Ratio-transformer bridge measurements showed that variations in individual observations were equivalent to measurement errors of about two per cent. These probably reflect variations in concentration of the mixture in the pipe. Data for increments in concentration of one per cent indicate that this is about the limit of resolution of the current system. The paper discusses the principles of operation of the impedance cell and measurement system. Results from the pilot study and proposed improvements in the impedance cell design are examined.

Jan 1, 1995

The accurate calculation of ore reserves is one of the most important functions under- taken at a potential or operating mine. In recent years there has been a trend towards recommending more and more complex techniques for the calculation of reserves. However these are not always necessary and many improvements could be made by the use of all potential data and a heavier geological input. An ore reserve should be the result of geological not mathe- matical or engineering reasoning. All ore reserve estimates are wrong and the important thing is to.recognise why they-are wrong and to take action to minimize the errors. Geostatistics and other complex mathematical techniques may appear to answer all our needs for ore reserve accuracy but there are many drawbacks, not least of which is the communi- cation gap which may develop between the operator and both management and production Personnel.

Jan 1, 1979

An empirical kinetic model is discussed that enables the number of stages in a carbon-in-pulp plant and the amount of carbon in each stage to be calculated for any desired metallurgical performance. It is shown that a knowledge of the kinetics of gold extraction by activated carbon in each stage assists plant operators in the important' areas of process control and optimization. Factors such as mixing efficiency, concentration and distribution of carbon through the plant, bypassing of pulp through a stage, and carbon poisoning are examined. The resin-in-pulp process for the extraction of gold cyanide is also discussed, and the chemistry of absorption and elution on strong- and weak-base resins is examined. In addition, operating results from a small-scale resin-in-pulp pilot plant are presented, and various applications in which resin-in-pulp may be preferable to carbon-in-pulp are discussed.

Jan 1, 1982

By Rynn J. M W, Paynter A

Recent studies by the authors have concerned themselves with assessing the earthquake risk to north-eastern Australia, based on available historical earthquake data for the area. There have been several significant earthquakes (Richter local magnitudes of the order of 6) concentrated in the Wide Bay - Burnett region in central eastern Queensland, although none of these has occurred close to a significant centre of population or development. Using derived average acceleration attenuation relations and world-wide data on earthquake-induced damage as a basis, conditions under which earthquake-induced liquefaction may occur have been investigated and presented in graphical form. Historical earthquake data for north-eastern Australia have been overlain on this graphical presentation and it has been demonstrated that the Wide Bay - Burnett region, in particular, may in the past have been on the verge of earthquake-induced liquefaction, where ground conditions are susceptible. When this is viewed in the context of the rapid growth in population and development in this area over recent years, the risk can no longer be ignored with impunity.

Jan 1, 1990

By D Hodson

Current classification of resources is entirely a subjective task. The various international reporting codes (such as the JORC Code) provide Competent Persons and practitioners with little specific guidance on the standard of work and levels of uncertainty required to classify resources into Measured, Indicated and Inferred. Furthermore, little guidance is given in the conversion of Resources to Reserves and the potential impacts on classification of uncertainties in the modifying factors. Working back from the intended use of the resource estimates, and in understanding the tolerance for uncertainty by the end user of such estimates, insights into the objective and requirements of classification can be determined. Following this approach a comprehensive set of (quantitative where possible) guidelines have been determined that will ensure resources meet the desired objective of each classification, and are consistent and comparable. The guidelines look at what is required for each step in the resource estimation process in order to ensure the final resource estimate meets the desired level of confidence. This approach provides a transparent, comprehensive, justifiable and largely objective method of classification. The implication of introducing such a guideline or approach is to highlight areas of a resource estimation that do not meet the requirements (ie drive the uncertainty beyond the objective) and then focus in on the risks that may flow on from that particular uncertainty, to mitigate or attempt to control those risks.

Jan 1, 2006

By R Dunne, D Yan

In flotation where a bulk flotation concentrate is produced or a gangue sulfide such as pyrite contaminates a concentrate, residual collector has to be removed from the sulfide surfaces to allow selective separation in a subsequent flotation step. Depending on the sulfide mineral, the main species that needs to be removed when using a xanthate collector is either a metal xanthate or dixanthogen. For the identification of surface species, specific solvents may be used to remove each species û metal xanthates are known to be soluble in acetone whilst dixanthogens are known to be soluble in non-polar solvents such as diethyl ether. Xanthates break down with time, temperature and pH into various decomposition products. The major decomposition product is dixanthogen which can aid flotation but other products such as perxanthate and carbon disulfide can have an adverse effect on flotation. Various analytical techniques can be employed to monitor the formation of decomposition products on the surface of the mineral and in solution. The best of these is ultraviolet spectroscopy as it has diagnostic peaks for decomposition product determination. In this work two approaches were taken to understand the relationship between the flotation of a chalcopyrite and pyrite from an ore containing these two minerals. One approach was to remove the xanthate species with an organic solvent and then use ultraviolet spectroscopy to determine the concentration of dissolved species. The second method involved measuring xanthate decomposition in solution by measuring the residual xanthate concentration using ultraviolet spectroscopy. These experiments confirmed the species adsorb at the surface of the mineral and how these species affect the recovery and grade of the valuable mineral. In both cases pH and temperature were varied and two xanthate collectors (SEX and PAX) were used to study these relationships. These relationships could be applied to industrial flotation systems and allow for more accurate determination of optimal xanthate dosage and hence save on reagent costs.

Jan 1, 2005

This paper summarises some observations regarding the way SAG and AG mills work based on the last ten years of pilot plant operation, grinding circuit design and operational reviews for various projects in Australia and overseas. The main purpose is to promote discussion on key factors influencing breakage in a SAG mill. The focus of the paper is on two questions: How do mill lifters and liners really work and have an effect on grinding? How does the mill charge composition impact on grinding performance? The focus of the paper is on observations of mill behaviour in both pilot plant trials and plant operation, particularly on Cadia ore. DEM, by others, and JKSimMet modelling of SAG mill performance have greatly assisted in forming the ideas expressed in the paper and both are valuable tools in developing our understanding of the comminution process. Put in the æextremeÆ form the major observations and conclusions expressed in this paper are that: the main purpose of mill lifters is to reduce mill liner wear and not to promote rock breakage; the often promoted theory that balls impacting the ætoe of the chargeÆ is a dominant form of breakage is incorrect; and fines production in a SAG mill is primarily a function of the rock load mass, with a secondary dependence on ball load for any given circuit configuration.

Jan 1, 2007

By T

THE Sulphide Corporation's works for the smelting of ores containing lead, gold, and silver are situated close to the Cockle Creek railway station, on the main Northern railway line, and are about 95 miles from Sydney and 10 miles from Newcastle. A branch line runs to the works, and siding accommodation and bins are provided for expeditiously handling all ores sent for treatment. The Corporation also possesses wharfage facilities at the port of Newcastle, where consignments of ores arriving by sea can be handled direct into railway trucks for conveyance to the works.The greater portion of the ore treated at Cockle Creek comes from the Corporation's mine at Broken Hill, but a large quantity of other grades is also purchased and treated.

Jan 1, 1918

By Visnovsky

The computing needs of a mine planning office vary greatly depending on the staff available and the nature of the work undertaken. Some offices work acceptably with few aids apart from hand held calculators while others use mainframe computers with associated data bases and sophisticated mine planning software. Not every mine planning office requires the big system approach but all can benefit from the intelligent use of small computers. There is virtually no limit to the design problems which can be solved using modern desktop computers. The simple language required encourages engineers to work interactively to facilitate both large and small computations. However a limit does exist in the speed and ease with which solutions can be obtained. The important ingredients for the successful application of such machines are a little computing knowledge, a flexible machine, and an engineer who really understands the mining problems confronting him. If these are available it is possible for the engineer to tailor the program to the task at hand and efficiently achieve the required result.

Jan 1, 1983

The firing of mass blasts at Isa Mine is a normal operating practice. Both electric and non-electric initiating systems are being used for this purpose. The advantages gained by large firings relate to the Planning, Scheduling, Services and Production functions of Isa Mine. More efficient us"e is made of manpower due to the concentrated charging effort and con- tinuity of the charging operation. In addition, the requirement for ring firing personnel to work at the edge of large stope voids is reduced. Better fragmentation results from the interaction of adjacent detonating rings of blastholes and in flight collisions. With mass blasts there is also less chance of large blocks of ore, created by faults or joints, falling into the stope and creating problems at the drawpoints. The formation of a large tonnage of broken ore facilitates production at scheduled rates from that stope source. The weight of explosive detonating during a mass blast can be considerable. Isa Mine has achieved satisfactory blasting results without excessive ground vibration levels and present knowledge indicates that pillar ground stab- ility has been maintained.

Jan 1, 1978

By Dundon P

The Broken Hill Proprietary Company Limited (BHP) is Australia's largest company with widespread commercial interests ranging from steel productin to minerals, oil and gas recovery. While these interests are worldwide, the Company operates or is partner in more than 30 Australian mining ventures. BHP Engineering (BHPE) is the in-house consultant to BHP but is also the largest consultancy in Australia available to general industry. Australian Groundwater Consultants Pty Limited (AGC) is a large, independent consultancy offering specialist services in all aspects of water resources, waste management and environmental engineering, both in Australia and overseas. AGC is particularly well regarded within the mining industry and has a considerable record of providing solutions for mine water related issues. By drawing on the extensive combined experience of AGC and BHP Engineering, this paper will summarize some of the unique ways in which water interacts with and impacts on mining operations in Australia, particularly in matters such as: Slope Stability Drainage and Dewatering Production Cost (Transport, Drilling, Blasting, etc) Water Supply Water Management Tailings and Waste Management Environmental Issues. The paper will also illustrate the cost benefit of providing major engineering works for reduction in total mining cost. It will be shown that, through advance planning and close interaction between outside experts (ie consultants) and on- site personnel, very significant operational cost savings can be made while at the same time achieving a safe and responsible mining environment.

Jan 1, 1988