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By W A. Ducker, R-H Yoon, M Mao

Froth flotation relies on an attractive force between a particle and a bubble to selectively extract particles from a mixture. The range and magnitude of this attractive force is an area of ongoing investigation. We describe measurements of the effect of dissolved gases on the long-range attractive surface forces between a silica plate and a glass sphere in aqueous octadecyltrimethylammonium chloride (C18TACl) solutions. The measurements follow on the work of Sakamoto et al (2002) who have concluded that long-range interactions occur in air-equilibrated surfactant solutions but not in degassed solutions. In the present work, we have measured attractive forces that have a much larger in magnitude than the expected van der Waals force in solutions that were degassed by the same procedure used by Sakamoto et al (2002). We find that the forces are most attractive at 5 + 10-6 M C18TACl, which is close to the charge compensation point (ccp) of the glass sphere. At this concentration, the attractive force decays exponentially with distance and the decay length is 34 in air-saturated solution, and 38 nm in degassed solutions. In both air-equilibrated and degassed solution, the force is quite sensitive to the concentration of surfactant. The force is also sensitive to the pH. We note that our degassing procedure increases the pH of the solution from about 5.7 to 6.6 (presumably by removal of dissolved CO2). We find that the forces measured in degassed solution can be reproduced by using a solution that was equilibrated in air, then the pH was increased by addition of NaOH. Therefore, we conclude that the main effect of degassing in our experiments is to raise the pH. We show that the range and magnitude of the attractive force decreases in the presence of salt (NaCl). This suggests an electrostatic mechanism for the attraction. Possible mechanisms for the attractive force are examined, including the mechanisms that rely on a patchy coverage of surfactant on the silica surface.

Jan 1, 2005

By Marwick PL

As part of its operations Hamersley Iron operates a heavy medium Concentrator to upgrade low grade, unsaleable iron ore to produce saleable lump and fines products. Firstly, the attempts at delivering a blended feed in both chemical and physical characteristics are presented. Improvements in blending controls are shown to have given process performance improvements. Secondly, improvements to the feed preparation section are detailed. These alterations are providing a much cleaner feed to the subsequent processing stages.

Jan 1, 1987

Twenty years of effort in developing the use of computers in the design and control of mineral treatment circuits has resulted in a sound base for future widespread application of the techniques.. The intent of this paper is to speculate to some extent about future applications of computer related techniques in the mineral extraction industries. The use of simulation methods for the analysis and design of circuits is discussed. In the area of process control, computers have been largely devoted to process monitoring and reporting tasks. The application of computers for the total control and optimization of complete plants is considered. Finally, the role of computer based modelling studies for definitions of optimum treatment flowsheets is suggested.

Jan 1, 1985

A wide variety of process streams are sampled for grade control in the mining industry. However, in many instances the overall precision of the resultant analyses is inadequate for the intended purpose, ie grade control and optimisation of resource utilisation. Consequently, special attention needs to be given to the sampling, sample preparation and analysis procedures in place to ensure that meaningful grade control decisions can be made based on the analyses generated. For example, it is virtually impossible to control a process to within, say, ¦0.2 per cent if the overall precision of the analyses is no better than 0.5 per cent. Hence, precision targets appropriate for the task need to be established and the overall precision achieved in practice monitored and controlled on an ongoing basis.

Jan 1, 2008

By Williams DJ, Battino S

The rapid crushing technique for the measurement of gas content of coal consists of accelerating the rate of gas desorption from coal by crushing. This technique allows the determination of gas content in the space of hours rather than days or weeks as required for the traditional slow desorption technique. The crushing technique is used particularly when gas content determinations are urgently required for mine safety purposes. The method is now routinely used in underground coal mines of NSW and to a lesser extent in QLD. Despite the rapidity and efficiency of this method, concerns have been raised upon the reliability of the method to deliver accurate results. Experience in Australia has shown that there is in fact some discrepancy in results between gas laboratories using the rapid crush technique. The development of rapid crushing techniques for seam gas content measurements in Australia and the main causes of variability in the gas content test results were investigated. The gas laboratories participating in the gas content testing were CSIRO Division of Coal and Energy, BHP Technical Services and GeoGas Pty. Ltd.

Jan 1, 1998

The Argyle AK1 Pit has been operating and producing over 25 per cent of the worldÆs diamonds by volume for over 20 years. The mining boom in Western Australia is creating upward cost pressures to ArgyleÆs mining operation while the price received for its product remains flat in comparison to many other Western Australian commodities. This incongruity, which when combined with other circumstances such as the pit being close to the end of its mine life, a decline in head grades and a tightening in operational constraints caused by the pitÆs maturity, is causing the leadership team at the mine to utilise innovative strategies in order to ensure that the open pit continues to perform economically until its final closure in late 2010. The strategies that will be discussed in this paper are step change business improvement methods, localisation of the workforce, employment of Aboriginal people and the use of a clear and concise consultation process in order to provide certainty to a workforce working in a pit during boom times where pit closure is imminent.

Jan 1, 2007

In a previous paper in these Proceedings(l) it was shown from a study of the bore'logs and analyses then available, that the brown coal seams of the Latrobe Valley areas show progressive changes in composition with increase of stratigraphic depth, equivalent to a rise in rank: These changes appear as:(i) An increase in ultimate carbon and hydrogen, calculated on a dry, ash-free basis, and(ii) An increase in calorific value, calculated on the, same basis, each of the order of 1% per 100 ft. of depth, and(iii) A decrease in moisture content of the order of 0.5% to 1.0% per 100 ft. of depth. The decrease in moisture content was found to be less regular than the other changes. In some bores the moisture content remained more or less constant throughout a single seam, or fluctuated slightly, decreasing stepwise on passage to the seam below.It was noted that individual analyses within a bore showed irregular fluctuations, tending to mask the general trend in composition change. This was particularly so for the moisture content, which had been determined for 10 ft. lengths of core, whereas the other components were determined for 50 ft. lengths of core. Averaging of the moisture contents over 50 ft. lengths reduced the masking effects of these irregularities. The suggestion was made that these irregularities arose from variations in the relative proportions of pollen, resin, wood (lignite) and woody attritus composing the core. Such variation in the coal seams has since been established in some detail for the...

Jan 1, 1948

Utah's Blackwater mine began operations in 1967. The four CQCA mines controlled by Utah followed over the period 1971 to 1979. Project feasibility studies for all these were based on open cut mining to overburden depths of 60 metres, with typical project lives of 12 to 16 years, depending on reserves Further studies, initiated after the mines had started, showed that continuation of open cut mining beyond the 60 metre highwall was viable. In 1973, the Deep Stripping Project (DSP) was launched to define the scope for stripping deeper, to determine what the additional equipment needs might be, and to pu forward proposals for a full scale trial system. The project commenced at grass roots with a literature survey, proceeded through a sequence of equipment evaluation, specification, design and manufacture to the commissioning of the Goonyella BWE system. Studies are continuing to assess the future deep stripping requirements for all Utah's Bowen Basin mines.

Jan 1, 1983

By Mingmin Dou

The behaviour and deportment of indium during the precipitation of sodium jarosite from Fe2(S04)3 - Na2SO4 solutions were investigated. Indium is readily precipitated with sodium jarosite, and the extent of In precipitation increases as the In concentration of the solution increases. It was shown that In 3+ substitutes for Fe 3+ in the jarosite structure to form a nearly ideal solid solution series. On a molar basis, the precipitation of Fe is slightly favoured over that of In, and the difference is reduced as the pH increases. Sodium jarosite precipitation becomes kinetically rapid at temperatures >70¦C, but increasing temperatures in the range 70 to 150¦C affect neither the relative precipitation of In and Fe nor the composition of the jarosite product. Low Na2SO4 concentrations result in reduced product yields and jarosite precipitates in which H3O' > Na+. The hydronium-rich precipitates have reduced In contents. Increasing the ZnSO4 concentration of the solution slightly increases the quantity of jarosite formed and results in the incorporation of -0.3 per cent Zn in the jarosite structure. Otherwise, the presence of ZnSO4 has no significant effect on the composition of the jarosite. Seeding accelerates the rate of jarosite precipitation but has a negligible influence on the deportment of In. The jarosite precipitation reaction at 98¦C is relatively rapid and near-steady state conditions are achieved in - 6 h even in the absence of seed. The initially precipitated jarosite is slightly enriched in In with respect to Fe. The ferric ion concentration of the solution has a significant influence on both the amount of jarosite formed and its composition. In particular, the jarosites precipitated from dilute Fe3+ media have significantly enhanced In contents. Hence, it may be possible to recover - 25 per cent of the dissolved In, at the 1000 mg/L level, in a jarosite precipitate assaying - ten per cent In by the controlled oxidation-precipitation of sodium jarosite from a ferrous sulphate processing solution.

Jan 1, 1993

This paper deals briefly with the geology and mineralisation of the Ediacara Mineral Field, which is located about 300 miles north of Adelaide in the Mount James Range.The field was discovered sane time prior to 1872. Total recorded production for the field amounts to a few hundred tons of lead and 36 tons of copper. Re-listing of the field during 1961-62 led to its classification as a Mississippi Valley type deposit. Diamond drilling has partly outlined the spread of mineralisation and confirmed its stratiform distribution,Sources for the metals are suggested and various possible mechanisms. of deposition are described.

Jan 1, 1963

By E R. Ramanaidou, M S. Piggott

Transport to and handling of iron ore at Port Hedland, Western Australia, results in the generation of airborne particulates that contribute to the atmospheric dust load, with concerns about potential local environmental impacts (eg mangrove swamps) and possible human health implications. Mineral and chemical characteristics of the Background soil samples were contaminated with particles of iron ore as martite octahedra and grains of micro-platy hematite as detected by scanning electron microscopy (SEM) in the 2.5 - 10 ¦m and 10 - 50 ¦m size fractions. Fossilized wood fragments similar to those observed in Yandicoogina fines ore were also detected in some background soil samples. With a predicted increase in demand of channel iron deposits (CID) ores and the inherently dusty Marra Mamba ores (eg West Angelas, MAC, OB29/30/35, Marandoo), in conjunction with particulate emissions from hot-briquetted iron and direct reduced iron (HBI/DRI) processing plants, there is the potential for additional sources of anthropogenic dust to contribute to background levels. Mineralogical and chemical characterisation of the entire range of particulates that could be produced is necessary for a complete understanding of their potential impact on the local environment.

Jan 1, 2002

By D Jordan, R Wilmoth, J LeFever

Exposed, open pit mine highwalls contribute significantly to the production of acid mine drainage (AMD) thus causing environmental concerns upon closure of an operating mine. Four innovative technologies were evaluated under the US Environmental Protection AgencyÆs, Mine Waste Technology (MWTP), Prevention of AMD Generation from Open Pit Highwalls Demonstration Project. This project is funded by the US Environmental Protection Agency (EPA) and jointly administered by the EPA and the US Department of Energy (DOE) through an Interagency Agreement. The objective of the field demonstration was to evaluate the technologies ability to decrease or eliminate acid generation from treated areas of the highwall in comparison an untreated highwall area. The field demonstration was performed at the Golden Sunlight Mine (GSM) a subsidiary of Placer Dome US, located near Whitehall, Montana. GSM is an operating gold mine. The highwall at GSM was divided into five plots measuring 15.24 by 15.24 m and each technology was assigned a plot with the fifth plot being used for comparison as a background control plot. The four technologies were spray-applied. The applied in situ treatment technologies included: a modified, furfuryl alcohol resin sealant, utilising wood and agricultural by-products to coat the rock surface; EcobondTM ARD, a phosphate based process that forms a stable, insoluble compound, coating the rock surface; and two AMD passivation technologies, magnesium oxide and the Dupont technology developed to create an inert layer/coating on the pyrite, preventing oxidation. The technologies were evaluated using the following methods: ASTM D 5744-96, accelerated weathering of solid materials using a modified humidity cells; mine wall residual wall rinse sampling; microscopy; and core drilling followed by water injection testing. The following paper describes the technologies used for passivation of acid generation from the highwall, the field demonstration, and the testing results from the background and each technology plot.

Jan 1, 2003

A laminar-flow furnace technique was used to study the combustion of 37-53 µm size fraction of Woodlawn copper concentrate containing 7.4 per cent zinc, 5.0 per cent lead and 22.5 per cent copper. Factors studied included the effect of time, temperature and the distribution of volatile elements between the panicles and the fume. Air was used for most of the work but a few tests were carried out using 1 per cent oxygen in nitrogen. Chemical analysis, X-ray diffraction, and scanning electron and optical microscopy of polished sections were used to characterize the reaction products.When the concentrate was combusted at low temperatures (800-900°C), the fume was rich in lead. At higher temperatures, this was diluled by increasing amounts of zinc and copper. 70 per cent of the zinc, 60 per cent of the lead and 40 per cent of the copper were found in the fume after oxidation at 1400°C. Lead, zinc and copper were present in the fume as anglesite (PbSO4), zincite (ZnO) and cuprite (Cu2O) respectively. The major phases present in the panicles were magnetite (Fe3O4) and/or cuprospinel (CuFe2O4), with some zincite and cuprite.Elemental copper was found in the particles oxidized in 1 per cent oxygen. Possible vapour species responsible for the vaporization are discussed.

Jan 1, 1985

By Singh TN

Rampura-Agucha Zinc-Lead deposit is unique as it is reported for the first time in the gneissic terrain with a rich oregrade quality of early to middle Proterozoic of Bhilwara supracrustal belt in the Precambrian of Northwest India. These sulphide ores are mostly confined to the graphite bearing Quartzofelspathic gneisses with intermittent bands of Calc-Silicate granofels and amphibolite. The ore and country rock mineralogy and their textural features are indicative of highly metamorphosed deposit and further the presence of marmatite and monoclinic phyrrhotite revealed high temperature environment of deposition.The present paper deals with some of the ideas about the ore genesis and petrographics of the associated rocks for Rampura-Agucha Zinc-Lead deposits of Bhilwara District (Rajasthan).

Jan 1, 1990

By Yanagase T, Nakamura T, Ueda Y

The possibility of removing the phos phorus and sulphur contained in steelmaking slag has been studied by observing directly through the microscope melts heated on Pt- filaments. After a CaO crystal was placed in the molten slag, distributions of P, S and other elements formed around the CaO crystal were determined with the aid of EPMA. The results indicated that a layer of 2CaO SiO2 is formed on solid CaO in CaO-Si02 melts. Then between CaO and the newly formed compound the molten slag tends to migrate through cracks. For higher Fe 2 03 contents, the layers of the compounds 2CaO.Si02 and 3CaO SiO2 formed around the CaO crystal are not continuous but look more like particles, which promotes the dissolution of CaO. Phosphorus in slag was found to be enriched in the 2CaOòSi02 layer. Phosphorus in the 2CaO SiO2 phase is not related to the primary slag composition, being about 5-7% P205.. Sulphur in slag,as well as the phos- phorus,was concentrated in the 2CaO.Si02 phase. Disintegration due to weathering observed for slags produced in these investigations appeared to be due principally to hydration of lime.

Jan 1, 1980

By Ö Aydan

Rock dynamics is one of the most important topics in the field of rock mechanics and rock engineering. The spectrum of rock dynamics is very wide and it includes the failure of rocks, rock masses and rock engineering structures such as rock bursting, spalling, popping, collapse, toppling, sliding, blasting, non-destructive testing, geophysical explorations, science and engineering of rocks, earthquakes, and impacts. Undoubtedly, the rock dynamics issues in Mars would remain to be the same. Although mankind has no direct access to Mars yet, the Mars exploration rovers (Opportunity, Sprit, Curiosity and Perseverance), Mars Reconnaissance Orbiter and InSight Lander provided very valuable data so that some rock dynamics issues can be recognised. The author reports his considerations on rock dynamics issues in Mars from very careful examination of images and data provided from MERs and MRO and discusses their implications.

Nov 29, 2022

By Mallett CW, Hobbs BE

This study examined the structures of the Bowen Basin in central Queensland, Australia, by a series of lineament analyses. These studies were carried out using published geological maps, NOAA-AVHRR imagery, and LANDSAT MSS. Comparisons between these various data sources allowed the discrimination of the nature of the observed lineament sets and the time of their development. These data, which have been verified by field work, allowed the development of an integrated structural model of the Basin as an area of compression. This is considered in the light of a plate tectonics framework for northeastern Australia. The study showed that geological structures of great significance to mining operations, such as strike slip faults and large thrusts, could be identified and mapped using a combination of satellite imagery and field investigation. The small scale view of the satellite imagery also facilitated the development of a structural model for the Bowen Basin.

Jan 1, 1986

By Mike Sharwood

This subject is to be discussed in greater depth by Mike Sharwood. It has also been the subject of a mini-symposium by the Melbourne Branch of the AusIMM in October, 1993. The papers from this symposium were distributed to the membership late last year "to raise their consciousness and to promote greater awareness and understanding of the wide range of liabilities that may arise". An introductory paper by Nicholson outlined the many areas in which liability may arise with particular emphasis on expert reports, eg: Takeovers Schemes of arrangement Acquisitions from associates Prospectuses Related party transactions Directors' duties Continuous disclosure Other influences (environmental, occupational health and safety, trade practices)

Jan 1, 1994

During its 60 years of existence the growth and development of Western Mining Corporation (WMC) has been greatly influenced by the men who led it. For the most part they, rather than any chance circumstances or good luck, determined the fortunes of the Company. This paper is essentially a series of biographical sketches of some of these men, together with a note of some of the major events which caused WMC to become the entity it is today.

Jan 1, 1993

By Sinha NH

ICI Australia and CSIRO have developed a novel process for extraction of zirconia from zircon sands. The two stage process involves a high temperature step and a wet chemical processing step. A pilot plant has been operating since November 1985 at CSIRO Division of Mineral Chemistry, Port Melbourne and construction of a full scale plant isplanned at Kwinana, WA.The plant has a high degree of flexibility and is capable of producing high purity zirconia up to about 99.99% and withinspecific particle size ranges. The products are being marketed by the joint company, 2-TECH Pty Ltd.

Jan 1, 1986