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Development of the Boleo Process Flow Sheet and the Direct Solvent Extraction (DSX) Circuit for Cobalt and Zinc Recovery The metallurgical process designed to treat the El Boleo Cu-Co-Zn-Mn ore involves a sulphuric acid leach in seawater under oxidative and then reductive conditions to maximise metal extraction. Copper and cobalt are recovered as cathodes by electrowinning, zinc and manganese as zinc sulphate monohydrate and high quality manganese carbonate, respectively, by precipitation after a number of separation and purification stages. One of the key purification stages of the Boleo metallurgical process is the CSIRO DSX circuit. The DSX circuit was developed using the synergistic solvent extraction (SSX) technology. Initially, a synthetic solution was studied, and by adding 0.4 M LIX63 to 0.5 M Versatic 10 in Shellsol D70, large synergistic shifts were obtained for cobalt (?pH50 4.24) and zinc (?pH50 1.62). After a single contact, the separation factor of metals over manganese reached over 6,000 for cobalt and over 380 for zinc, indicating excellent separation of cobalt and good separation of zinc from manganese, magnesium and calcium. The SSX system was further optimised with the modified synthetic pilot plant solution. The extraction of cobalt and Zn after a single contact was 93 per cent and 70 per cent, respectively, while the Mn concentration in the loaded organic solution was only 0.28 g/L. A proof of principle pilot plant operation was conducted in 2004 and a demonstration pilot plant for final engineering design in 2006 with outstanding performance of the DSX circuit. For the demonstration pilot plant, the overall recovery of cobalt and zinc exceeded 99 per cent with a raffinate containing only 4 mg/L Zn and 1 mg/L Co. The DSX organic system showed no sign of degradation during the pilot plant operation, indicating good chemical stability under the anticipated commercial operating conditions. The DSX circuit will be implemented in the future Boleo processing plant.

Sep 13, 2010

By Georgene Renner

At the beginning of the 1990s, Communism fell and signaled the end of the Cold War. The world rejoiced but also watched and waited to see how those countries would restructure themselves. The 1990 SME Annual Meeting was held at the Salt Palace Center in Salt Lake City, UT. The keynote session featured Alistair Frame, chairman of RTZ; Paul Queneau, professor of metallurgy at the University of Utah; and TS Ary, director of the U.S. Bureau of Mines. The SME Board of Directors voted to hire a Manager of Public Information and Education to be the GEM Program coordinator. This person was to collect and disseminate information that could be used by individual members and Local Sections to interface with government personnel and the general public.

Jan 1, 2007

By Marco Lombard, Paulus Kapolo, Christopher J. Greet

"The conversion of a concentrator from one grinding media type to another is a major undertaking in terms of both financial and technical risk. So, a strategy of completing sufficient laboratory and field tests to mitigate this risk, and give the operation confidence that advancing to plant trial will give a high probability for success.The objectives of this paper are twofold: to provide the reader with a strategy for mitigating risk prior to undertaking a plant trial; and to provide a statistical basis for analysing plant trial data. That is, when employing an electrochemically inert grinding media in the primary grinding circuit it is possible to change the pulp chemistry of the system and improve the metallurgical response of the ore.This paper tracks the changes in pulp chemistry and metallurgical performance of Rosh Pinah Zinc Corporation’s silver/lead/zinc concentrator as the primary ball mill was converted from forged steel grinding media to high chrome grinding media. The changed in metallurgical performance are correlated to the shift in pulp chemistry.INTRODUCTIONTheoryBruckard et al (2011) recently published an article describe the effect of the grinding environment on the flotation of copper sulphides. While this paper confined its discussion to copper sulphides the arguments presented apply equally to other sulphide mineral systems. Broadly, these studies indicate that most sulphide minerals are more noble than the grinding media used during comminution. Therefore, the sulphide minerals are cathodic with respect to the forged steel grinding media, and the following reactions apply:Cathode (sulphide mineral): ½O2 + H2O + 2e- ? 2OH- (1)Anode (grinding media): Fe ? Fe2+ + 2e- (2)A galvanic couple between the grinding media and the sulphide mineral(s) exists, which increases the corrosion rate of the forged steel media. The corrosion products of the grinding media, iron oxy-hydroxide species, invariably precipitate on to the surfaces of the sulphide minerals thereby affecting their floatability (Johnson, 2002).The application of more electrochemically inert grinding media to “real” ore systems at an industrial level to improve metallurgical performance has not gained universal acceptance. The aim of this paper is to provide a protocol for conducting laboratory and plant test work that clearly demonstrate that metallurgical benefits are not only possible, but measureable, by way of example. In this case, the work conducted at Rosh Pinah Zinc Corporation in Namibia is described."

Jan 1, 2013

The extractive industry has been faced with a situation where there has been no systematic and formalised training and education structure available. Previous structures which were available, e.g. the quarrying diploma and the mining papers as a part of an engineering degree, have suffered the same fate as the Dodo. They are now extinct.   In providing for a training strategy, the past strategies need to be examined and reasons behind their demise examined. This paper examines the reasons for past failures in education and training in the extractives industry, the factors that need to be taken into account in creating an education and training culture, the strategies required, the Government regulations and trans-Tasman agreements, and the quality management which must surround the entire training programme.

Jan 1, 1997

By T. A. E. Breen

A new high intensity grinding technology has been developed and is now being commercialized by Hicom International of Australia. This has led to the development and manufacture of Hicom 120 grinding mills which are now being sold internationally for a range of mining industry applications. The first commercial process application has been for the diamond sector, where the ability of the mill to remove host kimberlite rock by attritioning, with no damage to the thereby liberated diamonds, is seen to be a most beneficial attribute. There are, however, many other mineral industry applications for this mill. The design of the Hicom mill is unique. Based on a high speed centrifugal motion of the grinding chamber, very high power intensity is delivered to the grinding process. Most significantly, a high acceleration field, 50 times stronger than gravity is produced, creating very high power input per unit of mill volume, and exceptionally fast particle breakage rates, typically 50 - 100 times greater than those in conventional tumbling mills. A mill developing such forces has significant implications to comminution technology and practice.

Jan 1, 1999

By Paul R. Smith

The Colorado School of Mines Research Institute (CSMRI) was founded in 1949 to fill mining industry and government needs for minerals research and development. The operations of scores of mines, mills, and plants around the world are based on the results of work done by the Research Institute. Among other things, the Research Institute conducts studies in geology, mine planning, mineralogy, size reduction, minerals processing, and hydrometallurgical techniques in extractive metallurgy. Many CSMRI projects also involve energy and environmental considerations. What follows is a summary of some of the studies in which the Research Institute has been and is currently involved, as well as some comments on trends and developments in the industry.

Jan 2, 1982

By Stephen C. Tadolini

The U.S. Bureau of Mines has developed ultrasonic measurement instrumentation capable of measuring strains and elongations on tensioned and untensioned mine roof bolting systems. This report evaluates the pulsed-phase-lock-loop and pulse-echo systems. The pulse-echo systems measure time of flight of a signal through the bolt. The ultrasonic instrument converts the measurement into elongations or stress. The most recent Bureau instrument development converts travel-time measurements directly into elongation, load, stress, and torque by simple data manipulation from the keyboard. Bolt preparation and instrument calibration are described in detail.

Jan 1, 1990

By R. Karl Zipf, Suresh Bhatt

Highwall mining is an important coal mining method. It appears that upwards of 60 highwall miners are presently in operation, and they may account for approximately 4% of total U.S. coal production. A review of the Mines Safety and Health Administration (MSHA) data over the 20 year period from 1983 to 2002 identified 9 fatalities attributable to auger and highwall mining of which inadequate ground control accounted for 1/3. In the past 5 years, 1 fatality occurred in highwall mining. Estimates of the manpower requirements in highwall mining suggest that its fatality rate is essentially the same as for surface coal mining, thus highwall mining appears to be a very safe modern mining method. Highwall stability is the major ground control related safety concern, and operators are required to develop and follow an appropriate highwall mining ground control plan. The plans usually specify the following geotechnical parameters: hole width, maximum hole depth, maximum overburden depth, seam thickness, web pillar width, barrier pillar width and number of holes between barriers. Calculated web pillar stability factor exceeded 1.3 for most designs evaluated. This study examined records from 5,289 highwall miner holes with a total completed footage of about 2,560,000 feet to understand the reasons for early pull out. Average lost footage is typically about 20% of planned footage. Only 35% of the holes reached planned depth, and 20% were short due to rockfalls. Water and adverse geology accounted for 15% of the losses. Mechanical/electrical problems, guidance, and slope stability problems accounted for the remaining 30%. Web pillar stability factor for these holes also exceeded 1.3 in 95% of cases. Best practices to avoid trapped miners include: avoid mining in stream valleys, avoid mining near outside corners, careful alignment of each hole and the use of an onboard guidance system. Several issues in highwall mining ground control require further investigation including highwall mining through old auger workings, highwall mining near old underground mines, multiple-seam and multiple lift highwall mining and finally the size and frequency of barrier pillars.

By A. B. Fox, R. P. Thackray, K. C. Mills

The role of mould fluxes in continuous casting is reviewed. The main functions of the flux are described and the importance of the flux in providing lubrication and the right level of heat transfer between the shell and the mould is described. The major problems of longitudinal, transverse and star cracking, gas and slag entrapment and deep oscillation marks in the steel product and ?sticker breakouts? are analysed. The important physical properties of the flux in combating these various problems are identified. Physical property data for the fluxes are given.

Jan 1, 2004

By J G. Webster-Brown, K L. Brown

The Waihi Region is host to many low sulphidation epithermal Au-Ag deposits. The Golden Cross mine located at the head of the Waitekauri River, eight kilometres NW of Waihi, was a gold mining operation that placed significant emphasis on environmental management. An assessment of the influence of this mining project on stream sediment geochemistry (Fe, Mn, As, Cu, Pb, Zn, Cr, Cd, Ni, Ag and Se) in the Waitekauri Catchment has been made. Effective waste management during the mine operation appears to have prevented contamination of stream sediment. Trace metal concentrations in the Waitekauri Catchment sediment have generally decreased since 1987, and are currently mainly below the ANZECC (2000) sediment quality guidelines. However, elevated As levels were recorded in the Upper Waitekauri River and Battery Stream, exceeding guideline values. Elevated levels of Cu, Pb, Zn and Cd were found in the Huanui Stream, a tributary of the lower Waitekauri River. This reflects the influence of past mining operations in the valley, as well as natural weathering of hydrothermally altered Coromandel Group andesite. At a number of sites, Mn concentrations also exceeded sediment quality guidelines, and this may be derived from the remediated Golden Cross mine site.

Jan 1, 2003

By Mait Mets

In Estonia, the deformations monitoring of 1500 buildings are currently under investigation, buildings on pile foundations make up 10 per cent of these. In the following text we will be considering the behaviour of pile foundation buildings in various parts of Estonia, in differing geotechnical conditions.

Jan 1, 2002

By Ammar Henchiri, Godfrey McDonald

"Breakwater Tunisia S.A.’s Bougrine mine is located in a semi-arid region of Tunisia characterized with Triassic salt domes. Due to extensive agricultural land-use in the mine area, a zero-discharge tailings facility design and high water recycling rates to the concentrator were chosen to minimize the environmental impact to the surrounding area. The process water supply has an accumulation of naturally occurring salts due to high evaporation rates and the need to recycle 70% of the process water. The elevated salt content of the process water had an adverse effect on the efficiency of the flotation reagents, which led to the production of lower quality zinc concentrate.The impact of the water salinity on the zinc concentrate quality was documented by extensive laboratory testing. A feasibility study was prepared and a decision was made to install a reverse osmosis plant for desalination of the process water. A plant was constructed during 2000 which currently supplies up to 85 m3/hr of de-mineralized water, equal to approximately 45% of the total process water requirement. The salinity of the process water decreased from about ten to twelve grams per litre before installation to less than three grams per litre. Together with minor modifications to the concentrator circuit, Breakwater Tunisia has increased the zinc concentrate grade from 50% zinc to 55% zinc without compromising the zinc recovery rate of approximately 84%.This paper discusses the successful installation of a reverse osmosis desalination plant that allowed Breakwater Tunisia to improve the grade of the Bougrine mine zinc concentrate and thus increase the net smelter return.INTRODUCTIONBreakwater Resources Ltd., through a wholly owned subsidiary, Breakwater Tunisia S.A., acquired the Bougrine underground mine and related assets in September 1997. During the winter of 1997/1998, the company rehabilitated the mining equipment, modified the concentrator circuit, developed a new mine ventilation system and prepared a new mining production program. The mine was reopened on May 2, 1998 and was in commercial production as of June 1, 1998."

Jan 1, 2003

By A. Griffiths, G. Vickell

"INTRODUCTIONA successful cyanide destruction process has to ensure environmental compliance at reasonable cost. That this is possible with hydrogen peroxide is shown by the fact that over twenty gold mines either already use H2O2 or intend to start using it within the next few months. About half of these mines are in Canada.This growth is remarkable, considering that the first treatment plant to use H2O2 for detoxifying cyanide was commissioned less than five years ago at Ok Tedi, in Papua New Guinea.Hydrogen peroxide is being applied to a wide range of situations, including:Treatment of CIP pulps; examples: Ok Tedi, PNG; Hope Brook, Nfld.Treatment of barren bleeds and filtrates; examples: Nickel Plate, B.C.; Puffy Lake, Man.Treatment of tailings pond discharge; examples: Detour Lake, Ont., Page Williams, Ont.Treatment of excess heap leach solution; examples: Hope Brook, Nfld; Gordex, NS.Treatment of barren heaps after heap leaching; examples: Alhambra, NV; Wharf Resources, S.D.Treatment of pond reclaim water to prevent either ""preg-robbing"" or depression of gold-bearing pyrite in a flotation step; example: Getchell, NV.Treatment of backfill to prevent possible groundwater contamination; example Hope Brook, Nfld.Treatment of tailings ponds to prevent bird kills; example: Paradise Peak, NV.""Emergency"" units to deal with unusual events such as freak storms or dam failures."

Jan 1, 1989

By M. Gouet-Kaplan, J. A. Finch, S. Gélinas

Methylisobutyl carbinol (MIBC) and methoxy polypropylene glycol (Dowfroth 250) bubble thin films were characterized by composition and thickness determinations, using FT-IR spectroscopy and UV-Visible spectrophotometry, respectively. The infrared investigation indicates that the role of frother molecules in creating bubble thin films is based on their effectiveness in inducing H-bonding reorganization of the surrounding free water molecules into a coherent network. From UV-Visible interference patterns, it is found that MIBC forms films with a measured critical end thickness of less than 160 nm, compared to 612 ± 30 nm for Dowfroth 250. The observed values of the free water layer thickness are comparable at 5.65 ± 0.28 µm for MIBC and 6.75 ± 0.34 µm for Dowfroth 250. A higher stability of an MIBC bubble over a Dowfroth 250 bubble is related to the different polarization and orientation of the molecules sustaining the boundary surface water network. The findings are used to explain the different action and associated froth characteristics of the two common industrial frothing agents.

Jan 1, 2006

By Luis Vassallo

El presente trabajo señala los beneficios que pueden obtenerse de la adopción inteligente de una estrategia de colaboración electrónica que responda a las necesidades de este segmento y que proporcione soluciones de verdadero valor agregado. Así, el modelo monolítico que prevaleció por muchos años, donde cada empresa era propietaria de las licencias mineras, operadora, mantenedora, contratista, vendedora, embarcadora y financiera, está desapareciendo. En la cadena de valor del proceso minero intervienen más empresas, contribuyendo valores agregados específicos y especializando funciones. Este cambio demanda mayores flexibilidades de los sistemas de información que deben ser totalmente abiertos, y permitir el intercambio instantáneo de información que facilite reaccionar oportunamente a las diferentes variables de la operación. Por ello, la colaboración electrónica permite a la minería adaptarse a un mundo que está cambiando.

Aug 25, 2002

By Marius B. Wechsler

There are considered deep piles which are fixed in blocks of rotating machinery foundations. A mathematical background is developed for determining the behavior of this kind of piles for motions caused by horizontal and vertical oscillations, as well as by roc-king and twisting. It is assumed that the piles come across a top soil layer of depth c, not capable of lateral support, and penetrate over a length b, in a bottom firm soil layer, or in a bottom soft soil layer in which vibrations can produce voids around the piles. With respect to b and c, as well as to the elastic properties of piles and soils, the analysis leads to the maximum bending moments and shear forces subjecting the piles, to the maximum lateral bearing on the bottom soil layer, as well as to the deflection of the pile and the displacement of the foundation block. The results of the performed analysis can be applied to seismic loads too, and they are illustrated by a numerical example.

Jan 1, 1987

AQUILA Mining Systems Ltd., designs, develops and delivers systems for measurement, analysis, simulation, control and automation to the mining, construction and petroleum industries. The objective of current efforts by AQUILA is the continued development and refinement of computerbased systems and techniques to automatically process monitored performance data from surface blasthole drills and mining shovels, and the management and coordination of these pieces of equipment by GPS (Global Positioning Systems).

Jan 1, 1994

By E. M. Watkin

"Land directly disturbed by hard rock mining activities in Ontario and Quebec was surveyed in 1974 as part of a country-wide assessment, (Murray 1977). Some 15, 000 hectares, or 5 7 square miles, are listed as having been disturbed by overburden removal, waste rock and tailings deposition (Table 1) in the region. That area represents sixty-eight per cent of the total area which ha1; been disturbed by mining in central and Atlantic Canada. Assessment of disturbed areas was undertaken using LANDSAT-1 and LANDSAT-2 satellite imagery. Certain limitations of the technique were recognized but the data obtained were considered a relatively acceptable assessment of the extent of disturbed areas larger than ten hectares.Approximately ten per cent of the land disturbed by mining in the two provinces has been reclaimed to varying degrees. Indeed, this proportion is correct for the country as a whole. As pointed out by Ripley, Redmann and Maxwell (1978), some of the land was disturbed long before environmental concern 01· reclamation were ever considered. In numerous instances reclamation will remain impossible until presently active operations are closed. Nevertheless, these authors feel such figures make it clear that reclamation has not been a high priority in Canada in the past. Canada is a vast country, and there has been little pressure toward efficient use of all land space. Most mining operations occur in areas distant from the country's population centres. Under these circumstances, therefore, the pressure to reduce the environmental impact of mining is much less than in the more densely populated areas of Europe and the eastern United States, where such activity can occur in or adjacent to large metropolitan areas."

Jan 1, 1980

By Warren E. Wilson

THE transportation of solids in pipe lines is a matter of deep concern in many fields of engineering. Much experimental and theoretical work has been done in an effort to devise means of designing pipe lines that will satisfactorily transport given solid loads, but there remain many unanswered questions in this field. The present discussion will be confined to a rather narrow portion of this field and will endeavor to point out certain factors that may well be considered when comparing the relative economy of various installations. The data have been presented previously but a new interpretation was prompted by a suggestion in a paper by Professor O'Brien,1 of the University of California, that the friction work per pound of dry material should be considered in determining the relative efficiency of various installations. This method of considering relative economy in various pipe lines leads to some rather unexpected conclusions, especially with reference to the economy of large pipe sizes. A previous suggestion by the writer3 concerning the economy of a rather peculiar type of installation is strengthened. It is not believed that the considerations set forth herein apply directly in the case of dredge lines, where economy is largely a matter of a high rate of pumping in order to reduce the unit overhead charge. However, it is believed that some value may be gained from these considerations in cases involving the disposal of a fixed amount of solids per unit time with a minimum expenditure of energy and at a low cost for replacement of worn pipes. Such situations are not uncommon in the disposal of mill tailings and the disposal of solids deposited from irrigation waters. It was found that data leading to general conclusions for various pipe sizes were not available but certain definite trends are indicated and methods of analyzing available data are presented in the hope that they may be of assistance in preparing engineering estimates on designs of pipe lines of the type described above. ENERGY. REQUIREMENTS Carrying out the idea contained in Professor O'Brien's paper concerning the method of computing energy required to transport solids, the following analysis leads to some rather interesting conclusions. Let us represent: [Solids load in terms of mass per unit time by W Ratio of mass of suspended solids to total mass of mixture flowing by p Volume rate of flow of mixture by Q Length of pipe by L Slope of energy grade line by s Mass per unit volume of solids by m, Mass per unit volume of liquid by ml Mass per unit volume of mixture by m,,, We then have as an expression for the solids load: W = pQm¬] The work done per unit mass, P, on the mixture to move it along the pipe the

Jan 1, 1945

The slags produced by the Imperial Smelting Process (ISP) are based on the system ZnO-?FeO?-Al2O3-CaO-SiO2. The slag chemistry is important to the process since it determines the fluxing practice and the operating temperature of the furnace required to produce fluid slag. The paper presents the results of the first systematic experimental investigation of these ZnO-containing slags in equilibrium with metallic iron, and provides information on the primary phase fields and liquidus temperatures in these slags over the range of compositions used in ISP practice. A feature of the slags is the presence of alumina, which has a major influence instabilizing the spinel phase. This information presented in the form of pseudo-ternary sections ZnO-?FeO?-(Al2O3+CaO+SiO2) enabling the data to be readily used by plant engineers. Keywords: liquidus temperature, ISP, EPMA, ZnO-?FeO?-Al2O3-CaO-SiO2, phase equilibria.

Jan 1, 2004