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By Stanislaus Skowronski

OVERPOLED copper, as commonly defined, is copper which has been excessively reduced during the poling period of the refining process. Owing to its porosity, such copper is unfit for commercial purposes. The cause of this phenomenon is undoubtedly the lack of oxides in the copper, yet this does not completely explain it. Refined copper of the same "pitch" and "set" varies considerably in oxygen contents, and analyses of overpoled bars also show similar wide differences; moreover, it is possible to melt copper in crucibles so as to obtain bars that are practically free from oxygen although they show a "tough pitch" and "level set" surface. Frederick Johnson advances the following theory: The regulation of the quantity of oxygen in copper is the keynote of all copper refining. It is the presence of a Well defined proportion of oxygen in the form of cuprous oxide, forming a copper-cuprous oxide eutectic, Which enables copper to be cast free from blowholes. It seems that When oxygen is present, other gases are less soluble in molten copper; When oxygen is absent, or is present in insufficient quantity, the copper dissolves other gases, such as hydrogen and carbon monoxide, Which are insoluble in the copper when solid, and, being rejected during the process of solidification, causes internal porosity and external ridges and excrescences.1 The "level set" of Wire bars, etc., is entirely the result of a compromise between the occluded gases and cuprous oxide. With excess of the former the metal would be "overpitch" and spongy, While an excess of the latter would result in the metal being "underpitch" and brittle.2 The result of the absorption and subsequent expulsion of reducing gases, carbon monoxide and hydrogen, and the effect of this action. on the overpoling of copper are in dispute; the literature on the subject is full of contradictory statements and will continue to be so until better analytical methods have been developed. Sulphur, however, is tangible. The refiner can see it in his button sample and consequently attributes to it any trouble that may happen during the melting of the copper.

Jan 3, 1918

By Balakrishnan Nanthakumar, Marek Pawlik, Dennis Grimm

"The anionic flotation of a high-iron phosphate ore from Agrium - Kapuskasing Phosphate Operations was investigated through batch flotation tests in the presence of soda ash. The flotation data were supplemented by titration of the flotation pulp with soda ash, analysis of process water chemistry, and determination of the mineralogical composition of the ore. The results of lab tests were applied to the flotation circuit design allowing the flotation plant to efficiently process problematic ores. Process control measures (pH, conductivity) were also developed.Calcium cations and sulfate anions were identified as the dominant ions present in the process water when the difficult-to-process ores are beneficiated in the flotation plant. The concentrations of calcium and sulfate ions were consistent with the presence of a small amount of a calcium sulfate mineral in the ore although an oxidation/weathering process of iron sulfide minerals present in the ore could also be responsible for the observed water chemistry and subsequent flotation problems with the ores. The latter possibility suggests that the long-term stockpiling of such ores may have a highly negative impact on the flotation process.The role of soda ash in the flotation circuit is to precipitate metal cations from the pulp thus allowing the tall oil-based collector to selectively interact with the phosphate components.INTRODUCTIONPhosphorus minerals are the main source of this element for the production of fertilizers, and the froth flotation process is the most important technology for beneficiating phosphate ores. The flotation concentrate from Agrium-Kapuskasing Phosphate Operations (KPO) is transported to Redwater Fertilizer Operations in Alberta (also operated by Agrium) where the phosphate concentrate is converted into a phosphate fertilizer and other important chemical products. The KPO phosphate ores differ widely in mineralogy and phosphate grades, and are broadly divided on-site into three classes. The easy-to-float A-type ores do not pose any major flotation problems, but the B-type and “marginal” ores, which are quite common in the KPO igneous phosphate deposit, are not always readily-floatable using the current reagent suites and process parameters (pulp density, feed particle size, pH). In fact, marginal ores are presently considered impossible to process by flotation. A-type ores contain normally more than 15% P2O5 and less than 8% ferric oxide equivalent (Fe2O3). B-type ores are approximately of the same P2O5 grades as A-type ores but their iron content may reach 30% Fe2O3. Any material containing less than 15% P2O5 is rejected as waste rock."

Jan 1, 2008

The key to the successful debt funding of a new mining project, whether in economically established or developing nations, is the submission of a comprehensive feasibility study. The feasibility study forms the basis from which the resource banker can construct financial models which govern the amount of available funds, the conditions which control the supply of such funds and the time period over which the loan may be repaid. The bank will wish to ensure that the feasibility study is the best representation and confirmation of reality possible because this model is the basis of the loan security package. Thus the study will be vigorously interrogated by independent experts in all its elements including the ore reserve, mineability, metallurgy, operating and capital cost profile, environmental factors and management. A well constructed feasibility study, undertaken by well recognised and respected independent consultants can save the client company a great deal of real and opportunity costs especially in relation to project timing. Once constructed and operating, the mining project may face one or more completion tests in relation to the loans provided. The genetics of such tests often relate to either the ability of the operating company to become solely responsible for the repayment of the loan or to be rewarded by lower interest rates or some other mechanism. Strong professionalism, accessible records, good checking procedures and high quality, competent site management will greatly assist the client company passing these tests. A record of well established technical competence with its bankers may well assist a company in the establishment of a mezzanine loan for the early development of its next project, thus allowing an earlier return of dividends to shareholders.

Jan 1, 1995

By Attie J. Goosen, William L. Spiteri

Although the physical characteristics of ANFO made from porous prilled ammonium nitrate (PPAN) have been altered by the addition of crystal modifiers, the optimisation of prilling processes and the admixture of waterproofing agents, the sensitivity of this explosive has not been modified on a commercial scale in the 40 years since its accidental discovery.

Jan 1, 1995

By Ettore Contestabile, Cameron Thomas

Implosive connectors such as XECONEXTn have been used extensively for joining electrical conductors. This implosive action of explosives has also been used in other forms of high-energy metal working with excellent results. However, the inherent blast energy of these units can cause environmental side effects (especially airblast) which may restrict their use around inhabited areas.

Jan 1, 1994

By R. L. Schmidt

One of a series published by the Bureau of Mines covering research investigations in rock drillability, this report of field drilling results extends earlier laboratory findings and provides a relatively simple procedure for predicting percussive drilling rates with reasonable accuracy. Two percussive drills mounted on a truck were used to drill a total of 25 rock types, and the results were used to develop a prediction equation. The equation was tested on a set of unrelated laboratory percussive drilling data, and the comparison between predicted and actual rates is shown in tabular form.

Jan 1, 1972

By S Chew, A Bennett, N Di Giorgio, B Osborne

After relining one of two blast furnaces and enlarging its sinter plant in 2009, BlueScope radically restructured its Port Kembla steelworks operation in 2011, shutting a blast furnace and halving its total production. This drastic move in response to unprecedented raw material prices relative to achievable steel prices was like that of many integrated steelmakers worldwide facing similar challenges. The 2011 restructure also saw major changes in the amount and type of iron ores and ferrous burdens purchased, and a fundamental reappraising of ‘value’ in iron ores. This paper outlines the changes to raw materials purchases from 2011 to 2017, how BlueScope has responded to the changes in pricing and raw materials quality, the effect on the sintering and blast furnace processes at Port Kembla resulting from higher gangue content, some of the broad technical and economic challenges faced by steelmakers confronted with lower quality iron ores and how BlueScope is meeting those challenges.CITATION:Di Giorgio, N, Bennett, A, Osborne, B and Chew, S, 2017. Recent Port Kembla experience with iron ore use – sintering and blast furnace, in Proceedings Iron Ore 2017, pp 25–30 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

Reduce accidents associated with handling of the electrical trailing cable and the water hose on mining equipment. Approach Two reels were mounted on a loading machine to store and release the lines as required during face operations. How It Works A hydraulic motor, which is actuated by a treadle valve in the operator's cab, controls the reel on which 50 feet of electrical power cable is stored. A spring motor resists unwinding of the other reel on which 50 feet of water hose is stored. Both reels are mounted on the right rear of the loading machine. See Figure 1. Following common mining practice, the cable and hose are anchored to fixed points at the first intersection outby the face. Tramming forward causes the cable and hose to be pulled from the reels. Depressing the treadle valve causes the electric cable reel to turn and wind-in any slack in the cable. The spring tension on the water hose reel automatically rewinds the water hose when the loader is trammed in reverse.

Jan 1, 1978

By John A. Wells, Leticia Conca, Kenneth G. Thomas

"Since about 2002 there has been significant capital cost escalation, not inflation, in the mining industry causing turmoil for successful project completion. Project capital costs have more than doubled and some cases tripled in this time period. This has rendered many projects to be economically challenged and in some cases not viable. In addition higher than expected operating costs have further adversely affected project metrics such as NPV and IRR. Capital cost increases for projects have been widely reported globally. This current paper reviews three items. Firstly, why such capital increases and the various components that make up capital estimates. Secondly, it looks at reasons why preliminary estimates, for example at scoping and pre-feasibility level, have been lower than the ultimate constructed costs. Such increases and differences in estimates have caused major problems for mine builders and have led to a general nervousness on the part of those providing project finance. Thirdly, what discipline is needed in project execution in an attempt to mitigate such capital increases. The paper will hopefully give a better understanding of the various issues and factors involved for those in the mining industry.INTRODUCTION The years 2012 and 2013 were a turbulent time for the mining industry. The European economic crisis, politics, metal price volatility and a wave of changes of CEO´s in some of the major mining companies all contributed to a challenging couple of years. Two issues stood out. First, the huge increases reported in the capital costs of projects, where increases of 100% - 300% were not uncommon and in some cases exceeded that during the first decade of the 21st century. Second, company write downs related to takeovers during the boom and the stabilization/correction in commodity prices. These have led to great uncertainty, made it difficult (or impossible) to raise project financing costs, contributed to the changes at CEO level and placed many projects either on hold or cancelled altogether. It is commonplace now to read of companies talking of reduced capital expenditure and making a complete review of their projects and operations to contain costs."

Jan 1, 2014

By D. D. Southworth

In 1981, 1982, and 1983, the Bureau of Mines examined the potential for lode deposits of platinum-group metals (PGM) in the Goodnews Bay ultramafic complex, Alaska. The complex consists of the Red Mountain, Suzie Mountain, and Smalls River ultramafic bodies and displays concentric zoning of rock types similar to complexes in southeast Alaska, British Columbia, and the Ural Mountains in the U.S.S.R. Results of the study indicate that platinum is preferentially associated with chromite and magnetite in the dunite core of the complex, and palladium is preferentidlly associated with sulfide minerals in the outer clinopyroxene-rich zones. the most promising targets for PGM lode deposits are the chromite-rich dunite at the heads of Fox Gulch and Squirrel Creek and iron-nickel and iron copper sulfide-bearing magnetite clinopyroxenite and hornblende-rich rocks outward of the dunite core, also in the Fox Gulch-Squirrel Creek area. Significant placer reserves are present in the unmined, deeply buried placer ground in the lower Salmon River Valley, and also in tailings from previous dredging.

Jan 1, 2011

By Paul G. Swanson

This investigation was conducted to identify the principle causes of spoil instability problems in the Eastern Coal Province. The study was also conducted to develop a matrix to predict the strength and groundwater parameters necessary to conduct stability analyses on a proposed reclamation scheme. Suggestive methods to reduce spoil instability potential are also included. Numerous physical property, strength, compressibility, chemical and mineralogical tests were conducted on mine spoil samples obtained from 11 different surface mine sites. Site characteristics that influence the position of the post reclamation groundwater table were identified. Distinct regions within the Eastern Coal Province with high incidences of surface mine slides or high landslide susceptibility were identified. The application of the predictive matrices developed in this study is for surface mine sites mined and reclaimed in general accordance with the Surface Mine Reclamation Control Act of 1977. A review of current mining practices and the relative effect on spoil stability is included.

Jan 1, 1983

By R Kerrich

Early-Archaean (3.26 Ga) volcanogenic massive sulphide (VMS) deposits located within the low strain and sub-prehnite-pumpellyite metamorphic-grade Strelley greenstone belt, East Pilbara, Western Australia, contain exceptionally well preserved sulphide textures which are directly analogous to those of sulphide chimneys formed by black smokers at present day submarine hydrothermal vents. The VMS deposits are associated with seafloor alteration zones in and below silica-carbonate laminites, at the top of tholeiitic to calc-alkaline intermediate and felsic rocks. VMS mineralisation comprises stratabound Zn-rich sulphide lenses with significant Cu and barite, and variable Pb and Ag, above Cu-rich stringer zones, all of which are similar to Phanerozoic polymetallic or Kuroko VMS deposits. Sulphide-sulphate mineralisation implicates hydrothermal discharge into sulphate-bearing ocean waters, ruling out a globally anoxic Archaean hydrosphere. The volcanic rocks and co-magmatic sub-volcanic intrusion hosting the VMS deposits are characterised by the conjunction of LILE>LREE>HREE, and Phanerozoic La/Yb with negative normalised anomalies of Nb, P and Ti, consistent with derivation via subduction zone hydrous metasomatism fusing the mantle lithosphere.

Jan 1, 1995

By Karen Mikkola, Gerald Luttrell, Jaisen Kohmuench, Glen Oswald, Michael Mankosa, Tracy Westerfield

Hydraulic separators are commonly used for particle size classification and gravity concentration of minerals and coal. Unfortunately, the efficiency of these processes can be quite low due to poor equipment design and variations in feed consistency. To help alleviate these problems, an industry-driven R&D program has been undertaken to develop a new generation of hydraulic separators that are more efficient and less costly to operate and maintain. Two of the most promising technologies, the CrossFlow and HydroFloat separators, have now been tested at industrial sites. The data obtained from these sites have been used to illustrate the potential performance improvements that can be realized through the application of these high-efficiency separators.

Jan 1, 2005

By Alexander May

The Bureau of Mines conducted studies to determine if phosphogypsum, a waste material from the processing of phosphate rock, contains hazardous toxic materials as defined by the Environmental Protection Agency (EPA) and whether leaching of these toxic materials and radium may occur. Samples of the phosphogypsum stockpiled material were evaluated using the EPA extraction procedure, atomic absorption, neutron activation, x-ray diffraction, and chemical and physical means. Radiological tests performed used both the germanium-lithium and emanation methods. The data show that the phosphogypsum stockpiles are not hazardous toxic waste as defined by EPA criteria. Trace elements and radium are not leached from the phosphogypsum stockpiles. Absorption of trace elements and radium by phosphogypsum is the major reason for their not being leached. The standard error of measurement of radium concentrations was 4.7 pCi/g.

Jan 1, 1983

By R. Benito

This paper describes the development of a life of mine schedule (LOM) for one of the world?s largest known sedimentary Copper-Cobalt districts located in the Katanga Province, Democratic Republic of Congo (DRC). A particular feature of the Tenke Fungurume LOM schedule is the considerable number of pits/phases for scheduling, each competing to provide the best ore available to a capacity constrained process facility. This paper discusses the main scheduling objectives and constraints, data pre-processing as a scheduling aid, the mine scheduling approach, and results and conclusions.

Jan 1, 2011

By Roe-Hoan Yoon

"Industrial flotation columns often suffer from low recoveries and high maintenance requirements because of poorly-designed air spargers. The MicrocelTM bubble generators were developed at Virginia Tech to overcome these problems. In this system, small air bubbles are generated by circulating a portion of the flotation pulp through a set of static in-line mixers. The small bubbles improve flotation kinetics and allow a higher recovery (or capacity) to be achieved. Other advantages of the system include reduced air consumption, plug-free operation and on-line maintenance. This article discusses the advantages of the MicrocelTM bubble generators and presents examples of successful in-plant demonstrations.IntroductionColumn cells are widely accepted in industry for cleaner operations because they are more selective than mechanically-agitated conventional cells. The improved selectivity can be attributed to the use of wash water which minimizes the entrainment of fine gangue particles into the froth product. Columns may also produce higher recoveries if the air sparging system is properly designed and steps are taken to minimize back-mixing. Furthermore, the quiescent conditions afforded by column cells may be beneficial for recovering coarse particles that are readily detached from bubbles under more turbulent conditions. Also, properly-designed columns offer advantages in terms of savings in floor space, reduced operating and capital costs, and simplified circuitry.It is unfortunate, however, that some of the advantages of columns are not fully realized in industrial practice. Some column circuits are unable to achieve their design capacity, while others require extensive maintenance programs. These shortcomings can usually be attributed to deficiencies associated with the design, scale-up and operation of the air-sparging system. In this article, some of the basic problems associated with commercial air sparging systems are discussed and alternatives are suggested."

Jan 1, 1994

By Phillip R. Moyle

Several deposits in the Sheep Hole/Cadiz Wilderness Study Area (WSA) have small identified or potential for undiscovered gold and silver resources. One prospect area is a potential target for molybdenum. Most base and precious metals and one uranium deposit in the study area are of the fissure-filling, contact metamorphic type associated with late stage fluids of the Cretaceous Cadiz Valley batholith. Some evidence suggests limited Tertiary and Quaternary mineralization. Mineral deposits are controlled by faults, shear zones, and joints which strike northwest and dip northeast or southwest. Although undefined, calcium, sodium, lithium, and strontium brines are inferred within the study area. Some potential for oil and gas and geothermal resources is indicated by the interest private industry has shown in the eastern part of the study area. INTRODUCTION The U.S. Bureau of lines and U.S. Geological Survey conducted a mineral survey of the Sheep Hole/Cadiz Wilderness Study Area (p1. 1) which encompasses approximately 205,000 acres (83,000 ha) in south-central San Bernardino County, California. The U.S. Bureau of Mines studied the mineral resources of mines, prospects and mineralized areas; geological, geochemical, and geophysical investigations were conducted by the U.S. Geological Survey.

Jan 1, 1982

By Robert L. Virta

This U.S. Bureau of Mines paper discusses the structure of the talc industry, talc production, processing of talc ore, applications and demand for talc, and the outlook for the talc industry.

Jan 1, 1989

By D. Dimitriadis, T. Polglase, W. Phillips, R. Jenny, M. Botz

Cyanidation processes for the extraction of gold or silver frequently involve the processing of sulfur-containing solids which react with cyanide to form thiocyanate. The formation of thiocyanate is an undesired side-reaction, and in many cases thiocyanate formation results in a prohibitively high cyanide consumption. With the increasing number of gold and silver mining projects which involve the processing of sulfide ores or concentrates or which utilize a biological sulfur oxidation process, more attention has been focused on minimizing thiocyanate formation and in treating solutions to eliminate toxicity associated with thiocyanate. Though not yet commercially applied, there are several technologies available to recover cyanide from thiocyanate to both reduce tailings toxicity and allow the reuse of cyanide otherwise lost to thiocyanate formation. This paper presents an overview of technologies available for recovering cyanide from thiocyanate along with estimated operating costs for the technologies. Pilot testing data suggests that in some cases, cyanide can be recovered from thiocyanate for approximately the same cost as newly purchased cyanide.

Jan 1, 2000

By Yanjie Liang

Elemental sulfur and volatilization kiln slag(VKS)containing heavy-metal produced by smelter factories were used to produce sulfured building material. The effects of heating mode, material proportion (MSulfur:MVKS), size of waste particles and ratio of aggregate to filler(A/F) on the mechanical properties and leaching toxicities of solidified stuff were investigated. The optimal conditions for the solidification are stepped heating mode, 3:7 ratio of MSulfur to MVKS, particle size less than 150µm and 3/17 ratio of A/F. Under the above optimal conditions, the compressive strength of solidified stuff rises to 35 MPa, and water absorption is down to 4%-6%.Furthermore, when NaOH is applied as an additive in the process of solidification, the 2+concentrations of most heavy metals except Pb have reached the national leaching toxicity standard. The results of X-ray diffraction reveal that sulfured solidification is caused by the physical encapsulation rather than chemical transformation.

Jan 1, 2010