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By V. I. Lakshmanan

Process Research ORTECH Inc. (PRO), with its in-depth knowledge on cobalt behaviour in nickel matte smelters and its novel mixed chloride hydrometallurgical processing, is developing a hybrid process to enhance cobalt recovery. PRO’s experimental data is compared with plant information on cobalt behaviour in smelters. In final stages of iron rejection in the converters, the thermodynamics of the matte-slag system dictates the undesirable transfer of the cobalt to the final converter slags. This results in much lower cobalt recovery in the product Copper/Nickel matte (<60%) in present copper and nickel smelters. This information is used to transfer cobalt into desired quantity of converter slag. The enriched cobalt slag is subjected to PRO mixed chloride process to recover nickel, and cobalt as high value salts of importance in lithium ion batteries. From a typical converter slag containing 3.5% Ni, 1.5% Co, and 1.0% Cu, PRO leach process extracts 98 % Ni, and 98 % Co, and 99% Cu. Application of this process to enhance cobalt recovery in typical Copper/Nickel smelters is presented. In addition, this will also enhance the Copper and Nickel recovery. Both these aspects are of interest to the Copper, Nickel, and cobalt producers. INTRODUCTION In pyrometallurgical extraction of copper and nickel from sulphide ores cobalt often occurs with copper and nickel. The requirement of cobalt is increasing due to its need in lithium ion cells used in electric vehicles. Therefore its efficient and economical extraction in a form suitable for use in lithium batteries is of great interest at present. In the pyrometallurgical processing of copper and nickel sulphide concentrates the concentrate is smelted to produce a furnace matte, which is then sent for converting to remove the iron to produce iron free (~1% Fe) matte for further processing to copper or nickel matte. The copper/nickel matte is processed for metals recovery by hydrometallurgical or vapo-metallurgical or oxidation – reduction routes to make market products. As shown in Figures 1 and 2 the slags are produced in the smelting step and in the converting steps. The metal losses in smelting are controlled by the oxygen pressure in that step and slag production which is controlled by concentrate grade. The slag produced in the converting step which is carried out at a higher oxygen pressure contains higher level of metals is often returned to the smelting step to increase value metals recovery.

Jan 1, 2019

By A. E. Harak

To determine the retorting characteristics of a column of mine-run, ungraded oil shale ranging in size from fines to 5-ton pieces, a 150-ton batch-type retort was designed and constructed at the Bureau of Mines Laramie Energy Research Center, Laramie, Wyo. The retort vessel is 45 feet high by 11 ½ feet inside diameter, and is supported in a 95-foot-high steel superstructure. Mine-run shale from the Bureau of Mines facility near Rifle, Colo., assaying about 25 gallons of oil per ton, was used as the test shale. To date, 11 runs have been completed, and the results of the last 10 of these are reported. The effects of oxygen content of the retorting gas and the superficial gas velocity of the retorting gas on oil recovery from a column of mine-run oil shale were studied. In one run, the average particle size of the shale was substantially increased to determine its effect on oil yield. Oil recoveries ranged from a low of 39.3 to a high of 65.8 volume-percent of Fischer assay.

Jan 1, 1974

Advances in Thickener Feedwell Design via Computational Fluid Dynamics Modelling

Sep 13, 2010

Experimental investigations were made into the decoppering of lead, tin, and bismuth using a technique which approximates on the small scale to industrial practice.Decoppering lead with sulphur alone in the absence of tin and silver did not proceed to low copper values. With a minimum of 0&#183;02 per cent Ag or 0&#183;10 per cent Sn, lead was decoppered to less than 0&#183;01 per cent Cuby stirring with 0&#183;2 per cent S over 10 min. Decoppering of tin or bismuth proceeded rapidly to very low levels in the absence of any &quot;catalytic&quot; impurities, at any rate in excess of those concentrations normally encountered in commercially pure tin or bismuth.

Jan 1, 1971

A South African gold mining rock-related fatal accident database has been analysed in order to determine rock-related fatality trends in the gold mining industry over the period 1990 to 1998. This analysis was extended further to include some of the individual reefs mined and focused particularly on the Carbon Leader Reef, the Ventersdorp Contact Reef, the Vaal Reef and the Basal Reef. Rock-related accident locations are also presented. A stope rock-related risk is proposed, where the fatality rate in terms of rock-related fatalities per million square metres mined for the gold mining industry as a whole is compared to individual reefs, allowing a stope rock-related risk to be attributed to the individual reef. This comparison is extended further by removing the contribution by the reef being evaluated from the industry data, thereby allowing this reef to be directly compared to the rest of the industry with respect to a stope rock-related risk.

Jan 1, 2001

By M. H. Rogers

Coal has been at the forefront of mankind?s drive to improve his quality of life and also for sustainable development, from the Industrial Revolution onwards. The international coal industry today is large, with some 3,7 billion tons being produced and consumed in 1997. South Africa is an important participant in the coal industry, selling some 220 million tons in 1997 of which 64 million tons were exported. It is the second-largest thermal coal exporting country in the world. Despite the size of the world coal industry, it is not immune to change. The address examines growth projections for the industry and the change drivers that will impact on it in the future. Environmental pressures, the most important of which being the climate change debate, the Kyoto Protocol arising from this debate and the development of clean coal technologies, to reduce the impact of coal production and usage on the environment are considered. Other major change drivers considered are competition from other sources of energy and that between coal producers, the deregulation of the electric power industry, corporate restructuring and for the South African producer, legislative reform. The declining (real term) coal price, the consequent squeeze on margins and the need for producers to actively contain costs is covered. Technology has, in the past, been the driver behind the growth and change of the South African coal industry and its future role in ensuring that coal is the fuel of choice for continued improvement in standards of living and economic development is addressed.

Jan 1, 1999

By Donald A. Bruce

The construction of major structures in karstic limestone terrains poses difficult problems to designer and contractor alike. This reflects the inherent variability of such conditions, and also the significant impacts caused by the construction processes themselves. Three case histories are provided of recent projects in the United States: the sealing of a major inflow into a quarry, the improvement of a highly loaded bridge pier foundation, and the installation of high capacity micropiles. Emphasis is placed on problem assessment and execution verification.

Jan 1, 2002

By P. C. Fletcher, E. Kaya

The Bond grindability testing procedure has been standardized to measure the same grindability values, i.e. Bond work index (BWi), for the same ore when tests are performed in different laboratories or by different operators. This is accomplished by the standardization of mill dimensions, tumbling speed, grinding ball charge weight and distribution, sample ore charge weight in the mill and operating practice. The results of this investigation reveal that the Bond work index grindability values may differ substantially with different standard Bond ball mills. This paper will review the results.

Jan 1, 2002

By Mika Muinonen

"Dewatering of nickel concentrate at the INCO Thompson integrated mine-metallurgical site takes place within the smelter plant. The eight original 60 foot diameter cable torque thickeners of which four were operational and eight Dorrco internal drum filters have been replaced with a single Outokumpu high rate thickener and a single Lasta pressure filter. The modernization has resulted in a filter cake which has a more stable and lower moisture content. Control of the entire dewatering process has been improved and costs have been reduced.Typical filter cake produced from the Dorrco filters during processing of high tonnages of Birchtree mine ore was ~20% moisture vs. ~13% moisture for concentrate produced from the Thompson mine ore. The high moistures were correlated with the amount of fine magnesium silicate gangue in the concentrate. As Birchtree ore processing rates have increased, this filter cake moisture became unacceptable because of material handling problems and the impact on furnace metallurgy. The Dorrco filters were replaced with the Lasta filter in 2003 that has consistently produced filter cake at ~11% moisture.This paper summarizes the piloting, design, installation and commissioning of the modernized dewatering circuit.INTRODUCTIONThe Thompson integrated nickel processing facility was built in 1958 and originally consisted of a mine-mill-smelter and, soon after, a refinery.Nickel concentrate is pumped from the mill as a dilute slurry directly to the smelter facility ~200 meters along an unheated pipe trestle. Originally, nickel concentrate was de-watered using up to 8 conventional 60-foot diameter thickeners and 8 internal vacuum drum filters."

Jan 1, 2006

By E. L. Singleton

The Bureau of Mines investigated extraction of aluminum from aluminum-silicon alloys as a means of utilizing domestic aluminum silicate ores for aluminum production. Aluminum was extracted from aluminum-silicon alloys by electrolysis in molten electrolytes of NaCl-KCI-AIC13 and NaCl-KCI-AIF3 in a laboratory-scale cell. Six alloys with aluminum contents ranging from 20 to 87 percent aluminum were tested, and aluminum products of primary grade or better were obtained. More than 80 percent of the aluminum was recovered with current efficiencies as high as 91 percent. Recovery of a metallurgical-grade silicon product from the anode residue by an acid leaching procedure was possible with the 50-50 and 65-35 Al-Si alloys.

Jan 1, 1972

Various reagents are added to flotation pulps to manipulate the chemical environment in order to create favourable conditions for the separation of the desired mineral from the unwanted gangue. Interactions occur between these reagents and between the other chemical parameters existing in the flotation pulp which complicate the elucidation of the behaviour of the respective reagents. This paper discusses the roles of the main classes of reagents added viz. collectors, frothers, depressants and activators, as well as the interactions between frothers and collectors. A case study reporting synergistic interactions between thiol collectors in the flotation of pyrite at pH = 4 is included. The use of Potassium n-butyl xanthate (PNBX) and a dithiocarbamate type collector (DTC) were tested both as pure collectors and as components in a collector mixture. In the batch flotation tests sulphur recovery and grade, water recovery, rate of recovery and image analysis of the surface froth were used to evaluate the effect of the mixture on the overall flotation performance. Bubble loading tests showed that the use of the mixture improved the efficiency of the particle collection process by bubbles. Thermochemical measurements of the adsorption of the collectors onto the mineral, indicated the formation of different surface products by the two collectors.

Jan 1, 1998

By Pietro Navarra

A great deal of effort has been expended on how to optimize conventional water cooling circuits in furnace cooling elements, and the results have been largely satisfactory. However, there is a general agreement that the proximity of high-pressure water passages to the flow of molten furnace products is a safety concern. Nonetheless there exists little alternative to the formula: increasing furnace integrity implies the incorporation of more extensive forced-convection water cooling systems. Recent developments in evaporative cooling technology have resulted in the development of a high-capacity heat pipe capable of operating under the thermally intense environments of a metallurgical furnace. The system functions using several kg of a working fluid (water) in total, has no moving parts, and allows for a significant reduction in cooling water requirements. Full-scale pilot tests of a copper tap hole and slag launder were done in 2003 and2005, with detailed results given in this paper.

Jan 1, 2006

By W. G. Pariseau

A crown pillar cave occurred at the Ropes Mine in December, 1987, that resulted in closure of the mine. Production was resumed soon afterwards with the formulation of a rock mechanics plan designed to address several issues of safety and stability. The plan proved to be successful and shows what can be accomplished in the realm of applied rock mechanics where a cooperative atmosphere exists.

Jan 1, 1989

By Ivor Hawkes

This report describes the results of a study to evaluate new design concepts for percussive rock drills that will result in quieter machines. It is shown that by incorporating such features as an efficient muffler, a plenum chamber integral with the machine body, and shroud tubes around the drill rods, etc., noise levels are reduced from about 114 dBA to about 95 dBA with very little change in drilling performance.

Jan 1, 1977

By E. G. Davis

As a result of interest by the U.S. Department of Energy, the Bureau of Mines conducted studies on comminution of bituminous coal to the 2-um particle size range using the Bureau-developed turbomill. Both "plant grind" size (80 pct minus 75 um) and microsize (minus 10 um) coal can be produced in a single step with the Bureau&apos;s turbomill. In 15 min, minus 2.4-mm coal milled in water with steel shot was reduced tc 65 pct minus 75 m and 26 pct minus 2 m, with an energy requirement of 139 kW^h/mt coal. Plant-grind size coal milled in water, with Ottawa sand as the milling medium, was reduced to more than 45 pct minus 2 m in 15 min, at 175 kW?h/mt. Plant-grind coal milled with steel shot was reduced to 57 pct minus 2 um in 15 min, at 138 kW?h/mt. When diesel fuel was substituted for water, the milling of the coal was less effective and less energy efficient. Keeping the pulp dispersed was critical. Without an effective dispersant, the slurry became very viscous with increased milling time, resulting in higher energy requirements, low heat dissipation, and poor grinding efficiency.

Jan 1, 1987

By J. M. Menacho, J. M. Reyes

"Batch and continuous regrind tests were conducted in 3 kW and 15 kW tower mill units, respectively. Single particle size classes of a chilean copper sulphide concentrate were employed in the batch tests, while a fraction of the plant stream was deviated to the continuous unit operated under different conditions.Results are interpreted in terms of the simplified grinding kinetic model energy-based and conveniently adapted to this application. Based on the above figures plus some industrial data supplied by MPSI Inc., a scale-up relationship was developed for the apparent specific rate of breakage siE, as a function of the net power draw P, i.e.siE = siE text (P/P test) 0.089This equation fit very well the available data at the three scales and its application to regrind 4400 t/day of rougher copper concentrate from 70% below 325 Tyler mesh to 95% below same mesh, involves around 30% energy-saving compared to standard ball mill for same grinding task.INTRODUCTIONImpact and abrasion-attrition breakage are two extreme mechanisms present in any grinding system in a proportion defined by specific design and operating conditions. Impact breakage is generally efficient for coarse grinding, while abrasion-attrition is adequate to produce fine particles. Efficiency of conventional tumbling mills decreases as fineness of the product increases, even though distribution of applied stresses is always much stronger than internal force distribution in the particles. On the other hand.in a vertically stirred ball mill like the tower mill, distribution of applied stresses and particle strengths are in the same order of magnitude, making possible nearly ideal abrasion conditions (1).Tower mill configuration includes a cylindrical body vertically mounted and provided with a central screw with flights to produce circulation of balls moved up through the inner region to return down by the external space. Fresh material can be fed into the top , center or bottom in order to assure appropriate agitation of suspended particles. Size reduction and evacuation rates should compensate settling of coarse particles to avoid sanding of the screw. Detailed description of the tower mill and its operation have been given elsewhere (2),(3)."

Jan 1, 1989

By Carlos Magno Palacios Arbizu

La calidad total es la estrategia que busca la mejorar la productividad y eficiencia de los productos que ofrece -en tanto sean reconocidos por este valor-, de forma que genera competitividad en las organizaciones peruanas y se presenta como respuesta a nuevos enfoques de gestión surgidos ante el proceso de globalización. En este sentido, el presente trabajo analiza la forma del avance en el nuevo enfoque de gestión de las empresas mineras, para así proponer alternativas de tratamiento e implementación de un modelo basado en la Calidad Total, de manera que esté alineado dentro de un sector que tenga características propias y diferenciadas de organizaciones de otros sectores productivos.

Sep 12, 2005

By C. O. Karacan, S. J. Schatzel, W. P. Diamond

In coal mining, longwall mining is a preferred method to maximize production by extracting large blocks of coal that have been outlined with a set of development entries. In U.S. mines, longwall panels are typically 305 m (1,000ft) wide (with a continual trend towards even wider panels), and usually over 3,050 m (10,000ft) in length. The increasing size of longwall panels, while helping to increase coal production, may also increase methane emissions due to the exposure of the mining environment to a larger area of fractured, gas-bearing strata. Thus, understanding the impact of increased panel widths on methane emissions, and designing gob gas ventholes and bleeder systems accordingly, can enhance the safety of the underground workforce by reducing their exposure to potentially explosive accumulations of methane/air mixtures. As part of its mine safety research program, NIOSH’s Pittsburgh Research Laboratory has initiated a reservoir modeling effort to better understand the interaction of the various geotechnical factors influencing gas flow within and to the underground longwall mining environment. A focus of this modeling effort has been 1) the prediction of the incremental amount of methane emissions to be expected due to increasing longwall panel widths, and 2) optimizing gob gas venthole completion practices to capture more of the gas in the subsided strata above longwall panels before it can enter the ventilation system of the underground workplace. The history matching phase of the study has been carried out on a 381-m (1,250ft) wide panel in the Pittsburgh Coalbed. Simulations have also been completed for a 442 m (1,450ft) wide panel to estimate the incremental increase in methane emissions and the performance of current gob gas venthole placement configurations. Additional venthole placement configurations were simulated to investigate options for optimizing methane capture from the subsided strata above the wider longwall panel.

By Michael Allen, Paul Worsey

In underground blasting, the pull of the initial cut is the limiting factor for the success of the rest of the round. By improving the pull of the first cut, a critical step is made towards improving the entire round. This project attempted to optimize a burn cut’s effective pull by varying the depths of the relief holes in the burn. The effect of varying the depths of the relief holes was investigated, including depths longer than that of the cut’s charged holes. The overall objective was to consistently achieve greater pull than in a standard burn, using an identical amount of explosives. Increased pull results in savings of both time and cost in underground heading advance.

Jan 1, 2015

By F. E. Chase

Mobile roof supports are shield-type support units mounted on crawler tracks. Mobile roof support (MRS) units are used during retreat mining, and they eliminate the setting of roadway, turn, and crosscut breaker posts which are required during pillar recovery operations. Mobiles are a more effective ground support than timbers, and their usage enhance the safety of section personnel and reduces material handling injuries. MRS usage is rapidly increasing, and approximately 40 U.S. coal mines have successfully employed this relatively new technology. This paper is in response to increasing requests from operators, State and Federal Regulatory Agencies, and others on the practical aspects of MRS usage in underground coal mines. During this investigation, nearly half of the U.S. mines which have utilized mobiles were visited. This report depicts the more common pillar extraction methods which operators have found successful. The Christmas tree and outside lift methods are illustrated and discussed. Roof control plans that do not require breaker posts or allow pillar extraction with fewer than four mobiles are also examined. In addition, operators&apos; experiences with setting pressures, loads, and rates of loading during pillar extraction are addressed. Mining and support strategies to more effectively control hillseams, weak roof, and gob overrides which have entrapped equipment are also discussed.

Jan 1, 1996