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By G. D. Tranter

The importance of ladle and teeming practice and its relationship to the yield and quality of the product has focused considerable attention on this phase of open-hearth operation. Inherently bad steel cannot be perfected by manipulation during teeming, but through the proper handling of "off heats" serious losses, which in many cases arise, can be greatly minimized. Conversely, good steel can be ruined as a result of poor workmanship in the pit, and rendered unsuitable for application to orders where exacting surface and physical requirements are essential. Sufficient evidence has been secured to warrant careful investigation of pit operations when an abnormal number of basic defects develop in the semifinished product or are found on the inspection table. This paper is written from the standpoint of the problems involved in making satisfactory ingots for sheet rolling. Furthermore, since rimming steel is almost universally used for manufacture of sheet, the data presented herein refer particularly to that type of steel. Going back some 30 years in open-hearth history, the word "pit" properly described the hole into which the ladle was lowered to receive the metal tapped from the furnace. The working space was necessarily limited, and the disposal of slag and metal overflowing the ladle or lost because of breakouts presented a serious problem. The equipment, of course, was rather crude in the light of present-day development. Often no ladle stands were provided, the ladle being hung on the crane beneath the runner. When delayed taps occurred, the ladle was often held in position for many hours, thus tying up pit operations and causing delays to adjacent furnaces. Because of crowded conditions, slag thimbles were not used and a network of cast-steel triangles and old tapping bars, placed before the heat was tapped, was the means for removing slag from the hole. Furnaces of different capacities were used

Jan 1, 1935

By Edward Thomas

ROCK bolting, third great change in postwar underground mining, is inseparably tied to the other two changes: better drilling and mechanized mining. Mechanized mining provided the impetus, when conventional supports restricted maneuver-ability of equipment-while carbide-tipped bits lent the means of drilling required holes cheaply. With the need and the tools at hand development snow- balled. In just six years, from January 1948 to January 1954, some 800 mines adopted bolting for systematic support, and over 100 of these mines now use rock bolts exclusively. Simultaneously, foreign mines have adopted the idea, but to a lesser extent. What held back this major change? The concept of fastening loose material to unbroken and apparently solid material is probably as old as mining itself, and sporadic use has been reported from virtually every mining region in the world. But falls of rock have always been the greatest source of both fatal and nonfatal accidents in underground mining and miners have understandable reluctance to work under roof or back material if they even suspect that it might be hanging like a "sword of Damocles" -supported only by a thin bolt.

Jan 11, 1954

By R. S. Rickard, H. D. Peterson, M. C. Fuerstenau, J. D. Miller

The flotation characteristics of the oxide copper minerals, malachite, azurite, and cuprite, have not presented the difficulty for concentration as have those of the copper silicate, chrysocolla. The copper carbonates and oxides respond reasonably well to flotation with conventional collectors, whereas chrysocolla will not respond to flotation with fatty acids or xanthates under normal flotation conditions. In this view then, other reagents will have to be devised to function as collectors for chrysocolla. The most obvious general class of reagents for this purpose would seem to be the organic copper chelating compounds. The utility of chelating agents as collectors in flotation systems has already been demonstrated.1-6

Jan 4, 1966

By L. W. Holm, A. K. Csaszar

A series of laboratory experiments was conducted in which oil was displaced from a porous medium by water-driven slugs of alcohols or similar solvents. The solvents used were soluble to some degree in both oil and water and covered the range of solubilities from complete solubility in oil to complete solubility in water. Displacement experiments were conducted on 2-and 3%-in. in diameter consolidated cores and 1-and 2-in. in diameter unconsolidated sand packs. The cores and sand packs ranged in length from 1 to 30 ft, and they were saturated with brine and crude or refined oils. The solvents used included ethyl alcohol, isopropyl alcohol (IPA), tertiary butyl alcohol (TBAI, secondary butyl alcohol (SBA), n-amyl alcohol (NAA), methyl ethyl ketone, acetone and others. It was found that all of the oil present in a porous medium could be miscibly displaced by injecting a slug of mutual solvent and driving it with water. The oil-recovery efficiency was dependent upon (1) the relative solubilities of the solvent in oil and water, and (2) the distance traversed by the flood. For complete oil recovery from cores, a smaller amount of a preferentially oil-soluble solvent was required, compared to the amount of preferentially water-soluble solvent needed. The size of the solvent slug required varied inversely with the linear flooding-path length raised to the 0.65 power. Water-driven dual solvent combinations (an oil-soluble solvent slug followed by a water-soluble solvent slug) were found to effect complete oil recovery with less total solvent than any single solvent used. In these dual-solvent displacement experiments, the slug size required varied inversely with length raised to the 0.55 power. Based upon the experimental results, a theory was developed to describe the displacement of oil and water by mutual solvents, and equations are presented to predict the production history in a linear system. These equations take into account the properties of the solvents and the porous medium. INTRODUCTION Oil-recovery processes which utilize displacing fluids that are miscible with the reservoir fluids have been studied extensively in recent years. Because of the poor contact efficiency and high pressure requirements of the LPG-gas displacement process there has been considerable interest in the alcohol-water process, and a number of studies have been made on the recovery of oil through the use of solvents which are mutually soluble in oil and water. An investigation by Sievert, Dew and Conleyl indicated that the use of mutual solvents would be limited because the presence of water in a porous medium would cause a phase break in the leading edge of the displacing solvent. Their study also showed that, in consolidated cores containing. only oil, the displacement of oil by a water-driven mutual-solvent slug of tertiary butyl alcohol (TBA) was affected by the viscosity ratios of the fluids involved. Gatlin and slobod3 concluded that an isopropyl alcohol (IPA) slug acts as a miscible piston, completely displacing both oil and water until the alcohol content of the mixing zone falls below the concentration necessary to maintain miscibility. Their study was conducted on uniform unconsolidated sand packs. They concluded further that IPA could be used effectively to recover oil from a watered-out sand. In a paper by Taber, Gamath and Reed4 relating an investigation on sandstone cores, it was stated that the displacement of oil by mutual solvents, particularly IPA, was not a miscible displacement and that no improvement in efficiency could be expected with increase in flooding-path length. However, their analytical analysis of the displacement mechanism using TBA is, in fact, one which indicates that the displacement is controlled by miscible mixing. They suggested that the lack of improvement in efficiency with flooding - path

By H. Shaw

IT is now generally recognized that the gravitational method of geophysical surveying is a valuable aid in elucidating the geological structure of the subsoil and enables the practical geologist to deduce the presence of useful deposits. The particular suitability of the torsion balance to the location of large and important subterranean structures has given rise to a wide application of this method by many of the important oil companies in their search for future supplies, and so intense have been these efforts that little has been heard of the method in other connections, with the exception of occasional references to its application in the location of hidden deposits of metallic ores, salt and lignite, and a number of accounts of its use in the elucidation of geological structures. Its success in the location of salt domes is well known, and establishes it as one of the most important of the geophysical methods, especially for the indirect location of oil. In the British Isles, however, no large occurrence of oil is likely to be revealed, and here the practical application of the gravitational method has been restricted almost entirely to the search for ores. This type of survey possesses well marked characteristics, and presents a gravitational problem that has necessitated the development of a special and probably unusual plan of campaign, full details of which it is hoped will shortly be published. The problems and difficulties encountered in this work are of necessity fundamentally related to those met with in the search for oil by means of the torsion balance, but they also possess several special and distinctive features which undoubtedly differentiate them from the obstacles confronting the oil prospector, and which call for special consideration and treatment.

Jan 1, 1928

By H. M. Callaway

There are key words common to Government and the minerals industry, the use of which immediately spark interest, argument and confusion. Among these is productivity, a term ranking for widespread misunderstanding with mineral self-sufficiency and mineral conservation. Each interpretation of these words tends to emphasize a single aspect and either minimize or ignore the complex dynamic system of things that influence the Nations mineral productiveness. This paper1, abstracted from a monograph on lead now being prepared for publication by the Bureau of Mines, not only sheds light on the trend of productivity in the lead-zinc mining industry but it presents the basis for forming a common general notion of what the term productivity implies.

Jan 11, 1961

By Charles H. Eldridge, Robert J. Anderson

When a metal or alloy is poured into a mold, internal stresses are set up by the cont,raction in volume on passing from the liquid state at the temperature of pouring to the solid state at the ordinary temperature. It is assumed by the writers that all castings are internally stressed. That any casting is internally stressed is shown by its warping or distortion on maturing at the ordinary temperature, by warping or cracking on heating, or by cracking or distortion on machining. In the investigation made by the writers, the internal stresses in cast non-ferrous alloys were studied with a view to examining the effects of heat treatment (i.e., simple anneal) on the release of such stresses. Data have been obtained that show quantitatively that internal stresses can be removed by appropriate heat treatment. The investigation was limited to a study of the effect of heat treatment on stress release in cast rings of the 87:7:5:1 copper-tin-zinc-lead alloy. The writers are indebted to E. G. Fahlman for the method used for inducing stress in cast rings; to M. E. Boyd for microscopic examination and for other aid; and to G. B. Dalrymple for the chemical analyses. General Information While casting stresses have been discussed considerably, they have usually been treated in a general way, and so far as the writers know no measurements of the magnitude of internal stresses in castings have been reported. It has been suggested by many investigators, particularly in the case of steel castings, that castings are internally stressed, and that these stresses can be removed by annealing. In a casting, the internal

Jan 1, 1923

By Robert J. Anderson, Charles H. Eldridge

When a metal or alloy is poured into a mold, internal stresses are set up by the cont,raction in volume on passing from the liquid state at the temperature of pouring to the solid state at the ordinary temperature. It is assumed by the writers that all castings are internally stressed. That any casting is internally stressed is shown by its warping or distortion on maturing at the ordinary temperature, by warping or cracking on heating, or by cracking or distortion on machining. In the investigation made by the writers, the internal stresses in cast non-ferrous alloys were studied with a view to examining the effects of heat treatment (i.e., simple anneal) on the release of such stresses. Data have been obtained that show quantitatively that internal stresses can be removed by appropriate heat treatment. The investigation was limited to a study of the effect of heat treatment on stress release in cast rings of the 87:7:5:1 copper-tin-zinc-lead alloy. The writers are indebted to E. G. Fahlman for the method used for inducing stress in cast rings; to M. E. Boyd for microscopic examination and for other aid; and to G. B. Dalrymple for the chemical analyses. General Information While casting stresses have been discussed considerably, they have usually been treated in a general way, and so far as the writers know no measurements of the magnitude of internal stresses in castings have been reported. It has been suggested by many investigators, particularly in the case of steel castings, that castings are internally stressed, and that these stresses can be removed by annealing. In a casting, the internal

Jan 1, 1923

By D. R. Uhlmann, T. P. Seward, O. Chalmers

A magnetic field has been used to damp out liquid convection during the solidification of castings. Ingots of Al-2 pct Cu were poured from various sperheats (10" to 65°C) into a room-temperature graphite mold located between the poles of an electromagnet. The effect on ingot structure of varying the strength and time of application of the magnetic field was investigated, and the results are interpreted in light 01- current theories of ingot structure. In the solidification of alloy systems, thermal gradients in the melt and differences in density of the constituents are expected to produce convective motion in the liquid. The thermal convection caused by temperature gradients should be present during the freezing of both alloys and pure materials, while the solute convection caused by density differences should be of concern only for alloys. The possible influence of this natural convection on the structure of castings has been discussed by Ruddle,' Chalmers, and Tiller. More recently, an experimental investigation of such effects was carried out by Cole and Bolling. These workers took stationary molds containing lead- and tin-based alloys and. using a brine solution. quenched them from various superheats above their respective liquidus temperatures. When grids were placed across the mold diameter to suppress convection, the grid region was later observed to contain a larger percentage of columnar grains than other parts of the casting or than similar castings poured without the grids present. From thermocouple measurements, they found the temperature in the grid region to be higher than that in the region outside the grids throughout the freezing process, and concluded that convection should be an important mode of heat transfer in normal castings. In addition to such convection arising from thermal gradients or differences in density of the constituents, a further source of convective motion, which we shall call "momentum convection", may be particularly important in small (laboratory-size) castings. By this term we refer to the convective motion produced in the initial pouring process, a motion which is damped out as the linear momentum and angular momentum of the liquid are dissipated. Besides these sources of convection, which are present to some extent in all castings. external influences may also be effective in producing convective motion. Examples of such "forced" convection which have been discussed in the literature include stirring the melt, shaking the mold, rotating the mold, and so forth The purpose of the present study was to examine the effect of convection on the structure of castings poured into a cold mold. In this work, a magnetic field was employed to damp out the convective motions within the liquid, and hence control the extent of con- The effect of a magnetic field on convective currents in a conducting liquid is to induce eddy currents which oppose and damp out the convective motion. vection. The technique of magnetic damping was previously used by Utech and F1emings" in their study of convective effects on impurity banding and other substructure in alloy crystals grown unidirectionally from the melt. In their investigation, fields as small as 200 gauss were found to be effective in damping the convection currents which influence the banding. I) EXPERIMENTAL TECHNIQUE In the present study, alloys of A1-2 wt pct Cu were poured into a room-temperature graphite mold. The mold, in the shape of a circular cylinder, 2 in. ID, 2-3/4 in. OD, 5 in. inside height, and 5-1/2 in. outside

Jan 1, 1967

By Richard Ely

Conservation Means Preservation, Improvement, Justice CONSERVATION, narrowly and strictly considered, means the preservation in unimpaired efficiency of the resources of the earth; or in a condition so nearly unimpaired as the nature of the case, or wise exhaustion, admits. And broadly considered, it means more than the word itself implies, for it naturally includes an examination of methods whereby the natural inheritance of the human race. may he improved; and still more broadly considered-and as used in popular discussion-it includes a treatment of the effects of productive conservation measures upon distribution. We shall give our attention briefly to the main points in this informal definition before we pass on to the thesis that conservation is largely a matter of property relations-that a wise conservation policy means wise property relations. Preservation of Natural Resources First, conservation suggests simply preservation, and, in the treatment of the subject which we have had in the United States, emphasis has been laid upon the past and present waste of natural resources and upon the means of putting a stop to this waste. The forests have been depleted; soil has been washed by rapidly flowing surface water from mountain sides. These rapidly flowing waters have produced high streams and devastating inundations, followed by low streams and impeded navigation. The forests have, moreover, been so removed as to bring great danger of fire, and destructive conflagrations have resulted in large waste of resources, including in some cases a destruction of the humus, supplying essential elements in the fertile soil. As a remedy we must have measures to reforest mountain sides, and this means large social control, very frequently taking the form of public ownership and management; but in addition we always find actual and proposed

Jan 2, 1916

By Anthony Anable

The definite trend to stricter specifications with respect to hydraulic concrete has become increasingly manifest in the last six years or so; but it remained for the vast reclamation projects of the Bureau of Reclamation of the Department of the Interior of the last few years to focus attention on this trend, and to demonstrate how thousands of tons of concrete-making aggregates can be produced continuously and automatically with a control of fineness comparable with that obtained with small samples in well equipped private and governmental laboratories. Pioneer work in this direction was done, to be sure, by private companies, notably the Kaiser Paving Co. of San Francisco, prior to the present vast public works program. Then in 1931 came the first great aggregates-preparation plant of the Six Companies, Inc. to supply construction materials for Boulder Darn1 in Nevada, and now, in 1936, the aggregates plant of the Mason-Walsh-Atkinson-Kier Co., general contractors on the Grand Coulee darn in Washington. At Boulder dam and to an even greater degree at Grand Coulee dam, sand production is recognized as probably the most important single element affecting the physical characteristics of the concrete. For in the construction of dams accurate grading of the fine aggregate has considerable bearing on the attainment of a uniform and homogeneous concrete of a high degree of workability and placeability and, at the same time, combining high density and low cement content. Low cement content is of value not only from the standpoint of ceonomy but also because the use of an unnecessarily rich concrete causes certain undesirable characteristics to develop. This paper will relate how at Grand Coulee dam methods that are more advanced than ever before are producing four sizes of gravel and a sand having a fineness modulus of 2.5-3.0. The design capacity is 1000 tons an hour. Significantly, the methods and equipment employed arc broadly those that have been used for a generation in metallurgical mills for accurately sizing and grading both precious

Jan 1, 1938

By Anthony Anable

The definite trend to stricter specifications with respect to hydraulic concrete has become increasingly manifest in the last six years or so; but it remained for the vast reclamation projects of the Bureau of Reclamation of the Department of the Interior of the last few years to focus attention on this trend, and to demonstrate how thousands of tons of concrete-making aggregates can be produced continuously and automatically with a control of fineness comparable with that obtained with small samples in well equipped private and governmental laboratories. Pioneer work in this direction was done, to be sure, by private companies, notably the Kaiser Paving Co. of San Francisco, prior to the present vast public works program. Then in 1931 came the first great aggregates-preparation plant of the Six Companies, Inc. to supply construction materials for Boulder Darn1 in Nevada, and now, in 1936, the aggregates plant of the Mason-Walsh-Atkinson-Kier Co., general contractors on the Grand Coulee darn in Washington. At Boulder dam and to an even greater degree at Grand Coulee dam, sand production is recognized as probably the most important single element affecting the physical characteristics of the concrete. For in the construction of dams accurate grading of the fine aggregate has considerable bearing on the attainment of a uniform and homogeneous concrete of a high degree of workability and placeability and, at the same time, combining high density and low cement content. Low cement content is of value not only from the standpoint of ceonomy but also because the use of an unnecessarily rich concrete causes certain undesirable characteristics to develop. This paper will relate how at Grand Coulee dam methods that are more advanced than ever before are producing four sizes of gravel and a sand having a fineness modulus of 2.5-3.0. The design capacity is 1000 tons an hour. Significantly, the methods and equipment employed arc broadly those that have been used for a generation in metallurgical mills for accurately sizing and grading both precious

Jan 1, 1938

ONE of the problems that confronts the chronicler of the Porphyry story is to determine the date from which Morenci should be regarded as one of the group. The mines have the distinction of being the first operated in Arizona for copper. A small smelter was in operation as early as 1873 and in the eighties two smelters accounted for a substantial production ranging from 3,000,000 to 6,000,000 lb. per year. The first concentrator was built in 1886, but the ores were principally oxidized, and direct smelting ore still supplied most of the production. As early as 1893, the mining of somewhat leaner porphyry ores, containing copper in the form of the sulphide mineral, chalcocite, was commenced; but these still were of comparatively high grade and the concentrators were plants of 100 to 400 tons daily capacity. Moreover, the backbone of operations was still the production of rich oxidized ores for direct smelting. They assayed 10 to 15 per cent copper and the sulphide milling ores assayed 3 to 4 per cent. A significant comment appears in the Copper Handbook for 1908. Speaking of the Arizona Copper Co., Ltd., which was to become the most important component of the present Morenci enterprise, the editor, Horace Stevens, says: "A tremendous amount of ore is in sight, ore reserves . . . being estimated at 10,370,600 tons . . . " It seems fair to infer from this that the property was not yet regarded as an immense low-grade mine, but that the copper content of perhaps 70 lb, to the ton made an ore of "medium " grade even according to the standards of the time. Although the concentrating ore was typical of that in the porphyry group of mines (except for its greater richness), no one seems to have the least inclination to take from Utah the

Jan 1, 1933

By R. W. Smith, R. J. Charles

Fractions of glass particles in the size range 0.5 to 5.0 µ were prepared by an elutriator that operates in a centrifugal field. Although mean sizes of commercially graded abrasive powders were ten times greater than those of samples prepared by the elutriator, frequency size plots for elutriator samples compared favorably. Efficiency of separation was low and amounts of material recovered by the elutriator were small, but the method should find use in preparation of small amounts of sized materials for laboratory investigations.

Aug 1, 1956

By D. L. Murphy

As the world's demand for iron ore increases and available sources are depleted, increasing attention will be centered on deposits in the Quebec and Labrador portions of the Labrador Trough. Improvements in the beneficiation of low grade iron ore stimulate exploration for deposits amenable to concentration. This study is centered on the Mt. Wright-Lake Carheil area, lying between Wabush Lake and Mt. Reed in Quebec. Described in detail are the general lithology, structural and economic geology, and mineralogy of the iron-formation. The iron ore province of Quebec and Baffin Island extends from the southern shore of Baffin Island southeasterly through the Labrador Trough to Matonipi Lake, approximately 185 miles northwest of Seven Islands. (See Fig. 1.) Future geologic field studies will very likely extend the limits of the province to include the ferruginous and associated rocks of the Lake Mistassini area. At present, only the deposits near Knob Lake and Lake Jeannine (Mt. Reed) have been brought into production although in the near future several other properties including those at Wabush Lake will commence operations. Within the next decade or so, as the world's demand for iron ore increases and available sources are depleted, this region will undoubtedly become a major mining district. Initial reports of iron-rich rocks in Labrador date back to the investigations undertaken by A. P. Low near the turn of the century. During the ensuing years the country was prospected chiefly for precious and nonferrous base metals because of its inaccessibility and the low tenor of the iron ore. In 1945 an evaluation of the direct shipping ores near Knob Lake indicated that sufficient reserves were present to justify the enormous capital expenditure required to bring the deposits into production. Initial open-pit mining began in 1954 following the construction of a townsite, a 360-mile long railway to Seven Islands, and an elaborate loading dock. Recent improvements in the beneficiation of low-grade iron ore have stimulated widespread exploration for deposits amenable to concentration, particularly along the southwest extension of the Trough. The Mt. Wright-Lake Carheil area, bounded by longitudes 66O45' and 67 30' west and latitudes 52 30' and 52 45' north, is a nearly rectangular tract of slightly less than 500 sq miles. It is in Saguenay County, 174 miles north-northwest of Seven Islands (see Fig. 1). Except for the periods of the spring breakup and the fall freeze up, the area is readily accessible by air.

Jan 1, 1962

By J. M. Morris

The point to be made most clear in this paper is the economic value of flotation in the Benguet mill flow sheet. It is rather a statement of effect with no attempt at a technical explanation of the cause. Certain well-known, easily understood reagents, mechanisms and principles have been adapted to the conditions at Benguet, and have proved to be more successful than was demonstrated in the laboratory. The mechanical and metallurgical development of this particular operation was arrived at by trial and error, with fortunately very little error. Changes were slow, of necessity, which in the end proved a blessing in that time was afforded for observation and analysis of the disturbing factors; and as a result each change was a definite step towards higher efficiency. Many of these steps were unpredictable from laboratory work because of the varied and differing characteristics of ores met with in daily operation of the mill, which were practically impossible to reproduce on a laboratory scale. The Benguet mill receives daily ores that differ as much as if they were delivered from three different properties. There is first the surface and upper-level zone, which produces an oxidized secondary ore containing considerable iron oxide, manganese oxide and some organic matter. Formerly, most of this ore consisted of very soft fill with some hard rock mixed in. It also contained an unusual amount of iron and aluminum sulfate, which formed hydrates upon entering the alkaline cyanide solution and caused excessive frothing. When flotation was introduced in the Benguet mill the general characteristics of this upper-level ore had changed considerably, in that it was practically all newly mined, fairly hard ore. It still contained many of the same disturbing elements, but was somewhat simpler to treat than formerly. The small proportion of fines is still troublesome in flotation, and plant practice probably does not show more than 80 per cent extraction on this small portion of the ore. No definite figure on this is available, as this particular ore is delivered at irregular intervals

Jan 1, 1939

By J. M. Morris

The point to be made most clear in this paper is the economic value of flotation in the Benguet mill flow sheet. It is rather a statement of effect with no attempt at a technical explanation of the cause. Certain well-known, easily understood reagents, mechanisms and principles have been adapted to the conditions at Benguet, and have proved to be more successful than was demonstrated in the laboratory. The mechanical and metallurgical development of this particular operation was arrived at by trial and error, with fortunately very little error. Changes were slow, of necessity, which in the end proved a blessing in that time was afforded for observation and analysis of the disturbing factors; and as a result each change was a definite step towards higher efficiency. Many of these steps were unpredictable from laboratory work because of the varied and differing characteristics of ores met with in daily operation of the mill, which were practically impossible to reproduce on a laboratory scale. The Benguet mill receives daily ores that differ as much as if they were delivered from three different properties. There is first the surface and upper-level zone, which produces an oxidized secondary ore containing considerable iron oxide, manganese oxide and some organic matter. Formerly, most of this ore consisted of very soft fill with some hard rock mixed in. It also contained an unusual amount of iron and aluminum sulfate, which formed hydrates upon entering the alkaline cyanide solution and caused excessive frothing. When flotation was introduced in the Benguet mill the general characteristics of this upper-level ore had changed considerably, in that it was practically all newly mined, fairly hard ore. It still contained many of the same disturbing elements, but was somewhat simpler to treat than formerly. The small proportion of fines is still troublesome in flotation, and plant practice probably does not show more than 80 per cent extraction on this small portion of the ore. No definite figure on this is available, as this particular ore is delivered at irregular intervals

Jan 1, 1939

By Charles Pack

EXTENSIVE progress has been made in the metallurgy of alloys for die castings. Enthusiastic proponents of some alloys are inclined to make extravagant claims for their materials, which may be justified by physical tests on test bars made from the respective alloys but are seldom justified by the results obtained with commercial die castings made from those alloys. Chemical analysis of the test bars and castings fails to determine the cause of these variations, since they are due to other physical factors entering into the commercial production of die castings. In this paper, an attempt will be made to outline some of the factors in commercial die-casting practice to which these variable results may be attributed, in the hope that the manufacturer of die castings, recognizing the importance of these factors, will devote more attention to them in the design and construction of dies and equipment. In 1914,1 the author defined die castings as "metal castings made by forcing molten metal, underpressure, into metallic molds or dies." This definition was given in order to differentiate die castings from other molded metal products such as "permanent-mold" castings, "slush" castings and similar products that are sometimes erroneously termed die castings. The term "die casting" could be interpreted to include all castings made in metal molds or dies; but since this term, like most of our technical nomenclature, has been developed by commercial practice we must look to this practice for its proper definition. The Germans, with their usual devotion to descriptive names, have adopted the name of spritzguss (squirt cast) for die castings. Undoubtedly this name is more descriptive of the die-casting process, where the metal is literally squirted into the die and serves to differentiate this process from other metal mold processes, where the metal is poured into the die. In the earlier paper mentioned, the author also emphasized the fact that the definition given for die castings indicated clearly that the satisfactory operation of the process must comprise three factors, all of which must be considered of vital importance to the successful operation of the die-casting process:

Jan 1, 1930

By John H. Bassarear

By 1968, Cyprus Pima was milling 34.5 kt /d (38,000 tpd) of copper ore using a conventional flowsheet consisting of three stages of crushing, rod milk and ball, mills. A 13.6 kt /d (15,000 tpd) expansion was put onstream late in 1971 using primary crushing, semiautogenous milk, and ball mills. Identical ore is treated in both concentrators. This paper shows the weight and life of each liner for each crusher and each mill over a four year period from 1974-1977. Media consumption is shown for the same period and a comparison is made between the two reduction methods.

Jan 1, 1983

By T. M. Geffen, H. N. Hall

One-third to one-half of the original oil is left in most reservoirs even after thorough gas driving or waterflooding. In contrast, essentially all of the oil contacted con be recovered by flooding with a solvent (a fluid miscible with the reservoir oil). It is not economical to fill a reservoir with solvent since the value of the solvent would very likely exceed that of the oil. A practical method would be to inject a small bank of solvent to displace the oil. This solvent bank in turn could be driven through the rock by a less valuable scavenging fluid, such as natural gas which is also miscible with the solvent. Such a method of oil recovery was studied in the laboratory using long (up to 95 ft) core systems. It was found that, as the solvent moves through the reservoir, the front end of the solvent bank becomes mixed with the oil and forms a relatively short mixing zone between undiluted crude oil and pure solvent. An engineering correlation was obtained which can be used to predict the length of this zone. Displacement of the solvent by natural gas can be achieved with complete miscibility (above the critical pressure of the gas-solvent system at reservoir temperature) or with partial miscibility at lower pressures. Under conditions of complete miscibility, it was found that the length of the gas-solvent mixing zone could be predicted from the correlation developed for the solvent-oil mixing zone. With partial miscibility, two phases exist and the solvent is displaced by a modified gas drive in which vaporization and condensation occur. Equations are developed to predict the performance of this type of displacement. Two plans are suggested for application of miscible fluid displacement. one for miscible displacement of the solvent and the other applying to lower pressures where partial miscibility occurs during solvent displacement. Calculations based on the laboratory tests indicated that a bank of solvent with a volume of less than 10 per cent of the hydrocarbon volume under consideration will generally be adequate to obtain high oil recovery from the portion of the reservoir contacted in miscible fluid displacement. INTRODUCTION The conventional methods by which oil is displaced from reservoir rock—solution gas drive, conventional gas drive, and waterflooding—are all processes in which the oil is expelled from the rock by direct displacement with a fluid immiscible with the oil. Because of the immiscible type displacement, complete recovery of the reservoir oil is not achieved. In economically successful flooding operations, as much as 50 per cent of the original oil may be abandoned in the reservoir as unrecoverable. The use of a solvent (miscible with oil, such as LPG) as an injection fluid does not have the undesirable displacement features common to the use of gas or water (immiscible with oil). It can be readily appreciated, however, that it would not be economically feasible to displace the oil and entirely replace it with a solvent. A process was therefore devised for use in field operations in which only a small volume of solvent would be required to obtain essentially complete oil recovery in the portion of the reservoir contacted. In this process, the solvent acts as a buffer between the reservoir oil and injected gas, allowing the natural gas to displace indirectly the oil with much greater efficiency than if the gas displaced the oil directly. DESCRIPTION OF OIL RECOVERY PROCESS The solvent oil recovery process will be described in

Jan 1, 1958